Prof. Dr. Christian Limberg
Research interests
Oxigenation chemistry, metal oxo complexes, heterobimetallic compounds
Research Fields in UniCat
Research Field D1
Research Field D2
Research Field D3
Selection of research projects
- Modelling of reactive metaloxo surface species as well as organometal intermediates on oxo surfaces
- Biomimetic O2 activation and oxidation
- Novel dinuclear complexes for the (often oxidative) conversion of hydrocarbons
- Matrix isolation studies
- Fundamental problems in organometallic and coordination chemistry
UniCat publications
| 788 The Conversion of Nickel-Bound CO to an Acetyl Thioester: Organometallic Chemistry Relevant to the Acetyl Co-enzyme A Synthase Active Site B. Horn, C. Limberg, C. Herwig, S. Mebs Angewandte Chemie International Edition 2011, 50, 12621 - 12625, 10.1002/anie.201105281 |
| 787 Organoelement Complexes of a Dinucleating Double β-Diiminato Ligand - Precedent Cases from Groups 1, 2 and 13 J. P. Falkenhagen, P. Haack, C. Limberg, B. Braun Zeitschrift für Anorganische und Allgemeine Chemie 2011, 637, 1741 - 1749, 10.1002/zaac.201100352 |
| 786 Four-coordinate Trispyrazolylborato Manganese and Iron Complexes with a Pyrazolato Co-ligand: Syntheses and Properties as Oxidation Catalysts T. Tietz, C. Limberg, R. Stößer, B. Ziemer Chemistry - A European Journal 2011, 17, 10010 - 10020, 10.1002/chem.201100343 |
| 785 N2 Activation in NiI-NN-NiI units: The Influence of Alkali Metal Cations and CO Reactivity B. Horn, S. Pfirrmann, C. Limberg, C. Herwig, B. Braun, S. Mebs, R. Metzinger Zeitschrift für Anorganische und Allgemeine Chemie 2011, 637, 1169 - 1174, |
| 671 An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions F. Pfaff, S. Kundu, M. Risch, S. Pandian, F. Heims, I. Pryjoms-Ray, P. Haack, R. Metzinger, E. Bill, H. Dau, P. Comba, K. Ray Angewandte Chemie International Edition 2011, 0, 0 - 0, http://onlinelibrary.wiley.com/doi/10.1002/anie.201005869/pdf |
| 527 Unprecedented Binding and Activation of CS2 in a Dinuclear Copper(I) Complex P. Haack, C. Limberg, T. Tietz, R. Metzinger Chemical Communications 2011, 0, 0 - 0, 10.1039/c1cc11518a |
| 526 The Mechanism of Water Oxidation: From Electrolysis via Homogenous to Biological Catalysis H. Dau, C. Limberg, T. Reier, M. Risch, S. Roggan, P. Strasser ChemCatChem 2010, 2, 724 - 761, |
| 525 Monooxygenase-Like Reactivity of an Unprecedented, Heterobimetallic FeO2Ni Moiety S. Yao, C. Herwig, Y. Xiong, A. Company, E. Bill, C. Limberg, M. Driess Angewandte Chemie International Edition 2010, 49, 7054 - 7058, |
| 494 Dinuclear Copper Complexes Based on Parallel ß-Diiminato Binding Sites and their Reactions with O2: Evidence for a Cu-O-Cu Entity P. Haack, C. Limberg, K. Ray, B. Braun, U. Kuhlmann, P. Hildebrandt, C. Herwig Inorganic Chemistry 2011, 50, 2133 - 2142, 10.1021/ic101249k |
| 428 A reduced Beta-diketiminato-ligated Ni3H4 unit catalyzing H/D exchange C. Limberg, S. Pfirrmann, C. Herwig, C. Knispel, B. Braun, R. Stößer, E. Bill Journal of the American Chemical Society 2010, 132, 13684 - 13691, 10.1021/ja106266v |
| 293 Reversible P4 Activation with Nickel(I) and an Eta3-Coordinated Tetraphosphorus Ligand between Two NiI Centers S. Yao, Y. Xiong, C. Milsmann, E. Bill, S. Pfirrmann, C. Limberg, M. Driess Chemistry - A European Journal 2010, 16, 436 - 439, 10.1002/chem.200902820 |
