Publications 2008

Number of records: 73

73“Roll-over” Cyclometalation of 2,2′-Bipyridine Platinum(II) Complexes in the Gas Phase: A Combined Experimental and Computational Study B. Butschke, M. Schlangen, D. Schröder, H. Schwarz Chemistry - A European Journal 2008, 35, 11050–11060, 10.1002/chem.200801658

72A “Side-on” Superoxonickel Complex [LNi(O )] with a Square-Planar Tetracoordinate Nickel(II) Center and Its Conversion into [LNi(μ-OH) NiL] S. Yao, E. Bill, C. Milsmann, K. Wieghardt, M. Driess Angewandte Chemie International Edition 2008, 37, 7110–7113, 10.1002/anie.200802234

71A Dinuclear Iron Complex Based on Parallel Malonate Binding Sites: Cooperative Activation of Dioxygen and Biomimetic Ligand Oxidation I. Siewert, C. Limberg, S. Demeshko, E. Hoppe Chemistry - A European Journal 2008, 30, 9377–9388, 10.1002/chem.200800955

70A hexafluorobenzene promoted ring-closing metathesis to form tetrasubstituted olefins D. Rost, M. Porta, S. Gessler, S. Blechert Tetrahedron Letters 2008, 41, 5968–5971, 10.1016/j.tetlet.2008.07.161

69A Highly Active Water‐Soluble Cross‐Coupling Catalyst Based on Dendritic Polyglycerol N‐Heterocyclic Carbene Palladium Complexes M. Meise, R. Haag ChemSusChem ChemSusChem 2008, 7, 637–642, 10.1002/cssc.200800042

68A low-coordinate nickel(ii) hydride complex and its reactivity S. Pfirrmann, C. Limberg, B. Ziemer Dalton Transactions 2008, 47, 6689– 10.1039/B816136B

67A metal-free polymeric photocatalyst for hydrogen production from water under visible light X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J. M. Carlsson, K. Domen, M. Antonietti Nature Materials nature materials 2008, 1, 76–80, 10.1038/NMAT2317

66A Trispyrazolylborato Iron Malonato Complex as a Functional Model for the Acetylacetone Dioxygenase I. Siewert, C. Limberg Angewandte Chemie International Edition 2008, 41, 7953–7956, 10.1002/anie.200802955

65Activation of Methane by Oligomeric (Al2O3)x+ (x=3,4,5): The Role of Oxygen-Centered Radicals in Thermal Hydrogen-Atom Abstraction S. Feyel, J. Döbler, R. Höckendorf, M. Beyer, J. Sauer, H. Schwarz Angewandte Chemie International Edition 2008, 10, 1946–1950, 10.1002/anie.200704791

64Alternating Copolymerizations Using a Grubbs-Type Initiator with an Unsymmetrical, Chiral N-Heterocyclic Carbene Ligand K. Vehlow, D. Wang, M. Buchmeiser, S. Blechert Angewandte Chemie International Edition 2008, 14, 2615–2618, 10.1002/anie.200704822

63Au Dimers on Thin MgO(001) Films: Flat and Charged or Upright and Neutral? V. Simic-Milosevic, M. Heyde, N. Nilius, T. König, H. P. Rust, M. Sterrer, T. Risse, H. J. Freund, L. Giordano, G. Pacchioni Journal of the American Chemical Society 2008, 25, 7814–7815, 10.1021/ja8024388

62Bi-stable neural state switches A. Berndt, O. Yizhar, L. A. Gunaydin, P. Hegemann, K. Deisseroth Nature Neuroscience 2008, 2, 229–234, 10.1038/nn.2247

61Carbon nanotube Bloch equations: A many-body approach to nonlinear and ultrafast optical properties M. Hirtschulz, F. Milde, E. Malić, S. Butscher, C. Thomsen, S. Reich, A. Knorr Physical Review B 2008, 3, 10.1103/PhysRevB.77.035403

60Chromophore Heterogeneity and Photoconversion in Phytochrome Crystals and Solution Studied by Resonance Raman Spectroscopy D. von Stetten, M. Günther, P. Scheerer, D. Murgida, M. Mroginski, N. Krauß, T. Lamparter, J. Zhang, D. Anstrom, R. Vierstra, K. Forest, P. Hildebrandt Angewandte Chemie International Edition 2008, 25, 4753–4755, 10.1002/anie.200705716

