Publikationen 2015

Anzahl der Datensätze: 216

216Orientation-Controlled Electrocatalytic Efficiency of an Adsorbed Oxygen-Tolerant Hydrogenase N. Heidary, T. Utesch, M. Zerball, M. Horch, D. Millo, J. Fritsch, O. Lenz, R. von Klitzing, P. Hildebrandt, A. Fischer, M. A. Mroginski, I. Zebger PLOS ONE 2015, 10, 10.1371/journal.pone.0143101

215A noble metal-free proton-exchange membrane fuel cell based on bio-inspired molecular catalysts P. D. Tran, A. Morozan, S. Archambault, J. Heidkamp, P. Chenevier, H. Dau, M. Fontecave, A. Martinent, B. Jousselme, V. Artero Chem. Sci. 2015, 6, 2050–2053, 10.1039/C4sc03774j

214Structure and Mechanism Leading to Formation of the Cysteine Sulfinate Product Complex of a Biomimetic Cysteine Dioxygenase Model M. Sallmann, S. Kumar, P. Chernev, J. Nehrkorn, A. Schnegg, D. Kumar, H. Dau, C. Limberg, S. P. de Visser Chemistry - A European Journal 2015, 21, 7470–7479, 10.1002/chem.201500644

213Water oxidation by amorphous cobalt-based oxides: in situ tracking of redox transitions and mode of catalysis M. Risch, F. Ringleb, M. Kohlhoff, P. Bogdanoff, P. Chernev, I. Zaharieva, H. Dau Energy Environ. Sci. 2015, 8, 661–674, 10.1039/C4ee03004d

212Atomistic Texture of Amorphous Manganese Oxides for Electrochemical Water Splitting Revealed by Ab Initio Calculations Combined with X-ray Spectroscopy G. Mattioli, I. Zaharieva, H. Dau, L. Guidoni Journal of the American Chemical Society 2015, 137, 10254–10267, 10.1021/jacs.5b05174

211From molecular copper complexes to composite electrocatalytic materials for selective reduction of CO2to formic acid T. N. Huan, E. S. Andreiadis, J. Heidkamp, P. Simon, E. Derat, S. Cobo, G. Royal, A. Bergmann, P. Strasser, H. Dau, V. Artero, M. Fontecave J. Mater. Chem. A 2015, 3, 3901–3907, 10.1039/C4ta07022d

210Optogenetic acidification of synaptic vesicles and lysosomes B. R. Rost, F. Schneider, M. K. Grauel, C. Wozny, C. G Bentz, A. Blessing, T. Rosenmund, T. J. Jentsch, D. Schmitz, P. Hegemann, C. Rosenmund Nature Neuroscience 2015, 18, 1845–1852, 10.1038/nn.4161

209Low frequency dynamics of the nitrogenase MoFe protein via femtosecond pump probe spectroscopy — Observation of a candidate promoting vibration M. Maiuri, I. Delfino, G. Cerullo, C. Manzoni, V. Pelmenschikov, Y. Guo, H. Wang, L. B. Gee, C. H. Dapper, W. E. Newton, S. P. Cramer Journal of Inorganic Biochemistry 2015, 153, 128–135, 10.1016/j.jinorgbio.2015.07.005

208Dehydrogenation of cycloalkanes at rhodium complexes bearing fluorinated cyclopentadienyl ligands F. Liebau, T. Braun, B. Braun Journal of Fluorine Chemistry 2015, 180, 192–200, 10.1016/j.jfluchem.2015.09.014

207Remarkable reactivity of a rhodium(i) boryl complex towards CO2and CS2: isolation of a carbido complex S. I. Kalläne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann, R. Laubenstein Chem. Commun. 2015, 51, 14613–14616, 10.1039/C5CC05606C

206Strengthening gold–gold bonds by complexing gold clusters with noble gases L. M. Ghiringhelli, S. V. Levchenko Inorganic Chemistry Communications 2015, 55, 153–156, 10.1016/j.inoche.2015.03.010

205Hybrid functionals for large periodic systems in an all-electron, numeric atom-centered basis framework S. V. Levchenko, X. Ren, J. Wieferink, R. Johanni, P. Rinke, V. Blum, M. Scheffler Computer Physics Communications 2015, 192, 60–69, 10.1016/j.cpc.2015.02.021

204Structure sensitivity of the oxidative activation of methane over MgO model catalysts: II. Nature of active sites and reaction mechanism P. Schwach, N. Hamilton, M. Eichelbaum, L. Thum, T. Lunkenbein, R. Schlögl, A. Trunschke Journal of Catalysis 2015, 329, 574–587, 10.1016/j.jcat.2015.05.008

203Structure sensitivity of the oxidative activation of methane over MgO model catalysts: I. Kinetic study P. Schwach, W. Frandsen, M. G. Willinger, R. Schlögl, A. Trunschke Journal of Catalysis 2015, 329, 560–573, 10.1016/j.jcat.2015.05.007

202Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide T. Lunkenbein, F. Girgsdies, A. Wernbacher, J. Noack, G. Auffermann, A. Yasuhara, A. Klein-Hoffmann, W. Ueda, M. Eichelbaum, A. Trunschke, R. Schlögl, M. G. Willinger Angewandte Chemie International Edition 2015, 54, 6828–6831, 10.1002/anie.201502236

201The Cell Factory Aspergillus Enters the Big Data Era: Opportunities and Challenges for Optimising Product Formation. V. Meyer, M. Fiedler, B. Nitsche, R. King Advances in Biochemical Engineering/Biotechnology 2015, 149, 91–132, 10.1007/10_2014_297

200Photochemical and electrocatalytic water oxidation activity of cobalt carbodiimide D. Ressnig, M. Shalom, J. Patscheider, R. Moré, F. Evangelisti, M. Antonietti, G. R. Patzke J. Mater. Chem. A 2015, 3, 5072–5082, 10.1039/c5ta00369e

199Nickel nitride as an efficient electrocatalyst for water splitting M. Shalom, D. Ressnig, X. Yang, G. Clavel, T. P. Fellinger, M. Antonietti J. Mater. Chem. A 2015, 3, 8171–8177, 10.1039/c5ta00078e

198Ionic liquid- and surfactant-controlled crystallization of WO3films H. Kaper, I. Djerdj, S. Gross, H. Amenitsch, M. Antonietti, B. M. Smarsly Phys. Chem. Chem. Phys. 2015, 17, 18138–18145, 10.1039/c5cp01869b

197Redefining biorefinery: the search for unconventional building blocks for materials D. Esposito, M. Antonietti Chem. Soc. Rev. 2015, 44, 5821–5835, 10.1039/c4cs00368c

196Highly Porous Materials as Tunable Electrocatalysts for the Hydrogen and Oxygen Evolution Reaction M. Ledendecker, G. Clavel, M. Antonietti, M. Shalom Advanced Functional Materials 2015, 25, 393–399, 10.1002/adfm.201402078

195Hybrid C3N4/Fluorine-Doped Tin Oxide Electrode Transfers Hydride for 1,4-NADH Cofactor Regeneration R. Cazelles, J. Liu, M. Antonietti ChemElectroChem 2015, 2, 333–337, 10.1002/celc.201402421

194Efficient Water Splitting Using a Simple Ni/N/C Paper Electrocatalyst J. Ren, M. Antonietti, T. P. Fellinger Advanced Energy Materials 2015, 5, 10.1002/aenm.201401660

193Bifunctional Metal-Free Catalysis of Mesoporous Noble Carbons for Oxygen Reduction and Evolution Reactions K. Sakaushi, T. P. Fellinger, M. Antonietti ChemSusChem 2015, 8, 1156–1160, 10.1002/cssc.201500102

192High Surface Iron/Cobalt-Containing Nitrogen-Doped Carbon Aerogels as Non-Precious Advanced Electrocatalysts for Oxygen Reduction K. Elumeeva, J. Ren, M. Antonietti, T. P. Fellinger ChemElectroChem 2015, 2, 584–591, 10.1002/celc.201402364

191Silver Phosphate/Graphitic Carbon Nitride as an Efficient Photocatalytic Tandem System for Oxygen Evolution X. Yang, H. Tang, J. Xu, M. Antonietti, M. Shalom ChemSusChem 2015, 8, 1350–1358, 10.1002/cssc.201403168

190Carbon-doped BN nanosheets for metal-free photoredox catalysis C. Huang, C. Chen, M. Zhang, L. Lin, X. Ye, S. Lin, M. Antonietti, X. Wang Nature Communications 2015, 6, 7698– 10.1038/ncomms8698

189Triazoles: A New Class of Precursors for the Synthesis of Negatively Charged Carbon Nitride Derivatives D. Dontsova, S. Pronkin, M. Wehle, Z. Chen, C. Fettkenhauer, G. Clavel, M. Antonietti Chemistry of Materials 2015, 27, 5170–5179, 10.1021/acs.chemmater.5b00812