| 292 Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein O. Sanganas, S. Löscher, S. Pfirrmann, N. Marinos, P. Glatzel, T. C. Weng, C. Limberg, M. Driess, H. Dau, M. Haumann Journal of Physics: Conference Series 2009, 190, 12199 - 12199, 10.1088/1742-6596/190/1/012199 |
| 284 O-O Bond Activation in Heterobimetallic Peroxides: Synthesis of the Peroxide [LNi(My,Eta2:Eta2-O2)K] and its Conversion into a Bis(My-Hydroxo) Nickel Zinc Complex S. Yao, Y. Xiong, M. Vogt, H. Grützmacher, C. Herwig, C. Limberg, M. Driess Angewandte Chemie International Edition 2009, 48, 8107 - 8110, 10.1002/anie.200903772 |
| 272 Beta-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing For H2 and N2 Activation C. Limberg, S. Pfirrmann, S. Yao, B. Ziemer, R. Stößer, M. Driess Organometallics 2009, 28, 6855 - 6860, 10.1021/om9007983 |
| 271 Low-Molecular Weight Analogues of the Soluble Methane Monooxygenase: From the Structural Mimicking of Resting-States and Intermediates to Functional Models C. Limberg, I. Siewert Chemistry - A European Journal 2009, 15, 10316 - 10328, 10.1002/chem.200901910 |
| 270 Stabilizing the Boat Conformation of Piperazines Coordinated to IronII: isoButyl Substituents Lead to Robust Oxidation Catalysts via Hyperconjugation C. Limberg, M. Ostermeier, C. Herwig, B. Ziemer Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 1823 - 1830, 10.1002/zaac.200900275 |
| 269 A Dinuclear Iron Complex Based on Parallel Malonate Binding Sites: Cooperative Activation of Dioxygen and Biomimetic Ligand Oxidation C. Limberg, I. Siewert, S. Demeshko, E. Hoppe Chemistry - A European Journal 2008, 14, 9377 - 9388, 10.1002/chem.200800955 |
| 176 A Novel Tripodal Ligand Containing Three Different N-Heterocyclic Donor Functions and Its Application in Catechol Dioxygenase Mimicking C. Limberg, M. Wagner, T. Tietz Chemistry - A European Journal 2009, 15, 5567 - 5576, 10.1002/chem.200802591 |
| 25 A Dinuclear NiI-Dinitrogen Complex and its Reduction in Single Electron Steps C. Limberg, S. Pfirrmann, C. Herwig, R. Stößer, B. Ziemer Angewandte Chemie International Edition 2009, 48, 3357 - 3361, 10.1002/anie.200805862 |
| 24 ß-Diketiminato ligands with Thioether Tethers C. Limberg, S. Pfirrmann, E. Hoppe Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 312 - 316, 10.1002/zaac.200800411 |
| 23 A low-coordinate nickel(II) hydride complex and its reactivity C. Limberg, S. Pfirrmann, B. Ziemer Dalton Transactions 2008, 47, 6689 - 6691, 10.1039/B816136B |
| 22 A Trispyrazolylborato Iron Malonato Complex as a Functional Model for the Acetylacetone Dioxygenase C. Limberg, I. Siewert Angewandte Chemie International Edition 2008, 47, 7953 - 7956, 10.1002/anie.200802955 |
| 20 Low-Coordinate Iron Complexes Based on Bis(pyrazolyl)borate and Their Reactivity C. Limberg, M. Wagner, B. Ziemer European Journal of Inorganic Chemistry 2008, 25, 3970 - 3976, 10.1002/ejic.200800314 |
| 19 Dinuclear iron complexes based on parallel ß-diiminato binding sites: syntheses, structures and reaction with O2 C. Limberg, M. F. Pilz, S. Demeshko, F. Meyer, B. Ziemer Dalton Transactions 2008, 14, 1917 - 1923, 10.1039/b715376g |