59Competitive Intramolecular Aryl- and Alkyl-CH Bond Activation and Ligand Evaporation from Gaseous Bisimino Complexes [Pt(L)(CH )((CH ) S)] (L=C H NC(CH )C(CH )NC H ) B. Butschke, M. Schlangen, D. Schröder, H. Schwarz Helvetica Chimica Acta 2008, 10, 1902–1915, 10.1002/hlca.200890204

58Coulomb effects in single-walled carbon nanotubes E. Malić, M. Hirtschulz, F. Milde, M. Richter, J. Maultzsch, S. Reich, A. Knorr physica status solidi (b) Physica Status Solidi B-Basic Solid State Physics 2008, 10, 2155–2158, 10.1002/pssb.200879612

57Counting Electrons Transferred through a Thin Alumina Film into Au Chains N. Nilius, M. V. Ganduglia-Pirovano, V. Brázdová, M. Kulawik, J. Sauer, H. J. Freund Physical Review Letters 2008, 9, 10.1103/PhysRevLett.100.096802

56Dendritic Polymers with a Core−Multishell Architecture: A Versatile Tool for the Stabilization of Nanoparticles J. Keilitz, M. R. Radowski, J. D. Marty, R. Haag, F. Gauffre, C. Mingotaud Chemistry of Materials 2008, 7, 2423–2425, 10.1021/cm8002639

55Dichotomic Reactivity of a Stable Silylene toward Terminal Alkynes: Facile CH Bond Insertion versus Autocatalytic Formation of Silacycloprop-3-ene S. Yao, C. van Wüllen, X. Y. Sun, M. Driess Angewandte Chemie International Edition 2008, 17, 3250–3253, 10.1002/anie.200704939

54Dinuclear iron complexes based on parallel β-diiminato binding sites: syntheses, structures and reaction with O2 M. F. Pilz, C. Limberg, S. Demeshko, F. Meyer, B. Ziemer Dalton Transactions 2008, 14, 1917– 10.1039/b715376g

53Direct Liquefaction of Biomass F. Behrendt, Y. Neubauer, M. Oevermann, B. Wilmes, N. Zobel Chemical Engineering & Technology 2008, 5, 667–677, 10.1002/ceat.200800077

52Direct Observation of the Gating Step in Protein Electron Transfer: Electric-Field-Controlled Protein Dynamics A. Kranich, H. K. Ly, P. Hildebrandt, D. H. Murgida Journal of the American Chemical Society 2008, 30, 9844–9848, 10.1021/ja8016895

51Disentangling interfacial redox processes of proteins by SERR spectroscopy D. H. Murgida, P. Hildebrandt Chemical Society Reviews 2008, 5, 937– 10.1039/B705976K

50Diverse Functional Consequences of Mutations in the Na /K -ATPase α -Subunit Causing Familial Hemiplegic Migraine Type 2 N. N. Tavraz, T. Friedrich, K. L. Dürr, J. B. Koenderink, E. Bamberg, T. Freilinger, M. Dichgans Journal of Biological Chemistry 2008, 45, 31097–31106, 10.1074/jbc.M802771200

49Electrocatalytic sulfite biosensor with human sulfite oxidase co-immobilized with cytochrome c in a polyelectrolyte-containing multilayer R. Spricigo, R. Dronov, F. Lisdat, S. Leimkühler, F. W. Scheller, U. Wollenberger Analytical and Bioanalytical Chemistry 2008, 1, 225–233, 10.1007/s00216-008-2432-y

48Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes M. Dochnahl, K. Löhnwitz, J. W. Pissarek, P. W. Roesky, S. Blechert Dalton Transactions 2008, 21, 2844– 10.1039/b719120k

47Encapsulation of Pt Nanoparticles as a Result of Strong Metal−Support Interaction with Fe O (111) Z. H. Qin, M. Lewandowski, Y. N. Sun, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C 2008, 27, 10209–10213, 10.1021/jp801756q

46Enzymatic oxidation of H2 in atmospheric O2: The electrochemistry of energy generation from trace H2 by aerobic by aerobic microorganisms J. A. Cracknell, K. A. Vincent, M. Ludwig, O. Lenz, B. Friedrich, F. A. Armstrong Journal of the American Chemical Society 2008, 130, 424–425, 10.1021/ja078299

45Ethylene Production via Oxidative Coupling of Methane (OCM) - Investigation of alternative separation processes G. Wozny, S. Stünkel, J. U. Repke Biblioteka Cyfrowa Politechniki Krakowskiej 2008, 105, 285–291,