188A Stable Single-Site Palladium Catalyst for Hydrogenations G. Vilé, D. Albani, M. Nachtegaal, Z. Chen, D. Dontsova, M. Antonietti, N. López, J. Pérez-Ramírez Angewandte Chemie International Edition 2015, 54, 11265–11269, 10.1002/anie.201505073

187The Synthesis of Nanostructured Ni5P4Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting M. Ledendecker, S. Krick Calderón, C. Papp, H. P. Steinrück, M. Antonietti, M. Shalom Angewandte Chemie International Edition 2015, 54, 12361–12365, 10.1002/anie.201502438

186Carbon Dioxide Activation and Reaction Induced by Electron Transfer at an Oxide-Metal Interface F. Calaza, C. Stiehler, Y. Fujimori, M. Sterrer, S. Beeg, M. Ruiz-Oses, N. Nilius, M. Heyde, T. Parviainen, K. Honkala, H. Häkkinen, H. J. Freund Angewandte Chemie International Edition 2015, 54, 12484–12487, 10.1002/anie.201501420

185The Electronic Factor in Alkane Oxidation Catalysis M. Eichelbaum, M. Hävecker, C. Heine, A. M. Wernbacher, F. Rosowski, A. Trunschke, R. Schlögl Angewandte Chemie International Edition 2015, 54, 2922–2926, 10.1002/anie.201410632

184The impact of steam on the electronic structure of the selective propane oxidation catalyst MoVTeNb oxide (orthorhombic M1 phase) C. Heine, M. Hävecker, A. Trunschke, R. Schlögl, M. Eichelbaum Phys. Chem. Chem. Phys. 2015, 17, 8983–8993, 10.1039/C5CP00289C

183Controlled Formation of Nickel Oxide Nanoparticles on Mesoporous Silica using Molecular Ni4O4Clusters as Precursors: Enhanced Catalytic Performance for Dry Reforming of Methane E. Baktash, P. Littlewood, J. Pfrommer, R. Schomäcker, M. Driess, A. Thomas ChemCatChem 2015, 7, 1280–1284, 10.1002/cctc.201402983

182Charge-induced dipole vs. relativistically enhanced covalent interactions in Ar-tagged Au-Ag tetramers and pentamers A. Shayeghi, R. Schäfer, D. M. Rayner, R. L. Johnston, A. Fielicke The Journal of Chemical Physics 2015, 143, 24310– 10.1063/1.4923255

181The Nature of Bonding between Argon and Mixed Gold-Silver Trimers A. Shayeghi, R. L. Johnston, D. M. Rayner, R. Schäfer, A. Fielicke Angewandte Chemie International Edition 2015, 54, 10675–10680, 10.1002/anie.201503845

180Far-IR Spectra and Structures of Small Cationic Ruthenium Clusters: Evidence for Cubic Motifs C. Kerpal, D. J. Harding, D. M. Rayner, J. T. Lyon, A. Fielicke Journal of Physical Chemistry C The Journal of Physical Chemistry C 2015, 119, 10869–10875, 10.1021/jp510471k

179Reactivity of an Octanuclear Copper(I) Siloxide Compound - Isolation of a Copper(II) Oxo Compound with a Supertetrahedral Core F. Schax, C. Limberg Zeitschrift für anorganische und allgemeine Chemie 2015, 641, 2060–2064, 10.1002/zaac.201500228

178A Structural and Functional Model for the 1-Aminocyclopropane-1-carboxylic Acid Oxidase M. Sallmann, F. Oldenburg, B. Braun, M. Réglier, A. J. Simaan, C. Limberg Angewandte Chemie International Edition 2015, 54, 12325–12328, 10.1002/anie.201502529

177Reaction of a polydentate cysteine-based ligand and its nickel(II) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity D. S. Warner, C. Limberg, F. J. Oldenburg, B. Braun Dalton Trans. 2015, 44, 18378–18385, 10.1039/C5DT02828K

176Sulfido and Cysteine Ligation Changes at the Molybdenum Cofactor during Substrate Conversion by Formate Dehydrogenase (FDH) fromRhodobacter capsulatus P. Schrapers, T. Hartmann, R. Kositzki, H. Dau, S. Reschke, C. Schulzke, S. Leimkühler, M. Haumann Inorganic Chemistry 2015, 54, 3260–3271, 10.1021/ic502880y

175CFD study on solids flow pattern and solids mixing characteristics in bubbling fluidized bed: Effect of fluidization velocity and bed aspect ratio M. Askarishahi, M. S. Salehi, H. R. Godini, G. Wozny Powder Technology 2015, 274, 379–392, 10.1016/j.powtec.2015.01.025

174Optimization during the process synthesis: enabling the oxidative coupling of methane by minimizing the energy required for the carbon dioxide removal E. Esche, D. Müller, S. Song, G. Wozny Journal of Cleaner Production 2015, 91, 100–108, 10.1016/j.jclepro.2014.12.034

173Pilot scale investigations of the removal of carbon dioxide from hydrocarbon gas streams using poly (ethylene oxide)–poly (butylene terephthalate) PolyActive™) thin film composite membranes T. Brinkmann, C. Naderipour, J. Pohlmann, J. Wind, T. Wolff, E. Esche, D. Müller, G. Wozny, B. Hoting Journal of Membrane Science 2015, 489, 237–247, 10.1016/j.memsci.2015.03.082

172Unlocking the potential of fungi: the QuantFung project Z. Büttel, R. Díaz, B. Dirnberger, M. Flak, S. Grijseels, M. J. Kwon, J. C. F. Nielsen, Y. Nygård, P. Phule, C. Pohl, S. Prigent, M. Randelovic, T. Schütze, D. Troppens, A. Viggiano Fungal Biology and Biotechnology 2015, 2, 10.1186/s40694-015-0016-0

171GTP-binding protein Era: a novel gene target for biofuel production G. P. Voshol, V. Meyer, C. A. M. J. J. van den Hondel BMC Biotechnology 2015, 15, 10.1186/s12896-015-0132-1

170Tet-on, or Tet-off, that is the question: Advanced conditional gene expression in Aspergillus F. Wanka, T. Cairns, S. Boecker, C. Berens, A. Happel, X. Zheng, J. Sun, S. Krappmann, V. Meyer Fungal Genetics and Biology 2015, 89, 72–83, 10.1016/j.fgb.2015.11.003

169Immobilization of thermostable nucleoside phosphorylases on MagReSyn® epoxide microspheres and their application for the synthesis of 2,6-dihalogenated purine nucleosides X. Zhou, I. A. Mikhailopulo, M. N. Cruz Bournazou, P. Neubauer Journal of Molecular Catalysis B: Enzymatic 2015, 115, 119–127, 10.1016/j.molcatb.2015.02.009

168Microelectrospotting as a new method for electrosynthesis of surface-imprinted polymer microarrays for protein recognition M. Bosserdt, J. Erdőssy, G. Lautner, J. Witt, K. Köhler, N. Gajovic-Eichelmann, A. Yarman, G. Wittstock, F. W. Scheller, R. E. Gyurcsányi Biosensors and Bioelectronics 2015, 73, 123–129, 10.1016/j.bios.2015.05.049

167Vectorially Imprinted Hybrid Nanofilm for Acetylcholinesterase Recognition K. J. Jetzschmann, G. Jágerszki, D. Dechtrirat, A. Yarman, N. Gajovic-Eichelmann, H. D. Gilsing, B. Schulz, R. E. Gyurcsányi, F. W. Scheller Advanced Functional Materials 2015, 25, 5178–5183, 10.1002/adfm.201501900

166Cytochrome c-Derived Hybrid Systems Based on Moleculary Imprinted Polymers A. Yarman, D. Dechtrirat, M. Bosserdt, K. J. Jetzschmann, N. Gajovic-Eichelmann, F. W. Scheller Electroanalysis 2015, 27, 573–586, 10.1002/elan.201400592

165Affecting the Catalytic Activity of the Known [Ru(tpy)(bpy)(OH2)]2+Complex in Water Oxidation by Utilization of a Hangman Ligand P. Wrzolek, M. Schwalbe European Journal of Inorganic Chemistry 2015, 2015, 4373–4378, 10.1002/ejic.201500632

164Natural Product Biosynthetic Diversity and Comparative Genomics of the Cyanobacteria E. Dittmann, M. Gugger, K. Sivonen, D. P. Fewer Trends in Microbiology 2015, 23, 642–652, 10.1016/j.tim.2015.07.008

163A Relativistic Quantum-Chemical Analysis of the trans Influence on1H NMR Hydride Shifts in Square-Planar Platinum(II) Complexes A. H. Greif, P. Hrobárik, V. Hrobáriková, A. V. Arbuznikov, J. Autschbach, M. Kaupp Inorganic Chemistry 2015, 54, 7199–7208, 10.1021/acs.inorgchem.5b00446

