Publications 2018

Number of records: 130

130 Vibrationally resolved absorption and fluorescence spectra of perylene and N-substituted derivatives from autocorrelation function approaches T. Xiong, R. Włodarczyk, P. Saalfrank Chemical Physics 2018, 515, 728–736, 10.1016/j.chemphys.2018.06.011

129 An efficient first principles method for molecular pump-probe NEXAFS spectra: Application to thymine and azobenzene C. Ehlert, M. Gühr, P. Saalfrank The Journal of Chemical Physics 2018, 149, 144112– 10.1063/1.5050488

128 Crystal structure of the red light-activated channelrhodopsin Chrimson K. Oda, J. Vierock, S. Oishi, S. Rodriguez-Rozada, R. Taniguchi, K. Yamashita, J. S. Wiegert, T. Nishizawa, P. Hegemann, O. Nureki Nature Communications 2018, 9, 10.1038/s41467-018-06421-9

127 Electrical properties, substrate specificity and optogenetic potential of the engineered light-driven sodium pump eKR2 C. Grimm, A. Silapetere, A. Vogt, Y. A. Bernal Sierra, P. Hegemann Scientific Reports 2018, 8, 10.1038/s41598-018-27690-w

126 Oxygen Activation in Oxidative Coupling of Methane on Calcium Oxide L. Thum, M. Rudolph, R. Schomäcker, Y. Wang, A. Tarasov, A. Trunschke, R. Schlögl The Journal of Physical Chemistry C 2018, 123, 8018–8026, 10.1021/acs.jpcc.8b07391

125 Nucleophilic versus Electrophilic Reactivity of Bioinspired Superoxido Nickel(II) Complexes C. Panda, A. Chandra, T. Corona, E. Andris, B. Pandey, S. Garai, N. Lindenmaier, S. Künstner, E. R. Farquhar, J. Roithová, G. Rajaraman, M. Driess, K. Ray Angewandte Chemie International Edition 2018, 57, 14883–14887, 10.1002/anie.201808085

124 Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions M. Guo, T. Corona, K. Ray, W. Nam ACS Central Science 2018, 5, 13–28, 10.1021/acscentsci.8b00698

123 Catalytic Generation and Chemoselective Transfer of Nucleophilic Hydrides from Dihydrogen F. Pape, L. T. Brechmann, J. F. Teichert Chemistry – A European Journal 2018, 10.1002/chem.201805530

122 One pot microwave synthesis of highly stable AuPd@Pd supported core–shell nanoparticles A. G. R. Howe, P. J. Miedziak, D. J. Morgan, Q. He, P. Strasser, J. K. Edwards Faraday Discussions 2018, 208, 409–425, 10.1039/c8fd00004b

121 The medical threat of mamba envenoming in sub-Saharan Africa revealed by genus-wide analysis of venom composition, toxicity and antivenomics profiling of available antivenoms S. Ainsworth, D. Petras, M. Engmark, R. D. Süssmuth, G. Whiteley, L. O. Albulescu, T. D. Kazandjian, S. C. Wagstaff, P. Rowley, W. Wüster, P. C. Dorrestein, A. S. Arias, J. M. Gutiérrez, R. A. Harrison, N. R. Casewell, J. J. Calvete Journal of Proteomics 2018, 172, 173–189, 10.1016/j.jprot.2017.08.016

120 Stereoselective Transfer Semi-Hydrogenation of Alkynes to -Olefins with -Heterocyclic Silylene-Manganese Catalysts Y. P. Zhou, Z. Mo, M. P. Luecke, M. Driess Chemistry - A European Journal 2018, 24, 4740–4740, 10.1002/chem.201800160

119 Nano-Sized Inorganic Energy-Materials by the Low-Temperature Molecular Precursor Approach C. Panda, P. W. Menezes, M. Driess Angewandte Chemie International Edition 2018, 57, 11130–11139, 10.1002/anie.201803673

118 Low-valent group 14 element hydride chemistry: towards catalysis T. J. Hadlington, M. Driess, C. Jones Chemical Society Reviews 2018, 47, 4176–4197, 10.1039/C7CS00649G

117 Metal nitrene-like reactivity of a SiN bond towards CO T. J. Hadlington, T. Szilvási, M. Driess Chemical Communications 2018, 54, 9352–9355, 10.1039/C8CC05238G

116 Chelate Silylene-Silyl Ligand Can Boost Rhodium-Catalyzed C−H Bond Functionalization Reactions Z. Mo, A. Kostenko, Y. P. Zhou, S. Yao, M. Driess Chemistry - A European Journal 2018, 24, 14608–14612, 10.1002/chem.201803089

115 Single‐Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs A. Merk, H. Großekappenberg, M. Schmidtmann, M. Luecke, C. Lorent, M. Driess, M. Oestreich, H. F. T. Klare, T. Müller Angewandte Chemie International Edition 2018, 57, 15267–15271, 10.1002/anie.201808922

114 Structurally Ordered Intermetallic Cobalt Stannide Nanocrystals for High‐Performance Electrocatalytic Overall Water‐Splitting P. W. Menezes, C. Panda, S. Garai, C. Walter, A. Guiet, M. Driess Angewandte Chemie International Edition 2018, 57, 15237–15242, 10.1002/anie.201809787

113 Gold-Decorated Biphase α-Fe O (0001): Activation by CO-Induced Surface Reduction H. Qiu, H. Kuhlenbeck, E. Bauer, H. J. Freund The Journal of Physical Chemistry C 2018, 123, 8221–8227, 10.1021/acs.jpcc.8b08521

