Publications 2013

Number of records: 203

203 Characterization of [4Fe-4S] Cluster Vibrations and Structure in Nitrogenase Fe Protein at Three Oxidation Levels via Combined NRVS, EXAFS, and DFT Analyses D. Mitra, S. J. George, Y. Guo, S. Kamali, S. Keable, J. W. Peters, V. Pelmenschikov, D. A. Case, S. P. Cramer Journal of the American Chemical Society 2013, 135, 2530–2543, 10.1021/ja307027n

202 Future of Biosensors: A Personal View F. W. Scheller, A. Yaman, T. Bachmann, T. Hirsch, S. Kubick, R. Renneberg, S. Schumacher, U. Wollenberger, C. Teller, F. F. Bier Advances in Biochemical Engineering/Biotechnology 2013, 140, 1–28, 10.1007/10_2013_251

201 Effect of the Protonation Degree of a Self-Assembled Monolayer on the Immobilization Dynamics of a [NiFe] Hydrogenase T. Utesch, D. Millo, M. A. Castro, P. Hildebrandt, I. Zebger, M. A. Mroginski Langmuir 2013, 29, 673–682, 10.1021/la303635q

200 Unraveling the Interfacial Electron Transfer Dynamics of Electroactive Microbial Biofilms Using Surface-Enhanced Raman Spectroscopy H. K. Ly, F. Harnisch, S. F. Hong, U. Schröder, P. Hildebrandt, D. Millo ChemSusChem 2013, 6, 487–492, 10.1002/cssc.201200626

199 Disentangling Electron Tunneling and Protein Dynamics of Cytochrome through a Rationally Designed Surface Mutation D. Alvarez-Paggi, W. Meister, U. Kuhlmann, I. Weidinger, K. Tenger, L. Zimányi, G. Rákhely, P. Hildebrandt, D. H. Murgida The Journal of Physical Chemistry B The Journal of Physical Chemistry B 2013, 117, 6061–6068, 10.1021/jp400832m

198 Morphology and Luminescence of ZnO Films Grown on a Au(111) Support F. Stavale, L. Pascua, N. Nilius, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2013, 117, 10552–10557, 10.1021/jp401939x

197 Identification of Crucial Amino Acids in Mouse Aldehyde Oxidase 3 That Determine Substrate Specificity M. Mahro, N. F. Brás, N. M. F. S. A. Cerqueira, C. Teutloff, C. Coelho, M. J. Romão, S. Leimkühler PLoS ONE 2013, 8, 10.1371/journal.pone.0082285

196 Facile Access to Mono- and Dinuclear Heteroleptic N-Heterocyclic Silylene Copper Complexes G. Tan, B. Blom, D. Gallego, M. Driess Organometallics 2013, 33, 363–369, 10.1021/om4011033

195 Bis- -Heterocyclic Carbene (NHC) Stabilized η -Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity B. Blom, G. Tan, S. Enthaler, S. Inoue, J. D. Epping, M. Driess Journal of the American Chemical Society 2013, 135, 18108–18120, 10.1021/ja410234x

194 A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene Y. Xiong, S. Yao, G. Tan, S. Inoue, M. Driess Journal of the American Chemical Society 2013, 135, 5004–5007, 10.1021/ja402477w

193 N-Heterocyclic Silylene (NHSi) Rhodium and Iridium Complexes: Synthesis, Structure, Reactivity, and Catalytic Ability M. Stoelzel, C. Präsang, B. Blom, M. Driess Australian Journal of Chemistry 2013, 66, 1163– 10.1071/CH13196

192 Dimensionally Stable Ru/Ir/TiO -Anodes with Tailored Mesoporosity for Efficient Electrochemical Chlorine Evolution N. Menzel, E. Ortel, K. Mette, R. Kraehnert, P. Strasser ACS Catalysis 2013, 3, 1324–1333, 10.1021/cs4000238

191 Micelle-Templated Oxides and Carbonates of Zinc, Cobalt, and Aluminum and a Generalized Strategy for Their Synthesis B. Eckhardt, E. Ortel, D. Bernsmeier, J. Polte, P. Strasser, U. Vainio, F. Emmerling, R. Kraehnert Chemistry of Materials 2013, 25, 2749–2758, 10.1021/cm400535d

190 Size-Controlled Synthesis of Colloidal Silver Nanoparticles Based on Mechanistic Understanding M. Wuithschick, B. Paul, R. Bienert, A. Sarfraz, U. Vainio, M. Sztucki, R. Kraehnert, P. Strasser, K. Rademann, F. Emmerling, J. Polte Chemistry of Materials 2013, 25, 4679–4689, 10.1021/cm401851g

189 Electrocatalytic Oxygen Evolution Reaction on Iridium Oxide Model Film Catalysts: Influence of Oxide Type and Catalyst Substrate Interactions T. Reier, I. Weidinger, P. Hildebrandt, R. Kraehnert, P. Strasser ECS Transactions ECS Transactions 2013, 58, 39–51, 10.1149/05802.0039ecst

188 Occurrence and biosynthesis of C-demethylactinomycins in actinomycin-producing Streptomyces chrysomallus and Streptomyces parvulus I. Crnovčić, J. Vater, U. Keller The Journal of Antibiotics 2013, 66, 211–218, 10.1038/ja.2012.120

187 Nitrogen- and phosphorus-co-doped carbons with tunable enhanced surface areas promoted by the doping additives J. P. Paraknowitsch, Y. Zhang, B. Wienert, A. Thomas Chemical Communications 2013, 49, 1208– 10.1039/c2cc37398j

186 Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications J. P. Paraknowitsch, A. Thomas Energy & Environmental Science 2013, 6, 2839– 10.1039/C3EE41444B

185 Covalent Triazine Frameworks Prepared from 1,3,5-Tricyanobenzene P. Katekomol, J. Roeser, M. Bojdys, J. Weber, A. Thomas Chemistry of Materials 2013, 25, 1542–1548, 10.1021/cm303751n

184 Dendritic Fluoroalcohols as Catalysts for Alkene Epoxidation with Hydrogen Peroxide A. Berkessel, J. Krämer, F. Mummy, J. M. Neudörfl, R. Haag Angewandte Chemie International Edition 2013, 52, 739–743, 10.1002/anie.201206003

183 Methane Coupling over Magnesium Oxide: How Doping Can Work P. Schwach, M. G. Willinger, A. Trunschke, R. Schlögl Angewandte Chemie International Edition 2013, 52, 11381–11384, 10.1002/anie.201305470

182 Effect of Exchange of the Cysteine Molybdenum Ligand with Selenocysteine on the Structure and Function of the Active Site in Human Sulfite Oxidase S. Reschke, D. Niks, H. Wilson, K. G. V. Sigfridsson, M. Haumann, K. V. Rajagopalan, R. Hille, S. Leimkühler Biochemistry 2013, 52, 8295–8303, 10.1021/bi4008512

181 A High-Valent Heterobimetallic [Cu (μ-O) Ni ] Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie International Edition 2013, 52, 5622–5626, 10.1002/anie.201300861

180 Active Mixed-Valent MnO Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles A. Indra, P. W. Menezes, I. Zaharieva, E. Baktash, J. Pfrommer, M. Schwarze, H. Dau, M. Driess Angewandte Chemie International Edition 2013, 52, 13206–13210, 10.1002/anie.201307543

179 Artificial photosynthesis as a frontier technology for energy sustainability T. Faunce, S. Styring, M. R. Wasielewski, G. W. Brudvig, A. W. Rutherford, J. Messinger, A. F. Lee, C. L. Hill, H. deGroot, M. Fontecave, D. R. MacFarlane, B. Hankamer, D. G. Nocera, D. M. Tiede, H. Dau, W. Hillier, L. Wang, R. Amal Energy & Environmental Science 2013, 6, 1074– 10.1039/C3ee40534f

178 Electrochemical water splitting by layered and 3D cross-linked manganese oxides: correlating structural motifs and catalytic activity A. Bergmann, I. Zaharieva, H. Dau, P. Strasser Energy & Environmental Science 2013, 6, 2745– 10.1039/C3ee41194j

