Prof. Dr. Christian Limberg - Publications

2394 Extending the Toolbox for the Modular Arrangement of Functions at Xanthene/Dibenzofuran Platforms: Introduction of Directly Linked Transition Metals beside Bismuthanes K. Materne, C. Spröwitz, B. Braun-Cula, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2018, 644, 700–705, 10.1002/zaac.201800180

2313 Stabilization of β-Diketiminato Nickel(I) with Alkaline Metal Halide Entities for Small Molecule Activation P. Holze, B. Braun-Cula, S. Mebs, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2018, 10.1002/zaac.201800100

2312 A Biomimetic Nickel Complex with a Reduced CO2Ligand Generated by Formate Deprotonation and Its Behaviour towards CO2 P. Zimmermann, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg Angewandte Chemie International Edition 2018, 57, 7230–7233, 10.1002/anie.201802655

2252 Activation of Small Molecules at Nickel(I) Moieties P. Zimmermann, C. Limberg Journal of the American Chemical Society 2017, 139, 4233–4242, 10.1021/jacs.6b12434

2251 O2activation at a trispyrazolylborato nickel(ii) malonato complex S. Hoof, M. Sallmann, C. Herwig, B. Braun-Cula, C. Limberg Dalton Transactions 2017, 46, 16792–16795, 10.1039/c7dt04056c

2250 Copper(i) complexes based on ligand systems with two different binding sites: synthesis, structures and reaction with O2 S. T. Li, B. Braun-Cula, S. Hoof, C. Limberg Dalton Transactions 2018, 47, 544–560, 10.1039/c7dt03752j

2203 Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application M. P. Luecke, D. Porwal, A. Kostenko, Y. P. Zhou, S. Yao, M. Keck, C. Limberg, M. Oestreich, M. Driess Dalton Transactions 2017, 46, 16412–16418, 10.1039/C7DT03301J

2079 Activation of Dioxygen at a Lewis Acidic Nickel(II) Complex: Characterization of a Metastable Organoperoxide Complex P. Holze, T. Corona, N. Frank, B. Braun-Cula, C. Herwig, A. Company, C. Limberg Angewandte Chemie International Edition 2017, 10.1002/anie.201609526

2078 Ligands with Two Different Binding Sites and O2Reactivity of their Copper(I) Complexes S. T. Li, B. Braun-Cula, S. Hoof, M. Dürr, I. Ivanović-Burmazović, C. Limberg European Journal of Inorganic Chemistry 2016, 2016, 4017–4027, 10.1002/ejic.201600420

2077 Cyclohexane oxidative dehydrogenation over copper oxide catalysts S. L. Nauert, F. Schax, C. Limberg, J. M. Notestein Journal of Catalysis 2016, 341, 180–190, 10.1016/j.jcat.2016.07.002

2064 Structure and Mechanism Leading to Formation of the Cysteine Sulfinate Product Complex of a Biomimetic Cysteine Dioxygenase Model M. Sallmann, S. Kumar, P. Chernev, J. Nehrkorn, A. Schnegg, D. Kumar, H. Dau, C. Limberg, S. P. de Visser Chemistry - A European Journal 2015, 21, 7470–7479, 10.1002/chem.201500644

1844 Reactivity of an Octanuclear Copper(I) Siloxide Compound - Isolation of a Copper(II) Oxo Compound with a Supertetrahedral Core F. Schax, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2015, 641, 2060–2064, 10.1002/zaac.201500228

1843 A Structural and Functional Model for the 1-Aminocyclopropane-1-carboxylic Acid Oxidase M. Sallmann, F. Oldenburg, B. Braun, M. Réglier, A. J. Simaan, C. Limberg Angewandte Chemie International Edition 2015, 54, 12325–12328, 10.1002/anie.201502529

1842 Reaction of a polydentate cysteine-based ligand and its nickel(II) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity D. S. Warner, C. Limberg, F. J. Oldenburg, B. Braun Dalton Trans. 2015, 44, 18378–18385, 10.1039/C5DT02828K

1841 An iron(II) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity H. Gehring, R. Metzinger, B. Braun, C. Herwig, S. Harder, K. Ray, C. Limberg Dalton Trans. 2016, 45, 2989–2996, 10.1039/C5DT04266F