112 Methane oxidative coupling process for producing ethylene from fossil- and bio-based methane H. R. Godini, A. Penteado, M. Khadivi, M. Azadi, T. Karsten, O. Görke, E. Esche, A. Orjuela, B. Mokhtarani, R. Schomäcker, G. Wozny, J. U. Repke Chemie Ingenieur Technik Chemie Ingenieur Technik 2018, 90, 1135–1136, 10.1002/cite.201855007

111 Hydrogen reduction and metal-support interaction in a metastable metal-oxide system: Pd on rhombohedral In2O3 L. Schlicker, M. F. Bekheet, A. Gili, A. Doran, A. Gurlo, K. Ploner, T. Schachinger, S. Penner Journal of Solid State Chemistry 2018, 266, 93–99, 10.1016/j.jssc.2018.07.010

110 H reduction of Gd- and Sm-doped ceria compared to pure CeO at high temperatures: effect on structure, oxygen nonstoichiometry, hydrogen solubility and hydroxyl chemistry M. Grünbacher, L. Schlicker, M. F. Bekheet, A. Gurlo, B. Klötzer, S. Penner Physical Chemistry Chemical Physics 2018, 20, 22099–22113, 10.1039/C8CP04350G

109 Structural investigations of La Sr FeO under reducing conditions: kinetic and thermodynamic limitations for phase transformations and iron exsolution phenomena T. Götsch, L. Schlicker, M. F. Bekheet, A. Doran, M. Grünbacher, C. Praty, M. Tada, H. Matsui, N. Ishiguro, A. Gurlo, B. Klötzer, S. Penner RSC Advances 2018, 8, 3120–3131, 10.1039/c7ra12309d

108 Formation of Pd-Ce intermetallic compounds by reductive metal-support interaction T. Götsch, K. Ploner, J. Bernardi, L. Schlicker, A. Gili, A. Doran, A. Gurlo, S. Penner Journal of Solid State Chemistry 2018, 265, 176–183, 10.1016/j.jssc.2018.05.036

107 Magnetic Properties of Reduced and Reoxidized Mn–Na WO /SiO : A Catalyst for Oxidative Coupling of Methane (OCM) W. Riedel, L. Thum, J. Möser, V. Fleischer, U. Simon, K. Siemensmeyer, A. Schnegg, R. Schomäcker, T. Risse, K. P. Dinse The Journal of Physical Chemistry C 2018, 122, 22605–22614, 10.1021/acs.jpcc.8b07386

106 Tailoring of ordered mesoporous silica COK-12: Room temperature synthesis of mesocellular foam and multilamellar vesicles M. G. Colmenares, U. Simon, F. Schmidt, S. Dey, J. Schmidt, A. Thomas, A. Gurlo Microporous and Mesoporous Materials 2018, 267, 142–149, 10.1016/j.micromeso.2018.03.015

105 Transmission and high temperature X-ray powder diffraction in variable gaseous environments L. Schlicker, A. Doran, P. Schneppmüller, A. Gili, M. Czasny, S. Penner, A. Gurlo Review of Scientific Instruments 2018, 89, 33904– 10.1063/1.5001695

104 Unified structural motifs of the catalytically active state of Co(oxyhydr)oxides during the electrochemical oxygen evolution reaction A. Bergmann, T. E. Jones, E. Martinez Moreno, D. Teschner, P. Chernev, M. Gliech, T. Reier, H. Dau, P. Strasser Nature Catalysis 2018, 1, 711–719, 10.1038/s41929-018-0141-2

103 Water Splitting: Unexpected Fe(VI) Trapped by Manipulation of Reaction Kinetics H. Dau Chem 2018, 4, 668–670, 10.1016/j.chempr.2018.03.018

102 A neodymium oxide nanoparticle-doped carbon felt as promising electrode for vanadium redox flow batteries A. Fetyan, G. A. El-Nagar, I. Derr, P. Kubella, H. Dau, C. Roth Electrochimica Acta 2018, 268, 59–65, 10.1016/j.electacta.2018.02.104

101 Reactivity Determinants in Electrodeposited Cu Foams for Electrochemical CO Reduction K. Klingan, T. Kottakkat, Z. P. Jovanov, S. Jiang, C. Pasquini, F. Scholten, P. Kubella, A. Bergmann, B. Roldan Cuenya, C. Roth, H. Dau ChemSusChem 2018, 11, 3449–3459, 10.1002/cssc.201801582

100 Water oxidation by a manganese–potassium cluster: Mn oxide as a kinetically dominant “true” catalyst for water oxidation Y. Mousazade, M. R. Mohammadi, P. Chernev, R. Bikas, R. Bagheri, Z. Song, T. Lis, H. Dau, M. M. Najafpour Catalysis Science & Technology 2018, 8, 4390–4398, 10.1039/C8CY01151F

99 A mononuclear cobalt complex for water oxidation: new controversies and puzzles R. Safdari, M. R. Mohammadi, M. Hołyńska, P. Chernev, H. Dau, M. M. Najafpour Dalton Transactions Dalton Transactions 2018, 47, 16668–16673, 10.1039/C8DT03147A

98 From an Fe P complex to FeP nanoparticles as efficient electrocatalysts for water-splitting S. Yao, V. Forstner, P. W. Menezes, C. Panda, S. Mebs, E. M. Zolnhofer, M. E. Miehlich, T. Szilvási, N. Ashok Kumar, M. Haumann, K. Meyer, H. Grützmacher, M. Driess Chemical Science 2018, 9, 8590–8597, 10.1039/C8SC03407A