177 Cyanamide route to calcium–manganese oxide foams for water oxidation E. Baktash, I. Zaharieva, M. Schröder, C. Goebel, H. Dau, A. Thomas Dalton Transactions Dalton Transactions 2013, 42, 16920– 10.1039/c3dt51693h

176 Synthesis of Asymmetrically Substituted Terpyridines by Palladium‐Catalyzed Direct CH Arylation of Pyridine ‐Oxides S. Duric, F. D. Sypaseuth, S. Hoof, E. Svensson, C. C. Tzschucke Chemistry – A European Journal 2013, 19, 17456–17463, 10.1002/chem.201302118

175 Stability and Metastability of Clusters in a Reactive Atmosphere: Theoretical Evidence for Unexpected Stoichiometries of S. Bhattacharya, S. V. Levchenko, L. M. Ghiringhelli, M. Scheffler Physical Review Letters 2013, 111, 10.1103/PhysRevLett.111.135501

174 Expanded genetic code for the engineering of ribosomally synthetized and post-translationally modified peptide natural products (RiPPs) N. Budisa Current Opinion in Biotechnology 2013, 24, 591–598, 10.1016/j.copbio.2013.02.026

173 Non-canonical amino acids as a useful synthetic biological tool for lipase-catalysed reactions in hostile environments C. G. Acevedo-Rocha, M. G. Hoesl, S. Nehring, M. Royter, C. Wolschner, B. Wiltschi, G. Antranikian, N. Budisa Catalysis Science & Technology Catalysis Science & Technology 2013, 3, 1198– 10.1039/c3cy20712a

172 Biocatalytic synthesis of (2S)-5,5,5-trifluoroleucine and improved resolution into (2S,4S) and (2S,4R) diastereoisomers H. Biava, N. Budisa Tetrahedron Letters 2013, 54, 3662–3665, 10.1016/j.tetlet.2013.04.128

171 Obtention of enantiomerically pure 5,5,5-trifluoro-l-isoleucine and 5,5,5-trifluoro-l-alloisoleucine H. Biava, N. Budisa Journal of Fluorine Chemistry Journal of Fluorine Chemistry 2013, 156, 372–377, 10.1016/j.jfluchem.2013.07.021

170 Enhanced production of the nonribosomal peptide antibiotic valinomycin in Escherichia coli through small-scale high cell density fed-batch cultivation J. Li, J. Jaitzig, F. Hillig, R. Süssmuth, P. Neubauer Applied Microbiology and Biotechnology Applied Microbiology and Biotechnology 2013, 98, 591–601, 10.1007/s00253-013-5309-8

169 Recombinant purine nucleoside phosphorylases from thermophiles: preparation, properties and activity towards purine and pyrimidine nucleosides X. Zhou, K. Szeker, B. Janocha, T. Böhme, D. Albrecht, I. A. Mikhailopulo, P. Neubauer FEBS Journal 2013, 280, 1475–1490, 10.1111/febs.12143

168 Simulations of the polarisation-dependent Raman intensity of -carotene in photosystem II crystals K. Brose, A. Zouni, F. Müh, M. A. Mroginski, J. Maultzsch Chemical Physics 2013, 418, 65–73, 10.1016/j.chemphys.2013.03.016

167 Modeling of the branching influence on liquid–liquid equilibrium of binary and ternary polymer solutions by lattice–cluster theory D. Browarzik, K. Langenbach, S. Enders, C. Browarzik The Journal of Chemical Thermodynamics The Journal of Chemical Thermodynamics 2013, 62, 56–63, 10.1016/j.jct.2013.02.018

166 The nonheme iron in photosystem II F. Müh, A. Zouni Photosynthesis Research Photosynthesis Research 2013, 116, 295–314, 10.1007/s11120-013-9926-y

165 Structural Changes of the Oxygen-evolving Complex in Photosystem II during the Catalytic Cycle C. Glöckner, J. Kern, M. Broser, A. Zouni, V. Yachandra, J. Yano Journal of Biological Chemistry 2013, 288, 22607–22620, 10.1074/jbc.M113.476622

164 Simultaneous Femtosecond X-ray Spectroscopy and Diffraction of Photosystem II at Room Temperature J. Kern, R. Alonso-Mori, R. Tran, J. Hattne, R. J. Gildea, N. Echols, C. Glockner, J. Hellmich, H. Laksmono, R. G. Sierra, B. Lassalle-Kaiser, S. Koroidov, A. Lampe, G. Han, S. Gul, D. DiFiore, D. Milathianaki, A. R. Fry, A. Miahnahri, D. W. Schafer, M. Messerschmidt, M. M. Seibert, J. E. Koglin, D. Sokaras, T. C. Weng, J. Sellberg, M. J. Latimer, R. W. Grosse-Kunstleve, P. H. Zwart, W. E. White, P. Glatzel, P. D. Adams, M. J. Bogan, G. J. Williams, S. Boutet, J. Messinger, A. Zouni, N. K. Sauter, V. K. Yachandra, U. Bergmann, J. Yano Science 2013, 340, 491–495, 10.1126/Science.1234273

163 Synthesis of Rhodium(I) Boryl Complexes: Catalytic N-H Activation of Anilines and Ammonia M. Teltewskoi, S. I. Kalläne, T. Braun, R. Herrmann European Journal of Inorganic Chemistry 2013, 2013, 5762–5768, 10.1002/ejic.201300972

162 Zinc Complexes with the N-Donor-Functionalized Cyclopentadienyl Ligand C Me (CH ) NMe M. A. Chilleck, T. Braun, R. Herrmann, B. Braun Organometallics 2013, 32, 1067–1074, 10.1021/om301181e

161 Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species M. Ahrens, G. Scholz, T. Braun, E. Kemnitz Angewandte Chemie International Edition 2013, 52, 5328–5332, 10.1002/anie.201300608

160 Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions M. F. Kuehnel, D. Lentz, T. Braun Angewandte Chemie International Edition 2013, 52, 3328–3348, 10.1002/anie.201205260

159 Microcystin production revisited: conjugate formation makes a major contribution S. Meissner, J. Fastner, E. Dittmann Environmental Microbiology Environmental Microbiology 2013, 15, 1810–1820, 10.1111/1462-2920.12072

158 Characterisation of paramagnetic Mo impurities on MgO(100) single-crystalline films grown on Mo(100) A. Gonchar, T. Risse Molecular Physics Molecular Physics 2013, 111, 2708–2716, 10.1080/00268976.2013.811305

157 Measuring Cation Transport by Na,K- and H,K-ATPase in Xenopus Oocytes by Atomic Absorption Spectrophotometry: An Alternative to Radioisotope Assays K. L. Dürr, N. N. Tavraz, S. Spiller, T. Friedrich Journal of Visualized Experiments Journal of Visualized Experiments 2013, 10.3791/50201

156 The Linker Pivot in Ci-VSP: The Key to Unlock Catalysis K. Hobiger, T. Utesch, M. A. Mroginski, G. Seebohm, T. Friedrich PLoS ONE 2013, 8, 10.1371/journal.pone.0070272

155 Voltage Dependence of Proton Pumping by Bacteriorhodopsin Mutants with Altered Lifetime of the M Intermediate S. Geibel, È. Lörinczi, E. Bamberg, T. Friedrich PLoS ONE 2013, 8, 10.1371/journal.pone.0073338

154 Functional characterization of a novel C-terminal mutation causing hemiplegic migraine and epilepsy T. Pisano, S. Spiller, D. Mei, R. Guerrini, C. Cianchetti, T. Friedrich, D. Pruna Cephalalgia Cephalalgia 2013, 33, 1302–1310, 10.1177/0333102413495116

153 A One-Pot Approach to Mesoporous Metal Oxide Ultrathin Film Electrodes Bearing One Metal Nanoparticle per Pore with Enhanced Electrocatalytic Properties A. Guiet, T. Reier, N. Heidary, D. Felkel, B. Johnson, U. Vainio, H. Schlaad, Y. Aksu, M. Driess, P. Strasser, A. Thomas, J. Polte, A. Fischer Chemistry of Materials 2013, 25, 4645–4652, 10.1021/cm401135z

