Publications 2018

Number of records: 119

119 One pot microwave synthesis of highly stable AuPd@Pd supported core–shell nanoparticles A. G. R. Howe, P. J. Miedziak, D. J. Morgan, Q. He, P. Strasser, J. K. Edwards Faraday Discussions 2018, 208, 409–425, 10.1039/c8fd00004b

118 The medical threat of mamba envenoming in sub-Saharan Africa revealed by genus-wide analysis of venom composition, toxicity and antivenomics profiling of available antivenoms S. Ainsworth, D. Petras, M. Engmark, R. D. Süssmuth, G. Whiteley, L. O. Albulescu, T. D. Kazandjian, S. C. Wagstaff, P. Rowley, W. Wüster, P. C. Dorrestein, A. S. Arias, J. M. Gutiérrez, R. A. Harrison, N. R. Casewell, J. J. Calvete Journal of Proteomics 2018, 172, 173–189, 10.1016/j.jprot.2017.08.016

117 Stereoselective Transfer Semi-Hydrogenation of Alkynes toE-Olefins withN-Heterocyclic Silylene-Manganese Catalysts Y. P. Zhou, Z. Mo, M. P. Luecke, M. Driess Chemistry - A European Journal 2018, 24, 4740–4740, 10.1002/chem.201800160

116 Nano-Sized Inorganic Energy-Materials by the Low-Temperature Molecular Precursor Approach C. Panda, P. W. Menezes, M. Driess Angewandte Chemie International Edition 2018, 57, 11130–11139, 10.1002/anie.201803673

115 Low-valent group 14 element hydride chemistry: towards catalysis T. J. Hadlington, M. Driess, C. Jones Chemical Society Reviews 2018, 47, 4176–4197, 10.1039/C7CS00649G

114 Metal nitrene-like reactivity of a SiN bond towards CO2 T. J. Hadlington, T. Szilvási, M. Driess Chemical Communications 2018, 54, 9352–9355, 10.1039/C8CC05238G

113 Chelate Silylene-Silyl Ligand Can Boost Rhodium-Catalyzed C−H Bond Functionalization Reactions Z. Mo, A. Kostenko, Y. P. Zhou, S. Yao, M. Driess Chemistry - A European Journal 2018, 24, 14608–14612, 10.1002/chem.201803089

112 Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs A. Merk, H. Großekappenberg, M. Schmidtmann, M. P. Luecke, C. Lorent, M. Driess, M. Oestreich, H. F. T. Klare, T. Müller Angewandte Chemie International Edition 2018, 57, 15267–15271, 10.1002/anie.201808922

111 Structurally Ordered Intermetallic Cobalt Stannide Nanocrystals for High-Performance Electrocatalytic Overall Water-Splitting P. W. Menezes, C. Panda, S. Garai, C. Walter, A. Guiet, M. Driess Angewandte Chemie International Edition 2018, 57, 15237–15242, 10.1002/anie.201809787

110 Gold-Decorated Biphase α-Fe2O3(0001): Activation by CO-Induced Surface Reduction H. Qiu, H. Kuhlenbeck, E. Bauer, H. J. Freund The Journal of Physical Chemistry C 2018, 123, 8221–8227, 10.1021/acs.jpcc.8b08521

109 Methane oxidative coupling process for producing ethylene from fossil- and bio-based methane H.  . Godini, A. Penteado, M. Khadivi, M. Azadi, T. Karsten, O. Görke, E. Esche, A. Orjuela, B. Mokhtarani, R. Schomäcker, G. Wozny, J. U. Repke Chemie Ingenieur Technik 2018, 90, 1135–1136, 10.1002/cite.201855007

108 Hydrogen reduction and metal-support interaction in a metastable metal-oxide system: Pd on rhombohedral In2O3 L. Schlicker, M. F. Bekheet, A. Gili, A. Doran, A. Gurlo, K. Ploner, T. Schachinger, S. Penner Journal of Solid State Chemistry 2018, 266, 93–99, 10.1016/j.jssc.2018.07.010

107 H2reduction of Gd- and Sm-doped ceria compared to pure CeO2at high temperatures: effect on structure, oxygen nonstoichiometry, hydrogen solubility and hydroxyl chemistry M. Grünbacher, L. Schlicker, M. F. Bekheet, A. Gurlo, B. Klötzer, S. Penner Physical Chemistry Chemical Physics 2018, 20, 22099–22113, 10.1039/C8CP04350G

106 Structural investigations of La0.6Sr0.4FeO3−δunder reducing conditions: kinetic and thermodynamic limitations for phase transformations and iron exsolution phenomena T. Götsch, L. Schlicker, M. F. Bekheet, A. Doran, M. Grünbacher, C. Praty, M. Tada, H. Matsui, N. Ishiguro, A. Gurlo, B. Klötzer, S. Penner RSC Advances 2018, 8, 3120–3131, 10.1039/c7ra12309d

105 Formation of Pd-Ce intermetallic compounds by reductive metal-support interaction T. Götsch, K. Ploner, J. Bernardi, L. Schlicker, A. Gili, A. Doran, A. Gurlo, S. Penner Journal of Solid State Chemistry 2018, 265, 176–183, 10.1016/j.jssc.2018.05.036

