2313 Stabilization of β-Diketiminato Nickel(I) with Alkaline Metal Halide Entities for Small Molecule Activation P. Holze, B. Braun-Cula, S. Mebs, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2018, 10.1002/zaac.201800100
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2312 A Biomimetic Nickel Complex with a Reduced CO2Ligand Generated by Formate Deprotonation and Its Behaviour towards CO2 P. Zimmermann, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg Angewandte Chemie International Edition 2018, 57, 7230–7233, 10.1002/anie.201802655
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2252 Activation of Small Molecules at Nickel(I) Moieties P. Zimmermann, C. Limberg Journal of the American Chemical Society 2017, 139, 4233–4242, 10.1021/jacs.6b12434
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2251 O2activation at a trispyrazolylborato nickel(ii) malonato complex S. Hoof, M. Sallmann, C. Herwig, B. Braun-Cula, C. Limberg Dalton Transactions 2017, 46, 16792–16795, 10.1039/c7dt04056c
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2250 Copper(i) complexes based on ligand systems with two different binding sites: synthesis, structures and reaction with O2 S. T. Li, B. Braun-Cula, S. Hoof, C. Limberg Dalton Transactions 2018, 47, 544–560, 10.1039/c7dt03752j
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2203 Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application M. P. Luecke, D. Porwal, A. Kostenko, Y. P. Zhou, S. Yao, M. Keck, C. Limberg, M. Oestreich, M. Driess Dalton Transactions 2017, 46, 16412–16418, 10.1039/C7DT03301J
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2079 Activation of Dioxygen at a Lewis Acidic Nickel(II) Complex: Characterization of a Metastable Organoperoxide Complex P. Holze, T. Corona, N. Frank, B. Braun-Cula, C. Herwig, A. Company, C. Limberg Angewandte Chemie International Edition 2017, 10.1002/anie.201609526
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2078 Ligands with Two Different Binding Sites and O2Reactivity of their Copper(I) Complexes S. T. Li, B. Braun-Cula, S. Hoof, M. Dürr, I. Ivanović-Burmazović, C. Limberg European Journal of Inorganic Chemistry 2016, 2016, 4017–4027, 10.1002/ejic.201600420
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2077 Cyclohexane oxidative dehydrogenation over copper oxide catalysts S. L. Nauert, F. Schax, C. Limberg, J. M. Notestein Journal of Catalysis 2016, 341, 180–190, 10.1016/j.jcat.2016.07.002
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2064 Structure and Mechanism Leading to Formation of the Cysteine Sulfinate Product Complex of a Biomimetic Cysteine Dioxygenase Model M. Sallmann, S. Kumar, P. Chernev, J. Nehrkorn, A. Schnegg, D. Kumar, H. Dau, C. Limberg, S. P. de Visser Chemistry - A European Journal 2015, 21, 7470–7479, 10.1002/chem.201500644
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1844 Reactivity of an Octanuclear Copper(I) Siloxide Compound - Isolation of a Copper(II) Oxo Compound with a Supertetrahedral Core F. Schax, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2015, 641, 2060–2064, 10.1002/zaac.201500228
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1843 A Structural and Functional Model for the 1-Aminocyclopropane-1-carboxylic Acid Oxidase M. Sallmann, F. Oldenburg, B. Braun, M. Réglier, A. J. Simaan, C. Limberg Angewandte Chemie International Edition 2015, 54, 12325–12328, 10.1002/anie.201502529
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1842 Reaction of a polydentate cysteine-based ligand and its nickel(II) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity D. S. Warner, C. Limberg, F. J. Oldenburg, B. Braun Dalton Trans. 2015, 44, 18378–18385, 10.1039/C5DT02828K
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1841 An iron(II) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity H. Gehring, R. Metzinger, B. Braun, C. Herwig, S. Harder, K. Ray, C. Limberg Dalton Trans. 2016, 45, 2989–2996, 10.1039/C5DT04266F
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1622 A Heterobimetallic Superoxide Complex formed through O2 Activation between Chromium(II) and a Lithium Cation F. Schax, S. Suhr, E. Bill, B. Braun, C. Herwig, C. Limberg Angewandte Chemie International Edition 2015, 54, 1352–1356, 10.1002/anie.201409294