162Relativistic and Solvation Effects on the Stability of Gold(III) Halides in Aqueous Solution K. Theilacker, H. B. Schlegel, M. Kaupp, P. Schwerdtfeger Inorganic Chemistry 2015, 54, 9869–9875, 10.1021/acs.inorgchem.5b01632

161Controlled ligand distortion and its consequences for structure, symmetry, conformation and spin-state preferences of iron(ii) complexes N. Kroll, K. Theilacker, M. Schoknecht, D. Baabe, D. Wiedemann, M. Kaupp, A. Grohmann, G. Hörner Dalton Trans. 2015, 44, 19232–19247, 10.1039/C5DT02502H

160Four-Component Relativistic Density Functional Theory Calculations of EPRg- and Hyperfine-Coupling Tensors Using Hybrid Functionals: Validation on Transition-Metal Complexes with Large Tensor Anisotropies and Higher-Order Spin–Orbit Effects S. Gohr, P. Hrobárik, M. Repiský, S. Komorovský, K. Ruud, M. Kaupp The Journal of Physical Chemistry A 2015, 119, 12892–12905, 10.1021/acs.jpca.5b10996

159Mass spectrometry guided venom profiling and bioactivity screening of the Anatolian Meadow Viper, Vipera anatolica B. Göçmen, P. Heiss, D. Petras, A. Nalbantsoy, R. D. Süssmuth Toxicon 2015, 107, 163–174, 10.1016/j.toxicon.2015.09.013

158Streptocollin, a Type IV Lanthipeptide Produced by Streptomyces collinus Tü 365 D. Iftime, M. Jasyk, A. Kulik, J. F. Imhoff, E. Stegmann, W. Wohlleben, R. D. Süssmuth, T. Weber ChemBioChem 2015, 16, 2615–2623, 10.1002/cbic.201500377

157Biosynthesis of the Peptide Antibiotic Feglymycin by a Linear Nonribosomal Peptide Synthetase Mechanism M. Gonsior, A. Mühlenweg, M. Tietzmann, S. Rausch, A. Poch, R. D. Süssmuth ChemBioChem 2015, 16, 2610–2614, 10.1002/cbic.201500432

156Molecular Adsorption Changes the Quantum Structure of Oxide-Supported Gold Nanoparticles: Chemisorption versus Physisorption C. Stiehler, F. Calaza, W. D. Schneider, N. Nilius, H. J. Freund Physical Review Letters 2015, 115, 368041–368045, 10.1103/PhysRevLett.115.036804

155Iridium Oxide Coatings with Templated Porosity as Highly Active Oxygen Evolution Catalysts: Structure-Activity Relationships M. Bernicke, E. Ortel, T. Reier, A. Bergmann, J. Ferreira de Araujo, P. Strasser, R. Kraehnert ChemSusChem 2015, 8, 1908–1915, 10.1002/cssc.201402988

154Time-resolved in situ studies on the formation mechanism of iron oxide nanoparticles using combined fast-XANES and SAXS A. Kabelitz, A. Guilherme, M. Joester, U. Reinholz, M. Radtke, R. Bienert, K. Schulz, R. Schmack, R. Kraehnert, F. Emmerling CrystEngComm 2015, 17, 8463–8470, 10.1039/C5CE01585E

153Electrospun Carbon Nanofibers as Alternative Electrode Materials for Vanadium Redox Flow Batteries A. Fetyan, I. Derr, M. K. Kayarkatte, J. Langner, D. Bernsmeier, R. Kraehnert, C. Roth ChemElectroChem 2015, 2, 2055–2060, 10.1002/celc.201500284

152Water-assisted nitrogen mediated crystallisation of ZnO films R. Muydinov, A. Steigert, S. Schönau, F. Ruske, R. Kraehnert, B. Eckhardt, I. Lauermann, B. Szyszka Thin Solid Films 2015, 590, 177–183, 10.1016/j.tsf.2015.07.034

151Turkevich in New Robes: Key Questions Answered for the Most Common Gold Nanoparticle Synthesis M. Wuithschick, A. Birnbaum, S. Witte, M. Sztucki, U. Vainio, N. Pinna, K. Rademann, F. Emmerling, R. Kraehnert, J. Polte ACS Nano 2015, 9, 7052–7071, 10.1021/acsnano.5b01579

150Propanol formation from CO2 and C2H4 with H2 over Au/TiO2: Effect of support and K doping S. J. Ahlers, R. Kraehnert, C. Kreyenschulte, M. M. Pohl, D. Linke, E. V. Kondratenko Catalysis Today 2015, 258, 684–690, 10.1016/j.cattod.2015.04.006

149O2Inhibition of Ni-Containing CO Dehydrogenase Is Partly Reversible M. Merrouch, J. Hadj-Saïd, L. Domnik, H. Dobbek, C. Léger, S. Dementin, V. Fourmond Chemistry - A European Journal 2015, 21, 18934–18938, 10.1002/chem.201502835

148Graphitic carbon nitride for photocatalytic degradation of sulfamethazine in aqueous solution under simulated sunlight irradiation H. Xiao, J. Zhu, A. Thomas RSC Adv. 2015, 5, 105731–105734, 10.1039/c5ra21895k

147PdHxEntrapped in a Covalent Triazine Framework Modulates Selectivity in Glycerol Oxidation C. E. Chan-Thaw, A. Villa, D. Wang, V. D. Santo, A. Orbelli Biroli, G. M. Veith, A. Thomas, L. Prati ChemCatChem 2015, 7, 2149–2154, 10.1002/cctc.201500055

146Quantum chemical ab initio prediction of proton exchange barriers between CH4 and different H-zeolites C. Tuma, J. Sauer The Journal of Chemical Physics 2015, 143, 102810– 10.1063/1.4923086

145Water on the MgO(001) Surface: Surface Reconstruction and Ion Solvation M. Ončák, R. Włodarczyk, J. Sauer The Journal of Physical Chemistry Letters 2015, 6, 2310–2314, 10.1021/acs.jpclett.5b00885

144Accurate Adsorption Thermodynamics of Small Alkanes in Zeolites. Ab initio Theory and Experiment for H-Chabazite G. Piccini, M. Alessio, J. Sauer, Y. Zhi, Y. Liu, R. Kolvenbach, A. Jentys, J. A. Lercher The Journal of Physical Chemistry C 2015, 119, 6128–6137, 10.1021/acs.jpcc.5b01739

143Enzyme-Modified Particles for Selective Biocatalytic Hydrogenation by Hydrogen-Driven NADH Recycling H. A. Reeve, L. Lauterbach, O. Lenz, K. A. Vincent ChemCatChem 2015, 7, 3480–3487, 10.1002/cctc.201500766

142 H2-driven biotransformation of n-octane to 1-octanol by a recombinant Pseudomonas putida strain co-synthesizing an O2-tolerant hydrogenase and a P450 monooxygenase T. H. Lonsdale, L. Lauterbach, S. Honda Malca, B. M. Nestl, B. Hauer, O. Lenz Chem. Commun. 2015, 51, 16173–16175, 10.1039/C5CC06078H

141 Active Site of the NAD+ -Reducing Hydrogenase from Ralstonia eutropha Studied by EPR Spectroscopy J. Löwenstein, L. Lauterbach, C. Teutloff, O. Lenz, R. Bittl The Journal of Physical Chemistry B 2015, 119, 13834–13841, 10.1021/acs.jpcb.5b04144

140Electrochemical and Infrared Spectroscopic Studies Provide Insight into Reactions of the NiFe Regulatory Hydrogenase from Ralstonia eutropha with O2 and CO P. A. Ash, J. Liu, N. Coutard, N. Heidary, M. Horch, I. Gudim, T. Simler, I. Zebger, O. Lenz, K. A. Vincent The Journal of Physical Chemistry B 2015, 119, 13807–13815, 10.1021/acs.jpcb.5b04164

139Key Amino Acids in the Bacterial (6-4) Photolyase PhrB from Agrobacterium fabrum D. Graf, J. Wesslowski, H. Ma, P. Scheerer, N. Krauß, I. Oberpichler, F. Zhang, T. Lamparter PLOS ONE 2015, 10, 10.1371/journal.pone.0140955

138Role of Structural Dynamics at the Receptor G Protein Interface for Signal Transduction A. S. Rose, U. Zachariae, H. Grubmüller, K. P. Hofmann, P. Scheerer, P. W. Hildebrand PLOS ONE 2015, 10, 10.1371/journal.pone.0143399