104 Magnetic Properties of Reduced and Reoxidized Mn–Na2WO4/SiO2: A Catalyst for Oxidative Coupling of Methane (OCM) W. Riedel, L. Thum, J. Möser, V. Fleischer, U. Simon, K. Siemensmeyer, A. Schnegg, R. Schomäcker, T. Risse, K. P. Dinse The Journal of Physical Chemistry C 2018, 122, 22605–22614, 10.1021/acs.jpcc.8b07386

103 Tailoring of ordered mesoporous silica COK-12: Room temperature synthesis of mesocellular foam and multilamellar vesicles M. G. Colmenares, U. Simon, F. Schmidt, S. Dey, J. Schmidt, A. Thomas, A. Gurlo Microporous and Mesoporous Materials 2018, 267, 142–149, 10.1016/j.micromeso.2018.03.015

102 Transmissionin situandoperandohigh temperature X-ray powder diffraction in variable gaseous environments L. Schlicker, A. Doran, P. Schneppmüller, A. Gili, M. Czasny, S. Penner, A. Gurlo Review of Scientific Instruments 2018, 89, 33904– 10.1063/1.5001695

101 Unified structural motifs of the catalytically active state of Co(oxyhydr)oxides during the electrochemical oxygen evolution reaction A. Bergmann, T. E. Jones, E. Martinez Moreno, D. Teschner, P. Chernev, M. Gliech, T. Reier, H. Dau, P. Strasser Nature Catalysis 2018, 1, 711–719, 10.1038/s41929-018-0141-2

100 Water Splitting: Unexpected Fe(VI) Trapped by Manipulation of Reaction Kinetics H. Dau Chem 2018, 4, 668–670, 10.1016/j.chempr.2018.03.018

99 A neodymium oxide nanoparticle-doped carbon felt as promising electrode for vanadium redox flow batteries A. Fetyan, G. A. El-Nagar, I. Derr, P. Kubella, H. Dau, C. Roth Electrochimica Acta 2018, 268, 59–65, 10.1016/j.electacta.2018.02.104

98 Reactivity Determinants in Electrodeposited Cu Foams for Electrochemical CO2Reduction K. Klingan, T. Kottakkat, Z. P. Jovanov, S. Jiang, C. Pasquini, F. Scholten, P. Kubella, A. Bergmann, B. Roldan Cuenya, C. Roth, H. Dau ChemSusChem 2018, 11, 3449–3459, 10.1002/cssc.201801582

97 Water oxidation by a manganese–potassium cluster: Mn oxide as a kinetically dominant “true” catalyst for water oxidation Y. Mousazade, M. R. Mohammadi, P. Chernev, R. Bikas, R. Bagheri, Z. Song, T. Lis, H. Dau, M. M. Najafpour Catalysis Science & Technology 2018, 8, 4390–4398, 10.1039/C8CY01151F

96 A mononuclear cobalt complex for water oxidation: new controversies and puzzles R. Safdari, M. R. Mohammadi, M. Hołyńska, P. Chernev, H. Dau, M. M. Najafpour Dalton Transactions 2018, 47, 16668–16673, 10.1039/C8DT03147A

95 From an Fe2P3complex to FeP nanoparticles as efficient electrocatalysts for water-splitting S. Yao, V. Forstner, P. W. Menezes, C. Panda, S. Mebs, E. M. Zolnhofer, M. E. Miehlich, T. Szilvási, N. Ashok Kumar, M. Haumann, K. Meyer, H. Grützmacher, M. Driess Chemical Science 2018, 9, 8590–8597, 10.1039/C8SC03407A

94 Stereoselective Alkyne Hydrohalogenation by Trapping of Transfer Hydrogenation Intermediates M. Das, T. Kaicharla, J. F. Teichert Organic Letters 2018, 20, 4926–4929, 10.1021/acs.orglett.8b02055

93 Extending the Toolbox for the Modular Arrangement of Functions at Xanthene/Dibenzofuran Platforms: Introduction of Directly Linked Transition Metals beside Bismuthanes K. Materne, C. Spröwitz, B. Braun-Cula, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2018, 644, 700–705, 10.1002/zaac.201800180

92 Bioinspired Designs, Molecular Premise and Tools for Evaluating the Ecological Importance of Antimicrobial Peptides E. Ongey, S. Pflugmacher, P. Neubauer Pharmaceuticals 2018, 11, 10.3390/ph11030068

91 Heterologous Biosynthesis, Modifications and Structural Characterization of Ruminococcin-A, a Lanthipeptide From the Gut Bacterium Ruminococcus gnavus E1, in Escherichia coli E. L. Ongey, R. T. Giessmann, M. Fons, J. Rappsilber, L. Adrian, P. Neubauer Frontiers in Microbiology 2018, 9, 10.3389/fmicb.2018.01688