1622 A Heterobimetallic Superoxide Complex formed through O2 Activation between Chromium(II) and a Lithium Cation F. Schax, S. Suhr, E. Bill, B. Braun, C. Herwig, C. Limberg Angewandte Chemie International Edition 2015, 54, 1352–1356, 10.1002/anie.201409294

1621 Bioinspired Copper(I) Complexes that Exhibit Monooxygenase and Catechol Dioxygenase Activity A. Arnold, R. Metzinger, C. Limberg Chemistry - A European Journal 2015, 21, 1198–1207, 10.1002/chem.201405155

1620 Dioxygen Activation by Siloxide Complexes of Chromium(II) and Chromium(IV) F. Schax, E. Bill, C. Herwig, C. Limberg Angewandte Chemie International Edition 2014, 53, 12741–12745, 10.1002/anie.201406313

1619 A Cubic Fe4Mo4 Oxo Framework and Its Reversible Four-Electron Redox Chemistry J. P. Falkenhagen, B. Braun, E. Bill, D. Sattler, C. Limberg Inorganic Chemistry 2014, 53, 7294–7308, 10.1021/ic500584a

1618 Three-Coordinate Nickel(II) and Nickel(I) Thiolate Complexes Based on the β-Diketiminate Ligand System B. Horn, C. Limberg, C. Herwig, B. Braun Inorganic Chemistry 2014, 53, 6867–6874, 10.1021/ic500698v

1617 Molecular CuII-O-CuII Complexes: Still Waters Run Deep P. Haack, C. Limberg Angewandte Chemie International Edition 2014, 53, 4282–4293, 10.1002/anie.201309505

1616 A Tripodal Trisilanol Ligand and Its Complexation Behavior towards CuI, CuII, and ZnII F. Schax, B. Braun, C. Limberg European Journal of Inorganic Chemistry 2014, 2014, 2124–2130, 10.1002/ejic.201400088

1615 A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O2 Reactivity R. Metzinger, S. Demeshko, C. Limberg Chemistry - A European Journal 2014, 20, 4721–4735, 10.1002/chem.201304535

1537 Hydride Binding to the Active Site of [FeFe]-Hydrogenase P. Chernev, C. Lambertz, A. Brünje, N. Leidel, K. G. V. Sigfridsson, R. Kositzki, C. H. Hsieh, S. Yao, R. Schiwon, M. Driess, C. Limberg, T. Happe, M. Haumann Inorganic Chemistry 2014, 53, 12164–12177, 10.1021/ic502047q

1353 A High-Valent Heterobimetallic [Cu(III) (μ-O) Ni(III)]2+ Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie International Edition 2013, 52, 5622–5626, 10.1002/anie.201300861

1280 A High-Valent Heterobimetallic [Cu (μ-O) Ni ] Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie 2013, 125, 5732–5736, 10.1002/ange.201300861

1262 Shining light on integrity of a tetracobalt-polyoxometalate water oxidation catalyst by X-ray spectroscopy before and after catalysis R. Schiwon, K. Klingan, H. Dau, C. Limberg Chemical Communications 2014, 50, 100– 10.1039/C3CC46629A

1261 Iron–molybdenum-oxo complexes as initiators for olefin autoxidation with O2 J. P. Falkenhagen, C. Limberg, S. Demeshko, S. Horn, M. Haumann, B. Braun, S. Mebs Dalton Transactions 2014, 43, 806– 10.1039/c3dt52349g

1148 Nickel(i)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO2 generating NiICO, NiIICO3 and NiIIC2O4NiII entities B. Horn, C. Limberg, C. Herwig, B. Braun Chemical Communications 2013, 49, 10923–10925, 10.1039/c3cc45407j

1147 Access to a CuII–O–CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity P. Haack, A. Kärgel, C. Greco, J. Dokic, B. Braun, F. F. Pfaff, S. Mebs, K. Ray, C. Limberg Journal of the American Chemical Society 2013, 135, 16148–16160, 10.1021/ja406721a

1146 Chiral Tripodal Ligand Containing Three N-Heterocyclic Donor Functions and its Copper Complexes: Crystallization of [LCu(I)]2 2+ /[L2Cu(II)]2+ Stereoisomers and Tyrosinase Activity A. Arnold, C. Limberg, R. Metzinger Inorganic Chemistry Zeitschrift für anorganische und allgemeine Chemie 2012, 51, 12210–12217, 10.1021/ic301391s

