Prof. Dr. Matthias Driess - Publications

2345 Facile Formation of Nanostructured Manganese Oxide Films as High-Performance Catalysts for the Oxygen Evolution Reaction C. Walter, P. W. Menezes, S. Loos, H. Dau, M. Driess ChemSusChem 2018, 11, 2554–2561, 10.1002/cssc.201800493

2335 A structurally versatile nickel phosphite acting as a robust bifunctional electrocatalyst for overall water splitting P. W. Menezes, C. Panda, S. Loos, F. Bunschei-Bruns, C. Walter, M. Schwarze, X. Deng, H. Dau, M. Driess Energy & Environmental Science 2018, 11, 1287–1298, 10.1039/c7ee03619a

2293 High Electromagnetic Field Enhancement of TiO2Nanotube Electrodes I. H. Öner, C. J. Querebillo, C. David, U. Gernert, C. Walter, M. Driess, S. Leimkühler, K. H. Ly, I. M. Weidinger Angewandte Chemie International Edition 2018, 57, 7225–7229, 10.1002/anie.201802597

2264 A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2M′] Complexes in Oxidation Reactions X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray Angewandte Chemie 2017, 129, 303–307, 10.1002/ange.201607611

2218 Optimized immobilization of ZnO:Co electrocatalysts realizes 5% efficiency in photo-assisted splitting of water A. Azarpira, J. Pfrommer, K. Olech, C. Höhn, M. Driess, B. Stannowski, T. Schedel-Niedrig, M. Lublow Journal of Materials Chemistry A 2016, 4, 3082–3090, 10.1039/C5TA07329D

2217 Boosting electrochemical water oxidation through replacement of OhCo sites in cobalt oxide spinel with manganese P. W. Menezes, A. Indra, V. Gutkin, M. Driess Chemical Communications 2017, 53, 8018–8021, 10.1039/C7CC03749J

2216 Stereoselective Transfer Semi-Hydrogenation of Alkynes toE-Olefins withN-Heterocyclic Silylene-Manganese Catalysts Y. P. Zhou, Z. Mo, M. P. Luecke, M. Driess Chemistry - A European Journal 2017, 23, 10.1002/chem.201705745

2215 Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols T. L. Gianetti, S. P. Annen, G. Santiso-Quinones, M. Reiher, M. Driess, H. Grützmacher Angewandte Chemie International Edition 2016, 55, 1854–1858, 10.1002/anie.201509288

2214 Morphology-Dependent Activities of Silver Phosphates: Visible-Light Water Oxidation and Dye Degradation P. W. Menezes, A. Indra, M. Schwarze, F. Schuster, M. Driess ChemPlusChem 2016, 81, 1068–1074, 10.1002/cplu.201500538

2213 Yolk@Shell Nanoarchitectures with Bimetallic Nanocores–Synthesis and Electrocatalytic Applications A. Guiet, T. Unmüssig, C. Göbel, U. Vainio, M. Wollgarten, M. Driess, H. Schlaad, J. Polte, A. Fischer ACS Applied Materials & Interfaces 2016, 8, 28019–28029, 10.1021/acsami.6b06595

2212 N-heterocyclic silylenes as powerful steering ligands in catalysis S. Raoufmoghaddam, Y. P. Zhou, Y. Wang, M. Driess Journal of Organometallic Chemistry 2017, 829, 2–10, 10.1016/j.jorganchem.2016.07.014

2211 Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting P. W. Menezes, A. Indra, C. Das, C. Walter, C. Göbel, V. Gutkin, D. Schmeiβer, M. Driess ACS Catalysis 2016, 7, 103–109, 10.1021/acscatal.6b02666

2210 Boosting Visible-Light-Driven Photocatalytic Hydrogen Evolution with an Integrated Nickel Phosphide-Carbon Nitride System A. Indra, A. Acharjya, P. W. Menezes, C. Merschjann, D. Hollmann, M. Schwarze, M. Aktas, A. Friedrich, S. Lochbrunner, A. Thomas, M. Driess Angewandte Chemie International Edition 2017, 56, 1653–1657, 10.1002/anie.201611605

2209 A facile corrosion approach to the synthesis of highly active CoOxwater oxidation catalysts A. Indra, P. W. Menezes, C. Das, C. Göbel, M. Tallarida, D. Schmeiβer, M. Driess Journal of Materials Chemistry A 2017, 5, 5171–5177, 10.1039/C6TA10650A