90 Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3or [H(OEt2)2][B{3,5-(CF3)2C6H3}4] H. Baumgarth, G. Meier, C. N. von Hahmann, T. Braun Dalton Transactions 2018, 47, 16299–16304, 10.1039/c8dt03853h

89 Palladium‐Catalyzed Three‐Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes W. Yuan, P. Orecchia, M. Oestreich Chemistry – A European Journal 2018, 24, 19175–19178, 10.1002/chem.201805595

88 Formation and Evolution of Ultrathin Silica Polymorphs on Ru(0001) Studied with Combinedin Situ, Real-Time Methods H. W. Klemm, M. J. Prieto, G. Peschel, A. Fuhrich, E. Madej, F. Xiong, D. Menzel, T. Schmidt, H. J. Freund The Journal of Physical Chemistry C 2018, 123, 8228–8243, 10.1021/acs.jpcc.8b08525

87 CO2Adsorption on CaO(001): Temperature-Programmed Desorption and Infrared Study X. Weng, Y. Cui, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C 2018, 123, 1880–1887, 10.1021/acs.jpcc.8b11415

86 Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON]+/CH4System S. Zhou, X. Sun, L. Yue, C. Guo, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 15902–15906, 10.1002/anie.201809583

85 Ta2+-mediated ammonia synthesis from N2and H2at ambient temperature C. Geng, J. Li, T. Weiske, H. Schwarz Proceedings of the National Academy of Sciences 2018, 115, 11680–11687, 10.1073/pnas.1814610115

84 Structures of the intermediates of Kok’s photosynthetic water oxidation clock J. Kern, R. Chatterjee, I. D. Young, F. D. Fuller, L. Lassalle, M. Ibrahim, S. Gul, T. Fransson, A. S. Brewster, R. Alonso-Mori, R. Hussein, M. Zhang, L. Douthit, C. de Lichtenberg, M. H. Cheah, D. Shevela, J. Wersig, I. Seuffert, D. Sokaras, E. Pastor, C. Weninger, T. Kroll, R. G. Sierra, P. Aller, A. Butryn, A. M. Orville, M. Liang, A. Batyuk, J. E. Koglin, S. Carbajo, S. Boutet, N. W. Moriarty, J. M. Holton, H. Dobbek, P. D. Adams, U. Bergmann, N. K. Sauter, A. Zouni, J. Messinger, J. Yano, V. K. Yachandra Nature 2018, 563, 421–425, 10.1038/s41586-018-0681-2

83 Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane C. Geng, J. Li, M. Schlangen, S. Shaik, X. Sun, N. Wang, T. Weiske, L. Yue, S. Zhou, H. Schwarz Dalton Transactions 2018, 47, 15271–15277, 10.1039/c8dt03048k

82 The Electric Field as a “Smart” Ligand in Controlling the Thermal Activation of Methane and Molecular Hydrogen L. Yue, N. Wang, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 14635–14639, 10.1002/anie.201805718

81 Surface Carbon as a Reactive Intermediate in Dry Reforming of Methane to Syngas on a 5% Ni/MnO Catalyst A. Gili, L. Schlicker, M. F. Bekheet, O. Görke, S. Penner, M. Grünbacher, T. Götsch, P. Littlewood, T. J. Marks, P. C. Stair, R. Schomäcker, A. Doran, S. Selve, U. Simon, A. Gurlo ACS Catalysis 2018, 8, 8739–8750, 10.1021/acscatal.8b01820

80 Spin Transition and Charge Transfer in Co2+/Co3+Complexes of Meridional Ligands Holding Nearby Redox-active Triarylamine L. Schnaubelt, H. Petzold, J. M. Speck, T. Rüffer, G. Hörner, H. Lang Zeitschrift für anorganische und allgemeine Chemie 2018, 10.1002/zaac.201800274

79 Bis-meridional Fe2+spincrossover complexes of phenyl and pyridyl substituted 2-(pyridin-2-yl)-1,10-phenanthrolines H. Petzold, P. Djomgoue, G. Hörner, C. Lochenie, B. Weber, T. Rüffer Dalton Transactions 2018, 47, 491–506, 10.1039/C7DT02320K

78 Tuning of Thiyl/Thiolate Complex Near-Infrared Chromophores of Platinum through Geometrical Constraints N. M. Mews, G. Hörner, H. Schubert, A. Berkefeld Inorganic Chemistry 2018, 57, 9670–9682, 10.1021/acs.inorgchem.8b00122

77 Redox Series of Cyclometalated Nickel Complexes [Ni((R)Ph(R′)bpy)Br]+/0/–/2–(H–(R)Ph(R′)bpy = Substituted 6-Phenyl-2,2′-bipyridine) A. Sandleben, N. Vogt, G. Hörner, A. Klein Organometallics 2018, 37, 3332–3341, 10.1021/acs.organomet.8b00559

76 Selective C−O Coupling Hidden in the Thermal Reaction of [Al2CuO5]+with Methane S. Zhou, X. Sun, L. Yue, M. Schlangen, H. Schwarz Chemistry - A European Journal 2018, 24, 14649–14653, 10.1002/chem.201804059