97 Stereoselective Alkyne Hydrohalogenation by Trapping of Transfer Hydrogenation Intermediates M. Das, T. Kaicharla, J. F. Teichert Organic Letters 2018, 20, 4926–4929, 10.1021/acs.orglett.8b02055

96 Extending the Toolbox for the Modular Arrangement of Functions at Xanthene/Dibenzofuran Platforms: Introduction of Directly Linked Transition Metals beside Bismuthanes K. Materne, C. Spröwitz, B. Braun-Cula, C. Limberg Zeitschrift für anorganische und allgemeine Chemie Zeitschrift für anorganische und allgemeine Chemie 2018, 644, 700–705, 10.1002/zaac.201800180

95 Bioinspired Designs, Molecular Premise and Tools for Evaluating the Ecological Importance of Antimicrobial Peptides E. Ongey, S. Pflugmacher, P. Neubauer Pharmaceuticals 2018, 11, 68– 10.3390/ph11030068

94 Heterologous Biosynthesis, Modifications and Structural Characterization of Ruminococcin-A, a Lanthipeptide From the Gut Bacterium Ruminococcus gnavus E1, in Escherichia coli E. L. Ongey, R. T. Giessmann, M. Fons, J. Rappsilber, L. Adrian, P. Neubauer Frontiers in Microbiology 2018, 9, 10.3389/fmicb.2018.01688

93 Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C F ) or [H(OEt ) ][B{3,5-(CF ) C H } ] H. Baumgarth, G. Meier, C. N. von Hahmann, T. Braun Dalton Transactions Dalton Transactions 2018, 47, 16299–16304, 10.1039/c8dt03853h

92 Trimethylamine ‐Oxide Electrochemical Biosensor with a Chimeric Enzyme B. Mitrova, A. F. T. Waffo, P. Kaufmann, C. Iobbi‐Nivol, S. Leimkühler, U. Wollenberger ChemElectroChem 2018, 6, 1732–1737, 10.1002/celc.201801422

91 Palladium‐Catalyzed Three‐Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes W. Yuan, P. Orecchia, M. Oestreich Chemistry – A European Journal 2018, 24, 19175–19178, 10.1002/chem.201805595

90 Formation and Evolution of Ultrathin Silica Polymorphs on Ru(0001) Studied with Combined , Real-Time Methods H. W. Klemm, M. J. Prieto, G. Peschel, A. Fuhrich, E. Madej, F. Xiong, D. Menzel, T. Schmidt, H. J. Freund The Journal of Physical Chemistry C 2018, 123, 8228–8243, 10.1021/acs.jpcc.8b08525

89 CO Adsorption on CaO(001): Temperature-Programmed Desorption and Infrared Study X. Weng, Y. Cui, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C 2018, 123, 1880–1887, 10.1021/acs.jpcc.8b11415

88 On the Intrinsic Reactivity of Diatomic 3d Transition-Metal Carbides in the Thermal Activation of Methane: Striking Electronic Structure Effects C. Geng, T. Weiske, J. Li, S. Shaik, H. Schwarz Journal of the American Chemical Society 2018, 10.1021/jacs.8b11739

87 Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON] /CH System S. Zhou, X. Sun, L. Yue, C. Guo, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 15902–15906, 10.1002/anie.201809583

86 Ta -mediated ammonia synthesis from N and H at ambient temperature C. Geng, J. Li, T. Weiske, H. Schwarz Proceedings of the National Academy of Sciences 2018, 115, 11680–11687, 10.1073/pnas.1814610115

85 Structures of the intermediates of Kok’s photosynthetic water oxidation clock J. Kern, R. Chatterjee, I. D. Young, F. D. Fuller, L. Lassalle, M. Ibrahim, S. Gul, T. Fransson, A. S. Brewster, R. Alonso-Mori, R. Hussein, M. Zhang, L. Douthit, C. de Lichtenberg, M. H. Cheah, D. Shevela, J. Wersig, I. Seuffert, D. Sokaras, E. Pastor, C. Weninger, T. Kroll, R. G. Sierra, P. Aller, A. Butryn, A. M. Orville, M. Liang, A. Batyuk, J. E. Koglin, S. Carbajo, S. Boutet, N. W. Moriarty, J. M. Holton, H. Dobbek, P. D. Adams, U. Bergmann, N. K. Sauter, A. Zouni, J. Messinger, J. Yano, V. K. Yachandra Nature 2018, 563, 421–425, 10.1038/s41586-018-0681-2

84 Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane C. Geng, J. Li, M. Schlangen, S. Shaik, X. Sun, N. Wang, T. Weiske, L. Yue, S. Zhou, H. Schwarz Dalton Transactions Dalton Transactions 2018, 47, 15271–15277, 10.1039/c8dt03048k

83 The Electric Field as a “Smart” Ligand in Controlling the Thermal Activation of Methane and Molecular Hydrogen L. Yue, N. Wang, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 14635–14639, 10.1002/anie.201805718

82 Surface Carbon as a Reactive Intermediate in Dry Reforming of Methane to Syngas on a 5% Ni/MnO Catalyst A. Gili, L. Schlicker, M. F. Bekheet, O. Görke, S. Penner, M. Grünbacher, T. Götsch, P. Littlewood, T. J. Marks, P. C. Stair, R. Schomäcker, A. Doran, S. Selve, U. Simon, A. Gurlo ACS Catalysis 2018, 8, 8739–8750, 10.1021/acscatal.8b01820