2208 Cobalt-Catalyzed Regioselective Borylation of Arenes: N-Heterocyclic Silylene as an Electron Donor in the Metal-Mediated Activation of C−H Bonds H. Ren, Y. P. Zhou, Y. Bai, C. Cui, M. Driess Chemistry - A European Journal 2017, 23, 5663–5667, 10.1002/chem.201605937

2207 Taming Silicon Congeners of CO and CO2: Synthesis of Monomeric SiIIand SiIVChalcogenide Complexes A. Burchert, R. Müller, S. Yao, C. Schattenberg, Y. Xiong, M. Kaupp, M. Driess Angewandte Chemie International Edition 2017, 56, 6298–6301, 10.1002/anie.201700530

2206 From a Molecular 2Fe-2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting C. Panda, P. W. Menezes, C. Walter, S. Yao, M. E. Miehlich, V. Gutkin, K. Meyer, M. Driess Angewandte Chemie International Edition 2017, 56, 10506–10510, 10.1002/anie.201706196

2205 Silylene-Nickel Promoted Cleavage of B−O Bonds: From Catechol Borane to the Hydroborylene Ligand T. J. Hadlington, T. Szilvási, M. Driess Angewandte Chemie International Edition 2017, 56, 7470–7474, 10.1002/anie.201702772

2204 Alkaline electrochemical water oxidation with multi-shelled cobalt manganese oxide hollow spheres A. Indra, P. W. Menezes, C. Das, D. Schmeißer, M. Driess Chemical Communications 2017, 53, 8641–8644, 10.1039/C7CC03566G

2203 Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application M. P. Luecke, D. Porwal, A. Kostenko, Y. P. Zhou, S. Yao, M. Keck, C. Limberg, M. Oestreich, M. Driess Dalton Transactions 2017, 46, 16412–16418, 10.1039/C7DT03301J

2202 Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins Y. Wang, A. Kostenko, S. Yao, M. Driess Journal of the American Chemical Society 2017, 139, 13499–13506, 10.1021/jacs.7b07167

2174 A Molecular Approach to Manganese Nitride Acting as a High Performance Electrocatalyst in the Oxygen Evolution Reaction C. Walter, P. W. Menezes, S. Orthmann, J. Schuch, P. Connor, B. Kaiser, M. Lerch, M. Driess Angewandte Chemie International Edition 2018, 57, 698–702, 10.1002/anie.201710460

2173 Striking transformations of the hydroborylene ligand in a HB:→NiIIcomplex with isocyanides and CO T. J. Hadlington, T. Szilvási, M. Driess Chemical Science 2018, 1–6, 10.1039/c7sc04792d

2156 Improving the Catalytic Activity in the Rhodium-Mediated Hydroformylation of Styrene by a Bis(N-heterocyclic silylene) Ligand M. Schmidt, B. Blom, T. Szilvási, R. Schomäcker, M. Driess European Journal of Inorganic Chemistry 2017, 2017, 1284–1291, 10.1002/ejic.201700148

2108 An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water Z. Mo, T. Szilvási, Y. P. Zhou, S. Yao, M. Driess Angewandte Chemie International Edition 2017, 56, 3699–3702, 10.1002/anie.201700625

2096 An S-Oxygenated [NiFe] Complex Modelling Sulfenate Intermediates of an O2-Tolerant Hydrogenase N. J. Lindenmaier, S. Wahlefeld, E. Bill, T. Szilvási, C. Eberle, S. Yao, P. Hildebrandt, M. Horch, I. Zebger, M. Driess Angewandte Chemie International Edition 2017, 56, 2208–2211, 10.1002/anie.201611069

2002 Changing the chemical and physical properties of high valent heterobimetallic bis-(μ-oxido) Cu–Ni complexes by ligand effects M. C. Kafentzi, M. Orio, M. Réglier, S. Yao, U. Kuhlmann, P. Hildebrandt, M. Driess, A. J. Simaan, K. Ray Dalton Trans. 2016, 45, 15994–16000, 10.1039/c6dt02391f

1999 A Single-Source Precursor Approach to Self-Supported Nickel-Manganese-Based Catalysts with Improved Stability for Effective Low-Temperature Dry Reforming of Methane P. W. Menezes, A. Indra, P. Littlewood, C. Göbel, R. Schomäcker, M. Driess ChemPlusChem 2016, 81, 370–377, 10.1002/cplu.201600064

1953 A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2M′] Complexes in Oxidation Reactions X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray Angewandte Chemie International Edition 2016, 10.1002/anie.201607611