75 Quantum-Chemical Approach to NMR Chemical Shifts in Paramagnetic Solids Applied to LiFePO4and LiCoPO4 A. Mondal, M. Kaupp The Journal of Physical Chemistry Letters 2018, 9, 1480–1484, 10.1021/acs.jpclett.8b00407

74 Efficient Light-Induced pKa Modulation Coupled to Base-Catalyzed Photochromism J. Gurke, Š. Budzák, B. M. Schmidt, D. Jacquemin, S. Hecht Angewandte Chemie International Edition 2018, 57, 4797–4801, 10.1002/anie.201801270

73 Label-Free MIP Sensors for Protein Biomarkers K. J. Jetzschmann, X. Zhang, A. Yarman, U. Wollenberger, F. W. Scheller Label-Free Biosensing M.J. Schöning, A. Poghossian Springer 2018, 291–321, 10.1007/5346_2017_3

72 Molecular LEGO by domain-imprinting of cytochrome P450 BM3 K. J. Jetzschmann, A. Yarman, L. Rustam, P. Kielb, V. B. Urlacher, A. Fischer, I. M. Weidinger, U. Wollenberger, F. W. Scheller Colloids and Surfaces B: Biointerfaces 2018, 164, 240–246, 10.1016/j.colsurfb.2018.01.047

71 Enhancement of the Electrocatalytic Activity of Thienyl-Substituted Iron Porphyrin Electropolymers by a Hangman Effect B. Neumann, R. Götz, P. Wrzolek, F. W. Scheller, I. M. Weidinger, M. Schwalbe, U. Wollenberger ChemCatChem 2018, 10, 10.1002/cctc.201800934

70 Hydrogen Spillover to Copper Clusters on Hydroxylated γ-Al2O3 G. Feng, M. V. Ganduglia-Pirovano, C. F. Huo, J. Sauer The Journal of Physical Chemistry C 2018, 122, 18445–18455, 10.1021/acs.jpcc.8b03764

69 Vanadium Oxide Oligomers and Ordered Monolayers Supported on CeO2(111): Structure and Stability Studied by Density Functional Theory C. Penschke, J. Paier, J. Sauer The Journal of Physical Chemistry C 2018, 122, 9101–9110, 10.1021/acs.jpcc.8b01998

68 Facile Formation of Nanostructured Manganese Oxide Films as High‐Performance Catalysts for the Oxygen Evolution Reaction C. Walter, P. W. Menezes, S. Loos, H. Dau, M. Driess ChemSusChem 2018, 11, 2554–2561, 10.1002/cssc.201800493

67 Geometric distortions in nickel (oxy)hydroxide electrocatalysts by redox inactive iron ions R. D. L. Smith, C. Pasquini, S. Loos, P. Chernev, K. Klingan, P. Kubella, M. R. Mohammadi, D. González-Flores, H. Dau Energy & Environmental Science 2018, 11, 2476–2485, 10.1039/C8EE01063C

66 Kα X-ray Emission Spectroscopy on the Photosynthetic Oxygen-Evolving Complex Supports Manganese Oxidation and Water Binding in the S3State N. Schuth, I. Zaharieva, P. Chernev, G. Berggren, M. Anderlund, S. Styring, H. Dau, M. Haumann Inorganic Chemistry 2018, 57, 10424–10430, 10.1021/acs.inorgchem.8b01674

65 The Concept of “Noble, Heteroatom-Doped Carbons,” Their Directed Synthesis by Electronic Band Control of Carbonization, and Applications in Catalysis and Energy Materials M. Antonietti, M. Oschatz Advanced Materials 2018, 30, 1706836– 10.1002/adma.201706836

64 Splitting Water by Electrochemistry and Artificial Photosynthesis: Excellent Science but a Nightmare of Translation? M. Antonietti, A. Savateev The Chemical Record 2018, 18, 969–972, 10.1002/tcr.201700062

63 A structurally versatile nickel phosphite acting as a robust bifunctional electrocatalyst for overall water splitting P. W. Menezes, C. Panda, S. Loos, F. Bunschei-Bruns, C. Walter, M. Schwarze, X. Deng, H. Dau, M. Driess Energy & Environmental Science 2018, 11, 1287–1298, 10.1039/C7EE03619A

62 Nickel-iron catalysts for electrochemical water oxidation – redox synergism investigated byin situX-ray spectroscopy with millisecond time resolution D. González-Flores, K. Klingan, P. Chernev, S. Loos, M. R. Mohammadi, C. Pasquini, P. Kubella, I. Zaharieva, R. D. L. Smith, H. Dau Sustainable Energy & Fuels 2018, 2, 1986–1994, 10.1039/C8SE00114F

61 Mehrstufige nichtlineare Regelung der autrotrophen Kultivierung von Ralstonia eutropha F. Neddermeyer, R. King Chemie Ingenieur Technik 2018, 90, 1249–1250, 10.1002/cite.201855259

60 Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation F. Forster, V. M. Rendón López, M. Oestreich Organometallics 2018, 37, 2656–2659, 10.1021/acs.organomet.8b00409

