Dr. Maria Schlangen
Research interests
Gas-phase ion and physical organic chemistry, combination of experimental studies with theoretical methods, organometallic chemistry, selective bond activation in organic molecules by transition-metal species
Research Fields in UniCat
2009-2011: A4
Selection of research projects
- Reaction of metal-clusters ions
- Generation of elusive neutrals
- Metal-mediated oxidations
- Reactive transition-metal compounds
- Metal-mediated bond activation
- Mass-spectrometic approaches to stereoselectivity
- Multiply charged ions
- Development of new MS techniques to explore the reactivity of transient neutrals
UniCat publications
| 2443 Direct Identification of Acetaldehyde Formation and Characterization of the Active Site in the [VPO ] /C H Couple by Gas‐Phase Vibrational Spectroscopy Y. Li, S. Debnath, M. Schlangen, W. Schöllkopf, K. R. Asmis, H. Schwarz Angewandte Chemie International Edition 2019, 52, 18868–18872, 10.1002/anie.201911040 |
| 2429 O−O Bond Formation and Liberation of Dioxygen Mediated by N ‐Coordinate Non‐Heme Iron(IV) Complexes N. Kroll, I. Speckmann, M. Schoknecht, J. Gülzow, M. Diekmann, J. Pfrommer, A. Stritt, M. Schlangen, A. Grohmann, G. Hörner Angewandte Chemie International Edition 2019, 38, 13472–13478, 10.1002/anie.201903902 |
| 2380 Thermal Activation of CH and H as Mediated by the Ruthenium Oxide Cluster Ions [RuO ] ( 1–3): On the Influence of Oxidation States X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Chemistry – A European Journal 2019, 14, 3550–3559, 10.1002/chem.201806187 |
| 2379 On the Remarkable Role of the Nitrogen Ligand in the Gas-Phase Redox Reaction of the N O/CO Couple Catalyzed by [NbN] X. Sun, S. Zhou, L. Yue, C. Guo, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2019, 11, 3635–3639, 10.1002/anie.201814460 |
| 2378 Tuning the Reactivities of the Heteronuclear [Al V O ] ( 1, 2) Cluster Oxides towards Methane by Varying the Composition of the Metal Centers S. Zhou, X. Sun, L. Yue, M. Schlangen, H. Schwarz Chemistry - A European Journal 2019, 12, 2967–2971, 10.1002/chem.201805908 |
| 2377 Intermediates of N-Heterocyclic Carbene (NHC) Dimerization Probed in the Gas Phase by Ion Mobility Mass Spectrometry: C−H⋅⋅⋅:C Hydrogen Bonding Versus Covalent Dimer Formation M. Paul, E. Detmar, M. Schlangen, M. Breugst, J. M. Neudörfl, H. Schwarz, A. Berkessel, M. Schäfer Chemistry - A European Journal 2019, 10, 2511–2518, 10.1002/chem.201803641 |
| 2374 Selektive Übertragung eines Stickstoffatoms im [CeON] /CH -System durch hocheffizientes Intersystem Crossing S. Zhou, X. Sun, L. Yue, C. Guo, M. Schlangen, H. Schwarz Angewandte Chemie 2018, 48, 16129–16133, 10.1002/ange.201809583 |
| 2373 Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON] /CH System S. Zhou, X. Sun, L. Yue, C. Guo, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 48, 15902–15906, 10.1002/anie.201809583 |
| 2369 Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane C. Geng, J. Li, M. Schlangen, S. Shaik, X. Sun, N. Wang, T. Weiske, L. Yue, S. Zhou, H. Schwarz Dalton Transactions Dalton Transactions 2018, 43, 15271–15277, 10.1039/c8dt03048k |
| 2368 Elektrisches Feld als “smarter” Ligandenersatz zur kontrollierten thermischen Aktivierung von Methan und molekularem Wasserstoff L. Yue, N. Wang, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie 2018, 44, 14845–14849, 10.1002/ange.201805718 |
| 2367 The Electric Field as a “Smart” Ligand in Controlling the Thermal Activation of Methane and Molecular Hydrogen L. Yue, N. Wang, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 44, 14635–14639, 10.1002/anie.201805718 |
| 2361 Selective C−O Coupling Hidden in the Thermal Reaction of [Al CuO ] with Methane S. Zhou, X. Sun, L. Yue, M. Schlangen, H. Schwarz Chemistry - A European Journal 2018, 55, 14649–14653, 10.1002/chem.201804059 |
| 2295 Über die Ursachen der deutlich unterschiedlichen Reaktivität von Ruthenium unter den [MO] /CH -Systemen (M=Fe, Ru, Os) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie 2018, 20, 6039–6043, 10.1002/ange.201800173 |