1145 Synthesis of a Chiral, Polydentate Ligand System Setting Out from L-Cysteine and First Nickel Complexes Thereof D. S. Warner, C. Limberg, S. Mebs Zeitschrift für anorganische und allgemeine Chemie 2013, 639, 1577–1583, 10.1002/zaac.201300071

954 Hydride Reactivity of NiII-X-NiII-Entities: Mixed-valent Hydrido Complexes and Reversible Metal Reduction H. Gehring, R. Metzinger, C. Herwig, J. Intemann, S. Harder, C. Limberg Chemistry - A European Journal 2013, 19, 1629–1636, 10.1002/chem.201203201

953 CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate B. Horn, C. Limberg, C. Herwig, M. Feist, S. Mebs Chemical Communications 2012, 48, 8243–8245, 10.1039/c2cc33846g

951 Sulfur-linked Phenolates as Ligands for the Syntheses of Low-Nuclearity Iron(III) Complexes R. Metzinger, C. Limberg Zeitschrift für Anorganische und Allgemeine Chemie 2012, 638, 2225–2234, 10.1002/zaac.201200389

950 Copper(I) Siloxides – Aggregated solid state structures, Cu-Cu interactions and dynamic solution behavior F. Schax, C. Limberg, C. Mügge European Journal of Inorganic Chemistry 2012, 2012, 4661–4668, 10.1002/ejic.201200294

949 A Trispyrazolylborato-Iron-Cysteinato-Complex as a functional Model for the Cysteine-Dioxygenase M. Sallmann, I. Siewert, L. Fohlmeister, C. Limberg, C. Knispel Angewandte Chemie International Edition 2012, 51, 2234–2237, 10.1002/anie.201107345

844 Activation and Coordination of Ammonia at [Cp*Ir(H)2]: NMR and Matrix Isolation Studies T. Braun, C. Limberg, A. K. Jungton, C. Herwig Chemistry - A European Journal 2012, 18, 10009–10013, 10.1002/chem.201201295

788 The Conversion of Nickel-Bound CO to an Acetyl Thioester: Organometallic Chemistry Relevant to the Acetyl Co-enzyme A Synthase Active Site B. Horn, C. Limberg, C. Herwig, S. Mebs Angewandte Chemie International Edition 2011, 50, 12621–12625, 10.1002/anie.201105281

787 Organoelement Complexes of a Dinucleating Double β-Diiminato Ligand - Precedent Cases from Groups 1, 2 and 13 J. P. Falkenhagen, P. Haack, C. Limberg, B. Braun Zeitschrift für Anorganische und Allgemeine Chemie 2011, 637, 1741–1749, 10.1002/zaac.201100352

786 Four-coordinate Trispyrazolylborato Manganese and Iron Complexes with a Pyrazolato Co-ligand: Syntheses and Properties as Oxidation Catalysts T. Tietz, C. Limberg, R. Stößer, B. Ziemer Chemistry - A European Journal 2011, 17, 10010–10020, 10.1002/chem.201100343

785 N2 Activation in NiI-NN-NiI units: The Influence of Alkali Metal Cations and CO Reactivity B. Horn, S. Pfirrmann, C. Limberg, C. Herwig, B. Braun, S. Mebs, R. Metzinger Zeitschrift für Anorganische und Allgemeine Chemie 2011, 637, 1169–1174, 10.1002/zaac.201100140

527 Unprecedented Binding and Activation of CS2 in a Dinuclear Copper(I) Complex P. Haack, C. Limberg, T. Tietz, R. Metzinger Chemical Communications 2011, 10.1039/c1cc11518a

526 The Mechanism of Water Oxidation: From Electrolysis via Homogenous to Biological Catalysis H. Dau, C. Limberg, T. Reier, M. Risch, S. Roggan, P. Strasser ChemCatChem 2010, 2, 724–761, 10.1002/cctc.201000126

525 Monooxygenase-Like Reactivity of an Unprecedented Heterobimetallic {FeO2Ni} Moiety S. Yao, C. Herwig, Y. Xiong, A. Company, E. Bill, C. Limberg, M. Driess Angewandte Chemie International Edition 2010, 49, 7054–7058, 10.1002/anie.201001914

494 Dinuclear Copper Complexes Based on Parallel ß-Diiminato Binding Sites and their Reactions with O2: Evidence for a Cu-O-Cu Entity P. Haack, C. Limberg, K. Ray, B. Braun, U. Kuhlmann, P. Hildebrandt, C. Herwig Inorganic Chemistry 2011, 50, 2133–2142, 10.1021/ic101249k