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1621 Bioinspired Copper(I) Complexes that Exhibit Monooxygenase and Catechol Dioxygenase Activity A. Arnold, R. Metzinger, C. Limberg Chemistry - A European Journal 2015, 21, 1198–1207, 10.1002/chem.201405155
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1620 Dioxygen Activation by Siloxide Complexes of Chromium(II) and Chromium(IV) F. Schax, E. Bill, C. Herwig, C. Limberg Angewandte Chemie International Edition 2014, 53, 12741–12745, 10.1002/anie.201406313
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1619 A Cubic Fe4Mo4 Oxo Framework and Its Reversible Four-Electron Redox Chemistry J. P. Falkenhagen, B. Braun, E. Bill, D. Sattler, C. Limberg Inorganic Chemistry 2014, 53, 7294–7308, 10.1021/ic500584a
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1618 Three-Coordinate Nickel(II) and Nickel(I) Thiolate Complexes Based on the β-Diketiminate Ligand System B. Horn, C. Limberg, C. Herwig, B. Braun Inorganic Chemistry 2014, 53, 6867–6874, 10.1021/ic500698v
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1617 Molecular CuII-O-CuII Complexes: Still Waters Run Deep P. Haack, C. Limberg Angewandte Chemie International Edition 2014, 53, 4282–4293, 10.1002/anie.201309505
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1616 A Tripodal Trisilanol Ligand and Its Complexation Behavior towards CuI, CuII, and ZnII F. Schax, B. Braun, C. Limberg European Journal of Inorganic Chemistry 2014, 2014, 2124–2130, 10.1002/ejic.201400088
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1615 A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O2 Reactivity R. Metzinger, S. Demeshko, C. Limberg Chemistry - A European Journal 2014, 20, 4721–4735, 10.1002/chem.201304535
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1537 Hydride Binding to the Active Site of [FeFe]-Hydrogenase P. Chernev, C. Lambertz, A. Brünje, N. Leidel, K. G. V. Sigfridsson, R. Kositzki, C. H. Hsieh, S. Yao, R. Schiwon, M. Driess, C. Limberg, T. Happe, M. Haumann Inorganic Chemistry 2014, 53, 12164–12177, 10.1021/ic502047q
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1353 A High-Valent Heterobimetallic [Cu(III) (μ-O) Ni(III)]2+ Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie International Edition 2013, 52, 5622–5626, 10.1002/anie.201300861
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1280 A High-Valent Heterobimetallic [Cu (μ-O) Ni ] Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie 2013, 125, 5732–5736, 10.1002/ange.201300861
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1262 Shining light on integrity of a tetracobalt-polyoxometalate water oxidation catalyst by X-ray spectroscopy before and after catalysis R. Schiwon, K. Klingan, H. Dau, C. Limberg Chemical Communications 2014, 50, 100– 10.1039/C3CC46629A
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1261 Iron–molybdenum-oxo complexes as initiators for olefin autoxidation with O2 J. P. Falkenhagen, C. Limberg, S. Demeshko, S. Horn, M. Haumann, B. Braun, S. Mebs Dalton Transactions 2014, 43, 806– 10.1039/c3dt52349g
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1148 Nickel(i)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO2 generating NiICO, NiIICO3 and NiIIC2O4NiII entities B. Horn, C. Limberg, C. Herwig, B. Braun Chemical Communications 2013, 49, 10923–10925, 10.1039/c3cc45407j
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1147 Access to a CuII–O–CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity P. Haack, A. Kärgel, C. Greco, J. Dokic, B. Braun, F. F. Pfaff, S. Mebs, K. Ray, C. Limberg Journal of the American Chemical Society 2013, 135, 16148–16160, 10.1021/ja406721a
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1146 Chiral Tripodal Ligand Containing Three N-Heterocyclic Donor Functions and its Copper Complexes: Crystallization of [LCu(I)]2 2+ /[L2Cu(II)]2+ Stereoisomers and Tyrosinase Activity A. Arnold, C. Limberg, R. Metzinger Inorganic Chemistry Zeitschrift für anorganische und allgemeine Chemie 2012, 51, 12210–12217, 10.1021/ic301391s
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1145 Synthesis of a Chiral, Polydentate Ligand System Setting Out from L-Cysteine and First Nickel Complexes Thereof D. S. Warner, C. Limberg, S. Mebs Zeitschrift für anorganische und allgemeine Chemie 2013, 639, 1577–1583, 10.1002/zaac.201300071