| 2294 On the Origin of the Distinctly Different Reactivity of Ruthenium in [MO] /CH Systems (M=Fe, Ru, Os) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 20, 5934–5937, 10.1002/anie.201800173 |
| 2256 Direkte Umwandlung von Methan zu protoniertem Formaldehyd bei Raumtemperatur in der Gasphase: Zur Rolle von Quecksilber unter den Oxidkationen der Zinktriade L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie 2018, 12, 3306–3310, 10.1002/ange.201712405 |
| 2255 Direct Room-Temperature Conversion of Methane into Protonated Formaldehyde: The Gas-Phase Chemistry of Mercury among the Zinc Triad Oxide Cations L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 12, 3251–3255, 10.1002/anie.201712405 |
| 2198 Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+ M. Firouzbakht, N. J. Rijs, M. Schlangen, M. Kaupp, H. Schwarz Topics in Catalysis 2018, 7, 575–584, 10.1007/s11244-018-0903-8 |
| 2148 Spin-Selective, Competitive Hydrogen-Atom Transfer versus CH O-Generation from the CH /[ReO ] Couple at Ambient Conditions S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2017, 69, 17469–17472, 10.1002/chem.201704892 |
| 2145 Elektronische Ursache konkurrierender Mechanismen bei der thermischen Aktivierung von Methan durch das heteronukleare Clusteroxid [Al ZnO ] S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 45, 14486–14490, 10.1002/ange.201704979 |
| 2144 Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al ZnO ] S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 45, 14297–14300, 10.1002/anie.201704979 |
| 2143 Ursachen der unterschiedlichen Reaktivität von [AlCeO ] ( 2 4) gegenüber Methan in Abhängigkeit vom Sauerstoffgehalt S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 1, 424–428, 10.1002/ange.201610424 |
| 2142 On the Electronic Origin of Remarkable Ligand Effects on the Reactivities of [NiL] Complexes (L=C H , C H N, CN) towards Methane S. Zhou, M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2017, 58, 14430–14433, 10.1002/chem.201703767 |
| 2139 Metal-Dependent Strengthening and Weakening of M−H and M−C Bonds by an Oxo Ligand: Thermal Gas-Phase Activation of Methane by [OMH] and [MH] (M=Mo, Ti) M. Firouzbakht, S. Zhou, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2017, 50, 12346–12352, 10.1002/chem.201701615 |
| 2134 Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane L. Yue, J. Li, S. Zhou, X. Sun, M. Schlangen, S. Shaik, H. Schwarz Angewandte Chemie International Edition 2017, 34, 10219–10223, 10.1002/anie.201703485 |
| 2133 Steuerung der Produktverteilung und der Mechanismen der thermischen Aktivierung von Methan durch Ligandeneffekte und elektrische Felder L. Yue, J. Li, S. Zhou, X. Sun, M. Schlangen, S. Shaik, H. Schwarz Angewandte Chemie 2017, 34, 10353–10357, 10.1002/ange.201703485 |
| 2132 Metallfreier, durch [Si O ] ( =2 5) katalysierter Sauerstofftransfer im N O/CO‐Redoxpaar bei Raumtemperatur X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 33, 10122–10126, 10.1002/ange.201703453 |
| 2131 Metal‐Free, Room‐Temperature Oxygen‐Atom Transfer in the N O/CO Redox Couple as Catalyzed by [Si O ] ( =2 5) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 33, 9990–9993, 10.1002/anie.201703453 |
| 2118 Sequential Gas-Phase Activation of Carbon Dioxide and Methane by [Re(CO) ] : The Sequence of Events Matters! S. Zhou, J. Li, M. Firouzbakht, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2017, 17, 6169–6176, 10.1021/jacs.7b01255 |
| 2110 On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO) ] /CH ( 0 3) Couples S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 11, 2997–3000, 10.1002/ange.201611826 |
| 2109 On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO) ] /CH ( 0 3) Couples S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 11, 2951–2954, 10.1002/anie.201611826 |
| 2095 Gas-phase reactions of cationic molybdenum and tungsten monoxide with ethanol: a combined experimental/computational exercise P. González-Navarrete, M. Schlangen, H. Schwarz Structural Chemistry Structural Chemistry 2016, 2, 403–413, 10.1007/s11224-016-0862-2 |