137Concentric-flow electrokinetic injector enables serial crystallography of ribosome and photosystem II R. G. Sierra, C. Gati, H. Laksmono, E. H. Dao, S. Gul, F. Fuller, J. Kern, R. Chatterjee, M. Ibrahim, A. S. Brewster, I. D. Young, T. Michels-Clark, A. Aquila, M. Liang, M. S. Hunter, J. E. Koglin, S. Boutet, E. A. Junco, B. Hayes, M. J. Bogan, C. Y. Hampton, E. V. Puglisi, N. K. Sauter, C. A. Stan, A. Zouni, J. Yano, V. K. Yachandra, S. M. Soltis, J. D. Puglisi, H. DeMirci Nature Methods 2015, 10.1038/nmeth.3667

136Improvements in serial femtosecond crystallography of photosystem II by optimizing crystal uniformity using microseeding procedures M. Ibrahim, R. Chatterjee, J. Hellmich, R. Tran, M. Bommer, V. K. Yachandra, J. Yano, J. Kern, A. Zouni Structural Dynamics 2015, 2, 41705– 10.1063/1.4919741

135The influence of poly(ethylene glycol) on the micelle formation of alkyl maltosides used in membrane protein crystallization F. Müh, D. DiFiore, A. Zouni Phys. Chem. Chem. Phys. 2015, 17, 11678–11691, 10.1039/C5CP00431D

134 Variation of Exciton-Vibrational Coupling in Photosystem II Core Complexes from Thermosynechococcus elongatus As Revealed by Single-Molecule Spectroscopy S. Skandary, M. Hussels, A. Konrad, T. Renger, F. Müh, M. Bommer, A. Zouni, A. J. Meixner, M. Brecht The Journal of Physical Chemistry B 2015, 119, 4203–4210, 10.1021/jp510631x

133Concepts in bio-molecular spectroscopy: vibrational case studies on metalloenzymes M. Horch, P. Hildebrandt, I. Zebger Phys. Chem. Chem. Phys. 2015, 17, 18222–18237, 10.1039/C5CP02447A

132Mimicking Tyrosine Phosphorylation in Human Cytochrome c by the Evolved tRNA Synthetase Technique A. Guerra-Castellano, A. Díaz-Quintana, B. Moreno-Beltrán, J. López-Prados, P. M. Nieto, W. Meister, J. Staffa, M. Teixeira, P. Hildebrandt, M. A. De la Rosa, I. Díaz-Moreno Chemistry - A European Journal 2015, 21, 15004–15012, 10.1002/chem.201502019

131 Nature of the Surface-Exposed Cytochrome-Electrode Interactions in Electroactive Biofilms of Desulfuromonas acetoxidans A. Alves, H. K. Ly, P. Hildebrandt, R. O. Louro, D. Millo The Journal of Physical Chemistry B 2015, 119, 7968–7974, 10.1021/acs.jpcb.5b03419

130SERR Spectroelectrochemical Study of Cytochrome cd1 Nitrite Reductase Co-Immobilized with Physiological Redox Partner Cytochrome c552 on Biocompatible Metal Electrodes C. M. Silveira, P. O. Quintas, I. Moura, J. J. G. Moura, P. Hildebrandt, M. G. Almeida, S. Todorovic, N. Lebedev PLOS ONE 2015, 10, 10.1371/journal.pone.0129940

129The Electrically Wired Molybdenum Domain of Human Sulfite Oxidase is Bioelectrocatalytically Active R. Spricigo, S. Leimkühler, L. Gorton, F. W. Scheller, U. Wollenberger European Journal of Inorganic Chemistry 2015, 2015, 3526–3531, 10.1002/ejic.201500034

128Direct Electron Transfer and Bioelectrocatalysis by a Hexameric, Heme Protein at Nanostructured Electrodes J. Tanne, J. H. Jeoung, L. Peng, A. Yarman, B. Dietzel, B. Schulz, D. Schad, H. Dobbek, U. Wollenberger, F. F. Bier, F. W. Scheller Electroanalysis 2015, 27, 2262–2267, 10.1002/elan.201500231

127Effective Electrochemistry of Human Sulfite Oxidase Immobilized on Quantum-Dots-Modified Indium Tin Oxide Electrode T. Zeng, S. Leimkühler, J. Koetz, U. Wollenberger ACS Applied Materials & Interfaces 2015, 7, 21487–21494, 10.1021/acsami.5b06665

126Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions M. Goswami, V. Lyaskovskyy, S. R. Domingos, W. J. Buma, S. Woutersen, O. Troeppner, I. Ivanović-Burmazović, H. Lu, X. Cui, X. P. Zhang, E. J. Reijerse, S. DeBeer, M. M. van Schooneveld, F. F. Pfaff, K. Ray, B. de Bruin Journal of the American Chemical Society 2015, 137, 5468–5479, 10.1021/jacs.5b01197

125 Reactivity of a Nickel(II) Bis(amidate) Complex with -Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species T. Corona, F. F. Pfaff, F. Acuña-Parés, A. Draksharapu, C. J. Whiteoak, V. Martin-Diaconescu, J. Lloret-Fillol, W. R. Browne, K. Ray, A. Company Chemistry - A European Journal 2015, 21, 15029–15038, 10.1002/chem.201501841

124Toward intrinsically colored peptides: Synthesis and investigation of the spectral properties of methylated azatryptophans in tryptophan-cage mutants B. P. Noichl, P. M. Durkin, N. Budisa Biopolymers 2015, 104, 585–600, 10.1002/bip.22709

123Dendronylation: Residue-specific chemoselective attachment of oligoglycerol dendrimers on proteins with noncanonical amino acids Y. Ma, B. N. S. Thota, R. Haag, N. Budisa Bioorganic & Medicinal Chemistry Letters 2015, 25, 5247–5249, 10.1016/j.bmcl.2015.09.055

122Chemical Evolution of a Bacterial Proteome M. G. Hoesl, S. Oehm, P. Durkin, E. Darmon, L. Peil, H. R. Aerni, J. Rappsilber, J. Rinehart, D. Leach, D. Söll, N. Budisa Angewandte Chemie International Edition 2015, 54, 10030–10034, 10.1002/anie.201502868

121Entropic Contribution of Elongation Factor P to Proline Positioning at the Catalytic Center of the Ribosome L. K. Doerfel, I. Wohlgemuth, V. Kubyshkin, A. L. Starosta, D. N. Wilson, N. Budisa, M. V. Rodnina Journal of the American Chemical Society 2015, 137, 12997–13006, 10.1021/jacs.5b07427

120Molecular architecture of the ribosome-bound Hepatitis C Virus internal ribosomal entry site RNA H. Yamamoto, M. Collier, J. Loerke, J. Ismer, A. Schmidt, T. Hilal, T. Sprink, K. Yamamoto, T. Mielke, J. Bürger, T. R. Shaikh, M. Dabrowski, P. W. Hildebrand, P. Scheerer, C. M. Spahn The EMBO Journal 2015, 34, 3042–3058, 10.15252/embj.201592469

119Z-Selective Copper(I)-Catalyzed Alkyne Semihydrogenation with Tethered Cu-Alkoxide Complexes F. Pape, N. O. Thiel, J. F. Teichert Chemistry - A European Journal 2015, 21, 15934–15938, 10.1002/chem.201501739

118Evaluating Catalytic Fixed-Bed Reactors for Dry Reforming of Methane with Detailed CFD G. D. Wehinger, T. Eppinger, M. Kraume Chemie Ingenieur Technik 2015, 87, 734–745, 10.1002/cite.201400153

117Structural Insights into the Incorporation of the Mo Cofactor into Sulfite Oxidase from Site-Directed Spin Labeling A. Hahn, C. Engelhard, S. Reschke, C. Teutloff, R. Bittl, S. Leimkühler, T. Risse Angewandte Chemie International Edition 2015, 54, 11865–11869, 10.1002/anie.201504772

116 Does the Surface Structure of Oxide Affect the Strong Metal-Support Interaction with Platinum? Platinum on Fe3O4 (0 0 1) versus Fe3O4 (1 1 1) K. Zhang, S. Shaikhutdinov, H. J. Freund ChemCatChem 2015, 7, 3725–3730, 10.1002/cctc.201500328

115Signal transduction in light-oxygen-voltage receptors lacking the adduct-forming cysteine residue E. F. Yee, R. P. Diensthuber, A. T. Vaidya, P. P. Borbat, C. Engelhard, J. H. Freed, R. Bittl, A. Möglich, B. R. Crane Nature Communications 2015, 6, 10079– 10.1038/ncomms10079

114Correction: Applying thermo-destabilization of microemulsions as a new method for co-catalyst loading on mesoporous polymeric carbon nitride – towards large scale applications M. Schröder, K. Kailasam, S. Rudi, K. Fündling, J. Rieß, M. Lublow, A. Thomas, R. Schomäcker, M. Schwarze RSC Adv. 2015, 5, 18279–18279, 10.1039/C5RA90012C