81 Spin Transition and Charge Transfer in Co /Co Complexes of Meridional Ligands Holding Nearby Redox-active Triarylamine L. Schnaubelt, H. Petzold, J. M. Speck, T. Rüffer, G. Hörner, H. Lang Zeitschrift für anorganische und allgemeine Chemie Zeitschrift für anorganische und allgemeine Chemie 2018, 644, 1257–1267, 10.1002/zaac.201800274

80 Bis-meridional Fe spincrossover complexes of phenyl and pyridyl substituted 2-(pyridin-2-yl)-1,10-phenanthrolines H. Petzold, P. Djomgoue, G. Hörner, C. Lochenie, B. Weber, T. Rüffer Dalton Transactions Dalton Transactions 2018, 47, 491–506, 10.1039/C7DT02320K

79 Tuning of Thiyl/Thiolate Complex Near-Infrared Chromophores of Platinum through Geometrical Constraints N. M. Mews, G. Hörner, H. Schubert, A. Berkefeld Inorganic Chemistry 2018, 57, 9670–9682, 10.1021/acs.inorgchem.8b00122

78 Redox Series of Cyclometalated Nickel Complexes [Ni((R)Ph(R′)bpy)Br] (H–(R)Ph(R′)bpy = Substituted 6-Phenyl-2,2′-bipyridine) A. Sandleben, N. Vogt, G. Hörner, A. Klein Organometallics 2018, 37, 3332–3341, 10.1021/acs.organomet.8b00559

77 Selective C−O Coupling Hidden in the Thermal Reaction of [Al CuO ] with Methane S. Zhou, X. Sun, L. Yue, M. Schlangen, H. Schwarz Chemistry - A European Journal 2018, 24, 14649–14653, 10.1002/chem.201804059

76 Quantum-Chemical Approach to NMR Chemical Shifts in Paramagnetic Solids Applied to LiFePO and LiCoPO A. Mondal, M. Kaupp The Journal of Physical Chemistry Letters 2018, 9, 1480–1484, 10.1021/acs.jpclett.8b00407

75 Label-Free MIP Sensors for Protein Biomarkers U. Wollenberger, A. Yarman, X. Zhang, K. J. Jetzschmann, F. W. Scheller Label-Free Biosensing M.J. Schöning, A. Poghossian Springer 2018, 291–321, 10.1007/5346_2017_3

74 Molecular LEGO by domain-imprinting of cytochrome P450 BM3 K. J. Jetzschmann, A. Yarman, L. Rustam, P. Kielb, V. B. Urlacher, A. Fischer, I. M. Weidinger, U. Wollenberger, F. W. Scheller Colloids and Surfaces B: Biointerfaces 2018, 164, 240–246, 10.1016/j.colsurfb.2018.01.047

73 Enhancement of the Electrocatalytic Activity of Thienyl‐Substituted Iron Porphyrin Electropolymers by a Hangman Effect B. Neumann, R. Götz, P. Wrzolek, F. W. Scheller, I. M. Weidinger, M. Schwalbe, U. Wollenberger ChemCatChem 2018, 10, 4353–4361, 10.1002/cctc.201800934

72 Hydrogen Spillover to Copper Clusters on Hydroxylated γ-Al O G. Feng, M. V. Ganduglia-Pirovano, C. F. Huo, J. Sauer The Journal of Physical Chemistry C 2018, 122, 18445–18455, 10.1021/acs.jpcc.8b03764

71 Vanadium Oxide Oligomers and Ordered Monolayers Supported on CeO (111): Structure and Stability Studied by Density Functional Theory C. Penschke, J. Paier, J. Sauer The Journal of Physical Chemistry C 2018, 122, 9101–9110, 10.1021/acs.jpcc.8b01998

70 Facile Formation of Nanostructured Manganese Oxide Films as High‐Performance Catalysts for the Oxygen Evolution Reaction C. Walter, P. W. Menezes, S. Loos, H. Dau, M. Driess ChemSusChem 2018, 11, 2554–2561, 10.1002/cssc.201800493

69 Geometric distortions in nickel (oxy)hydroxide electrocatalysts by redox inactive iron ions R. D. L. Smith, C. Pasquini, S. Loos, P. Chernev, K. Klingan, P. Kubella, M. R. Mohammadi, D. González-Flores, H. Dau Energy & Environmental Science 2018, 11, 2476–2485, 10.1039/C8EE01063C

68 Kα X-ray Emission Spectroscopy on the Photosynthetic Oxygen-Evolving Complex Supports Manganese Oxidation and Water Binding in the S State N. Schuth, I. Zaharieva, P. Chernev, G. Berggren, M. Anderlund, S. Styring, H. Dau, M. Haumann Inorganic Chemistry 2018, 57, 10424–10430, 10.1021/acs.inorgchem.8b01674

67 The Concept of “Noble, Heteroatom-Doped Carbons,” Their Directed Synthesis by Electronic Band Control of Carbonization, and Applications in Catalysis and Energy Materials M. Antonietti, M. Oschatz Advanced Materials 2018, 30, 1706836– 10.1002/adma.201706836

66 Splitting Water by Electrochemistry and Artificial Photosynthesis: Excellent Science but a Nightmare of Translation? M. Antonietti, A. Savateev The Chemical Record 2018, 18, 969–972, 10.1002/tcr.201700062

65 A structurally versatile nickel phosphite acting as a robust bifunctional electrocatalyst for overall water splitting P. W. Menezes, C. Panda, S. Loos, F. Bunschei-Bruns, C. Walter, M. Schwarze, X. Deng, H. Dau, M. Driess Energy & Environmental Science 2018, 11, 1287–1298, 10.1039/C7EE03619A