| 2067 Thermal Methane Activation by the Metal-Free Cluster Cation [Si O ] X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2017, 7, 1498–1501, 10.1002/chem.201605496 |
| 2056 Electrostatic and Charge-Induced Methane Activation by a Concerted Double C–H Bond Insertion C. Geng, J. Li, T. Weiske, M. Schlangen, S. Shaik, H. Schwarz Journal of the American Chemical Society 2017, 4, 1684–1689, 10.1021/jacs.6b12514 |
| 2054 Striking Doping Effects on Thermal Methane Activation Mediated by the Heteronuclear Metal Oxides [ AlO ] ( =V, Nb, and Ta) X. N. Wu, J. Li, M. Schlangen, S. Zhou, P. González-Navarrete, H. Schwarz Chemistry - A European Journal 2017, 4, 788–792, 10.1002/chem.201605226 |
| 1970 Zum Ursprung der effizienten thermischen Chemisorption von Methan durch den heteronuklearen Metalloxidcluster [Al TaO ] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 47, 15090–15094, 10.1002/ange.201608999 |
| 1969 Thermische Dehydrierung von Methan durch [ReN] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 47, 15085–15089, 10.1002/ange.201607960 |
| 1968 Thermische Methanaktivierung durch [Si O ] und [Si O H ] : Reaktivitätssteigerung durch Hydrierung X. Sun, S. Zhou, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 42, 13540–13543, 10.1002/ange.201607864 |
| 1967 Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC] with Methane under Ambient Conditions J. Li, S. Zhou, M. Schlangen, T. Weiske, H. Schwarz Angewandte Chemie 2016, 42, 13266–13269, 10.1002/ange.201606707 |
| 1966 Effiziente, thermische Aktivierung von Methan durch TaN unter C-N-Kupplung S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 38, 11851–11855, 10.1002/ange.201606259 |
| 1965 Die Chemie von [AuO] /CH in der Gasphase: Selektive Sauerstoffatom-Übertragung auf, statt Wasserstoffatom-Abstraktion von Methan S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 36, 11036–11039, 10.1002/ange.201605259 |
| 1964 Spinabhängige, thermische Aktivierung von Methan durch den geschlossenschaligen Cluster [TaO ] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 25, 7374–7377, 10.1002/ange.201601965 |
| 1963 Thermal Activation of Methane by [HfO] and [XHfO] (X=F, Cl, Br, I) and the Origin of a Remarkable Ligand Effect S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 27, 7685–7688, 10.1002/anie.201602312 |
| 1961 Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane H. Schwarz, P. González-Navarrete, J. Li, M. Schlangen, X. Sun, T. Weiske, S. Zhou Organometallics 2016, 1, 8–17, 10.1021/acs.organomet.6b00372 |
| 1958 On the Origin of the Remarkably Variable Reactivities of [AlCeO ] ( 2 4) towards Methane as a Function of Oxygen Content S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 1, 413–416, 10.1002/anie.201610424 |
| 1950 Thermal Dehydrogenation of Methane by [ReN] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 47, 14863–14866, 10.1002/anie.201607960 |
| 1949 The Origin of the Efficient, Thermal Chemisorption of Methane by the Heteronuclear Metal-Oxide Cluster [Al TaO ] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 47, 14867–14871, 10.1002/anie.201608999 |
| 1948 Mechanistic aspects of CO2 activation mediated by phenyl yttrium cation: A combined experimental/theoretical study M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Journal of Catalysis 2016, 68–74, 10.1016/j.jcat.2015.09.012 |
| 1943 Thermal Methane Activation by [Si O ] and [Si O H ] : Reactivity Enhancement by Hydrogenation X. Sun, S. Zhou, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 42, 13345–13348, 10.1002/anie.201607864 |
| 1942 Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC] with Methane under Ambient Conditions J. Li, S. Zhou, M. Schlangen, T. Weiske, H. Schwarz Angewandte Chemie International Edition 2016, 42, 13072–13075, 10.1002/anie.201606707 |
| 1936 Efficient Room-Temperature Methane Activation by the Closed-Shell, Metal-Free Cluster [OSiOH] : A Novel Mechanistic Variant X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 40, 14257–14263, 10.1002/chem.201601981 |