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954 Hydride Reactivity of NiII-X-NiII-Entities: Mixed-valent Hydrido Complexes and Reversible Metal Reduction H. Gehring, R. Metzinger, C. Herwig, J. Intemann, S. Harder, C. Limberg Chemistry - A European Journal 2013, 19, 1629–1636, 10.1002/chem.201203201
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953 CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate B. Horn, C. Limberg, C. Herwig, M. Feist, S. Mebs Chemical Communications 2012, 48, 8243–8245, 10.1039/c2cc33846g
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951 Sulfur-linked Phenolates as Ligands for the Syntheses of Low-Nuclearity Iron(III) Complexes R. Metzinger, C. Limberg Zeitschrift für Anorganische und Allgemeine Chemie 2012, 638, 2225–2234, 10.1002/zaac.201200389
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950 Copper(I) Siloxides – Aggregated solid state structures, Cu-Cu interactions and dynamic solution behavior F. Schax, C. Limberg, C. Mügge European Journal of Inorganic Chemistry 2012, 2012, 4661–4668, 10.1002/ejic.201200294
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949 A Trispyrazolylborato-Iron-Cysteinato-Complex as a functional Model for the Cysteine-Dioxygenase M. Sallmann, I. Siewert, L. Fohlmeister, C. Limberg, C. Knispel Angewandte Chemie International Edition 2012, 51, 2234–2237, 10.1002/anie.201107345
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844 Activation and Coordination of Ammonia at [Cp*Ir(H)2]: NMR and Matrix Isolation Studies T. Braun, C. Limberg, A. K. Jungton, C. Herwig Chemistry - A European Journal 2012, 18, 10009–10013, 10.1002/chem.201201295
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788 The Conversion of Nickel-Bound CO to an Acetyl Thioester: Organometallic Chemistry Relevant to the Acetyl Co-enzyme A Synthase Active Site B. Horn, C. Limberg, C. Herwig, S. Mebs Angewandte Chemie International Edition 2011, 50, 12621–12625, 10.1002/anie.201105281
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787 Organoelement Complexes of a Dinucleating Double β-Diiminato Ligand - Precedent Cases from Groups 1, 2 and 13 J. P. Falkenhagen, P. Haack, C. Limberg, B. Braun Zeitschrift für Anorganische und Allgemeine Chemie 2011, 637, 1741–1749, 10.1002/zaac.201100352
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786 Four-coordinate Trispyrazolylborato Manganese and Iron Complexes with a Pyrazolato Co-ligand: Syntheses and Properties as Oxidation Catalysts T. Tietz, C. Limberg, R. Stößer, B. Ziemer Chemistry - A European Journal 2011, 17, 10010–10020, 10.1002/chem.201100343
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785 N2 Activation in NiI-NN-NiI units: The Influence of Alkali Metal Cations and CO Reactivity B. Horn, S. Pfirrmann, C. Limberg, C. Herwig, B. Braun, S. Mebs, R. Metzinger Zeitschrift für Anorganische und Allgemeine Chemie 2011, 637, 1169–1174, 10.1002/zaac.201100140
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527 Unprecedented Binding and Activation of CS2 in a Dinuclear Copper(I) Complex P. Haack, C. Limberg, T. Tietz, R. Metzinger Chemical Communications 2011, 10.1039/c1cc11518a
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526 The Mechanism of Water Oxidation: From Electrolysis via Homogenous to Biological Catalysis H. Dau, C. Limberg, T. Reier, M. Risch, S. Roggan, P. Strasser ChemCatChem 2010, 2, 724–761, 10.1002/cctc.201000126
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525 Monooxygenase-Like Reactivity of an Unprecedented Heterobimetallic {FeO2Ni} Moiety S. Yao, C. Herwig, Y. Xiong, A. Company, E. Bill, C. Limberg, M. Driess Angewandte Chemie International Edition 2010, 49, 7054–7058, 10.1002/anie.201001914
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494 Dinuclear Copper Complexes Based on Parallel ß-Diiminato Binding Sites and their Reactions with O2: Evidence for a Cu-O-Cu Entity P. Haack, C. Limberg, K. Ray, B. Braun, U. Kuhlmann, P. Hildebrandt, C. Herwig Inorganic Chemistry 2011, 50, 2133–2142, 10.1021/ic101249k