44Fluxionality and σ-Aromaticity in Small Yttrium-Doped Gold Clusters L. Lin, T. Höltzl, P. Gruene, P. Claes, G. Meijer, A. Fielicke, P. Lievens, M. T. Nguyen ChemPhysChem ChemPhysChem 2008, 17, 2471–2474, 10.1002/cphc.200800580

43From a Paramagnetic, Mononuclear Supersulfidonickel(II) Complex to a Diamagnetic Dimer with a Four-Sulfur Two-Electron Bond S. Yao, C. Milsmann, E. Bill, K. Wieghardt, M. Driess Journal of the American Chemical Society 2008, 41, 13536–13537, 10.1021/ja806101h

42From Microporous Regular Frameworks to Mesoporous Materials with Ultrahigh Surface Area: Dynamic Reorganization of Porous Polymer Networks P. Kuhn, A. Forget, D. Su, A. Thomas, M. Antonietti Journal of the American Chemical Society 2008, 40, 13333–13337, 10.1021/ja803708s

41Gas-phase activation of methane by ligated transition-metal cations D. Schroder, H. Schwarz Proceedings of the National Academy of Sciences 2008, 47, 18114–18119, 10.1073/pnas.0801849105

40Gated Electron Transfer of Yeast Iso-1 Cytochrome c on Self-Assembled Monolayer-Coated Electrodes J. J. Feng, D. H. Murgida, U. Kuhlmann, T. Utesch, M. A. Mroginski, P. Hildebrandt, I. M. Weidinger The Journal of Physical Chemistry B 2008, 47, 15202–15211, 10.1021/jp8062383

39Gold Supported on Thin Oxide Films: From Single Atoms to Nanoparticles T. Risse, S. Shaikhutdinov, N. Nilius, M. Sterrer, H. J. Freund Accounts of Chemical Research Accounts of Chemical Research 2008, 8, 949–956, 10.1021/ar800078m

38Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts A. Thomas, A. Fischer, F. Goettmann, M. Antonietti, J. O. Müller, R. Schlögl, J. M. Carlsson Journal of Materials Chemistry 2008, 41, 4893– 10.1039/b800274f

37Human and Drosophila Cryptochromes Are Light Activated by Flavin Photoreduction in Living Cells N. Hoang, E. Schleicher, S. Kacprzak, J. P. Bouly, M. Picot, W. Wu, A. Berndt, E. Wolf, R. Bittl, M. Ahmad PLoS Biology 2008, 7, 10.1371/journal.pbio.0060160

36Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed by Ultrafast Infrared Spectroscopy C. Bonetti, T. Mathes, I. H. M. van Stokkum, K. M. Mullen, M. L. Groot, R. van Grondelle, P. Hegemann, J. T. M. Kennis Biophysical Journal Biophysical Journal 2008, 10, 4790–4802, 10.1529/biophysj.108.139246

35Hydrogen Production under Aerobic Conditions by Membrane-Bound Hydrogenases from Ralstonia Species G. Goldet, A. F. Wait, J. A. Cracknell, K. A. Vincent, M. Ludwig, O. Lenz, B. Friedrich, F. A. Armstrong Journal of the American Chemical Society 2008, 33, 11106–11113, 10.1021/ja8027668

34Influence of Carbon Deposition on the Hydrogen Distribution in Pd Nanoparticles and Their Reactivity in Olefin Hydrogenation M. Wilde, K. Fukutani, W. Ludwig, B. Brandt, J. H. Fischer, S. Schauermann, H. J. Freund Angewandte Chemie International Edition 2008, 48, 9289–9293, 10.1002/anie.200801923

33Insertion of Molecular Oxygen in Transition-Metal Hydride Bonds, Oxygen-Bond Activation, and Unimolecular Dissociation of Metal Hydroperoxide Intermediates. Short Communication M. Schlangen, H. Schwarz Helvetica Chimica Acta 2008, 3, 379–386, 10.1002/hlca.200890043

32Iridium derivatives of fluorinated aromatics by C–H activation: isolation of classical and non-classical hydrides M. A. Salomon, T. Braun, I. Krossing Dalton Transactions 2008, 38, 5197– 10.1039/b807077f

31Li atoms deposited on single crystalline MgO(001) surface. A combined experimental and theoretical study J. C. Lian, E. Finazzi, C. Di Valentin, T. Risse, H. J. Gao, G. Pacchioni, H. J. Freund Chemical Physics Letters 2008, 4, 308–311, 10.1016/j.cplett.2007.11.049

30Ligand Effects on the Mechanisms of Thermal Bond Activation in the Gas-Phase Reactions NiX /CH →Ni(CH ) /HX (X=H, CH , OH, F). Short Communication M. Schlangen, H. Schwarz Helvetica Chimica Acta 2008, 12, 2203–2210, 10.1002/hlca.200890238