59 Robust electrografted interfaces on metal oxides for electrocatalysis – anin situspectroelectrochemical study T. G. A. A. Harris, R. Götz, P. Wrzolek, V. Davis, C. E. Knapp, K. Ly, P. Hildebrandt, M. Schwalbe, I. Weidinger, I. Zebger, A. Fischer Journal of Materials Chemistry A 2018, 6, 15200–15212, 10.1039/C8TA02983K

58 Electrosynthesized MIPs for transferrin: Plastibodies or nano-filters? X. Zhang, A. Yarman, J. Erdossy, S. Katz, I. Zebger, K. J. Jetzschmann, Z. Altintas, U. Wollenberger, R. E. Gyurcsányi, F. W. Scheller Biosensors and Bioelectronics 2018, 105, 29–35, 10.1016/j.bios.2018.01.011

57 Catalytic Activity and Proton Translocation of Reconstituted Respiratory Complex I Monitored by Surface-Enhanced Infrared Absorption Spectroscopy O. Gutiérrez-Sanz, E. Forbrig, A. P. Batista, M. M. Pereira, J. Salewski, M. A. Mroginski, R. Götz, A. L. De Lacey, J. Kozuch, I. Zebger Langmuir 2018, 34, 5703–5711, 10.1021/acs.langmuir.7b04057

56 Solar Water Splitting with a Hydrogenase Integrated in Photoelectrochemical Tandem Cells D. H. Nam, J. Z. Zhang, V. Andrei, N. Kornienko, N. Heidary, A. Wagner, K. Nakanishi, K. P. Sokol, B. Slater, I. Zebger, S. Hofmann, J. C. Fontecilla-Camps, C. B. Park, E. Reisner Angewandte Chemie International Edition 2018, 57, 10595–10599, 10.1002/anie.201805027

55 Photosynthesis supported by a chlorophyll f-dependent, entropy-driven uphill energy transfer in Halomicronema hongdechloris cells adapted to far-red light F. J. Schmitt, Z. Y. Campbell, M. V. Bui, A. Hüls, T. Tomo, M. Chen, E. G. Maksimov, S. I. Allakhverdiev, T. Friedrich Photosynthesis Research 2018, 10.1007/s11120-018-0556-2

54 In situ spectroelectrochemical studies into the formation and stability of robust diazonium-derived interfaces on gold electrodes for the immobilization of an oxygen-tolerant hydrogenase T. G. A. A. Harris, N. Heidary, J. Kozuch, S. Frielingsdorf, O. Lenz, M. A. Mroginski, P. Hildebrandt, I. Zebger, A. Fischer ACS Applied Materials & Interfaces 2018, 10, 23380–23391, 10.1021/acsami.8b02273

53 O2-Tolerant H2Activation by an Isolated Large Subunit of a [NiFe] Hydrogenase S. Hartmann, S. Frielingsdorf, A. Ciaccafava, C. Lorent, J. Fritsch, E. Siebert, J. Priebe, M. Haumann, I. Zebger, O. Lenz Biochemistry 2018, 57, 5339–5349, 10.1021/acs.biochem.8b00760

52 Engineering 'Golden' Fluorescence by Selective Pressure Incorporation of Non-canonical Amino Acids and Protein Analysis by Mass Spectrometry and Fluorescence T. Baumann, F. J. Schmitt, A. Pelzer, V. J. Spiering, G. J. Freiherr von Sass, T. Friedrich, N. Budisa Journal of Visualized Experiments 2018, 10.3791/57017

51 Fully electrochemical MIP sensor for artemisinin A. F. T. Waffo, C. Yesildag, G. Caserta, S. Katz, I. Zebger, M. C. Lensen, U. Wollenberger, F. W. Scheller, Z. Altintas Sensors and Actuators B: Chemical 2018, 275, 163–173, 10.1016/j.snb.2018.08.018

50 Antimicrobial Peptides Produced by Selective Pressure Incorporation of Non-canonical Amino Acids J. H. Nickling, T. Baumann, F. J. Schmitt, M. Bartholomae, O. P. Kuipers, T. Friedrich, N. Budisa Journal of Visualized Experiments 2018, 10.3791/57551

49 Model systems in heterogeneous catalysis: towards the design and understanding of structure and electronic properties Q. Pan, L. Li, S. Shaikhutdinov, Y. Fujimori, M. Hollerer, M. Sterrer, H. J. Freund Faraday Discussions 2018, 208, 307–323, 10.1039/c7fd00209b

48 Correction to: Aspergillus niger is a superior expression host for the production of bioactive fungal cyclodepsipeptides S. Boecker, S. Grätz, D. Kerwat, L. Adam, D. Schirmer, L. Richter, T. Schütze, D. Petras, R. D. Süssmuth, V. Meyer Fungal Biology and Biotechnology 2018, 5, 10.1186/s40694-018-0051-8

47 3D Anionic Silicate Covalent Organic Framework with srs Topology O. Yahiaoui, A. N. Fitch, F. Hoffmann, M. Fröba, A. Thomas, J. Roeser Journal of the American Chemical Society 2018, 140, 5330–5333, 10.1021/jacs.8b01774