113Mesoporous Carbon Nitride-Tungsten Oxide Composites for Enhanced Photocatalytic Hydrogen Evolution K. Kailasam, A. Fischer, G. Zhang, J. Zhang, M. Schwarze, M. Schröder, X. Wang, R. Schomäcker, A. Thomas ChemSusChem 2015, 8, 1404–1410, 10.1002/cssc.201403278

112Hydrogen Evolution Reaction in a Large-Scale Reactor using a Carbon Nitride Photocatalyst under Natural Sunlight Irradiation M. Schröder, K. Kailasam, J. Borgmeyer, M. Neumann, A. Thomas, R. Schomäcker, M. Schwarze Energy Technology 2015, 3, 1014–1017, 10.1002/ente.201500142

111Reactor material and gas dilution effects on the performance of miniplant-scale fluidized-bed reactors for oxidative coupling of methane S. Sadjadi, U. Simon, H. R. Godini, O. Görke, R. Schomäcker, G. Wozny Chemical Engineering Journal 2015, 281, 678–687, 10.1016/j.cej.2015.06.079

110Synthesis of Mixed Silylene-Carbene Chelate Ligands from N-Heterocyclic Silylcarbenes Mediated by Nickel G. Tan, S. Enthaler, S. Inoue, B. Blom, M. Driess Angewandte Chemie International Edition 2015, 54, 2214–2218, 10.1002/anie.201409739

109Using nickel manganese oxide catalysts for efficient water oxidation P. W. Menezes, A. Indra, O. Levy, K. Kailasam, V. Gutkin, J. Pfrommer, M. Driess Chem. Commun. 2015, 51, 5005–5008, 10.1039/C4CC09671A

108Uncovering Structure-Activity Relationships in Manganese-Oxide-Based Heterogeneous Catalysts for Efficient Water Oxidation A. Indra, P. W. Menezes, M. Driess ChemSusChem 2015, 8, 776–785, 10.1002/cssc.201402812

107Heterogeneous Water Oxidation: Surface Activity versus Amorphization Activation in Cobalt Phosphate Catalysts D. González-Flores, I. Sánchez, I. Zaharieva, K. Klingan, J. Heidkamp, P. Chernev, P. W. Menezes, M. Driess, H. Dau, M. L. Montero Angewandte Chemie International Edition 2015, 54, 2472–2476, 10.1002/anie.201409333

106High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology-Dependent Activity P. W. Menezes, A. Indra, D. González-Flores, N. R. Sahraie, I. Zaharieva, M. Schwarze, P. Strasser, H. Dau, M. Driess ACS Catalysis 2015, 5, 2017–2027, 10.1021/cs501724v

105Dual Catalytic Activity of Palladium Doped with a Rhodium Complex in a One-pot, Four Step Process L. Shapiro, M. Driess, D. Avnir ChemCatChem 2015, 7, 2033–2037, 10.1002/cctc.201500240

104Hydrophobic Nanoreactor Soft-Templating: A Supramolecular Approach to Yolk@Shell Materials A. Guiet, C. Göbel, K. Klingan, M. Lublow, T. Reier, U. Vainio, R. Kraehnert, H. Schlaad, P. Strasser, I. Zaharieva, H. Dau, M. Driess, J. Polte, A. Fischer Advanced Functional Materials 2015, 25, 6228–6240, 10.1002/adfm.201502388

103Biomimetic [2Fe-2S] Clusters with Extensively Delocalized Mixed-Valence Iron Centers S. Yao, F. Meier, N. Lindenmaier, R. Rudolph, B. Blom, M. Adelhardt, J. Sutter, S. Mebs, M. Haumann, K. Meyer, M. Kaupp, M. Driess Angewandte Chemie International Edition 2015, 54, 12506–12510, 10.1002/anie.201506788

102 Correction to Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal-1,10- Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N Is Not Always an “Inert” Buffer Gas N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Analytical Chemistry 2015, 87, 11601–11601, 10.1021/acs.analchem.5b03989

101Minimum information about a biosynthetic gene cluster M. H. Medema, R. Kottmann, P. Yilmaz, R. Süssmuth, and coworkers Nature Chemical Biology 2015, 11, 625–631, 10.1038/nchembio.1890

100Extending the Scope of the B(C6F5)3-Catalyzed C=N Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones J. Mohr, D. Porwal, I. Chatterjee, M. Oestreich Chemistry - A European Journal 2015, 21, 17583–17586, 10.1002/chem.201503509

99B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another I. Chatterjee, Z. W. Qu, S. Grimme, M. Oestreich Angewandte Chemie International Edition 2015, 54, 12158–12162, 10.1002/anie.201504941

98Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex T. T. Metsänen, D. Gallego, T. Szilvási, M. Driess, M. Oestreich Chem. Sci. 2015, 6, 7143–7149, 10.1039/C5SC02855H

97Mechanism of the cooperative Si–H bond activation at Ru–S bonds T. Stahl, P. Hrobárik, C. D. F. Königs, Y. Ohki, K. Tatsumi, S. Kemper, M. Kaupp, H. F. T. Klare, M. Oestreich Chem. Sci. 2015, 6, 4324–4334, 10.1039/C5SC01035G

96Model Approach in Heterogeneous Catalysis: Kinetics and Thermodynamics of Surface Reactions S. Schauermann, H. J. Freund Accounts of Chemical Research 2015, 48, 2775–2782, 10.1021/acs.accounts.5b00237

95Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts N. R. Sahraie, U. I. Kramm, J. Steinberg, Y. Zhang, A. Thomas, T. Reier, J. P. Paraknowitsch, P. Strasser Nature Communications 2015, 6, 8618– 10.1038/ncomms9618

94Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution A. Bergmann, E. Martinez-Moreno, D. Teschner, P. Chernev, M. Gliech, J. F. de Araújo, T. Reier, H. Dau, P. Strasser Nature Communications 2015, 6, 8625– 10.1038/NCOMMS9625

93 Venom Proteomics of Indonesian King Cobra, Ophiophagus hannah : Integrating Top-Down and Bottom-Up Approaches D. Petras, P. Heiss, R. D. Süssmuth, J. J. Calvete Journal of Proteome Research 2015, 14, 2539–2556, 10.1021/acs.jproteome.5b00305

92Lipocarbazole, an efficient lipid peroxidation inhibitor anchored in the membrane G. Fabre, A. Hänchen, C. A. Calliste, K. Berka, S. Banala, M. Otyepka, R. D. Süssmuth, P. Trouillas Bioorganic & Medicinal Chemistry 2015, 23, 4866–4870, 10.1016/j.bmc.2015.05.031

91The Albicidin Resistance Factor AlbD Is a Serine Endopeptidase That Hydrolyzes Unusual Oligoaromatic-Type Peptides L. Vieweg, J. Kretz, A. Pesic, D. Kerwat, S. Grätz, M. Royer, S. Cociancich, A. Mainz, R. D. Süssmuth Journal of the American Chemical Society 2015, 137, 7608–7611, 10.1021/jacs.5b04099

90Scale-up bioprocess development for production of the antibiotic valinomycin in Escherichia coli based on consistent fed-batch cultivations J. Li, J. Jaitzig, P. Lu, R. D. Süssmuth, P. Neubauer Microbial Cell Factories 2015, 14, 10.1186/s12934-015-0272-y

89 Distinct Mechanistic Differences in the Hydrogen-Atom Transfer from Methane and Water by the Heteronuclear Oxide Cluster [Ga2MgO4] J. Li, X. N. Wu, S. Zhou, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2015, 54, 12298–12302, 10.1002/anie.201503763

88 Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal–1,10-Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N Is Not Always an “Inert” Buffer Gas N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Analytical Chemistry 2015, 87, 9769–9776, 10.1021/acs.analchem.5b01985

87Probing the electronic properties and charge state of gold nanoparticles on ultrathin MgO versus thick doped CaO films Y. Cui, C. Stiehler, N. Nilius, H. J. Freund Physical Review B 2015, 92, 754441–754448, 10.1103/PhysRevB.92.075444

86 2nd coordination sphere controlled electron transfer of iron hangman complexes on electrodes probed by surface enhanced vibrational spectroscopy H. K. Ly, P. Wrzolek, N. Heidary, R. Götz, M. Horch, J. Kozuch, M. Schwalbe, I. M. Weidinger Chem. Sci. 2015, 10.1039/C5SC02560E

85 Resonance Raman Spectroscopic Analysis of the [NiFe] Active Site and the Proximal [4Fe-3S] Cluster of an O2 -Tolerant Membrane-Bound Hydrogenase in the Crystalline State E. Siebert, Y. Rippers, S. Frielingsdorf, J. Fritsch, A. Schmidt, J. Kalms, S. Katz, O. Lenz, P. Scheerer, L. Paasche, V. Pelmenschikov, U. Kuhlmann, M. A. Mroginski, I. Zebger, P. Hildebrandt The Journal of Physical Chemistry B 2015, 119, 13785–13796, 10.1021/acs.jpcb.5b04119