29Linking density functional and density-matrix theory: Picosecond electron relaxation at the Si(100) surface N. Buecking, P. Kratzer, M. Scheffler, A. Knorr Physical Review B 2008, 23, 10.1103/PhysRevB.77.233305

28Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxideclusters K. Merz, M. Moreno, E. Löffler, L. Khodeir, A. Rittermeier, K. Fink, K. Kotsis, M. Muhler, M. Driess Chem. Commun. 2008, 1, 73–75, 10.1039/b714806b

27Low-Coordinate Iron Complexes Based on Bis(pyrazolyl)borate and Their Reactivity M. Wagner, C. Limberg, B. Ziemer European Journal of Inorganic Chemistry European Journal of Inorganic Chemistry 2008, 25, 3970–3976, 10.1002/ejic.200800314

26Metal-free activation of C–C multiple bonds through halide ion pairs: Diels–Alder reactions with subsequent aromatization H. Kaper, M. Antonietti, F. Goettmann Tetrahedron Letters 2008, 29, 4546–4549, 10.1016/j.tetlet.2008.05.027

25Module Extension of a Non-Ribosomal Peptide Synthetase of the Glycopeptide Antibiotic Balhimycin Produced by D. Butz, T. Schmiederer, B. Hadatsch, W. Wohlleben, T. Weber, R. D. Süssmuth ChemBioChem 2008, 8, 1195–1200, 10.1002/cbic.200800068

24On the Mechanisms of Degenerate Ligand Exchange in [M(CH3)]+/CH4 Couples (M=Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt) as Explored by Mass Spectrometric and Computational Studies: Oxidative Addition/Reductive Elimination versus σ-Complex-Assisted Metathesis M. Armélin, M. Schlangen, H. Schwarz Chemistry - A European Journal 2008, 17, 5229–5236, 10.1002/chem.200800029

23Oxidation of Anilines with Hydrogen Peroxide and Selenium Dioxide as ­Catalyst C. Gebhardt, B. Priewisch, E. Irran, K. Rück-Braun Synthesis 2008, 12, 1889–1894, 10.1055/s-2008-1067088

22Oxide ultra-thin films on metals: new materials for the design of supported metal catalysts H. J. Freund, G. Pacchioni Chemical Society Reviews 2008, 10, 2224– 10.1039/b718768h

21Photoinduced Processes in Riboflavin: Superposition of ππ*−nπ* States by Vibronic Coupling, Transfer of Vibrational Coherence, and Population Dynamics under Solvent Control A. Weigel, A. L. Dobryakov, M. Veiga, J. L. Pérez Lustres The Journal of Physical Chemistry A Journal Of Physical Chemistry A 2008, 47, 12054–12065, 10.1021/jp805962u

20Photosynthetic water oxidation at elevated dioxygen partial pressure monitored by time-resolved X-ray absorption measurements M. Haumann, A. Grundmeier, I. Zaharieva, H. Dau Proceedings of the National Academy of Sciences 2008, 45, 17384–17389, 10.1073/pnas.0802596105

19Preparation and Catalytic Performance\nof Novel Dimeric Tetranuclear Zinc Complexes in Hydroamination of\nAlkenes at Room Temperature M. Biyikal, K. Löhnwitz, P. Roesky, S. Blechert Synlett Synlett 2008, 20, 3106–3110, 10.1055/s-0028-1087418

18Properties of Alkali Metal Atoms Deposited on a MgO Surface: A Systematic Experimental and Theoretical Study E. Finazzi, C. Di Valentin, G. Pacchioni, M. Chiesa, E. Giamello, H. Gao, J. Lian, T. Risse, H. J. Freund Chemistry - A European Journal 2008, 14, 4404–4414, 10.1002/chem.200702012

17Raman excitation profiles of β -carotene - novel insights into the nature of the ν1-band N. Tschirner, M. Schenderlein, K. Brose, E. Schlodder, M. A. Mroginski, P. Hildebrandt, C. Thomsen physica status solidi (b) Physica Status Solidi B-Basic Solid State Physics 2008, 10, 2225–2228, 10.1002/pssb.200879649

16Red-shifted optogenetic excitation: a tool for fast neural control derived from Volvox carteri F. Zhang, M. Prigge, F. Beyrière, S. P. Tsunoda, J. Mattis, O. Yizhar, P. Hegemann, K. Deisseroth Nature Neuroscience 2008, 6, 631–633, 10.1038/nn.2120