46 Bifunctional Electrocatalysts for Overall Water Splitting from an Iron/Nickel-Based Bimetallic Metal-Organic Framework/Dicyandiamide Composite X. Zhao, P. Pachfule, S. Li, J. R. J. Simke, J. Schmidt, A. Thomas Angewandte Chemie International Edition 2018, 57, 8921–8926, 10.1002/anie.201803136

45 Stabilization of β-Diketiminato Nickel(I) with Alkaline Metal Halide Entities for Small Molecule Activation P. Holze, B. Braun-Cula, S. Mebs, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2018, 10.1002/zaac.201800100

44 A Biomimetic Nickel Complex with a Reduced CO2Ligand Generated by Formate Deprotonation and Its Behaviour towards CO2 P. Zimmermann, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg Angewandte Chemie International Edition 2018, 57, 7230–7233, 10.1002/anie.201802655

43 Crystal structure and functional characterization of selenocysteine-containing glutathione peroxidase 4 suggests an alternative mechanism of peroxide reduction A. Borchert, J. Kalms, S. R. Roth, M. Rademacher, A. Schmidt, H. G. Holzhutter, H. Kuhn, P. Scheerer Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids 2018, 1863, 1095–1107, 10.1016/j.bbalip.2018.06.006

42 An incretin-based tri-agonist promotes superior insulin secretion from murine pancreatic islets via PLC activation N. Khajavi, B. Finan, O. Kluth, T. D. Müller, S. Mergler, A. Schulz, G. Kleinau, P. Scheerer, A. Schürmann, T. Gudermann, M. H. Tschöp, H. Krude, R. D. DiMarchi, H. Biebermann Cellular Signalling 2018, 51, 13–22, 10.1016/j.cellsig.2018.07.006

41 Binding, Thermodynamics, and Selectivity of a Non-peptide Antagonist to the Melanocortin-4 Receptor N. Saleh, G. Kleinau, N. Heyder, T. Clark, P. W. Hildebrand, P. Scheerer Frontiers in Pharmacology 2018, 9, 10.3389/fphar.2018.00560

40 The Trace Amine-Associated Receptor 1 Agonist 3-Iodothyronamine Induces Biased Signaling at the Serotonin 1b Receptor J. Bräunig, J. Dinter, C. S. Höfig, S. Paisdzior, M. Szczepek, P. Scheerer, M. Rosowski, J. Mittag, G. Kleinau, H. Biebermann Frontiers in Pharmacology 2018, 9, 10.3389/fphar.2018.00222

39 Custom Hydrosilane Synthesis Based on Monosilane W. Yuan, P. Smirnov, M. Oestreich Chem 2018, 4, 1443–1450, 10.1016/j.chempr.2018.03.017

38 Stepwise Methane-to-Methanol Conversion on CuO/SBA-15 H. V. Le, S. Parishan, A. Sagaltchik, H. Ahi, A. Trunschke, R. Schomäcker, A. Thomas Chemistry - A European Journal 2018, 10.1002/chem.201801135

37 Investigation into Consecutive Reactions of Ethane and Ethene Under the OCM Reaction Conditions over MnxOy–Na2WO4/SiO2 Catalyst S. Parishan, E. Nowicka, V. Fleischer, C. Schulz, M. G. Colmenares, F. Rosowski, R. Schomäcker Catalysis Letters 2018, 148, 1659–1675, 10.1007/s10562-018-2384-6

36 Photocatalytic CO2Reduction by Mesoporous Polymeric Carbon Nitride Photocatalysts M. Tasbihi, A. Acharjya, A. Thomas, M. Reli, N. AmbroŽová, K. Kočcí, R. Schomäcker Journal of Nanoscience and Nanotechnology 2018, 18, 5636–5644, 10.1166/jnn.2018.15445

35 Terminal Hydride Species in [FeFe]-Hydrogenases Are Vibrationally Coupled to the Active Site Environment C. C. Pham, D. W. Mulder, V. Pelmenschikov, P. W. King, M. W. Ratzloff, H. Wang, N. Mishra, E. E. Alp, J. Zhao, M. Y. Hu, K. Tamasaku, Y. Yoda, S. P. Cramer Angewandte Chemie International Edition 2018, 57, 10605–10609, 10.1002/anie.201805144

34 Thermal O–H Bond Activation of Water As Mediated by Heteronuclear [Al2Mg2O5]•+: Evidence for Oxygen-Atom Scrambling C. Geng, J. Li, T. Weiske, H. Schwarz Journal of the American Chemical Society 2018, 140, 9275–9281, 10.1021/jacs.8b05618

33 High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT V. Pelmenschikov, L. B. Gee, H. Wang, K. C. MacLeod, S. F. McWilliams, K. L. Skubi, S. P. Cramer, P. L. Holland Angewandte Chemie International Edition 2018, 57, 9367–9371, 10.1002/anie.201804601