152 Cytochrome P450 Interacts Directly with the Nonribosomal Peptide Synthetase to Generate Three Amino Acid Precursors in Skyllamycin Biosynthesis S. Uhlmann, R. D. Süssmuth, M. J. Cryle ACS Chemical Biology ACS Chemical Biology 2013, 8, 2586–2596, 10.1021/cb400555e

151 Champacyclin, a New Cyclic Octapeptide from Streptomyces Strain C42 Isolated from the Baltic Sea A. Pesic, H. Baumann, K. Kleinschmidt, P. Ensle, J. Wiese, R. Süssmuth, J. Imhoff Marine Drugs Marine Drugs 2013, 11, 4834–4857, 10.3390/md11124834

150 Arg-Thz is a minimal substrate for the Nα,Nα-arginyl methyltransferase involved in the biosynthesis of plantazolicin N. A. Piwowarska, S. Banala, H. S. Overkleeft, R. D. Süssmuth Chemical Communications 2013, 49, 10703– 10.1039/c3cc45898a

149 Reconstituted Biosynthesis of the Nonribosomal Macrolactone Antibiotic Valinomycin in J. Jaitzig, J. Li, R. D. Süssmuth, P. Neubauer ACS Synthetic Biology ACS Synthetic Biology 2013, 3, 432–438, 10.1021/sb400082j

148 Quantum Chemical Free Energies: Structure Optimization and Vibrational Frequencies in Normal Modes G. Piccini, J. Sauer Journal of Chemical Theory and Computation 2013, 9, 5038–5045, 10.1021/ct4005504

147 Accurate adsorption energies of small molecules on oxide surfaces: CO–MgO(001) A. D. Boese, J. Sauer Physical Chemistry Chemical Physics 2013, 15, 16481– 10.1039/C3CP52321G

146 Numerische Untersuchung von Schüttungen sphärischer und nichtsphärischer Füllkörper mithilfe von DEM und CFD T. Eppinger, G. Wehinger, N. Jurtz, M. Kraume Chemie Ingenieur Technik Chemie Ingenieur Technik 2013, 85, 1376–1377, 10.1002/cite.201250708

145 Anforderungen an eine OCM-Kinetik aus ingenieurstechnischer Sicht G. D. Wehinger, T. Eppinger, M. Kraume Chemie Ingenieur Technik Chemie Ingenieur Technik 2013, 85, 1381–1381, 10.1002/cite.201250590

144 A Microgel Construction Kit for Bioorthogonal Encapsulation and pH-Controlled Release of Living Cells D. Steinhilber, T. Rossow, S. Wedepohl, F. Paulus, S. Seiffert, R. Haag Angewandte Chemie International Edition 2013, 52, 13538–13543, 10.1002/anie.201308005

143 A Rare Uranyl(VI)-Alkyl Ate Complex [Li(DME) ] [UO (CH SiMe ) ] and Its Comparison with a Homoleptic Uranium(VI)-Hexaalkyl L. A. Seaman, P. Hrobárik, M. F. Schettini, S. Fortier, M. Kaupp, T. W. Hayton Angewandte Chemie International Edition 2013, 52, 3259–3263, 10.1002/anie.201209611

142 Investigations in the phase system Li–MgO–Y–Zr with respect to defect forming and catalytic performance A. Berthold, R. Mitdank, U. Simon, S. Arndt, H. Schubert Journal of Physics and Chemistry of Solids Journal of Physics and Chemistry of Solids 2013, 74, 997–1006, 10.1016/j.jpcs.2013.02.020

141 Facile synthesis of carbon nitride micro-/nanoclusters with photocatalytic activity for hydrogen evolution J. Liu, J. Huang, D. Dontosova, M. Antonietti RSC Advances 2013, 3, 22988– 10.1039/c3ra44490b

140 Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott–Schottky heterojunctions for catalysis X. H. Li, M. Antonietti Chemical Society Reviews 2013, 42, 6593– 10.1039/c3cs60067j

139 A Sustainable Route towards Imidazolium Building Blocks Based on Biomass Molecules D. Esposito, S. Kirchhecker, M. Antonietti Chemistry - A European Journal 2013, 19, 15097–15100, 10.1002/chem.201302806

138 Refining the Interpretation of Near-Infrared Band Shapes in a Polyynediyl Molecular Wire M. Parthey, J. B. G. Gluyas, P. A. Schauer, D. S. Yufit, J. A. K. Howard, M. Kaupp, P. J. Low Chemistry - A European Journal 2013, 19, 9780–9784, 10.1002/chem.201301747

137 Syntheses, Spectroelectrochemical Studies, and Molecular and Electronic Structures of Ferrocenyl Ene-diynes K. B. Vincent, Q. Zeng, M. Parthey, D. S. Yufit, J. A. K. Howard, F. Hartl, M. Kaupp, P. J. Low Organometallics 2013, 32, 6022–6032, 10.1021/om400535y

136 Synthesis and Bonding in Carbene Complexes of an Unsymmetrical Dilithio Methandiide: A Combined Experimental and Theoretical Study V. H. Gessner, F. Meier, D. Uhrich, M. Kaupp Chemistry – A European Journal 2013, 19, 16729–16739, 10.1002/chem.201303115

135 From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction D. Gallego, A. Brück, E. Irran, F. Meier, M. Kaupp, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2013, 135, 15617–15626, 10.1021/ja408137t

134 Does the environment around the H-cluster allow coordination of the pendant amine to the catalytic iron center in [FeFe] hydrogenases? Answers from theory T. Miyake, M. Bruschi, U. Cosentino, C. Baffert, V. Fourmond, C. Léger, G. Moro, L. De Gioia, C. Greco JBIC Journal of Biological Inorganic Chemistry JBIC Journal of Biological Inorganic Chemistry 2013, 18, 693–700, 10.1007/s00775-013-1014-4

133 Towards [NiFe]-hydrogenase biomimetic models that couple H2 binding with functionally relevant intramolecular electron transfers: a quantum chemical study C. Greco Dalton Transactions Dalton Transactions 2013, 42, 13845– 10.1039/C3DT50836F

132 H Binding and Splitting on a New-Generation [FeFe]-Hydrogenase Model Featuring a Redox-Active Decamethylferrocenyl Phosphine Ligand: A Theoretical Investigation C. Greco Inorganic Chemistry 2013, 52, 1901–1908, 10.1021/ic302118h

131 Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11 K. Ray, F. Heims, F. F. Pfaff European Journal of Inorganic Chemistry 2013, 2013, 3784–3807, 10.1002/ejic.201300223

130 Redox Non-Innocence of a -Heterocyclic Nitrenium Cation Bound to a Nickel–Cyclam Core F. Heims, F. F. Pfaff, S. L. Abram, E. R. Farquhar, M. Bruschi, C. Greco, K. Ray Journal of the American Chemical Society 2013, 136, 582–585, 10.1021/ja4099559

129 Frauenförderung zwischen heterogenen Logiken. Der Fall eines Nachwuchsförderprogramms in der deutschen Exzellenzinitiative M. Norkus, R. Schmidt, G. Petschick Swiss Journal of Sociology 2013, 39, 383–404,

128 Performance Analysis of a Porous Packed Bed Membrane Reactor for Oxidative Coupling of Methane: Structural and Operational Characteristics H. R. Godini, A. Gili, O. Görke, U. Simon, K. Hou, G. Wozny Energy & Fuels 2013, 28, 877–890, 10.1021/ef402041b

127 Design and demonstration of an experimental membrane reactor set-up for oxidative coupling of methane H. R. Godini, H. Trivedi, A. G. de Villasante, O. Görke, S. Jašo, U. Simon, A. Berthold, W. Witt, G. Wozny Chemical Engineering Research and Design Chemical Engineering Research and Design 2013, 91, 2671–2681, 10.1016/j.cherd.2013.05.025