| 1935 Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions J. Li, S. Zhou, J. Zhang, M. Schlangen, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 35, 11368–11377, 10.1021/jacs.6b07246 |
| 1934 Efficient Room-Temperature Activation of Methane by TaN under C−N Coupling S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 38, 11678–11681, 10.1002/anie.201606259 |
| 1933 The Unique Gas-Phase Chemistry of the [AuO] /CH Couple: Selective Oxygen-Atom Transfer to, Rather than Hydrogen-Atom Abstraction from, Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 36, 10877–10880, 10.1002/anie.201605259 |
| 1927 On the Activation of Methane and Carbon Dioxide by [HTaO] and [TaOH] in the Gas Phase: A Mechanistic Study M. Firouzbakht, N. J. Rijs, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2016, 30, 10581–10589, 10.1002/chem.201601339 |
| 1920 Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO ] (X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer J. Li, S. Zhou, J. Zhang, M. Schlangen, T. Weiske, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 25, 7973–7981, 10.1021/jacs.6b03798 |
| 1918 Thermische Aktivierung von Methan durch [HfO] und [XHfO] (X=F, Cl, Br, I): ein außergewöhnlicher Ligandeneffekt und dessen Ursache S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 27, 7816–7819, 10.1002/ange.201602312 |
| 1917 Spin-Selective Thermal Activation of Methane by Closed-Shell [TaO ] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 25, 7257–7260, 10.1002/anie.201601965 |
| 1913 Differences and Commonalities in the Gas-Phase Reactions of Closed-Shell Metal Dioxide Clusters [MO ] (M=V, Nb, and Ta) with Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 21, 7225–7228, 10.1002/chem.201600498 |
| 1846 Bond Activation by Metal–Carbene Complexes in the Gas Phase S. Zhou, J. Li, M. Schlangen, H. Schwarz Accounts of Chemical Research 2016, 3, 494–502, 10.1021/acs.accounts.5b00023 |
| 1845 Mechanistic Aspects of the Holmium-Mediated, Reciprocal Hydrogen/Sulfur Exchange in the Gas Phase: C H CH +CH S→C H CHS+CH S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 13, 4336–4339, 10.1002/chem.201600061 |
| 1840 On the Origin of Room-temperature, Au -mediated Coupling of a Methylene Ligand with H . Implications for the Mechanism of Methane Dehydrogenation. J. Li , S. Zhou, M. Schlangen, T. Weiske, H. Schwarz ChemistrySelect ChemistrySelect 2016, 3, 444–447, 10.1002/slct.201600073 |
| 1839 Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO] Complexes with Fluoromethanes (CH F , = 1–3) N. J. Rijs, P. González-Navarrete, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2016, 9, 3125–3135, 10.1021/jacs.5b12972 |
| 1792 Breaking and Making of Carbon-Carbon Bonds by Lanthanides and Third-Row Transition Metals S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 9, 3073–3076, 10.1002/chem.201504571 |
| 1791 Unravelling Mechanistic Aspects of the Gas-Phase Ethanol Conversion: An Experimental and Computational Study on the Thermal Reactions of MO (M=Mo, W) with Ethanol P. González-Navarrete, M. Schlangen, X. N. Wu, H. Schwarz Chemistry - A European Journal 2016, 9, 3077–3083, 10.1002/chem.201504929 |
| 1786 Zur Rolle der Elektronenstruktur des heteronuklearen Oxidclusters [Ga Mg O ] in der thermischen Aktivierung von Methan und Ethan: ein ungewöhnlicher Dotierungseffekt J. Li, X. N. Wu, M. Schlangen, S. Zhou, P. González-Navarrete, S. Tang, H. Schwarz Angewandte Chemie 2015, 17, 5163–5167, 10.1002/ange.201412441 |
| 1785 Zum Mechanismus des Wasserstoffatomtransfers von Wasser auf den heteronuklearen Oxidcluster [Ga Mg O ] : außergewöhnliche Effekte der elektronischen Struktur J. Li, S. Zhou, X. N. Wu, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie 2015, 40, 12028–12032, 10.1002/ange.201505336 |
| 1784 Deutlich unterschiedliche Mechanismen der Wasserstoffatomabstraktion aus Methan und Wasser durch den heteronuklearen Oxidcluster [Ga MgO ] J. Li, X. N. Wu, S. Zhou, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie 2015, 42, 12472–12477, 10.1002/ange.201503763 |