64 Nickel-iron catalysts for electrochemical water oxidation – redox synergism investigated by X-ray spectroscopy with millisecond time resolution D. González-Flores, K. Klingan, P. Chernev, S. Loos, M. R. Mohammadi, C. Pasquini, P. Kubella, I. Zaharieva, R. D. L. Smith, H. Dau Sustainable Energy & Fuels 2018, 2, 1986–1994, 10.1039/C8SE00114F

63 Mehrstufige nichtlineare Regelung der autrotrophen Kultivierung von F. Neddermeyer, R. King Chemie Ingenieur Technik Chemie Ingenieur Technik 2018, 90, 1249–1250, 10.1002/cite.201855259

62 -Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation F. Forster, V. M. Rendón López, M. Oestreich Organometallics 2018, 37, 2656–2659, 10.1021/acs.organomet.8b00409

61 Robust electrografted interfaces on metal oxides for electrocatalysis – an spectroelectrochemical study T. G. A. A. Harris, R. Götz, P. Wrzolek, V. Davis, C. E. Knapp, K. Ly, P. Hildebrandt, M. Schwalbe, I. Weidinger, I. Zebger, A. Fischer Journal of Materials Chemistry A 2018, 6, 15200–15212, 10.1039/C8TA02983K

60 Electrosynthesized MIPs for transferrin: Plastibodies or nano-filters? X. Zhang, A. Yarman, J. Erdossy, S. Katz, I. Zebger, K. J. Jetzschmann, Z. Altintas, U. Wollenberger, R. E. Gyurcsányi, F. W. Scheller Biosensors and Bioelectronics 2018, 105, 29–35, 10.1016/j.bios.2018.01.011

59 Catalytic Activity and Proton Translocation of Reconstituted Respiratory Complex I Monitored by Surface-Enhanced Infrared Absorption Spectroscopy O. Gutiérrez-Sanz, E. Forbrig, A. P. Batista, M. M. Pereira, J. Salewski, M. A. Mroginski, R. Götz, A. L. De Lacey, J. Kozuch, I. Zebger Langmuir 2018, 34, 5703–5711, 10.1021/acs.langmuir.7b04057

58 Solar Water Splitting with a Hydrogenase Integrated in Photoelectrochemical Tandem Cells D. H. Nam, J. Z. Zhang, V. Andrei, N. Kornienko, N. Heidary, A. Wagner, K. Nakanishi, K. P. Sokol, B. Slater, I. Zebger, S. Hofmann, J. C. Fontecilla‐Camps, C. B. Park, E. Reisner Angewandte Chemie International Edition 2018, 57, 10595–10599, 10.1002/anie.201805027

57 Photosynthesis supported by a chlorophyll f-dependent, entropy-driven uphill energy transfer in Halomicronema hongdechloris cells adapted to far-red light F. J. Schmitt, Z. Y. Campbell, M. V. Bui, A. Hüls, T. Tomo, M. Chen, E. G. Maksimov, S. I. Allakhverdiev, T. Friedrich Photosynthesis Research 2018, 139, 185–201, 10.1007/s11120-018-0556-2

56 In Situ Spectroelectrochemical Studies into the Formation and Stability of Robust Diazonium-Derived Interfaces on Gold Electrodes for the Immobilization of an Oxygen-Tolerant Hydrogenase T. G. A. A. Harris, N. Heidary, J. Kozuch, S. Frielingsdorf, O. Lenz, M. A. Mroginski, P. Hildebrandt, I. Zebger, A. Fischer ACS Applied Materials & Interfaces 2018, 10, 23380–23391, 10.1021/acsami.8b02273

55 O -Tolerant H Activation by an Isolated Large Subunit of a [NiFe] Hydrogenase S. Hartmann, S. Frielingsdorf, A. Ciaccafava, C. Lorent, J. Fritsch, E. Siebert, J. Priebe, M. Haumann, I. Zebger, O. Lenz Biochemistry 2018, 57, 5339–5349, 10.1021/acs.biochem.8b00760

54 Engineering \'Golden\' Fluorescence by Selective Pressure Incorporation of Non-canonical Amino Acids and Protein Analysis by Mass Spectrometry and Fluorescence T. Baumann, F. J. Schmitt, A. Pelzer, V. J. Spiering, G. J. Freiherr von Sass, T. Friedrich, N. Budisa Journal of Visualized Experiments 2018, 10.3791/57017

53 Fully electrochemical MIP sensor for artemisinin A. F. T. Waffo, C. Yesildag, G. Caserta, S. Katz, I. Zebger, M. C. Lensen, U. Wollenberger, F. W. Scheller, Z. Altintas Sensors and Actuators B: Chemical 2018, 275, 163–173, 10.1016/j.snb.2018.08.018

52 Antimicrobial Peptides Produced by Selective Pressure Incorporation of Non-canonical Amino Acids J. H. Nickling, T. Baumann, F. J. Schmitt, M. Bartholomae, O. P. Kuipers, T. Friedrich, N. Budisa Journal of Visualized Experiments 2018, 10.3791/57551

51 Model systems in heterogeneous catalysis: towards the design and understanding of structure and electronic properties Q. Pan, L. Li, S. Shaikhutdinov, Y. Fujimori, M. Hollerer, M. Sterrer, H. J. Freund Faraday Discussions 2018, 208, 307–323, 10.1039/c7fd00209b