126 Dual-membrane reactor for methane oxidative coupling and dry methane reforming: Reactor integration and process intensification H. R. Godini, S. Xiao, M. Kim, O. Görke, S. Song, G. Wozny Chemical Engineering and Processing: Process Intensification Chemical Engineering and Processing: Process Intensification 2013, 74, 153–164, 10.1016/j.cep.2013.09.007

125 Exploring the reactivity of nickel complexes in hydrodecyanation reactions S. Enthaler, M. Weidauer, E. Irran, J. D. Epping, R. Kretschmer, C. I. Someya Journal of Organometallic Chemistry Journal of Organometallic Chemistry 2013, 745, 262–274, 10.1016/j.jorganchem.2013.07.068

124 Exploring the coordination chemistry of 1-benzoyl-4,5-dihydro-3,5-bis(trifluoromethyl)-1H-pyrazol-5-ol to copper C. I. Someya, S. Inoue, S. Enthaler Inorganic Chemistry Communications Inorganic Chemistry Communications 2013, 38, 131–134, 10.1016/j.inoche.2013.10.016

123 Microbial and Animal Rhodopsins: Structures, Functions, and Molecular Mechanisms O. P. Ernst, D. T. Lodowski, M. Elstner, P. Hegemann, L. S. Brown, H. Kandori Chemical Reviews Chemical Reviews 2013, 114, 126–163, 10.1021/cr4003769

122 Charge competition with oxygen molecules determines the growth of gold particles on doped CaO films Y. Cui, K. Huang, N. Nilius, H. J. Freund Faraday Discussions Faraday Discussions 2013, 162, 153– 10.1039/C3FD20130A

121 CO oxidation over ZnO films on Pt(111) at near-atmospheric pressures Y. Martynova, B. H. Liu, M. E. McBriarty, I. M. N. Groot, M. J. Bedzyk, S. Shaikhutdinov, H. J. Freund Journal of Catalysis 2013, 301, 227–232, 10.1016/j.jcat.2013.02.018

120 Towards Realistic Surface Science Models of Heterogeneous Catalysts: Influence of Support Hydroxylation and Catalyst Preparation Method M. Sterrer, H. J. Freund Catalysis Letters 2013, 143, 375–385, 10.1007/s10562-013-0987-5

119 STM Luminescence Spectroscopy of Intrinsic Defects in ZnO(0001̅) Thin Films F. Stavale, N. Nilius, H. J. Freund The Journal of Physical Chemistry Letters The Journal of Physical Chemistry Letters 2013, 4, 3972–3976, 10.1021/jz401823c

118 CO Oxidation on Metal-Supported Ultrathin Oxide Films: What Makes Them Active? Y. Martynova, S. Shaikhutdinov, H. J. Freund ChemCatChem 2013, 5, 2162–2166, 10.1002/cctc.201300212

117 Adsorption, Activation, and Dissociation of Oxygen on Doped Oxides Y. Cui, X. Shao, M. Baldofski, J. Sauer, N. Nilius, H. J. Freund Angewandte Chemie International Edition 2013, 52, 11385–11387, 10.1002/anie.201305119

116 Well-Ordered Transition Metal Oxide Layers in Model Catalysis – A Series of Case Studies H. Kuhlenbeck, S. Shaikhutdinov, H. J. Freund Chemical Reviews Chemical Reviews 2013, 113, 3986–4034, 10.1021/cr300312n

115 Hydroxylation of Metal-Supported Sheet-Like Silica Films B. Yang, E. Emmez, W. E. Kaden, X. Yu, J. A. Boscoboinik, M. Sterrer, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2013, 117, 8336–8344, 10.1021/jp401935u

114 Patterned Defect Structures Predicted for Graphene Are Observed on Single-Layer Silica Films B. Yang, J. A. Boscoboinik, X. Yu, S. Shaikhutdinov, H. J. Freund Nano Letters 2013, 13, 4422–4427, 10.1021/nl402264k

113 A portable quartz micro balance for physical vapor deposition techniques S. Stuckenholz, C. Büchner, G. Thielsch, M. Heyde, H. J. Freund Review of Scientific Instruments 2013, 84, 85118– 10.1063/1.4819030

112 Model studies on heterogeneous catalysts at the atomic scale: From supported metal particles to two-dimensional zeolites H. J. Freund, M. Heyde, N. Nilius, S. Schauermann, S. Shaikhutdinov, M. Sterrer Journal of Catalysis 2013, 308, 154–167, 10.1016/j.jcat.2013.06.007

111 Electron quantization in arbitrarily shaped gold islands on MgO thin films C. Stiehler, Y. Pan, W. D. Schneider, P. Koskinen, H. Häkkinen, N. Nilius, H. J. Freund Physical Review B 2013, 88, 10.1103/PhysRevB.88.115415

110 Controlling the charge state of single Mo dopants in a CaO film Y. Cui, N. Nilius, H. J. Freund, S. Prada, L. Giordano, G. Pacchioni Physical Review B 2013, 88, 10.1103/PhysRevB.88.205421

109 Titration of Ions in the Surface by Au Adatoms Y. Pan, N. Nilius, H. J. Freund, J. Paier, C. Penschke, J. Sauer Physical Review Letters 2013, 111, 10.1103/PhysRevLett.111.206101

108 Gold Adsorption on CeO Thin Films Grown on Ru(0001) Y. Pan, Y. Cui, C. Stiehler, N. Nilius, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2013, 117, 21879–21885, 10.1021/jp407605m

107 Exploring the Structure of Paramagnetic Centers in SBA-15 Supported Vanadia Catalysts with Pulsed One- and Two-Dimensional Electron Paramagnetic Resonance (EPR) and Electron Nuclear Double Resonance (ENDOR) A. Dinse, T. Wolfram, C. Carrero, R. Schlögl, R. Schomäcker, K. P. Dinse The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2013, 117, 16921–16932, 10.1021/jp4042342

106 Anomalous reactivity of supported V2O5 nanoparticles for propane oxidative dehydrogenation: influence of the vanadium oxide precursor C. A. Carrero, C. J. Keturakis, A. Orrego, R. Schomäcker, I. E. Wachs Dalton Transactions Dalton Transactions 2013, 42, 12644– 10.1039/c3dt50611h

105 Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism J. Hermeke, M. Mewald, M. Oestreich Journal of the American Chemical Society 2013, 135, 17537–17546, 10.1021/ja409344w

104 The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis, Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum‐Chemical Analyses K. Müther, P. Hrobárik, V. Hrobáriková, M. Kaupp, M. Oestreich Chemistry – A European Journal 2013, 19, 16579–16594, 10.1002/chem.201302885

103 Interaction of CO with Electron-Rich Defects on MgO(100) S. Sicolo, J. Sauer The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2013, 117, 8365–8373, 10.1021/jp402546k

102 Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment J. Paier, C. Penschke, J. Sauer Chemical Reviews Chemical Reviews 2013, 113, 3949–3985, 10.1021/cr3004949

101 Analysis of the interaction of the molybdenum hydroxylase PaoABC from Escherichia coli with positively and negatively charged metal complexes A. Badalyan, E. G. Yoga, V. Schwuchow, S. Pöller, W. Schuhmann, S. Leimkühler, U. Wollenberger Electrochemistry Communications Electrochemistry Communications 2013, 37, 5–7, 10.1016/j.elecom.2013.09.017

100 Sensors based on cytochrome P450 and CYP mimicking systems A. Yarman, U. Wollenberger, F. W. Scheller Electrochimica Acta 2013, 110, 63–72, 10.1016/j.electacta.2013.03.154

99 Electrochemically driven biocatalysis of the oxygenase domain of neuronal nitric oxide synthase in indium tin oxide nanoparticles/polyvinyl alcohol nanocomposite X. Xu, U. Wollenberger, J. Qian, K. Lettau, C. Jung, S. Liu Bioelectrochemistry 2013, 94, 7–12, 10.1016/j.bioelechem.2013.04.005