| 1771 Efficient Room-Temperature, Au -Mediated Coupling of a Carbene Ligand with Methane To Generate C H ( 4, 6) S. Zhou, J. Li, X. N. Wu, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 1, 441–444, 10.1002/anie.201509320 |
| 1770 Au -vermittelte, effiziente Kupplung eines Carbenliganden mit Methan: Bildung von C H ( 4, 6) bei Raumtemperatur S. Zhou, J. Li, X. N. Wu, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 1, 452–455, 10.1002/ange.201509320 |
| 1715 Correction to Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal-1,10- Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N Is Not Always an “Inert” Buffer Gas N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Analytical Chemistry 2015, 22, 11601–11601, 10.1021/acs.analchem.5b03989 |
| 1701 Distinct Mechanistic Differences in the Hydrogen-Atom Transfer from Methane and Water by the Heteronuclear Oxide Cluster [Ga MgO ] J. Li, X. N. Wu, S. Zhou, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2015, 42, 12298–12302, 10.1002/anie.201503763 |
| 1700 Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal–1,10-Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N Is Not Always an “Inert” Buffer Gas N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Analytical Chemistry 2015, 19, 9769–9776, 10.1021/acs.analchem.5b01985 |
| 1694 “Stripping” the Carbon Atom of Methyl Halide by a Cationic Holmium Complex: A Gas-Phase Study S. Zhou, M. Schlangen, J. Li, X. N. Wu, H. Schwarz Chemistry - A European Journal 2015, 41, 14305–14308, 10.1002/chem.201502183 |
| 1693 On the Mechanisms of Hydrogen-Atom Transfer from Water to the Heteronuclear Oxide Cluster [Ga Mg O ] : Remarkable Electronic Structure Effects J. Li, S. Zhou, X. N. Wu, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2015, 40, 11861–11864, 10.1002/anie.201505336 |
| 1687 Carbon-Atom Extrusion from Halobenzenes and Its Coupling with a Methylene Ligand to Form Acetylene S. Zhou, M. Schlangen, J. Li, X. N. Wu, H. Schwarz Chemistry - A European Journal 2015, 27, 9629–9631, 10.1002/chem.201501871 |
| 1678 Ligand-Controlled CO Activation Mediated by Cationic Titanium Hydride Complexes, [LTiH] (L=Cp , O) S. Y. Tang, N. J. Rijs, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 23, 8483–8490, 10.1002/chem.201500722 |
| 1653 Activation of Methane and Carbon Dioxide Mediated by Transition-Metal Doped Magnesium Oxide Clusters [MMgO] (M=Sc-Zn) J. Li, P. González-Navarrete, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 7780–7789, 10.1002/chem.201500715 |
| 1644 On the Role of the Electronic Structure of the Heteronuclear Oxide Cluster [Ga Mg O ] in the Thermal Activation of Methane and Ethane: An Unusual Doping Effect J. Li, X. N. Wu, M. Schlangen, S. Zhou, P. González-Navarrete, S. Tang, H. Schwarz Angewandte Chemie International Edition 2015, 17, 5074–5078, 10.1002/anie.201412441 |
| 1643 Mechanistic aspects of the gas-phase coupling of thioanisole and chlorobenzene to dibenzothiophene catalyzed by atomic Ho S. Zhou, M. Schlangen, H. Schwarz Physical Chemistry Chemical Physics Phys. Chem. Chem. Phys. 2015, 14, 9564–9568, 10.1039/c5cp01038a |
| 1484 Mechanistic Aspects of the Gas-Phase Reactions of Halobenzenes with Bare Lanthanide Cations: A Combined Experimental/Theoretical Investigation S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 5, 2123–2131, 10.1002/chem.201405964 |
| 1444 Highly regioselective hydride transfer, oxidative dehydrogenation, and hydrogen-atom abstraction in the thermal gas-phase chemistry of [Zn(OH)] /C H X. N. Wu, H. T. Zhao, J. Li, M. Schlangen, H. Schwarz Phys. Chem. Chem. Phys. Phys. Chem. Chem. Phys. 2014, 48, 26617–26623, 10.1039/c4cp02139h |
| 1432 Mechanisms of Metal-mediated C−N Coupling Processes: A Synergistic Relationship Between Gas-phase Experiments and Computational Chemistry H. Schwarz, R. Kretschmer, M. Schlangen Understanding Organometallic Reaction Mechanisms and Catalysis Ananikov, Valentine Wiley-VCH 2014, |