84The Activation Pathway of Human Rhodopsin in Comparison to Bovine Rhodopsin R. Kazmin, A. Rose, M. Szczepek, M. Elgeti, E. Ritter, R. Piechnick, K. P. Hofmann, P. Scheerer, P. W. Hildebrand, F. J. Bartl Journal of Biological Chemistry 2015, 290, 20117–20127, 10.1074/jbc.M115.652172

83Structure-based biophysical analysis of the interaction of rhodopsin with G protein and arrestin. M. E. Sommer, M. Elgeti, P. W. Hildebrand, M. Szczepek, K. P. Hofmann, P. Scheerer Methods in Enzymology 2015, 556, 563–608, 10.1016/bs.mie.2014.12.014

82“Stripping” the Carbon Atom of Methyl Halide by a Cationic Holmium Complex: A Gas-Phase Study S. Zhou, M. Schlangen, J. Li, X. N. Wu, H. Schwarz Chemistry - A European Journal 2015, 21, 14305–14308, 10.1002/chem.201502183

81 On the Mechanisms of Hydrogen-Atom Transfer from Water to the Heteronuclear Oxide Cluster [Ga2Mg2O5].+ : Remarkable Electronic Structure Effects J. Li, S. Zhou, X. N. Wu, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2015, 54, 11861–11864, 10.1002/anie.201505336

80Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy H. Ogata, T. Krämer, H. Wang, D. Schilter, V. Pelmenschikov, M. van Gastel, F. Neese, T. B. Rauchfuss, L. B. Gee, A. D. Scott, Y. Yoda, Y. Tanaka, W. Lubitz, S. P. Cramer Nature Communications 2015, 6, 7890– 10.1038/ncomms8890

79Enhanced CO Oxidation on the Oxide/Metal Interface: From Ultra-High Vacuum to Near-Atmospheric Pressures Q. Pan, X. Weng, M. Chen, L. Giordano, G. Pacchioni, C. Noguera, J. Goniakowski, S. Shaikhutdinov, H. J. Freund ChemCatChem 2015, 7, 2620–2627, 10.1002/cctc.201500394

78Correlations between metal spin states and vibrational spectra of a trinuclear Fe(II) complex exhibiting spin crossover T. P. Gerasimova, S. A. Katsyuba, L. G. Lavrenova, V. Pelmenschikov, M. Kaupp Journal of Molecular Structure 2015, 1101, 8–13, 10.1016/j.molstruc.2015.08.001

77Characterization of O--Centers on Single Crystalline MgO(001)-Films A. Gonchar, J. Lian, T. Risse, H. J. Freund, C. Di Valentin, G. Pacchioni Topics in Catalysis 2015, 58, 811–823, 10.1007/s11244-015-0421-x

76Doping Effects in Cluster-Mediated Bond Activation H. Schwarz Angewandte Chemie International Edition 2015, 54, 10090–10100, 10.1002/anie.201500649

75Carbon-Atom Extrusion from Halobenzenes and Its Coupling with a Methylene Ligand to Form Acetylene S. Zhou, M. Schlangen, J. Li, X. N. Wu, H. Schwarz Chemistry - A European Journal 2015, 21, 9629–9631, 10.1002/chem.201501871

74MgO on Mo(001): Local Work Function Measurements above Pristine Terrace and Line Defect Sites S. Stuckenholz, C. Büchner, M. Heyde, H. J. Freund The Journal of Physical Chemistry C 2015, 119, 12283–12290, 10.1021/jp512575n

73 Asymmetric Biocatalytic Amination of Ketones at the Expense of NH3 and Molecular Hydrogen A. K. Holzer, K. Hiebler, F. G. Mutti, R. C. Simon, L. Lauterbach, O. Lenz, W. Kroutil Organic Letters 2015, 17, 2431–2433, 10.1021/acs.orglett.5b01154

72 Cofactor composition and function of a H2-sensing regulatory hydrogenase as revealed by Mössbauer and EPR Spectroscopy F. Roncaroli, E. Bill, B. Friedrich, O. Lenz, W. Lubitz, M. E. Pandelia Chem. Sci. 2015, 10.1039/C5SC01560J

71Docking and Migration of Carbon Monoxide in Nitrogenase: The Case for Gated Pockets from Infrared Spectroscopy and Molecular Dynamics L. B. Gee, I. Leontyev, A. Stuchebrukhov, A. D. Scott, V. Pelmenschikov, S. P. Cramer Biochemistry 2015, 54, 3314–3319, 10.1021/acs.biochem.5b00216

70Defect complexes in Li-doped MgO N. A. Richter, F. Stavale, S. V. Levchenko, N. Nilius, H. J. Freund, M. Scheffler Physical Review B 2015, 91, 195305– 10.1103/PhysRevB.91.195305

69Weak thermal reduction of biphase Fe2O3(0001) films grown on Pt(111): Sub-surface Fe2+ formation H. Qiu, V. Staemmler, H. Kuhlenbeck, E. Bauer, H. J. Freund Surface Science 2015, 641, 30–36, 10.1016/j.susc.2015.04.025

68Spectroscopic Observation of Calcium-Induced Reorientation of Cellobiose Dehydrogenase Immobilized on Electrodes and its Effect on Electrocatalytic Activity P. Kielb, M. Sezer, S. Katz, F. Lopez, C. Schulz, L. Gorton, R. Ludwig, U. Wollenberger, I. Zebger, I. M. Weidinger ChemPhysChem 2015, 10.1002/cphc.201500112

67Alumina coated nickel nanoparticles as a highly active catalyst for dry reforming of methane E. Baktash, P. Littlewood, R. Schomäcker, A. Thomas, P. C. Stair Applied Catalysis B: Environmental 2015, 179, 122–127, 10.1016/j.apcatb.2015.05.018

66 Ligand-Controlled CO2 Activation Mediated by Cationic Titanium Hydride Complexes, [LTiH]+ ( L= Cp2 , O) S. Y. Tang, N. J. Rijs, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 8483–8490, 10.1002/chem.201500722

65Thermal hydrogen-atom transfer from methane: A mechanistic exercise H. Schwarz Chemical Physics Letters 2015, 629, 91–101, 10.1016/j.cplett.2015.04.022

64Experimental Validation of Robust Process Design and Control Based on Gaussian Mixture Densities N. Rossner, R. King 9th IFAC International Symposium on Advanced Control of Chemical Processes 2015,

63Model-Based Control to Maximise Biomass and PHB in the Autotrophic Cultivation of Ralstonia Eutropha F. Neddermeyer, N. Rossner, R. King 9th IFAC International Symposium on Advanced Control of Chemical Processes 2015,

62Microporous polymer network films covalently bound to gold electrodes D. Becker, N. Heidary, M. Horch, U. Gernert, I. Zebger, J. Schmidt, A. Fischer, A. Thomas Chem. Commun. 2015, 51, 4283–4286, 10.1039/C4CC09637A

61Controlling hydrogenation selectivity with Pd catalysts on carbon nitrides functionalized silica T. Yuan, H. Gong, K. Kailasam, Y. Zhao, A. Thomas, J. Zhu Journal of Catalysis 2015, 326, 38–42, 10.1016/j.jcat.2015.03.007

60 Controlled Formation of Nickel Oxide Nanoparticles on Mesoporous Silica using Molecular Ni4O4 Clusters as Precursors: Enhanced Catalytic Performance for Dry Reforming of Methane E. Baktash, P. Littlewood, J. Pfrommer, R. Schomäcker, M. Driess, A. Thomas ChemCatChem 2015, 7, 1280–1284, 10.1002/cctc.201402983

59Structural Snapshots of Actively Translating Human Ribosomes E. Behrmann, J. Loerke, T. Budkevich, K. Yamamoto, A. Schmidt, P. Penczek, M. Vos, J. Bürger, T. Mielke, P. Scheerer, C. T. Spahn Cell 2015, 161, 845–857, 10.1016/j.cell.2015.03.052

58The Class III Cyclobutane Pyrimidine Dimer Photolyase Structure Reveals a New Antenna Chromophore Binding Site and Alternative Photoreduction Pathways P. Scheerer, F. Zhang, J. Kalms, D. von Stetten, N. Krauß, I. Oberpichler, T. Lamparter Journal of Biological Chemistry 2015, 290, 11504–11514, 10.1074/jbc.M115.637868

57Photochemical chromophore isomerization in histidine kinase rhodopsin HKR1 M. Luck, S. Bruun, A. Keidel, P. Hegemann, P. Hildebrandt FEBS Letters 2015, 589, 1067–1071, 10.1016/j.febslet.2015.03.024