50 Correction to: Aspergillus niger is a superior expression host for the production of bioactive fungal cyclodepsipeptides S. Boecker, S. Grätz, D. Kerwat, L. Adam, D. Schirmer, L. Richter, T. Schütze, D. Petras, R. D. Süssmuth, V. Meyer Fungal Biology and Biotechnology 2018, 5, 10.1186/s40694-018-0051-8

49 3D Anionic Silicate Covalent Organic Framework with srs Topology O. Yahiaoui, A. N. Fitch, F. Hoffmann, M. Fröba, A. Thomas, J. Roeser Journal of the American Chemical Society 2018, 140, 5330–5333, 10.1021/jacs.8b01774

48 Bifunctional Electrocatalysts for Overall Water Splitting from an Iron/Nickel-Based Bimetallic Metal-Organic Framework/Dicyandiamide Composite X. Zhao, P. Pachfule, S. Li, J. R. J. Simke, J. Schmidt, A. Thomas Angewandte Chemie International Edition 2018, 57, 8921–8926, 10.1002/anie.201803136

47 Stabilization of β-Diketiminato Nickel(I) with Alkaline Metal Halide Entities for Small Molecule Activation P. Holze, B. Braun-Cula, S. Mebs, C. Limberg Zeitschrift für anorganische und allgemeine Chemie Zeitschrift für anorganische und allgemeine Chemie 2018, 644, 973–981, 10.1002/zaac.201800100

46 A Biomimetic Nickel Complex with a Reduced CO Ligand Generated by Formate Deprotonation and Its Behaviour towards CO P. Zimmermann, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg Angewandte Chemie International Edition 2018, 57, 7230–7233, 10.1002/anie.201802655

45 Crystal structure and functional characterization of selenocysteine-containing glutathione peroxidase 4 suggests an alternative mechanism of peroxide reduction A. Borchert, J. Kalms, S. R. Roth, M. Rademacher, A. Schmidt, H. G. Holzhutter, H. Kuhn, P. Scheerer Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids 2018, 1863, 1095–1107, 10.1016/j.bbalip.2018.06.006

44 An incretin-based tri-agonist promotes superior insulin secretion from murine pancreatic islets via PLC activation N. Khajavi, B. Finan, O. Kluth, T. D. Müller, S. Mergler, A. Schulz, G. Kleinau, P. Scheerer, A. Schürmann, T. Gudermann, M. H. Tschöp, H. Krude, R. D. DiMarchi, H. Biebermann Cellular Signalling 2018, 51, 13–22, 10.1016/j.cellsig.2018.07.006

43 Binding, Thermodynamics, and Selectivity of a Non-peptide Antagonist to the Melanocortin-4 Receptor N. Saleh, G. Kleinau, N. Heyder, T. Clark, P. W. Hildebrand, P. Scheerer Frontiers in Pharmacology 2018, 9, 10.3389/fphar.2018.00560

42 The Trace Amine-Associated Receptor 1 Agonist 3-Iodothyronamine Induces Biased Signaling at the Serotonin 1b Receptor J. Bräunig, J. Dinter, C. S. Höfig, S. Paisdzior, M. Szczepek, P. Scheerer, M. Rosowski, J. Mittag, G. Kleinau, H. Biebermann Frontiers in Pharmacology 2018, 9, 10.3389/fphar.2018.00222

41 Custom Hydrosilane Synthesis Based on Monosilane W. Yuan, P. Smirnov, M. Oestreich Chem 2018, 4, 1443–1450, 10.1016/j.chempr.2018.03.017

40 Stepwise Methane-to-Methanol Conversion on CuO/SBA-15 H. V. Le, S. Parishan, A. Sagaltchik, H. Ahi, A. Trunschke, R. Schomäcker, A. Thomas Chemistry - A European Journal 2018, 24, 12592–12599, 10.1002/chem.201801135

39 Investigation into Consecutive Reactions of Ethane and Ethene Under the OCM Reaction Conditions over MnxOy–Na2WO4/SiO2 Catalyst S. Parishan, E. Nowicka, V. Fleischer, C. Schulz, M. G. Colmenares, F. Rosowski, R. Schomäcker Catalysis Letters 2018, 148, 1659–1675, 10.1007/s10562-018-2384-6

38 Photocatalytic CO Reduction by Mesoporous Polymeric Carbon Nitride Photocatalysts M. Tasbihi, A. Acharjya, A. Thomas, M. Reli, N. AmbroŽová, K. Kočcí, R. Schomäcker Journal of Nanoscience and Nanotechnology 2018, 18, 5636–5644, 10.1166/jnn.2018.15445

37 Terminal Hydride Species in [FeFe]‐Hydrogenases Are Vibrationally Coupled to the Active Site Environment C. C. Pham, D. W. Mulder, V. Pelmenschikov, P. W. King, M. W. Ratzloff, H. Wang, N. Mishra, E. E. Alp, J. Zhao, M. Y. Hu, K. Tamasaku, Y. Yoda, S. P. Cramer Angewandte Chemie International Edition 2018, 57, 10605–10609, 10.1002/anie.201805144

36 Thermal O–H Bond Activation of Water As Mediated by Heteronuclear [Al Mg O ] : Evidence for Oxygen-Atom Scrambling C. Geng, J. Li, T. Weiske, H. Schwarz Journal of the American Chemical Society 2018, 140, 9275–9281, 10.1021/jacs.8b05618