98 Concentration of Vacancies at Metal-Oxide Surfaces: Case Study of MgO(100) N. A. Richter, S. Sicolo, S. V. Levchenko, J. Sauer, M. Scheffler Physical Review Letters 2013, 111, 10.1103/PhysRevLett.111.045502

97 Catalytic Production of Hydrogen Peroxide and Water by Oxygen-Tolerant [NiFe]-Hydrogenase during H Cycling in the Presence of O L. Lauterbach, O. Lenz Journal of the American Chemical Society 2013, 135, 17897–17905, 10.1021/ja408420d

96 Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution A. J. Healy, P. A. Ash, O. Lenz, K. A. Vincent Physical Chemistry Chemical Physics 2013, 15, 7055– 10.1039/c3cp00119a

95 Stability enhancement of an O2-tolerant NAD+-reducing [NiFe]-hydrogenase by a combination of immobilisation and chemical modification N. Herr, J. Ratzka, L. Lauterbach, O. Lenz, M. B. Ansorge-Schumacher Journal of Molecular Catalysis B: Enzymatic 2013, 97, 169–174, 10.1016/j.molcatb.2013.06.009

94 H -driven cofactor regeneration with NAD(P) -reducing hydrogenases L. Lauterbach, O. Lenz, K. A. Vincent FEBS Journal 2013, 280, 3058–3068, 10.1111/febs.12245

93 Novel, Oxygen-Insensitive Group 5 [NiFe]-Hydrogenase in Ralstonia eutropha C. Schäfer, B. Friedrich, O. Lenz Applied and Environmental Microbiology 2013, 79, 5137–5145, 10.1128/AEM.01576-13

92 Resonance Raman Spectroscopy as a Tool to Monitor the Active Site of Hydrogenases E. Siebert, M. Horch, Y. Rippers, J. Fritsch, S. Frielingsdorf, O. Lenz, F. Velazquez Escobar, F. Siebert, L. Paasche, U. Kuhlmann, F. Lendzian, M. A. Mroginski, I. Zebger, P. Hildebrandt Angewandte Chemie International Edition 2013, 52, 5162–5165, 10.1002/anie.201209732

91 Coupling Biocatalysis with Molecular Imprinting in a Biomimetic Sensor A. Yarman, F. W. Scheller Angewandte Chemie International Edition 2013, 52, 11521–11525, 10.1002/anie.201305368

90 Genome mining reveals the genus Xanthomonas to be a promising reservoir for new bioactive non-ribosomally synthesized peptides M. Royer, R. Koebnik, M. Marguerettaz, V. Barbe, G. P. Robin, C. Brin, S. Carrere, C. Gomez, M. Hügelland, G. H. Völler, J. Noëll, I. Pieretti, S. Rausch, V. Verdier, S. Poussier, P. Rott, R. D. Süssmuth, S. Cociancich BMC Genomics BMC Genomics 2013, 14, 658– 10.1186/1471-2164-14-658

89 Elimination Reactions of Esters in the Biosynthesis of Polyketides and Ribosomal Peptides B. Krawczyk, E. F. van Herwerden, H. S. Overkleeft, R. D. Süssmuth Angewandte Chemie International Edition 2013, 52, 9082–9084, 10.1002/anie.201304851

88 Biotransformation of the Fungal Phytotoxin Fomannoxin by Soil Streptomycetes N. Horlacher, J. Nachtigall, D. Schulz, R. D. Süssmuth, R. Hampp, H. P. Fiedler, S. D. Schrey Journal of Chemical Ecology Journal of Chemical Ecology 2013, 39, 931–941, 10.1007/s10886-013-0290-3

87 Involvement and Unusual Substrate Specificity of a Prolyl Oligopeptidase in Class III Lanthipeptide Maturation G. H. Völler, B. Krawczyk, P. Ensle, R. D. Süssmuth Journal of the American Chemical Society 2013, 135, 7426–7429, 10.1021/ja402296m

86 Conformational investigation of antibiotic proximicin by X-ray structure analysis and quantum studies suggest a stretched conformation of this type of γ-peptide A. Denisiuk, V. Schubert, F. E. Wolter, E. Irran, P. Trouillas, R. D. Süssmuth Bioorganic & Medicinal Chemistry Bioorganic & Medicinal Chemistry 2013, 21, 3582–3589, 10.1016/j.bmc.2013.02.051

85 Alanine Scan of the Peptide Antibiotic Feglymycin: Assessment of Amino Acid Side Chains Contributing to Antimicrobial Activity A. Hänchen, S. Rausch, B. Landmann, L. Toti, A. Nusser, R. D. Süssmuth ChemBioChem 2013, 14, 625–632, 10.1002/cbic.201300032

84 Characterization of the Biosynthetic Genes for 10,11-Dehydrocurvularin, a Heat Shock Response-Modulating Anticancer Fungal Polyketide from Aspergillus terreus Y. Xu, P. Espinosa-Artiles, V. Schubert, Y. m. Xu, W. Zhang, M. Lin, A. A. L. Gunatilaka, R. Süssmuth, I. Molnár Applied and Environmental Microbiology 2013, 79, 2038–2047, 10.1128/AEM.03334-12

83 Total Synthesis of the Ribosomally Synthesized Linear Azole-Containing Peptide Plantazolicin A from S. Banala, P. Ensle, R. D. Süssmuth Angewandte Chemie International Edition 2013, 52, 9518–9523, 10.1002/anie.201302266

82 The Lantibiotic Peptide Labyrinthopeptin A1 Demonstrates Broad Anti-HIV and Anti-HSV Activity with Potential for Microbicidal Applications G. Férir, M. I. Petrova, G. Andrei, D. Huskens, B. Hoorelbeke, R. Snoeck, J. Vanderleyden, J. Balzarini, S. Bartoschek, M. Brönstrup, R. D. Süssmuth, D. Schols PLoS ONE 2013, 8, 10.1371/journal.pone.0064010

81 Nickel(i)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO2 generating NiICO, NiIICO3 and NiIIC2O4NiII entities B. Horn, C. Limberg, C. Herwig, B. Braun Chemical Communications 2013, 49, 10923– 10.1039/c3cc45407j

80 Access to a Cu –O–Cu Motif: Spectroscopic Properties, Solution Structure, and Reactivity P. Haack, A. Kärgel, C. Greco, J. Dokic, B. Braun, F. F. Pfaff, S. Mebs, K. Ray, C. Limberg Journal of the American Chemical Society 2013, 135, 16148–16160, 10.1021/ja406721a

79 Synthesis of a Chiral, Polydentate Ligand System Setting Out from -Cysteine and First Nickel Complexes Thereof D. S. Warner, C. Limberg, S. Mebs Zeitschrift für anorganische und allgemeine Chemie Zeitschrift für anorganische und allgemeine Chemie 2013, 639, 1577–1583, 10.1002/zaac.201300071

78 Redox-Dependent Structural Transformations of the [4Fe-3S] Proximal Cluster in O -Tolerant Membrane-Bound [NiFe]-Hydrogenase: A DFT Study V. Pelmenschikov, M. Kaupp Journal of the American Chemical Society 2013, 135, 11809–11823, 10.1021/ja402159u

77 Charge Separation Promoted Activation of Molecular Oxygen by Neutral Gold Clusters A. P. Woodham, G. Meijer, A. Fielicke Journal of the American Chemical Society 2013, 135, 1727–1730, 10.1021/ja312223t

76 Not so loosely bound rare gas atoms: finite-temperature vibrational fingerprints of neutral gold-cluster complexes L. M. Ghiringhelli, P. Gruene, J. T. Lyon, D. M. Rayner, G. Meijer, A. Fielicke, M. Scheffler New Journal of Physics 2013, 15, 83003– 10.1088/1367-2630/15/8/083003

75 Zero-field splittings in metHb and metMb with aquo and fluoro ligands: a FD-FT THz-EPR study J. Nehrkorn, B. M. Martins, K. Holldack, S. Stoll, H. Dobbek, R. Bittl, A. Schnegg Molecular Physics Molecular Physics 2013, 111, 2696–2707, 10.1080/00268976.2013.809806