32 Water Formation under Silica Thin Films: Real-Time Observation of a Chemical Reaction in a Physically Confined Space M. J. Prieto, H. W. Klemm, F. Xiong, D. M. Gottlob, D. Menzel, T. Schmidt, H. J. Freund Angewandte Chemie International Edition 2018, 57, 10.1002/anie.201802000

31 Controlling the charge state of supported nanoparticles in catalysis: lessons from model systems G. Pacchioni, H. J. Freund Chemical Society Reviews 2018, 47, 8474–8502, 10.1039/c8cs00152a

30 Experimental Identification of the Active Site in the Heteronuclear Redox Couples [AlVOx]+./CO/N2O (x=3, 4) by Gas-Phase IR Spectroscopy S. Debnath, H. Knorke, W. Schöllkopf, S. Zhou, K. R. Asmis, H. Schwarz Angewandte Chemie International Edition 2018, 57, 7448–7452, 10.1002/anie.201804056

29 On the Origin of the Distinctly Different Reactivity of Ruthenium in [MO]+/CH4Systems (M=Fe, Ru, Os) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 5934–5937, 10.1002/anie.201800173

28 High Electromagnetic Field Enhancement of TiO2Nanotube Electrodes I. H. Öner, C. J. Querebillo, C. David, U. Gernert, C. Walter, M. Driess, S. Leimkühler, K. H. Ly, I. M. Weidinger Angewandte Chemie International Edition 2018, 57, 7225–7229, 10.1002/anie.201802597

27 Hydrogen evolution by cobalt hangman porphyrins under operating conditions studied by vibrational spectro-electrochemistry P. Kielb, M. Horch, P. Wrzolek, R. Goetz, K. H. Ly, J. Kozuch, M. Schwalbe, I. M. Weidinger Catalysis Science & Technology 2018, 8, 1849–1857, 10.1039/C7CY02253K

26 ATP-dependent substrate reduction at an [Fe8S9] double-cubane cluster J. H. Jeoung, H. Dobbek Proceedings of the National Academy of Sciences 2018, 115, 2994–2999, 10.1073/pnas.1720489115

25 The arrestin-1 finger loop interacts with two distinct conformations of active rhodopsin M. Elgeti, R. Kazmin, A. S. Rose, M. Szczepek, P. W. Hildebrand, F. J. Bartl, P. Scheerer, K. P. Hofmann Journal of Biological Chemistry 2018, 293, 4403–4410, 10.1074/jbc.M117.817890

24 Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminum Chlorofluoride B. Calvo, T. Braun, E. Kemnitz ChemCatChem 2018, 10, 403–406, 10.1002/cctc.201701327

23 Tracking the route of molecular oxygen in O2-tolerant membrane-bound [NiFe] hydrogenase J. Kalms, A. Schmidt, S. Frielingsdorf, T. Utesch, G. Gotthard, D. von Stetten, P. van der Linden, A. Royant, M. A. Mroginski, P. Carpentier, O. Lenz, P. Scheerer Proceedings of the National Academy of Sciences 2018, 115, 10.1073/pnas.1712267115

22 Direct Room-Temperature Conversion of Methane into Protonated Formaldehyde: The Gas-Phase Chemistry of Mercury among the Zinc Triad Oxide Cations L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 3251–3255, 10.1002/anie.201712405

21 Copper(i) complexes based on ligand systems with two different binding sites: synthesis, structures and reaction with O2 S. T. Li, B. Braun-Cula, S. Hoof, C. Limberg Dalton Transactions 2018, 47, 544–560, 10.1039/c7dt03752j

20 Active Salt/Silica-Templated 2D Mesoporous FeCo-Nx-Carbon as Bifunctional Oxygen Electrodes for Zinc-Air Batteries S. Li, C. Cheng, X. Zhao, J. Schmidt, A. Thomas Angewandte Chemie International Edition 2018, 57, 1856–1862, 10.1002/anie.201710852

19 Carbon Monoxide Oxidation on Metal-Supported Monolayer Oxide Films: Establishing Which Interface is Active K. Zhang, L. Li, S. Shaikhutdinov, H. J. Freund Angewandte Chemie International Edition 2018, 57, 1261–1265, 10.1002/anie.201710934

18 Charge Control in Model Catalysis: The Decisive Role of the Oxide-Nanoparticle Interface W. D. Schneider, M. Heyde, H. J. Freund Chemistry - A European Journal 2018, 24, 2317–2327, 10.1002/chem.201703169

17 Ordered mesoporous WO2.83: selective reduction synthesis, exceptional localized surface plasmon resonance and enhanced hydrogen evolution reaction activity H. Cheng, M. Klapproth, A. Sagaltchik, S. Li, A. Thomas Journal of Materials Chemistry A 2018, 6, 2249–2256, 10.1039/c7ta09579a

16 Ionic Liquid-Assisted Synthesis of Mesoporous Carbons with Surface-Enriched Nitrogen for the Hydrogen Evolution Reaction X. Zhao, S. Li, H. Cheng, J. Schmidt, A. Thomas ACS Applied Materials & Interfaces 2018, 10, 3912–3920, 10.1021/acsami.7b14919