| 1406 On divorcing isomers, dissecting reactivity, and resolving mechanisms of propane CH and aryl CX (X=halogen) bond activations mediated by a ligated copper(III) oxo complex N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Chemical Physics Letters 2014, 408–424, 10.1016/j.cplett.2014.05.005 |
| 1399 Thermal Ethane Activation by Bare [V O ] and [Nb O ] Cluster Cations: on the Origin of Their Different Reactivities X. N. Wu, S. Y. Tang, H. T. Zhao, T. Weiske, M. Schlangen, H. Schwarz Chemistry - A European Journal 2014, 22, 6672–6677, 10.1002/chem.201402055 |
| 1121 Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations R. Kretschmer, M. Schlangen, H. Schwarz ChemPlusChem ChemPlusChem 2013, 9, 952–958, 10.1002/cplu.201300138 |
| 1098 Einfache und doppelte N-H-Aktivierung in NH durch [Al O ] : Erzeugung des Aminylradikals und von Nitren bei Raumtemperatur R. Kretschmer, Z. C. Wang, M. Schlangen, H. Schwarz Angewandte Chemie 2013, 36, 9691–9695, 10.1002/ange.201302506 |
| 1097 Single and Double NH Bond Activation of Ammonia by [Al O ] : Room Temperature Formation of the Aminyl Radical and Nitrene R. Kretschmer, Z. C. Wang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 36, 9513–9517, 10.1002/anie.201302506 |
| 1096 Thermal Methane Activation by a Binary V-Nb Transition-Metal Oxide Cluster Cation: A Further Example for the Crucial Role of Oxygen-Centered Radicals Z. C. Wang, J. W. Liu, M. Schlangen, T. Weiske, D. Schröder, J. Sauer, H. Schwarz Chemistry - A European Journal 2013, 35, 11496–11501, 10.1002/chem.201302133 |
| 1095 Isomer-Selective Thermal Activation of Methane in the Gas Phase by [HMO] and [M(OH)] (M=Ti and V) R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 23, 6097–6101, 10.1002/anie.201300900 |
| 1067 Mechanistic Aspects of Gas-Phase Hydrogen-Atom Transfer from Methane to [CO] and [SiO] : Why Do They Differ? N. Dietl, A. Troiani, M. Schlangen, O. Ursini, G. Angelini, Y. Apeloig, G. de Petris, H. Schwarz Chemistry - A European Journal 2013, 21, 6662–6669, 10.1002/chem.201204157 |
| 1016 Structure and Chemistry of the Heteronuclear Oxo-Cluster [VPO ] : A Model System for the Gas-Phase Oxidation of Small Hydrocarbons N. Dietl, T. Wende, K. Chen, L. Jiang, M. Schlangen, X. Zhang, K. R. Asmis, H. Schwarz Journal of the American Chemical Society 2013, 9, 3711–3721, 10.1021/ja400198y |
| 935 C–N coupling in the gas-phase reactions of ammonia and [M(CH)]+ (M = Ni, Pd, Pt): a combined experimental/computational exercise R. Kretschmer, M. Schlangen, H. Schwarz Dalton Transactions 2013, 12, 4153– 10.1039/c3dt32596b |
| 913 Gas-Phase Reactions of Cationic Vanadium-Phosphorus Oxide Clusters with C H ( 4, 6): A DFT-Based Analysis of Reactivity Patterns N. Dietl, X. Zhang, C. van der Linde, M. K. Beyer, M. Schlangen, H. Schwarz Chemistry - A European Journal 2013, 9, 3017–3028, 10.1002/chem.201203050 |
| 863 On the Origin of the Surprisingly Sluggish Redox Reaction of the N O/CO Couple Mediated by [Y O ] and [YAlO ] Cluster Ions in the Gas Phase J. B. Ma, Z. C. Wang, M. Schlangen, S. G. He, H. Schwarz Angewandte Chemie International Edition 2013, 4, 1226–1230, 10.1002/anie.201208559 |
| 855 Effects of Ligands, Cluster Size, and Charge State in Gas-Phase Catalysis: A Happy Marriage of Experimental and Computational Studies M. Schlangen, H. Schwarz Catalysis Letters 2012, 11, 1265–1278, 10.1007/s10562-012-0892-3 |
| 820 Thermal Reactions of YAlO with Methane: Increasing the Reactivity of Y O and the Selectivity of Al O by Doping J. B. Ma, Z. C. Wang, M. Schlangen, S. G. He, H. Schwarz Angewandte Chemie International Edition 2012, 24, 5991–5994, 10.1002/anie.201201698 |
| 819 A computational study on the intriguing mechanisms of the gas-phase thermal activation of methane by bare [Ni(H)(OH)]+ O. Lakuntza, J. M. Matxain, F. Ruipérez, M. Besora, F. Maseras, J. M. Ugalde, M. Schlangen, H. Schwarz Physical Chemistry Chemical Physics 2012, 26, 9306– 10.1039/c2cp23502a |
| 814 Thermal Ammonia Activation by Cationic Transition-Metal Hydrides of the First Row - Small but Mighty R. Kretschmer, M. Schlangen, H. Schwarz Chemistry - An Asian Journal 2012, 6, 1214–1220, 10.1002/asia.201101045 |