428 A reduced Beta-diketiminato-ligated Ni3H4 unit catalyzing H/D exchange C. Limberg, S. Pfirrmann, C. Herwig, C. Knispel, B. Braun, R. Stößer, E. Bill Journal of the American Chemical Society 2010, 132, 13684–13691, 10.1021/ja106266v

293 Reversible P4 Activation with Nickel(I) and an Eta3-Coordinated Tetraphosphorus Ligand between Two NiI Centers S. Yao, Y. Xiong, C. Milsmann, E. Bill, S. Pfirrmann, C. Limberg, M. Driess Chemistry - A European Journal 2010, 16, 436–439, 10.1002/chem.200902820

292 Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein O. Sanganas, S. Löscher, S. Pfirrmann, N. Marinos, P. Glatzel, T. C. Weng, C. Limberg, M. Driess, H. Dau, M. Haumann Journal of Physics: Conference Series 2009, 190, 12199–12199, 10.1088/1742-6596/190/1/012199

284 O-O Bond Activation in Heterobimetallic Peroxides: Synthesis of the Peroxide [LNi(My,Eta2:Eta2-O2)K] and its Conversion into a Bis(My-Hydroxo) Nickel Zinc Complex S. Yao, Y. Xiong, M. Vogt, H. Grützmacher, C. Herwig, C. Limberg, M. Driess Angewandte Chemie International Edition 2009, 48, 8107–8110, 10.1002/anie.200903772

272 Beta-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing For H2 and N2 Activation C. Limberg, S. Pfirrmann, S. Yao, B. Ziemer, R. Stößer, M. Driess Organometallics 2009, 28, 6855–6860, 10.1021/om9007983

271 Low-Molecular Weight Analogues of the Soluble Methane Monooxygenase: From the Structural Mimicking of Resting-States and Intermediates to Functional Models C. Limberg, I. Siewert Chemistry - A European Journal 2009, 15, 10316–10328, 10.1002/chem.200901910

270 Stabilizing the Boat Conformation of Piperazines Coordinated to IronII: iso­Butyl Substituents Lead to Robust Oxidation Catalysts via Hyperconjugation C. Limberg, M. Ostermeier, C. Herwig, B. Ziemer Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 1823–1830, 10.1002/zaac.200900275

269 A Dinuclear Iron Complex Based on Parallel Malonate Binding Sites: Cooperative Activation of Dioxygen and Biomimetic Ligand Oxidation C. Limberg, I. Siewert, S. Demeshko, E. Hoppe Chemistry - A European Journal 2008, 14, 9377–9388, 10.1002/chem.200800955

176 A Novel Tripodal Ligand Containing Three Different N-Heterocyclic Donor Functions and Its Application in Catechol Dioxygenase Mimicking C. Limberg, M. Wagner, T. Tietz Chemistry - A European Journal 2009, 15, 5567–5576, 10.1002/chem.200802591

25 A Dinuclear NiI-Dinitrogen Complex and its Reduction in Single Electron Steps C. Limberg, S. Pfirrmann, C. Herwig, R. Stößer, B. Ziemer Angewandte Chemie International Edition 2009, 48, 3357–3361, 10.1002/anie.200805862

24 ß-Diketiminato ligands with Thioether Tethers C. Limberg, S. Pfirrmann, E. Hoppe Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 312–316, 10.1002/zaac.200800411

23 A low-coordinate nickel(II) hydride complex and its reactivity C. Limberg, S. Pfirrmann, B. Ziemer Dalton Transactions 2008, 47, 6689–6691, 10.1039/B816136B

22 A Trispyrazolylborato Iron Malonato Complex as a Functional Model for the Acetylacetone Dioxygenase C. Limberg, I. Siewert Angewandte Chemie International Edition 2008, 47, 7953–7956, 10.1002/anie.200802955

20 Low-Coordinate Iron Complexes Based on Bis(pyrazolyl)borate and Their Reactivity C. Limberg, M. Wagner, B. Ziemer European Journal of Inorganic Chemistry 2008, 25, 3970–3976, 10.1002/ejic.200800314

19 Dinuclear iron complexes based on parallel ß-diiminato binding sites: syntheses, structures and reaction with O2 C. Limberg, M. F. Pilz, S. Demeshko, F. Meyer, B. Ziemer Dalton Transactions 2008, 14, 1917–1923, 10.1039/b715376g