15 Batch and continuous synthesis upscaling of powder and monolithic ordered mesoporous silica COK-12 M. G. Colmenares, U. Simon, O. Cruz, A. Thomas, O. Goerke, A. Gurlo Microporous and Mesoporous Materials 2018, 256, 102–110, 10.1016/j.micromeso.2017.08.002

14 Enzymatic and spectroscopic properties of a thermostable [NiFe]‑hydrogenase performing H2-driven NAD+ reduction in the presence of O2 J. Preissler, S. Wahlefeld, C. Lorent, C. Teutloff, M. Horch, L. Lauterbach, S. P. Cramer, I. Zebger, O. Lenz Biochimica et Biophysica Acta (BBA) - Bioenergetics 2018, 1859, 8–18, 10.1016/j.bbabio.2017.09.006

13 First-principles supercell calculations of small polarons with proper account for long-range polarization effects S. Kokott, S. V. Levchenko, P. Rinke, M. Scheffler New Journal of Physics 2018, 10.1088/1367-2630/aaaf44

12 Investigation of the role of the Na 2 WO 4 /Mn/SiO 2catalyst composition in the oxidative coupling of methane by chemical looping experiments V. Fleischer, U. Simon, S. Parishan, M. G. Colmenares, O. Görke, A. Gurlo, W. Riedel, L. Thum, J. Schmidt, T. Risse, K. P. Dinse, R. Schomäcker Journal of Catalysis 2018, 360, 102–117, 10.1016/j.jcat.2018.01.022

11 Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation P. Pachfule, A. Acharjya, J. Roeser, T. Langenhahn, M. Schwarze, R. Schomäcker, A. Thomas, J. Schmidt Journal of the American Chemical Society 2018, 140, 1423–1427, 10.1021/jacs.7b11255

10 Chemical looping as a reactor concept for the oxidative coupling of methane over the Mn x O y -Na 2 WO 4 /SiO 2catalyst, benefits and limitation S. Parishan, P. Littlewood, A. Arinchtein, V. Fleischer, R. Schomäcker Catalysis Today 2018, 311, 40–47, 10.1016/j.cattod.2017.08.019

9 Dual-wavelength 3D photoacoustic imaging of mammalian cells using a photoswitchable phytochrome reporter protein J. Märk, H. Dortay, A. Wagener, E. Zhang, J. Buchmann, C. Grötzinger, T. Friedrich, J. Laufer Communications Physics 2018, 1, 10.1038/s42005-017-0003-2

8 Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+ M. Firouzbakht, N. J. Rijs, M. Schlangen, M. Kaupp, H. Schwarz Topics in Catalysis 2018, 61, 575–584, 10.1007/s11244-018-0903-8

7 Exact Mapping from Many‐Spin Hamiltonians to Giant‐Spin Hamiltonians S. Ghassemi Tabrizi, A. V. Arbuznikov, M. Kaupp Chemistry – A European Journal 2018, 24, 4689–4702, 10.1002/chem.201705897

6 Modulating the Molybdenum Coordination Sphere ofEscherichia coliTrimethylamineN-Oxide Reductase P. Kaufmann, B. R. Duffus, B. Mitrova, C. Iobbi-Nivol, C. Teutloff, M. Nimtz, L. Jänsch, U. Wollenberger, S. Leimkühler Biochemistry 2018, 57, 1130–1143, 10.1021/acs.biochem.7b01108

5 Spectroelectrochemical insights into structural and redox properties of immobilized endonuclease III and its catalytically inactive mutant E. Moe, F. Rollo, C. M. Silveira, M. Sezer, P. Hildebrandt, S. Todorovic Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2018, 188, 149–154, 10.1016/j.saa.2017.06.050

4 A Molecular Approach to Manganese Nitride Acting as a High Performance Electrocatalyst in the Oxygen Evolution Reaction C. Walter, P. W. Menezes, S. Orthmann, J. Schuch, P. Connor, B. Kaiser, M. Lerch, M. Driess Angewandte Chemie International Edition 2018, 57, 698–702, 10.1002/anie.201710460

3 Striking transformations of the hydroborylene ligand in a HB:→NiIIcomplex with isocyanides and CO T. J. Hadlington, T. Szilvási, M. Driess Chemical Science 2018, 9, 2595–2600, 10.1039/C7SC04792D

2 Sterically Stabilized Terminal Hydride of a Diiron Dithiolate M. R. Carlson, D. L. Gray, C. P. Richers, W. Wang, P. H. Zhao, T. B. Rauchfuss, V. Pelmenschikov, C. C. Pham, L. B. Gee, H. Wang, S. P. Cramer Inorganic Chemistry 2018, 57, 1988–2001, 10.1021/acs.inorgchem.7b02903

1 Mechanistic insights into the role of prenyl-binding protein PrBP/δ in membrane dissociation of phosphodiesterase 6 B. M. Qureshi, A. Schmidt, E. Behrmann, J. Bürger, T. Mielke, C. M. T. Spahn, M. Heck, P. Scheerer Nature Communications 2018, 9, 10.1038/s41467-017-02569-y