| 813 Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry N. Dietl, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2012, 23, 5544–5555, 10.1002/anie.201108363 |
| 812 Neutral Metal Atoms Acting as a Leaving Group in Gas-Phase S 2 Reactions: M(CH ) + NH → CH NH + M (M = Zn, Cd, Hg) R. Kretschmer, M. Schlangen, M. Kaupp, H. Schwarz Organometallics 2012, 10, 3816–3824, 10.1021/om300116c |
| 806 Direct Conversion of Methane into Formaldehyde Mediated by [Al2O3].+ at Room Temperature Z. C. Wang, N. Dietl, R. Kretschmer, J. B. Ma, T. Weiske, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2012, 15, 3703–3707, 10.1002/anie.201200015 |
| 804 CN and CC Bond Formations in the Thermal Reactions of “Bare” Ni(NH2)+ with C2H4: Mechanistic Insight on the Metal-Mediated Hydroamination of an Unactivated Olefin R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2012, 14, 3483–3488, 10.1002/anie.201104433 |
| 777 Mechanistic Aspects and Elementary Steps of NH Bond Activation of Ammonia and CN Coupling Induced by Gas-Phase Ions: A Combined Experimental/Computational Exercise R. Kretschmer, M. Schlangen, H. Schwarz Chemistry - A European Journal 2012, 1, 40–49, 10.1002/chem.201102494 |
| 771 Catalytic Redox Reactions in the CO/N2O System Mediated by the Bimetallic Oxide-Cluster Couple AlVO3+/AlVO4+ Z. C. Wang, N. Dietl, R. Kretschmer, T. Weiske, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2011, 51, 12351–12354, 10.1002/anie.201105691 |
| 668 Probing elementary steps of nickel-mediated bond activation in gas-phase reactions: Ligand- and cluster-size effects H. Schwarz, M. Schlangen Journal of Catalysis 2011, 284, 126–137, |
| 663 Structure of the Oxygen-Rich Cluster Cation Al O and its Reactivity toward Methane and Water Z. C. Wang, T. Weiske, R. Kretschmer, M. Schlangen, M. Kaupp, H. Schwarz Journal of the American Chemical Society 2011, 42, 16930–16937, 10.1021/ja206258x |
| 656 Thermal Activation of Methane and Ethene by Bare MO.+ (M=Ge, Sn, and Pb): A Combined Theoretical/Experimental Study K. Chen, Z. C. Wang, M. Schlangen, Y. D. Wu, X. Zhang, H. Schwarz Chemistry - A European Journal 2011, 35, 9619–9625, 10.1002/chem.201101538 |
| 602 Effiziente und selektive Monomethylierung kontra N-H-Bindungsaktivierung von Ammoniak: atomares Zink als Abgangsgruppe in einer SN2-Reaktion von “nacktem” Zn(CH3)+ und NH3 R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie 2011, 23, 5499–5503, 10.1002/ange.201100096 |
| 601 Efficient and Selective Gas-Phase Monomethylation versus NH Bond Activation of Ammonia by “Bare” Zn(CH3)+: Atomic Zinc as a Leaving Group in an SN2 Reaction R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2011, 23, 5387–5391, 10.1002/anie.201100096 |
| 589 Über die Rolle von [CuO]+ bei spinselektiven Wasserstoff- und Sauerstoff-Übertragungen in der Aktivierung von Methan N. Dietl, C. van der Linde, M. Schlangen, M. K. Beyer, H. Schwarz Angewandte Chemie 2011, 21, 5068–5072, 10.1002/ange.201100606 |
| 588 Diatomic [CuO]+ and Its Role in the Spin-Selective Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Methane N. Dietl, C. van der Linde, M. Schlangen, M. K. Beyer, H. Schwarz Angewandte Chemie International Edition 2011, 21, 4966–4969, 10.1002/anie.201100606 |
| 489 Thermal Activation of NH Bonds by Transition-metal Oxide Cations: Does a Hierarchy Exist in the First Row? R. Kretschmer, X. Zhang, M. Schlangen, H. Schwarz Chemistry - A European Journal 2011, 14, 3886–3892, 10.1002/chem.201003620 |
| 420 Generation, Reactivity Towards Hydrocarbons, and Electronic Structure of Heteronuclear Vanadium Phosphorous Oxygen Cluster Ions N. Dietl, R. F. Höckendorf, M. Schlangen, M. Lerch, M. K. Beyer, H. Schwarz Angewandte Chemie International Edition 2011, 6, 1430–1434, 10.1002/anie.201005258 |
| 419 Directed, Remote Gas-Phase CH and CC Bond Activations by Metal Oxide Cations Anchored to a Nitrile Group N. Dietl, M. Schlangen, H. Schwarz Chemistry - A European Journal 2011, 6, 1783–1788, 10.1002/chem.201003041 |