74 Visualizing the substrate-, superoxo-, alkylperoxo-, and product-bound states at the nonheme Fe(II) site of homogentisate dioxygenase J. H. Jeoung, M. Bommer, T. Y. Lin, H. Dobbek Proceedings of the National Academy of Sciences Proceedings of the National Academy of Sciences 2013, 110, 12625–12630, 10.1073/pnas.1302144110

73 Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO Fixation A. M. Appel, J. E. Bercaw, A. B. Bocarsly, H. Dobbek, D. L. DuBois, M. Dupuis, J. G. Ferry, E. Fujita, R. Hille, P. J. A. Kenis, C. A. Kerfeld, R. H. Morris, C. H. F. Peden, A. R. Portis, S. W. Ragsdale, T. B. Rauchfuss, J. N. H. Reek, L. C. Seefeldt, R. K. Thauer, G. L. Waldrop Chemical Reviews Chemical Reviews 2013, 113, 6621–6658, 10.1021/cr300463y

72 Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates L. Zámostná, M. Ahrens, T. Braun Journal of Fluorine Chemistry Journal of Fluorine Chemistry 2013, 155, 132–142, 10.1016/j.jfluchem.2013.05.021

71 α-Dialdimine Complexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen and Dihydrogen A. Eiβler, P. Kläring, F. Emmerling, T. Braun European Journal of Inorganic Chemistry 2013, 2013, 4775–4788, 10.1002/ejic.201300625

70 Hybrid hierarchical patterns of gold nanoparticles and poly(ethylene glycol) microstructures J. Chen, M. Arafeh, A. Guiet, D. Felkel, A. Loebus, S. M. Kelleher, A. Fischer, M. C. Lensen Journal of Materials Chemistry C Journal of Materials Chemistry C 2013, 1, 7709– 10.1039/C3TC30811A

69 Energy, Equipment and Cost Savings by Using a Membrane Unit in an Amine-Based Absorption Process for CO Removal S. Song, E. Esche, S. Stünkel, T. Brinkmann, J. Wind, S. Shishatskiy, G. Wozny Chemie Ingenieur Technik 2013, 85, 1221–1227, 10.1002/cite.201200242

68 Resonance Raman Characterization of the Ammonia-Generated Oxo Intermediate of Cytochrome Oxidase from J. Kozuch, I. von der Hocht, F. Hilbers, H. Michel, I. M. Weidinger Biochemistry 2013, 52, 6197–6202, 10.1021/bi400535m

67 Potential-Dependent Surface-Enhanced Resonance Raman Spectroscopy at Nanostructured TiO : A Case Study on Cytochrome b X. X. Han, C. Köhler, J. Kozuch, U. Kuhlmann, L. Paasche, A. Sivanesan, I. M. Weidinger, P. Hildebrandt Small 2013, 9, 4175–4181, 10.1002/smll.201301070

66 Modulation of direct electron transfer of cytochrome c by use of a molecularly imprinted thin film M. Bosserdt, N. Gajovic-Eichelman, F. W. Scheller Analytical and Bioanalytical Chemistry 2013, 405, 6437–6444, 10.1007/s00216-013-7009-8

65 A Biosensor for Aromatic Aldehydes Comprising the Mediator Dependent PaoABC-Aldehyde Oxidoreductase A. Badalyan, M. Neumann-Schaal, S. Leimkühler, U. Wollenberger Electroanalysis The Journal of Physical Chemistry C 2013, 25, 101–108, 10.1002/elan.201200362

64 Tunable Electric Field Enhancement and Redox Chemistry on TiO Island Films via Covalent Attachment to Ag or Au Nanostructures A. Sivanesan, K. H. Ly, W. Adamkiewicz, K. Stiba, S. Leimkühler, I. M. Weidinger The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2013, 117, 11866–11872, 10.1021/jp4032578

63 Bioelectrocatalysis at mesoporous antimony doped tin oxide electrodes—Electrochemical characterization and direct enzyme communication S. Frasca, A. Molero Milan, A. Guiet, C. Goebel, F. Pérez-Caballero, K. Stiba, S. Leimkühler, A. Fischer, U. Wollenberger Electrochimica Acta Biochimica et Biophysica Acta (BBA) - Bioenergetics 2013, 110, 172–180, 10.1016/j.electacta.2013.03.144

62 Molybdenum enzymes, their maturation and molybdenum cofactor biosynthesis in Escherichia coli C. Iobbi-Nivol, S. Leimkühler Biochimica et Biophysica Acta (BBA) - Bioenergetics Biochimica et Biophysica Acta (BBA) - Bioenergetics 2013, 1827, 1086–1101, 10.1016/j.bbabio.2012.11.007

61 The oxygen-tolerant and NAD -dependent formate dehydrogenase from is able to catalyze the reduction of CO to formate T. Hartmann, S. Leimkühler FEBS Journal 2013, 280, 6083–6096, 10.1111/febs.12528

60 Identification of a Bis-molybdopterin Intermediate in Molybdenum Cofactor Biosynthesis in S. Reschke, K. G. V. Sigfridsson, P. Kaufmann, N. Leidel, S. Horn, K. Gast, C. Schulzke, M. Haumann, S. Leimkühler Journal of Biological Chemistry 2013, 288, 29736–29745, 10.1074/jbc.M113.497453

59 Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations R. Kretschmer, M. Schlangen, H. Schwarz ChemPlusChem ChemPlusChem 2013, 78, 952–958, 10.1002/cplu.201300138

58 Towards an Understanding of Channelrhodopsin Function: Simulations Lead to Novel Insights of the Channel Mechanism H. C. Watanabe, K. Welke, D. J. Sindhikara, P. Hegemann, M. Elstner Journal of Molecular Biology 2013, 425, 1795–1814, 10.1016/j.jmb.2013.01.033

57 Genetically encoded calcium indicators for multi-color neural activity imaging and combination with optogenetics J. Akerboom, N. Carreras Calderón, L. Tian, S. Wabnig, M. Prigge, J. Tolö, A. Gordus, M. B. Orger, K. E. Severi, J. J. Macklin, R. Patel, S. R. Pulver, T. J. Wardill, E. Fischer, C. Schüler, T. W. Chen, K. S. Sarkisyan, J. S. Marvin, C. I. Bargmann, D. S. Kim, S. Kügler, L. Lagnado, P. Hegemann, A. Gottschalk, E. R. Schreiter, L. L. Looger Frontiers in Molecular Neuroscience Frontiers in Molecular Neuroscience 2013, 6, 10.3389/fnmol.2013.00002

56 From channelrhodopsins to optogenetics P. Hegemann, G. Nagel EMBO Molecular Medicine EMBO Molecular Medicine 2013, 5, 173–176, 10.1002/emmm.201202387

55 Optogenetic Modulation of an Adenylate Cyclase in Demonstrates a Requirement of the Parasite cAMP for Host-Cell Invasion and Stage Differentiation A. Hartmann, R. D. Arroyo-Olarte, K. Imkeller, P. Hegemann, R. Lucius, N. Gupta Journal of Biological Chemistry 2013, 288, 13705–13717, 10.1074/jbc.M113.465583

54 Direct methane oxidation over Pt-modified nitrogen-doped carbons M. Soorholtz, R. J. White, T. Zimmermann, M. M. Titirici, M. Antonietti, R. Palkovits, F. Schüth Chem. Commun. Journal of Materials Chemistry A 2013, 49, 240–242, 10.1039/c2cc36232e

53 Mesoporous nitrogen-doped carbon for copper-mediated Ullmann-type C–O/–N/–S cross-coupling reactions P. Zhang, J. Yuan, H. Li, X. Liu, X. Xu, M. Antonietti, Y. Wang RSC Adv. Journal of Materials Chemistry A 2013, 3, 1890–1895, 10.1039/c2ra22559j