56 Orthogonal Translation Meets Electron Transfer: In Vivo Labeling of Cytochrome c for Probing Local Electric Fields J. Völler, H. Biava, B. Koksch, P. Hildebrandt, N. Budisa ChemBioChem 2015, 16, 742–745, 10.1002/cbic.201500022

55Surface enhanced vibrational spectroscopic evidence for an alternative DNA-independent redox activation of endonuclease III E. Moe, M. Sezer, P. Hildebrandt, S. Todorovic Chem. Commun. 2015, 51, 3255–3257, 10.1039/C4CC09498K

54Surface enhanced resonance Raman detection of a catalytic intermediate of DyP-type peroxidase S. Todorovic, P. Hildebrandt, L. O. Martins Phys. Chem. Chem. Phys. 2015, 17, 11954–11957, 10.1039/C5CP01283J

53Voltage sensitive phosphatases: emerging kinship to protein tyrosine phosphatases from structure-function research K. Hobiger, T. Friedrich Frontiers in Pharmacology 2015, 6, 10.3389/fphar.2015.00020

52 Activation of Methane and Carbon Dioxide Mediated by Transition-Metal Doped Magnesium Oxide Clusters [MMgO]+/o/- (M=Sc-Zn) J. Li, P. González-Navarrete, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 7780–7789, 10.1002/chem.201500715

51Surface-Tuned Electron Transfer and Electrocatalysis of Hexameric Tyrosine-Coordinated Heme Protein L. Peng, T. Utesch, A. Yarman, J. H. Jeoung, S. Steinborn, H. Dobbek, M. A. Mroginski, J. Tanne, U. Wollenberger, F. W. Scheller Chemistry - A European Journal 2015, 21, 7596–7602, 10.1002/chem.201405932

50 How the [NiFe4S4] Cluster of CO Dehydrogenase Activates CO2 and NCO- J. Fesseler, J. H. Jeoung, H. Dobbek Angewandte Chemie International Edition 2015, 10.1002/anie.201501778

49 Synthesis and structure of rhodium(I) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds L. Zámostná, S. Sander, T. Braun, R. Laubenstein, B. Braun, R. Herrmann, P. Kläring Dalton Trans. 2015, 10.1039/c5dt00819k

48Formation of Water Chains on CaO(001): What Drives the 1D Growth? X. Zhao, X. Shao, Y. Fujimori, S. Bhattacharya, L. M. Ghiringhelli, H. J. Freund, M. Sterrer, N. Nilius, S. V. Levchenko J. Phys. Chem. Lett. The Journal of Physical Chemistry Letters 2015, 6, 1204–1208, 10.1021/acs.jpclett.5b00223

47Electrocatalytic Carbon Dioxide Reduction by Using Cationic Pentamethylcyclopentadienyl-Iridium Complexes with Unsymmetrically Substituted Bipyridine Ligands F. D. Sypaseuth, C. Matlachowski, M. Weber, M. Schwalbe, C. C. Tzschucke Chemistry - A European Journal 2015, 21, 6564–6571, 10.1002/chem.201404367

46 On the Role of the Electronic Structure of the Heteronuclear Oxide Cluster [Ga2Mg2O5].+ in the Thermal Activation of Methane and Ethane: An Unusual Doping Effect J. Li, X. N. Wu, M. Schlangen, S. Zhou, P. González-Navarrete, S. Tang, H. Schwarz Angewandte Chemie International Edition 2015, 54, 5074–5078, 10.1002/anie.201412441

45 Mechanistic aspects of the gas-phase coupling of thioanisole and chlorobenzene to dibenzothiophene catalyzed by atomic Ho S. Zhou, M. Schlangen, H. Schwarz Phys. Chem. Chem. Phys. 2015, 17, 9564–9568, 10.1039/c5cp01038a

44Evolution of the electronic structure of CaO thin films following Mo interdiffusion at high temperature Y. Cui, Y. Pan, L. Pascua, H. Qiu, C. Stiehler, H. Kuhlenbeck, N. Nilius, H. J. Freund Physical Review B 2015, 91, 35418–35418, 10.1103/PhysRevB.91.035418

43 Impact of the iron−sulfur cluster proximal to the active site on the catalytic function of an O2-tolerant NAD-reducing [NiFe]-hydrogenase K. Karstens, S. Wahlefeld, M. Horch, M. Grunzel, L. Lauterbach, F. Lendzian, I. Zebger, O. Lenz Biochemistry 2015, 54, 389–403, 10.1021/bi501347u

42Structural differences of oxidized iron−sulfur and nickel−iron cofactors in O2-tolerant and O2-sensitive hydrogenases studied by X-ray absorption spectroscopy K. G. V. Sigfridsson, N. Leidel, O. Sanganas, P. Chernev, O. Lenz, K. S. Yoon, H. Nishihara, A. Parkin, F. A. Armstrong, S. Dementin, M. Rousset, A. L. De Lacey, M. Haumann Biochimica et Biophysica Acta (BBA) - Bioenergetics 2015, 1847, 162–170, 10.1016/j.bbabio.2014.06.011

41 Nuclear resonance vibrational spectroscopy reveals the FeS cluster composition and active site vibrational properties of an O2-tolerant NAD-reducing [NiFe] hydrogenase L. Lauterbach, H. Wang, M. Horch, L. B. Gee, Y. Yoda, Y. Tanaka, I. Zebger, O. Lenz, S. P. Cramer Chem. Sci. 2015, 6, 1055–1060, 10.1039/C4SC02982H

40Reversible active site sulfoxygenation can explain the oxygen tolerance of a NAD-reducing [NiFe] hydrogenase and its unusual infrared spectroscopic properties M. Horch, L. Lauterbach, M. A. Mroginski, P. Hildebrandt, O. Lenz, I. Zebger Journal of the American Chemical Society 2015, 137, 2555–2564, 10.1021/ja511154y

39High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting K. Ray, F. Heims, M. Schwalbe, W. Nam Current Opinion in Chemical Biology 2015, 25, 159–171, 10.1016/j.cbpa.2015.01.014

38A pH Responsive Redox Hydrogel for Electrochemical Detection of Redox Silent Biocatalytic Processes. Control of Hydrogel Solvation A. Contin, S. Frasca, J. Vivekananthan, S. Leimkühler, U. Wollenberger, N. Plumeré, W. Schuhmann Electroanalysis 2015, 27, 10.1002/elan.201400621

37Reliable palladium nanoparticle syntheses in aqueous solution: the importance of understanding precursor chemistry and growth mechanism F. Kettemann, M. Wuithschick, G. Caputo, R. Kraehnert, N. Pinna, K. Rademann, J. Polte CrystEngComm 2015, 17, 1865–1870, 10.1039/C4CE01025F

36Pd/TiO2 coatings with template-controlled mesopore structure as highly active hydrogenation catalyst E. Ortel, J. Polte, D. Bernsmeier, B. Eckhardt, B. Paul, A. Bergmann, P. Strasser, F. Emmerling, R. Kraehnert Applied Catalysis A: General 2015, 493, 25–32, 10.1016/j.apcata.2014.12.044

35Enhanced photocatalytic performance in atomic layer deposition grown TiO2 thin films via hydrogen plasma treatment A. Sasinska, T. Singh, S. Wang, S. Mathur, R. Kraehnert Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 2015, 33, 1– 10.1116/1.4904503

34Electrochemically dealloyed platinum with hierarchical pore structure as highly active catalytic coating R. Kraehnert, E. Ortel, B. Paul, B. Eckhardt, M. Kanis, R. Liu, A. Antoniou Catal. Sci. Technol. 2015, 5, 206–216, 10.1039/C4CY00851K

33 A Heterobimetallic Superoxide Complex formed through O2 Activation between Chromium(II) and a Lithium Cation F. Schax, S. Suhr, E. Bill, B. Braun, C. Herwig, C. Limberg Angewandte Chemie International Edition 2015, 54, 1352–1356, 10.1002/anie.201409294

32Bioinspired Copper(I) Complexes that Exhibit Monooxygenase and Catechol Dioxygenase Activity A. Arnold, R. Metzinger, C. Limberg Chemistry - A European Journal 2015, 21, 1198–1207, 10.1002/chem.201405155

31Systems Approaches to Predict the Functions of Glycoside Hydrolases during the Life Cycle of Aspergillus niger Using Developmental Mutants ΔbrlA and ΔflbA J. M. van Munster, B. M. Nitsche, M. Akeroyd, L. Dijkhuizen, M. J. E. C. van der Maarel, A. F. J. Ram, J. H. Yu PLOS ONE 2015, 10, 10.1371/journal.pone.0116269