1947 A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes Y. P. Zhou, S. Raoufmoghaddam, T. Szilvási, M. Driess Angewandte Chemie International Edition 2016, 55, 12868–12872, 10.1002/anie.201606979

1946 Active and Stable Nickel-Based Electrocatalysts Based on the ZnO:Ni System for Water Oxidation in Alkaline Media J. Pfrommer, A. Azarpira, A. Steigert, K. Olech, P. W. Menezes, R. F. Duarte, X. Liao, R. G. Wilks, M. Bär, T. Schedel-Niedrig, M. Driess ChemCatChem 2017, 9, 672–676, 10.1002/cctc.201600922

1945 Uncovering the prominent role of metal ions in octahedral versus tetrahedral sites of cobalt–zinc oxide catalysts for efficient oxidation of water P. W. Menezes, A. Indra, A. Bergmann, P. Chernev, C. Walter, H. Dau, P. Strasser, M. Driess J. Mater. Chem. A 2016, 4, 10014–10022, 10.1039/C6TA03644A

1855 Controlled Formation of Nickel Oxide Nanoparticles on Mesoporous Silica using Molecular Ni4O4Clusters as Precursors: Enhanced Catalytic Performance for Dry Reforming of Methane E. Baktash, P. Littlewood, J. Pfrommer, R. Schomäcker, M. Driess, A. Thomas ChemCatChem 2015, 7, 1280–1284, 10.1002/cctc.201402983

1853 Enhancing of catalytic properties of vanadia via surface doping with phosphorus using atomic layer deposition V. E. Strempel, D. Löffler, J. Kröhnert, K. Skorupska, B. Johnson, R. N. d'Alnoncourt, M. Driess, F. Rosowski Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 2016, 34, 1– 10.1116/1.4936390

1817 Biomimetische [2Fe-2S]-Cluster mit stark delokalisierten gemischtvalenten Eisenzentren S. Yao, F. Meier, N. Lindenmaier, R. Rudolph, B. Blom, M. Adelhardt, J. Sutter, S. Mebs, M. Haumann, K. Meyer, M. Kaupp, M. Driess Angewandte Chemie 2015, 127, 12686–12690, 10.1002/ange.201506788

1724 Nickel as a co-catalyst for photocatalytic hydrogen evolution on graphitic-carbon nitride (sg-CN): what is the nature of the active species? A. Indra, P. W. Menezes, K. Kailasam, D. Hollmann, M. Schröder, A. Thomas, A. Brückner, M. Driess Chem. Commun. 2016, 52, 104–107, 10.1039/C5CC07936E

1723 Synthesis of Mixed Silylene-Carbene Chelate Ligands from N-Heterocyclic Silylcarbenes Mediated by Nickel G. Tan, S. Enthaler, S. Inoue, B. Blom, M. Driess Angewandte Chemie International Edition 2015, 54, 2214–2218, 10.1002/anie.201409739

1722 Using nickel manganese oxide catalysts for efficient water oxidation P. W. Menezes, A. Indra, O. Levy, K. Kailasam, V. Gutkin, J. Pfrommer, M. Driess Chem. Commun. 2015, 51, 5005–5008, 10.1039/C4CC09671A

1721 Uncovering Structure-Activity Relationships in Manganese-Oxide-Based Heterogeneous Catalysts for Efficient Water Oxidation A. Indra, P. W. Menezes, M. Driess ChemSusChem 2015, 8, 776–785, 10.1002/cssc.201402812

1720 Heterogeneous Water Oxidation: Surface Activity versus Amorphization Activation in Cobalt Phosphate Catalysts D. González-Flores, I. Sánchez, I. Zaharieva, K. Klingan, J. Heidkamp, P. Chernev, P. W. Menezes, M. Driess, H. Dau, M. L. Montero Angewandte Chemie International Edition 2015, 54, 2472–2476, 10.1002/anie.201409333

1719 High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology-Dependent Activity P. W. Menezes, A. Indra, D. González-Flores, N. R. Sahraie, I. Zaharieva, M. Schwarze, P. Strasser, H. Dau, M. Driess ACS Catalysis 2015, 5, 2017–2027, 10.1021/cs501724v

1718 Dual Catalytic Activity of Palladium Doped with a Rhodium Complex in a One-pot, Four Step Process L. Shapiro, M. Driess, D. Avnir ChemCatChem 2015, 7, 2033–2037, 10.1002/cctc.201500240