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428 A reduced Beta-diketiminato-ligated Ni3H4 unit catalyzing H/D exchange C. Limberg, S. Pfirrmann, C. Herwig, C. Knispel, B. Braun, R. Stößer, E. Bill Journal of the American Chemical Society 2010, 132, 13684–13691, 10.1021/ja106266v
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293 Reversible P4 Activation with Nickel(I) and an Eta3-Coordinated Tetraphosphorus Ligand between Two NiI Centers S. Yao, Y. Xiong, C. Milsmann, E. Bill, S. Pfirrmann, C. Limberg, M. Driess Chemistry - A European Journal 2010, 16, 436–439, 10.1002/chem.200902820
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292 Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein O. Sanganas, S. Löscher, S. Pfirrmann, N. Marinos, P. Glatzel, T. C. Weng, C. Limberg, M. Driess, H. Dau, M. Haumann Journal of Physics: Conference Series 2009, 190, 12199–12199, 10.1088/1742-6596/190/1/012199
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284 O-O Bond Activation in Heterobimetallic Peroxides: Synthesis of the Peroxide [LNi(My,Eta2:Eta2-O2)K] and its Conversion into a Bis(My-Hydroxo) Nickel Zinc Complex S. Yao, Y. Xiong, M. Vogt, H. Grützmacher, C. Herwig, C. Limberg, M. Driess Angewandte Chemie International Edition 2009, 48, 8107–8110, 10.1002/anie.200903772
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272 Beta-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing For H2 and N2 Activation C. Limberg, S. Pfirrmann, S. Yao, B. Ziemer, R. Stößer, M. Driess Organometallics 2009, 28, 6855–6860, 10.1021/om9007983
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271 Low-Molecular Weight Analogues of the Soluble Methane Monooxygenase: From the Structural Mimicking of Resting-States and Intermediates to Functional Models C. Limberg, I. Siewert Chemistry - A European Journal 2009, 15, 10316–10328, 10.1002/chem.200901910
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270 Stabilizing the Boat Conformation of Piperazines Coordinated to IronII: isoButyl Substituents Lead to Robust Oxidation Catalysts via Hyperconjugation C. Limberg, M. Ostermeier, C. Herwig, B. Ziemer Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 1823–1830, 10.1002/zaac.200900275
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269 A Dinuclear Iron Complex Based on Parallel Malonate Binding Sites: Cooperative Activation of Dioxygen and Biomimetic Ligand Oxidation C. Limberg, I. Siewert, S. Demeshko, E. Hoppe Chemistry - A European Journal 2008, 14, 9377–9388, 10.1002/chem.200800955
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176 A Novel Tripodal Ligand Containing Three Different N-Heterocyclic Donor Functions and Its Application in Catechol Dioxygenase Mimicking C. Limberg, M. Wagner, T. Tietz Chemistry - A European Journal 2009, 15, 5567–5576, 10.1002/chem.200802591
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25 A Dinuclear NiI-Dinitrogen Complex and its Reduction in Single Electron Steps C. Limberg, S. Pfirrmann, C. Herwig, R. Stößer, B. Ziemer Angewandte Chemie International Edition 2009, 48, 3357–3361, 10.1002/anie.200805862
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24 ß-Diketiminato ligands with Thioether Tethers C. Limberg, S. Pfirrmann, E. Hoppe Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 312–316, 10.1002/zaac.200800411
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23 A low-coordinate nickel(II) hydride complex and its reactivity C. Limberg, S. Pfirrmann, B. Ziemer Dalton Transactions 2008, 47, 6689–6691, 10.1039/B816136B
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22 A Trispyrazolylborato Iron Malonato Complex as a Functional Model for the Acetylacetone Dioxygenase C. Limberg, I. Siewert Angewandte Chemie International Edition 2008, 47, 7953–7956, 10.1002/anie.200802955
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20 Low-Coordinate Iron Complexes Based on Bis(pyrazolyl)borate and Their Reactivity C. Limberg, M. Wagner, B. Ziemer European Journal of Inorganic Chemistry 2008, 25, 3970–3976, 10.1002/ejic.200800314
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19 Dinuclear iron complexes based on parallel ß-diiminato binding sites: syntheses, structures and reaction with O2 C. Limberg, M. F. Pilz, S. Demeshko, F. Meyer, B. Ziemer Dalton Transactions 2008, 14, 1917–1923, 10.1039/b715376g
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