30Exploring the Reactivity of Nickel Pincer Complexes in the Decomposition of Formic Acid to CO2/H2 and the Hydrogenation of NaHCO3 to HCOONa S. Enthaler, A. Brück, A. Kammer, H. Junge, E. Irran, S. Gülak ChemCatChem 2015, 7, 65–69, 10.1002/cctc.201402716

29Synthesis, characterization and application of iron N-substituted imidazole complexes with the motif ClFeL4OFeCl3 P. Döhlert, E. Irran, R. Kretschmer, S. Enthaler Inorganic Chemistry Communications 2015, 51, 4–8, 10.1016/j.inoche.2014.10.038

28Synthesis, characterization and application of nickel(II) complexes modified with N,N',N''-pincer ligands F. Czerny, P. Döhlert, M. Weidauer, E. Irran, S. Enthaler Inorganica Chimica Acta 2015, 425, 118–123, 10.1016/j.ica.2014.10.003

27 Applying γ-Substituted Prolines in the Peptide: Polarity Contradicts Preorganization D. Dietz, V. Kubyshkin, N. Budisa ChemBioChem 2015, 16, 403–406, 10.1002/cbic.201402654

26Covalent Attachment of Cyclic TAT Peptides to GFP Results in Protein Delivery into Live Cells with Immediate Bioavailability N. Nischan, H. D. Herce, F. Natale, N. Bohlke, N. Budisa, M. C. Cardoso, C. P. R. Hackenberger Angewandte Chemie International Edition 2015, 54, 1950–1953, 10.1002/anie.201410006

25Recycling Concept for End-of-Life Silicones: Boron Trifluoride Diethyl Etherate as Depolymerization Reagent to Produce Difluorodimethylsilane as Useful Commodity P. Döhlert, J. Pfrommer, S. Enthaler ACS Sustainable Chemistry & Engineering 2015, 3, 163–169, 10.1021/sc500666d

24The naturally born fusariotoxin enniatin B and sorafenib exert synergistic activity against cervical cancer in vitro and in vivo R. Dornetshuber-Fleiss, D. Heilos, T. Mohr, L. Richter, R. D. Süssmuth, M. Zlesak, A. Novicky, P. Heffeter, R. Lemmens-Gruber, W. Berger Biochemical Pharmacology 2015, 93, 318–331, 10.1016/j.bcp.2014.12.013

23The gyrase inhibitor albicidin consists of p-aminobenzoic acids and cyanoalanine S. Cociancich, A. Pesic, D. Petras, S. Uhlmann, J. Kretz, V. Schubert, L. Vieweg, S. Duplan, M. Marguerettaz, J. Noëll, I. Pieretti, M. Hügelland, S. Kemper, A. Mainz, P. Rott, M. Royer, R. D. Süssmuth Nature Chemical Biology 2015, 10.1038/nchembio.1734

22 Total Synthesis of Albicidin: A Lead Structure from Xanthomonas albilineans for Potent Antibacterial Gyrase Inhibitors J. Kretz, D. Kerwat, V. Schubert, S. Grätz, A. Pesic, S. Semsary, S. Cociancich, M. Royer, R. D. Süssmuth Angewandte Chemie International Edition 2015, 54, 1969–1973, 10.1002/anie.201409584

21Site-Directed and Global Incorporation of Orthogonal and Isostructural Noncanonical Amino Acids into the Ribosomal Lasso Peptide Capistruin R. S. Al Toma, A. Kuthning, M. P. Exner, A. Denisiuk, J. Ziegler, N. Budisa, R. D. Süssmuth ChemBioChem 2015, 16, 503–509, 10.1002/cbic.201402558

20Cobalt-Manganese-Based Spinels as Multifunctional Materials that Unify Catalytic Water Oxidation and Oxygen Reduction Reactions P. W. Menezes, A. Indra, N. R. Sahraie, A. Bergmann, P. Strasser, M. Driess ChemSusChem 2015, 8, 164–171, 10.1002/cssc.201402699

19A Neutral Tetraphosphacyclobutadiene Ligand in Cobalt(I) Complexes S. Yao, N. Lindenmaier, Y. Xiong, S. Inoue, T. Szilvási, M. Adelhardt, J. Sutter, K. Meyer, M. Driess Angewandte Chemie International Edition 2015, 54, 1250–1254, 10.1002/anie.201409469

18Type II thioesterase improves heterologous biosynthesis of valinomycin in Escherichia coli J. Li, J. Jaitzig, L. Theuer, O. E. Legala, R. D. Süssmuth, P. Neubauer Journal of Biotechnology 2015, 193, 16–22, 10.1016/j.jbiotec.2014.10.037

17Miniature direct electron transfer based sulphite/oxygen enzymatic fuel cells T. Zeng, D. Pankratov, M. Falk, S. Leimkühler, S. Shleev, U. Wollenberger Biosensors and Bioelectronics 2015, 66, 39–42, 10.1016/j.bios.2014.10.080

16C–H and C–F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps for the Catalytic Borylation of Fluorinated Aromatics S. I. Kalläne, M. Teltewskoi, T. Braun, B. Braun Organometallics 2015, 150121145048004– 10.1021/om500952x

15Cationic Zinc Organyls as Precatalysts for Hydroamination Reactions M. A. Chilleck, L. Hartenstein, T. Braun, P. W. Roesky, B. Braun Chemistry - A European Journal 2015, 21, 2594–2602, 10.1002/chem.201405662

14Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks T. Ahrens, J. Kohlmann, M. Ahrens, T. Braun Chemical Reviews 2015, 115, 931–972, 10.1021/cr500257c

13Calculating average surface enhancement factors of randomly nanostructured electrodes by a combination of SERS and impedance spectroscopy J. Kozuch, N. Petrusch, D. Gkogkou, U. Gernert, I. M. Weidinger Phys. Chem. Chem. Phys. 2015, 10.1039/C4CP05015K

12Analysis of structure-function relationships in cytochrome c oxidase and its biomimetic analogs via resonance Raman and surface enhanced resonance Raman spectroscopies I. M. Weidinger Biochimica et Biophysica Acta (BBA) - Bioenergetics 2015, 1847, 119–125, 10.1016/j.bbabio.2014.09.002

11An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties I. Monte-Pérez, S. Kundu, K. Ray Zeitschrift für anorganische und allgemeine Chemie 2015, 641, 78–82, 10.1002/zaac.201400389

10Biosynthesis and Function of Extracellular Glycans in Cyanobacteria J. C. Kehr, E. Dittmann Life 2015, 5, 164–180, 10.3390/life5010164

9 Functional assessment of mycosporine-like amino acids in Microcystis aeruginosa strain PCC 7806 C. Hu, G. Völler, R. Süßmuth, E. Dittmann, J. C. Kehr Environmental Microbiology 2015, 17, 1548–1559, 10.1111/1462-2920.12577

8 Nostopeptolide plays a governing role during cellular differentiation of the symbiotic cyanobacterium A. Liaimer, E. J. N. Helfrich, K. Hinrichs, A. Guljamow, K. Ishida, C. Hertweck, E. Dittmann Proceedings of the National Academy of Sciences 2015, 112, 1862–1867, 10.1073/pnas.1419543112

7Ni0.05Mn0.95O catalysts for the dry reforming of methane P. Littlewood, X. Xie, M. Bernicke, A. Thomas, R. Schomäcker Catalysis Today 2015, 242, 111–118, 10.1016/j.cattod.2014.07.054

6Mechanistic Aspects of the Gas-Phase Reactions of Halobenzenes with Bare Lanthanide Cations: A Combined Experimental/Theoretical Investigation S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 2123–2131, 10.1002/chem.201405964

5Phonon-Mediated Electron Transport through CaO Thin Films Y. Cui, S. Tosoni, W. D. Schneider, G. Pacchioni, N. Nilius, H. J. Freund Physical Review Letters 2015, 114, 16804–16805, 10.1103/PhysRevLett.114.016804

4Controlling fertilization and cAMP signaling in sperm by optogenetics V. Jansen, L. Alvarez, M. Balbach, T. Strünker, P. Hegemann, U. B. Kaupp, D. Wachten eLife 2015, 4, 10.7554/eLife.05161

3Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State T. T. Metsänen, M. Oestreich Organometallics 2015, 34, 543–546, 10.1021/om501279a

2 B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source I. Chatterjee, M. Oestreich Angewandte Chemie International Edition 2015, 54, 1965–1968, 10.1002/anie.201409246

1 Feasibility study of the Mn–Na2WO4/SiO2catalytic system for the oxidative coupling of methane in a fluidized-bed reactor S. Sadjadi, S. Jašo, H. R. Godini, S. Arndt, M. Wollgarten, R. Blume, O. Görke, R. Schomäcker, G. Wozny, U. Simon Catal. Sci. Technol. 2015, 5, 942–952, 10.1039/c4cy00822g