35 High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT V. Pelmenschikov, L. B. Gee, H. Wang, K. C. MacLeod, S. F. McWilliams, K. L. Skubi, S. P. Cramer, P. L. Holland Angewandte Chemie International Edition 2018, 57, 9367–9371, 10.1002/anie.201804601

34 Water Formation under Silica Thin Films: Real-Time Observation of a Chemical Reaction in a Physically Confined Space M. J. Prieto, H. W. Klemm, F. Xiong, D. M. Gottlob, D. Menzel, T. Schmidt, H. J. Freund Angewandte Chemie International Edition 2018, 57, 8749–8753, 10.1002/anie.201802000

33 Controlling the charge state of supported nanoparticles in catalysis: lessons from model systems G. Pacchioni, H. J. Freund Chemical Society Reviews 2018, 47, 8474–8502, 10.1039/c8cs00152a

32 Experimental Identification of the Active Site in the Heteronuclear Redox Couples [AlVO ] /CO/N O ( 3, 4) by Gas-Phase IR Spectroscopy S. Debnath, H. Knorke, W. Schöllkopf, S. Zhou, K. R. Asmis, H. Schwarz Angewandte Chemie International Edition 2018, 57, 7448–7452, 10.1002/anie.201804056

31 On the Origin of the Distinctly Different Reactivity of Ruthenium in [MO] /CH Systems (M=Fe, Ru, Os) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 5934–5937, 10.1002/anie.201800173

30 High Electromagnetic Field Enhancement of TiO Nanotube Electrodes I. H. Öner, C. J. Querebillo, C. David, U. Gernert, C. Walter, M. Driess, S. Leimkühler, K. H. Ly, I. M. Weidinger Angewandte Chemie International Edition 2018, 57, 7225–7229, 10.1002/anie.201802597

29 Hydrogen evolution by cobalt hangman porphyrins under operating conditions studied by vibrational spectro-electrochemistry P. Kielb, M. Horch, P. Wrzolek, R. Goetz, K. H. Ly, J. Kozuch, M. Schwalbe, I. M. Weidinger Catalysis Science & Technology Catalysis Science & Technology 2018, 8, 1849–1857, 10.1039/C7CY02253K

28 ATP-dependent substrate reduction at an [Fe S ] double-cubane cluster J. H. Jeoung, H. Dobbek Proceedings of the National Academy of Sciences 2018, 115, 2994–2999, 10.1073/pnas.1720489115

27 The arrestin-1 finger loop interacts with two distinct conformations of active rhodopsin M. Elgeti, R. Kazmin, A. S. Rose, M. Szczepek, P. W. Hildebrand, F. J. Bartl, P. Scheerer, K. P. Hofmann Journal of Biological Chemistry 2018, 293, 4403–4410, 10.1074/jbc.M117.817890

26 Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminum Chlorofluoride B. Calvo, T. Braun, E. Kemnitz ChemCatChem 2018, 10, 403–406, 10.1002/cctc.201701327

25 Four-electron reduction of dioxygen to water by a trinuclear copper complex X. Engelmann, E. R. Farquhar, J. England, K. Ray Inorganica Chimica Acta Inorganica Chimica Acta 2018, 481, 159–165, 10.1016/j.ica.2017.11.014

24 Tracking the route of molecular oxygen in O -tolerant membrane-bound [NiFe] hydrogenase J. Kalms, A. Schmidt, S. Frielingsdorf, T. Utesch, G. Gotthard, D. von Stetten, P. van der Linden, A. Royant, M. A. Mroginski, P. Carpentier, O. Lenz, P. Scheerer Proceedings of the National Academy of Sciences 2018, 115, 10.1073/pnas.1712267115

23 Direct Room-Temperature Conversion of Methane into Protonated Formaldehyde: The Gas-Phase Chemistry of Mercury among the Zinc Triad Oxide Cations L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 3251–3255, 10.1002/anie.201712405

22 Copper( ) complexes based on ligand systems with two different binding sites: synthesis, structures and reaction with O S. T. Li, B. Braun-Cula, S. Hoof, C. Limberg Dalton Transactions Dalton Transactions 2018, 47, 544–560, 10.1039/c7dt03752j

21 Active Salt/Silica-Templated 2D Mesoporous FeCo-N -Carbon as Bifunctional Oxygen Electrodes for Zinc-Air Batteries S. Li, C. Cheng, X. Zhao, J. Schmidt, A. Thomas Angewandte Chemie International Edition 2018, 57, 1856–1862, 10.1002/anie.201710852

20 Carbon Monoxide Oxidation on Metal-Supported Monolayer Oxide Films: Establishing Which Interface is Active K. Zhang, L. Li, S. Shaikhutdinov, H. J. Freund Angewandte Chemie International Edition 2018, 57, 1261–1265, 10.1002/anie.201710934

19 Charge Control in Model Catalysis: The Decisive Role of the Oxide-Nanoparticle Interface W. D. Schneider, M. Heyde, H. J. Freund Chemistry - A European Journal 2018, 24, 2317–2327, 10.1002/chem.201703169

18 Ordered mesoporous WO : selective reduction synthesis, exceptional localized surface plasmon resonance and enhanced hydrogen evolution reaction activity H. Cheng, M. Klapproth, A. Sagaltchik, S. Li, A. Thomas Journal of Materials Chemistry A Journal of Materials Chemistry A 2018, 6, 2249–2256, 10.1039/c7ta09579a

17 Ionic Liquid-Assisted Synthesis of Mesoporous Carbons with Surface-Enriched Nitrogen for the Hydrogen Evolution Reaction X. Zhao, S. Li, H. Cheng, J. Schmidt, A. Thomas ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces 2018, 10, 3912–3920, 10.1021/acsami.7b14919