15Redox-linked protein dynamics of cytochrome c probed by time-resolved surface enhanced infrared absorption spectroscopy N. Wisitruangsakul, I. Zebger, K. H. Ly, D. H. Murgida, S. Ekgasit, P. Hildebrandt Physical Chemistry Chemical Physics 2008, 34, 5276– 10.1039/b806528d

14Room-Temperature Alkyne-Nitrile Metathesis and Unambiguous Proof for the Existence of a High-Valent Iron-Nitrido Dication in the Gas Phase. Short Communication J. Boyd, M. Schlangen, A. Grohmann, H. Schwarz Helvetica Chimica Acta 2008, 8, 1430–1434, 10.1002/hlca.200890155

13SERR-Spectroelectrochemical Study of a Oxygen Reductase in a Biomimetic Construct S. Todorovic, A. Verissimo, N. Wisitruangsakul, I. Zebger, P. Hildebrandt, M. M. Pereira, M. Teixeira, D. H. Murgida The Journal of Physical Chemistry B 2008, 51, 16952–16959, 10.1021/jp807862m

12Silver Nanocoral Structures on Electrodes:  A Suitable Platform for Protein-Based Bioelectronic Devices J. J. Feng, P. Hildebrandt, D. H. Murgida Langmuir Langmuir 2008, 5, 1583–1586, 10.1021/la703092c

11Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C–H bond activation S. Yao, C. van Wüllen, M. Driess Chemical Communications 2008, 42, 5393– 10.1039/b811952j

10Structures of Neutral Au7, Au19, and Au20 Clusters in the Gas Phase P. Gruene, D. M. Rayner, B. Redlich, A. F. G. van der Meer, J. T. Lyon, G. Meijer, A. Fielicke Science 2008, 5889, 674–676, 10.1126/science.1161166

9Synthese, Charakterisierung und Reaktivität von Molybdänoxidnitriden S. Berendts, M. Huber, M. Weiß, M. Lehmann, T. Ressler, M. Lerch Zeitschrift für anorganische und allgemeine Chemie 2008, 11, 2029–2029, 10.1002/zaac.200870042

8The adsorption of CO on group 10 (Ni, Pd, Pt) transition-metal clusters P. Gruene, A. Fielicke, G. Meijer, D. M. Rayner Physical Chemistry Chemical Physics 2008, 40, 6144– 10.1039/b808341j

7The influence of a 2-component model on the computed regeneration behaviour of an uncoated diesel particulate filter M. Bogdanić, F. Behrendt, F. Mertins Chemical Engineering Science 2008, 10, 2601–2613, 10.1016/j.ces.2008.01.036

6The manganese complex of photosystem II in its reaction cycle—Basic framework and possible realization at the atomic level H. DAU, M. HAUMANN Coordination Chemistry Reviews Coordination Chemistry Reviews 2008, 3, 273–295, 10.1016/j.ccr.2007.09.001

5The Mechanism of Assembly and Cofactor Insertion into Xanthine Dehydrogenase S. Schumann, M. Saggu, N. Möller, S. D. Anker, F. Lendzian, P. Hildebrandt, S. Leimkühler Journal of Biological Chemistry 2008, 24, 16602–16611, 10.1074/jbc.M709894200

4Theory of ultrafast intraband relaxation in carbon nanotubes M. Hirtschulz, F. Milde, E. Malic, C. Thomsen, S. Reich, A. Knorr physica status solidi (b) Physica Status Solidi B-Basic Solid State Physics 2008, 10, 2164–2168, 10.1002/pssb.200879583

3Transient heat transfer in packed beds: The significance of the history term N. Zobel, F. Behrendt International Journal of Heat and Mass Transfer International Journal of Heat and Mass Transfer 2008, 15, 3816–3824, 10.1016/j.ijheatmasstransfer.2007.10.040

2Unique role of orbital angular momentum in subshell-resolved photoionization of C M. A. McCune, M. E. Madjet, H. S. Chakraborty Journal of Physics B: Atomic, Molecular and Optical Physics Journal of Physics B 2008, 20, 201003– 10.1088/0953-4075/41/20/201003

1When an Encapsulating Oxide Layer Promotes Reaction on Noble Metals: Dewetting and In situ Formation of an “Inverted” FeO x /Pt Catalyst Y. N. Sun, Z. H. Qin, M. Lewandowski, S. Kaya, S. Shaikhutdinov, H. J. Freund Catalysis Letters 2008, 1, 31–35, 10.1007/s10562-008-9643-x