52 On the Way to Artificial Photosynthesis: Simple Materials and System Designs for Photoelectrodes M. Antonietti Angewandte Chemie International Edition Journal of Materials Chemistry A 2013, 52, 1086–1087, 10.1002/anie.201207937

51 Surface Area Control and Photocatalytic Activity of Conjugated Microporous Poly(benzothiadiazole) Networks K. Zhang, D. Kopetzki, P. H. Seeberger, M. Antonietti, F. Vilela Angewandte Chemie International Edition Journal of Materials Chemistry A 2013, 52, 1432–1436, 10.1002/anie.201207163

50 Tunable nitrogen-doped carbon aerogels as sustainable electrocatalysts in the oxygen reduction reaction S. A. Wohlgemuth, T. P. Fellinger, P. Jäker, M. Antonietti Journal of Materials Chemistry A Journal of Materials Chemistry A 2013, 1, 4002– 10.1039/c3ta10352h

49 “Salt Templating”: A Simple and Sustainable Pathway toward Highly Porous Functional Carbons from Ionic Liquids N. Fechler, T. P. Fellinger, M. Antonietti Advanced Materials Scientific Reports 2013, 25, 75–79, 10.1002/adma.201203422

48 Electro- and Photochemical Water Oxidation on Ligand-free Co O Nanoparticles with Tunable Sizes M. Grzelczak, J. Zhang, J. Pfrommer, J. Hartmann, M. Driess, M. Antonietti, X. Wang ACS Catalysis Scientific Reports 2013, 3, 383–388, 10.1021/cs3007523

47 Facilitating room-temperature Suzuki coupling reaction with light: Mott-Schottky photocatalyst for C-C-coupling X. H. Li, M. Baar, S. Blechert, M. Antonietti Scientific Reports Scientific Reports 2013, 3, 10.1038/srep01743

46 Bio-inspired NADH regeneration by carbon nitride photocatalysis using diatom templates J. Liu, M. Antonietti Energy & Environmental Science Energy & Environmental Science 2013, 6, 1486– 10.1039/c3ee40696b

45 Improving Carbon Nitride Photocatalysis by Supramolecular Preorganization of Monomers M. Shalom, S. Inal, C. Fettkenhauer, D. Neher, M. Antonietti Journal of the American Chemical Society 2013, 135, 7118–7121, 10.1021/ja402521s

44 Chemical Conversion of Sugars to Lactic Acid by Alkaline Hydrothermal Processes D. Esposito, M. Antonietti ChemSusChem 2013, 6, 989–992, 10.1002/cssc.201300092

43 Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran) S. Enthaler, A. Trautner ChemSusChem 2013, 6, 1334–1336, 10.1002/cssc.201300380

42 Dual functionality of formamidine polymers, as ligands and as bases, in ruthenium-catalysed hydrogen evolution from formic acid S. Enthaler, H. Junge, A. Fischer, A. Kammer, S. Krackl, J. D. Epping Polymer Chemistry Polymer Chemistry 2013, 4, 2741– 10.1039/C3PY00120B

41 Nickel-catalyzed hydrodehalogenation of aryl halides M. Weidauer, E. Irran, C. I. Someya, M. Haberberger, S. Enthaler Journal of Organometallic Chemistry Journal of Organometallic Chemistry 2013, 729, 53–59, 10.1016/j.jorganchem.2013.01.014

40 Nickel-catalyzed Hydrodecyanation of Carbon-Cyano Bonds M. Weidauer, C. I. Someya, E. Irran, S. Enthaler Asian Journal of Organic Chemistry 2013, 2, 150–156, 10.1002/ajoc.201200185

39 Nickel-catalyzed C(sp2)–C(sp2) Cross Coupling Reactions of Sulfur-Functionalities and Grignard Reagents C. I. Someya, M. Weidauer, S. Enthaler Catalysis Letters 2013, 143, 424–431, 10.1007/s10562-013-0979-5

38 Application of a Bis(silylene) Nickel Complex as Precatalyst in C–C Bond Formation Reactions C. I. Someya, M. Haberberger, W. Wang, S. Enthaler, S. Inoue Chemistry Letters Chemistry Letters 2013, 42, 286–288, 10.1246/cl.2013.286

37 Application of fatty acid chlorides in the iron-catalyzed depolymerization of polyethers S. Enthaler European Journal of Lipid Science and Technology 2013, 115, 239–245, 10.1002/ejlt.201200301

36 Single and Double NH Bond Activation of Ammonia by [Al O ] : Room Temperature Formation of the Aminyl Radical and Nitrene R. Kretschmer, Z. C. Wang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 52, 9513–9517, 10.1002/anie.201302506

35 Thermal Methane Activation by a Binary V-Nb Transition-Metal Oxide Cluster Cation: A Further Example for the Crucial Role of Oxygen-Centered Radicals Z. C. Wang, J. W. Liu, M. Schlangen, T. Weiske, D. Schröder, J. Sauer, H. Schwarz Chemistry - A European Journal 2013, 19, 11496–11501, 10.1002/chem.201302133

34 Isomer-Selective Thermal Activation of Methane in the Gas Phase by [HMO] and [M(OH)] (M=Ti and V) R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 52, 6097–6101, 10.1002/anie.201300900

33 Particle shape optimization by changing from an isotropic to an anisotropic nanostructure: preparation of highly active and stable supported Pt catalysts in microemulsions R. Y. Parapat, M. Wijaya, M. Schwarze, S. Selve, M. Willinger, R. Schomäcker Nanoscale 2013, 5, 796–805, 10.1039/c2nr32122j

32 Interaction of Probe Molecules with Bridging Hydroxyls of Two-Dimensional Zeolites: A Surface Science Approach J. A. Boscoboinik, X. Yu, E. Emmez, B. Yang, S. Shaikhutdinov, F. D. Fischer, J. Sauer, H. J. Freund The Journal of Physical Chemistry C J. Phys. Chem. C 2013, 117, 13547–13556, 10.1021/jp405533s

31 Full-Length Structure of a Sensor Histidine Kinase Pinpoints Coaxial Coiled Coils as Signal Transducers and Modulators R. P. Diensthuber, M. Bommer, T. Gleichmann, A. Möglich Structure 2013, 21, 1127–1136, 10.1016/j.str.2013.04.024

30 Magnetic Silver Hybrid Nanoparticles for Surface-Enhanced Resonance Raman Spectroscopic Detection and Decontamination of Small Toxic Molecules X. X. Han, A. M. Schmidt, G. Marten, A. Fischer, I. M. Weidinger, P. Hildebrandt ACS Nano 2013, 7, 3212–3220, 10.1021/nn305892j

29 Parallelisiertes System zum Screening und zur Charakterisierung von Biokatalysatoren E. Lyagin, A. Drews, M. Kraume GIT Labor-Fachzeitschrift 2013, 5, 322–324,

28 Crystal structure of pre-activated arrestin p44 Y. J. Kim, K. P. Hofmann, O. P. Ernst, P. Scheerer, H. W. Choe, M. E. Sommer Nature 2013, 497, 142–146, 10.1038/nature12133

27 Photolytic C–H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent B. Rábay, T. Braun, J. P. Falkenhagen Dalton Transactions 2013, 42, 8058– 10.1039/c3dt33022b

26 Crystal structure of a prokaryotic (6-4) photolyase with an Fe-S cluster and a 6,7-dimethyl-8-ribityllumazine antenna chromophore F. Zhang, P. Scheerer, I. Oberpichler, T. Lamparter, N. Krauss Proceedings of the National Academy of Sciences 2013, 110, 7217–7222, 10.1073/pnas.1302377110

25 Mechanistic Aspects of Gas-Phase Hydrogen-Atom Transfer from Methane to [CO] and [SiO] : Why Do They Differ? N. Dietl, A. Troiani, M. Schlangen, O. Ursini, G. Angelini, Y. Apeloig, G. de Petris, H. Schwarz Chemistry - A European Journal 2013, 19, 6662–6669, 10.1002/chem.201204157