| 404 Darstellung, Reaktivität gegenüber Kohlenwasserstoffen und elektronische Struktur von heteronuclearen Vanadium-Phosphor-Sauerstoff-Clusterionen N. Dietl, R. F. Höckendorf, M. Schlangen, M. Lerch, M. K. Beyer, H. Schwarz Angewandte Chemie 2011, 6, 1466–1470, 10.1002/ange.201005258 |
| 399 Conversion of Methane to Methanol: Nickel, Palladium, and Platinum (d9) Cations as Catalysts for the Oxidation of Methane by Ozone at Room Temperature A. Božović, S. Feil, G. K. Koyanagi, A. A. Viggiano, X. Zhang, M. Schlangen, H. Schwarz, D. K. Bohme Chemistry - A European Journal 2010, 38, 11605–11610, 10.1002/chem.201000627 |
| 397 Selective CH versus OH Bond Activation of CH3OH upon Electrospraying Methanolic Solutions of MX2 (M=Fe, Co, Ni; X=Br, I): A DFT Study M. Schlangen, H. Schwarz ChemCatChem ChemCatChem 2010, 7, 799–802, 10.1002/cctc.201000042 |
| 298 Metal-dependent alternative activation of O–H and C–H bonds of methanol: on the formation and structure of “bare” [M,C,H3,O]+ complexes (M = Fe, Co, Ni) in the gas phase M. Schlangen, H. Schwarz Chemical Communications 2010, 11, 1878– 10.1039/b924493j |
| 268 Facile Dissociation of [(LNi ) E ] Dichalcogenides: Evidence for [LNi E ] Superselenides and Supertellurides in Solution S. Yao, Y. Xiong, X. Zhang, M. Schlangen, H. Schwarz, C. Milsmann, M. Driess Angewandte Chemie International Edition 2009, 25, 4551–4554, 10.1002/anie.200901132 |
| 231 Ligand and electronic-structure effects in metal-mediated gas-phase activation of methane: A cold approach to a hot problem M. Schlangen, H. Schwarz Dalton Transactions 2009, 46, 10155– 10.1039/b915165f |
| 221 A Redox Non-Innocent Ligand Controls the Life Time of a Reactive Quartet Excited State - An MCSCF Study of [Ni(H)(OH)]+ H. Schwarz, Y. Dede, X. Zhang, M. Schlangen, M. H. Baik Journal of the American Chemical Society 2009, 131, 12634–12642, |
| 118 Platinum(II)-mediated dehydrosulfurization and oxidative carbon–carbon coupling in the gas-phase decomposition of thioethers B. Butschke, M. Schlangen, D. Schröder, H. Schwarz International Journal of Mass Spectrometry International Journal of Mass Spectrometry 2009, 1, 3–8, 10.1016/j.ijms.2008.10.019 |
| 95 Room-Temperature Alkyne-Nitrile Metathesis and Unambiguous Proof for the Existence of a High-Valent Iron-Nitrido Dication in the Gas Phase. Short Communication J. Boyd, M. Schlangen, A. Grohmann, H. Schwarz Helvetica Chimica Acta 2008, 8, 1430–1434, 10.1002/hlca.200890155 |
| 94 Competitive Intramolecular Aryl- and Alkyl-CH Bond Activation and Ligand Evaporation from Gaseous Bisimino Complexes [Pt(L)(CH )((CH ) S)] (L=C H NC(CH )C(CH )NC H ) B. Butschke, M. Schlangen, D. Schröder, H. Schwarz Helvetica Chimica Acta 2008, 10, 1902–1915, 10.1002/hlca.200890204 |
| 93 “Roll-over” Cyclometalation of 2,2′-Bipyridine Platinum(II) Complexes in the Gas Phase: A Combined Experimental and Computational Study B. Butschke, M. Schlangen, D. Schröder, H. Schwarz Chemistry - A European Journal 2008, 35, 11050–11060, 10.1002/chem.200801658 |
| 92 DFT Studies on the Thermal Activation of Molecular Oxygen by Bare [Ni(H)(OH)] X. Zhang, M. Schlangen, M. H. Baik, Y. Dede, H. Schwarz Helvetica Chimica Acta 2009, 1, 151–164, 10.1002/hlca.200800411 |
| 91 Ligand Effects on the Mechanisms of Thermal Bond Activation in the Gas-Phase Reactions NiX /CH →Ni(CH ) /HX (X=H, CH , OH, F). Short Communication M. Schlangen, H. Schwarz Helvetica Chimica Acta 2008, 12, 2203–2210, 10.1002/hlca.200890238 |
| 89 On the Mechanisms of Degenerate Ligand Exchange in [M(CH3)]+/CH4 Couples (M=Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt) as Explored by Mass Spectrometric and Computational Studies: Oxidative Addition/Reductive Elimination versus σ-Complex-Assisted Metathesis M. Armélin, M. Schlangen, H. Schwarz Chemistry - A European Journal 2008, 17, 5229–5236, 10.1002/chem.200800029 |
| 86 Insertion of Molecular Oxygen in Transition-Metal Hydride Bonds, Oxygen-Bond Activation, and Unimolecular Dissociation of Metal Hydroperoxide Intermediates. Short Communication M. Schlangen, H. Schwarz Helvetica Chimica Acta 2008, 3, 379–386, 10.1002/hlca.200890043 |