16 Batch and continuous synthesis upscaling of powder and monolithic ordered mesoporous silica COK-12 M. G. Colmenares, U. Simon, O. Cruz, A. Thomas, O. Goerke, A. Gurlo Microporous and Mesoporous Materials 2018, 256, 102–110, 10.1016/j.micromeso.2017.08.002

15 Enzymatic and spectroscopic properties of a thermostable [NiFe]‑hydrogenase performing H2-driven NAD+-reduction in the presence of O2 J. Preissler, S. Wahlefeld, C. Lorent, C. Teutloff, M. Horch, L. Lauterbach, S. P. Cramer, I. Zebger, O. Lenz Biochimica et Biophysica Acta (BBA) - Bioenergetics 2018, 1859, 8–18, 10.1016/j.bbabio.2017.09.006

14 First-principles supercell calculations of small polarons with proper account for long-range polarization effects S. Kokott, S. V. Levchenko, P. Rinke, M. Scheffler New Journal of Physics 2018, 20, 33023– 10.1088/1367-2630/aaaf44

13 Investigation of the role of the Na2WO4/Mn/SiO2 catalyst composition in the oxidative coupling of methane by chemical looping experiments V. Fleischer, U. Simon, S. Parishan, M. G. Colmenares, O. Görke, A. Gurlo, W. Riedel, L. Thum, J. Schmidt, T. Risse, K. P. Dinse, R. Schomäcker Journal of Catalysis 2018, 360, 102–117, 10.1016/j.jcat.2018.01.022

12 Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation P. Pachfule, A. Acharjya, J. Roeser, T. Langenhahn, M. Schwarze, R. Schomäcker, A. Thomas, J. Schmidt Journal of the American Chemical Society 2018, 140, 1423–1427, 10.1021/jacs.7b11255

11 Chemical looping as a reactor concept for the oxidative coupling of methane over the MnxOy-Na2WO4/SiO2 catalyst, benefits and limitation S. Parishan, P. Littlewood, A. Arinchtein, V. Fleischer, R. Schomäcker Catalysis Today 2018, 311, 40–47, 10.1016/j.cattod.2017.08.019

10 Stereoselective Transfer Semi-Hydrogenation of Alkynes to -Olefins with -Heterocyclic Silylene-Manganese Catalysts Y. P. Zhou, Z. Mo, M. P. Luecke, M. Driess Chemistry - A European Journal 2018, 24, 4780–4784, 10.1002/chem.201705745

9 Dual-wavelength 3D photoacoustic imaging of mammalian cells using a photoswitchable phytochrome reporter protein J. Märk, H. Dortay, A. Wagener, E. Zhang, J. Buchmann, C. Grötzinger, T. Friedrich, J. Laufer Communications Physics Communications Physics 2018, 1, 10.1038/s42005-017-0003-2

8 Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+ M. Firouzbakht, N. J. Rijs, M. Schlangen, M. Kaupp, H. Schwarz Topics in Catalysis 2018, 61, 575–584, 10.1007/s11244-018-0903-8

7 Exact Mapping from Many‐Spin Hamiltonians to Giant‐Spin Hamiltonians S. Ghassemi Tabrizi, A. V. Arbuznikov, M. Kaupp Chemistry – A European Journal 2018, 24, 4689–4702, 10.1002/chem.201705897

6 Modulating the Molybdenum Coordination Sphere of Trimethylamine -Oxide Reductase P. Kaufmann, B. R. Duffus, B. Mitrova, C. Iobbi-Nivol, C. Teutloff, M. Nimtz, L. Jänsch, U. Wollenberger, S. Leimkühler Biochemistry 2018, 57, 1130–1143, 10.1021/acs.biochem.7b01108

5 Spectroelectrochemical insights into structural and redox properties of immobilized endonuclease III and its catalytically inactive mutant E. Moe, F. Rollo, C. M. Silveira, M. Sezer, P. Hildebrandt, S. Todorovic Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2018, 188, 149–154, 10.1016/j.saa.2017.06.050

4 A Molecular Approach to Manganese Nitride Acting as a High Performance Electrocatalyst in the Oxygen Evolution Reaction C. Walter, P. W. Menezes, S. Orthmann, J. Schuch, P. Connor, B. Kaiser, M. Lerch, M. Driess Angewandte Chemie International Edition 2018, 57, 698–702, 10.1002/anie.201710460

3 Striking transformations of the hydroborylene ligand in a HB:→Ni complex with isocyanides and CO T. J. Hadlington, T. Szilvási, M. Driess Chemical Science 2018, 9, 2595–2600, 10.1039/C7SC04792D

2 Sterically Stabilized Terminal Hydride of a Diiron Dithiolate M. R. Carlson, D. L. Gray, C. P. Richers, W. Wang, P. H. Zhao, T. B. Rauchfuss, V. Pelmenschikov, C. C. Pham, L. B. Gee, H. Wang, S. P. Cramer Inorganic Chemistry 2018, 57, 1988–2001, 10.1021/acs.inorgchem.7b02903

1 Mechanistic insights into the role of prenyl-binding protein PrBP/δ in membrane dissociation of phosphodiesterase 6 B. M. Qureshi, A. Schmidt, E. Behrmann, J. Bürger, T. Mielke, C. M. T. Spahn, M. Heck, P. Scheerer Nature Communications Nature Communications 2018, 9, 10.1038/s41467-017-02569-y