24 Structure, function and biosynthesis of O2-tolerant hydrogenases J. Fritsch, O. Lenz, B. Friedrich Nature Reviews Microbiology Nature Reviews Microbiology 2013, 11, 106–114, 10.1038/nrmicro2940

23 Calculation of the high pressure phase equilibrium in hyperbranched polymer systems with the lattice-cluster theory K. Langenbach, S. Enders, C. Browarzik, D. Browarzik The Journal of Chemical Thermodynamics 2013, 59, 107–113, 10.1016/j.jct.2012.12.002

22 Structure and Chemistry of the Heteronuclear Oxo-Cluster [VPO ] : A Model System for the Gas-Phase Oxidation of Small Hydrocarbons N. Dietl, T. Wende, K. Chen, L. Jiang, M. Schlangen, X. Zhang, K. R. Asmis, H. Schwarz Journal of the American Chemical Society 2013, 135, 3711–3721, 10.1021/ja400198y

21 Lithium-molybdate nanostructures grown on the Mo(001) surface F. Stavale, N. Nilius, H. J. Freund Surface Science 2013, 609, 78–84, 10.1016/j.susc.2012.11.007

20 First experimental proof for aberration correction in XPEEM: Resolution, transmission enhancement, and limitation by space charge effects T. Schmidt, A. Sala, H. Marchetto, E. Umbach, H. J. Freund Ultramicroscopy Ultramicroscopy 2013, 126, 23–32, 10.1016/j.ultramic.2012.11.004

19 Steering the Growth of Metal Ad-particles via Interface Interactions Between a MgO Thin Film and a Mo Support S. Benedetti, F. Stavale, S. Valeri, C. Noguera, H. J. Freund, J. Goniakowski, N. Nilius Advanced Functional Materials 2013, 23, 75–80, 10.1002/adfm.201201502

18 Facile Low-Temperature Approach to Tin-Containing ZnO Nanocrystals with Tunable Tin Concentrations Using Heterobimetallic Sn/Zn Single-Source Precursors M. Tsaroucha, Y. Aksu, J. D. Epping, M. Driess ChemPlusChem ChemPlusChem 2013, 78, 62–69, 10.1002/cplu.201200259

17 New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules B. Blom, M. Stoelzel, M. Driess Chemistry - A European Journal 2013, 19, 40–62, 10.1002/chem.201203072

16 Nonheme oxoiron( ) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity D. Wang, K. Ray, M. J. Collins, E. R. Farquhar, J. R. Frisch, L. Gómez, T. A. Jackson, M. Kerscher, A. Waleska, P. Comba, M. Costas, L. Que Chem. Sci. 2013, 4, 282–291, 10.1039/C2SC21318D

15 Ribosomally synthesized and post-translationally modified peptide natural products: overview and recommendations for a universal nomenclature P. G. Arnison, M. J. Bibb, G. Bierbaum, A. A. Bowers, T. S. Bugni, G. Bulaj, J. A. Camarero, D. J. Campopiano, G. L. Challis, J. Clardy, P. D. Cotter, D. J. Craik, M. Dawson, E. Dittmann, S. Donadio, P. C. Dorrestein, K. D. Entian, M. A. Fischbach, J. S. Garavelli, U. Göransson, C. W. Gruber, D. H. Haft, T. K. Hemscheidt, C. Hertweck, C. Hill, A. R. Horswill, M. Jaspars, W. L. Kelly, J. P. Klinman, O. P. Kuipers, A. J. Link, W. Liu, M. A. Marahiel, D. A. Mitchell, G. N. Moll, B. S. Moore, R. Müller, S. K. Nair, I. F. Nes, G. E. Norris, B. M. Olivera, H. Onaka, M. L. Patchett, J. Piel, M. J. T. Reaney, S. Rebuffat, R. P. Ross, H. G. Sahl, E. W. Schmidt, M. E. Selsted, K. Severinov, B. Shen, K. Sivonen, L. Smith, T. Stein, R. D. Süssmuth, J. R. Tagg, G. L. Tang, A. W. Truman, J. C. Vederas, C. T. Walsh, J. D. Walton, S. C. Wenzel, J. M. Willey, W. A. van der Donk Nat. Prod. Rep. 2013, 30, 108–160, 10.1039/c2np20085f

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13 Resolving kinetics and dynamics of a catalytic reaction inside a fixed bed reactor by combined kinetic and spectroscopic profiling M. Geske, O. Korup, R. Horn Catal. Sci. Technol. Catalysis Science and Technology 2013, 3, 169–175, 10.1039/c2cy20489d

12 Catalytic partial oxidation of methane on platinum investigated by spatial reactor profiles, spatially resolved spectroscopy, and microkinetic modeling O. Korup, C. F. Goldsmith, G. Weinberg, M. Geske, T. Kandemir, R. Schlögl, R. Horn Journal of Catalysis 2013, 297, 1–16, 10.1016/j.jcat.2012.08.022

11 C–N coupling in the gas-phase reactions of ammonia and [M(CH)]+ (M = Ni, Pd, Pt): a combined experimental/computational exercise R. Kretschmer, M. Schlangen, H. Schwarz Dalton Transactions 2013, 42, 4153– 10.1039/c3dt32596b

10 Heterologous Expression and Engineering Studies of Labyrinthopeptins, Class III Lantibiotics from Actinomadura namibiensis J. M. Krawczyk, G. H. Völler, B. Krawczyk, J. Kretz, M. Brönstrup, R. D. Süssmuth Chemistry & Biology 2013, 20, 111–122, 10.1016/j.chembiol.2012.10.023

9 Gas-Phase Reactions of Cationic Vanadium-Phosphorus Oxide Clusters with C H ( 4, 6): A DFT-Based Analysis of Reactivity Patterns N. Dietl, X. Zhang, C. van der Linde, M. K. Beyer, M. Schlangen, H. Schwarz Chemistry - A European Journal 2013, 19, 3017–3028, 10.1002/chem.201203050

8 One-Pot Synthesis of Supported, Nanocrystalline Nickel Manganese Oxide for Dry Reforming of Methane X. Xie, T. Otremba, P. Littlewood, R. Schomäcker, A. Thomas ACS Catalysis ACS Catalysis 2013, 3, 224–229, 10.1021/cs3003963

7 Rise of the Zinc Age in Homogeneous Catalysis? S. Enthaler ACS Catalysis ACS Catalysis 2013, 3, 150–158, 10.1021/cs300685q

6 Straightforward Iron-Catalyzed Synthesis of Vinylboronates by the Hydroboration of Alkynes M. Haberberger, S. Enthaler Chemistry - An Asian Journal 2013, 8, 50–54, 10.1002/asia.201200931

5 Techno-economic analysis of integrating the methane oxidative coupling and methane reforming processes H. R. Godini, S. Xiao, S. Jašo, S. Stünkel, D. Salerno, N. X. Son, S. Song, G. Wozny Fuel Processing Technology Fuel Processing Technology 2013, 106, 684–694, 10.1016/j.fuproc.2012.10.002

4 A Heterobimetallic Approach To Stabilize the Elusive Disulfur Radical Trianion (“Subsulfide”) ${{\rm S}{{{{\bullet}}3- \hfill \atop 2\hfill}}}$ S. Yao, P. Hrobárik, F. Meier, R. Rudolph, E. Bill, E. Irran, M. Kaupp, M. Driess Chemistry - A European Journal 2013, 19, 1246–1253, 10.1002/chem.201203642

3 Combining Spectroscopy and Theory to Evaluate Structural Models of Metalloenzymes: A Case Study on the Soluble [NiFe] Hydrogenase from M. Horch, Y. Rippers, M. A. Mroginski, P. Hildebrandt, I. Zebger ChemPhysChem 2013, 14, 185–191, 10.1002/cphc.201200853

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1 Effect of Ionic Strength and Layer Number on Swelling of Polyelectrolyte Multilayers in Water Vapour S. Dodoo, B. N. Balzer, T. Hugel, A. Laschewsky, R. v. Klitzing Soft Materials Soft Materials 2013, 11, 157–164, 10.1080/1539445X.2011.607203