1717 Hydrophobic Nanoreactor Soft-Templating: A Supramolecular Approach to Yolk@Shell Materials A. Guiet, C. Göbel, K. Klingan, M. Lublow, T. Reier, U. Vainio, R. Kraehnert, H. Schlaad, P. Strasser, I. Zaharieva, H. Dau, M. Driess, J. Polte, A. Fischer Advanced Functional Materials 2015, 25, 6228–6240, 10.1002/adfm.201502388

1716 Biomimetic [2Fe-2S] Clusters with Extensively Delocalized Mixed-Valence Iron Centers S. Yao, F. Meier, N. Lindenmaier, R. Rudolph, B. Blom, M. Adelhardt, J. Sutter, S. Mebs, M. Haumann, K. Meyer, M. Kaupp, M. Driess Angewandte Chemie International Edition 2015, 54, 12506–12510, 10.1002/anie.201506788

1711 Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex T. T. Metsänen, D. Gallego, T. Szilvási, M. Driess, M. Oestreich Chem. Sci. 2015, 6, 7143–7149, 10.1039/C5SC02855H

1672 Controlled Formation of Nickel Oxide Nanoparticles on Mesoporous Silica using Molecular Ni4O4 Clusters as Precursors: Enhanced Catalytic Performance for Dry Reforming of Methane E. Baktash, P. Littlewood, J. Pfrommer, R. Schomäcker, M. Driess, A. Thomas ChemCatChem 2015, 7, 1280–1284, 10.1002/cctc.201402983

1548 Cobalt-Manganese-Based Spinels as Multifunctional Materials that Unify Catalytic Water Oxidation and Oxygen Reduction Reactions P. W. Menezes, A. Indra, N. R. Sahraie, A. Bergmann, P. Strasser, M. Driess ChemSusChem 2015, 8, 164–171, 10.1002/cssc.201402699

1547 A Neutral Tetraphosphacyclobutadiene Ligand in Cobalt(I) Complexes S. Yao, N. Lindenmaier, Y. Xiong, S. Inoue, T. Szilvási, M. Adelhardt, J. Sutter, K. Meyer, M. Driess Angewandte Chemie International Edition 2015, 54, 1250–1254, 10.1002/anie.201409469

1546 Chelating N-Heterocyclic Silylenes as Steering Ligands in Catalysis M. Drieß, B. Blom, D. Gallego, G. Tan Reference Module in Chemistry, Molecular Sciences and Chemical Engineering Elsevier Elsevier 2014,

1541 A Molecular Approach to Self-Supported Cobalt-Substituted ZnO Materials as Remarkably Stable Electrocatalysts for Water Oxidation J. Pfrommer, M. Lublow, A. Azarpira, C. Göbel, M. Lücke, A. Steigert, M. Pogrzeba, P. W. Menezes, A. Fischer, T. Schedel-Niedrig, M. Driess Angewandte Chemie 2014, 126, 5283–5287, 10.1002/ange.201400243

1540 Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic C—H Bonds Directed by a Secondary Amine Q. Li, M. Driess, J. F. Hartwig Angewandte Chemie International Edition 2014, 53, 8471–8474, 10.1002/anie.201404620

1539 Elucidating the Effect of the Nucleophilicity of the Silyl Group in the Reduction of CO2 to CO Mediated by Silyl-Copper(I) Complexes G. Tan, B. Blom, D. Gallego, E. Irran, M. Driess Chemistry - A European Journal 2014, 20, 9400–9408, 10.1002/chem.201402017

1538 High Catalytic Synergism between the Components of the Rhenium Complex@Silver Hybrid Material in Alkene Epoxidations A. Indra, M. Greiner, A. K. Gericke, R. Schlögl, D. Avnir, M. Driess ChemCatChem 2014, 6, 1935–1939, 10.1002/cctc.201402042

1537 Hydride Binding to the Active Site of [FeFe]-Hydrogenase P. Chernev, C. Lambertz, A. Brünje, N. Leidel, K. G. V. Sigfridsson, R. Kositzki, C. H. Hsieh, S. Yao, R. Schiwon, M. Driess, C. Limberg, T. Happe, M. Haumann Inorganic Chemistry 2014, 53, 12164–12177, 10.1021/ic502047q

1536 Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C–H Bonds for the Synthesis of 1,3-Diols B. Li, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 136, 6586–6589, 10.1021/ja5026479

1535 An Elusive Hydridoaluminum(I) Complex for Facile C–H and C–O Bond Activation of Ethers and Access to Its Isolable Hydridogallium(I) Analogue: Syntheses, Structures, and Theoretical Studies G. Tan, T. Szilvási, S. Inoue, B. Blom, M. Driess Journal of the American Chemical Society 2014, 136, 9732–9742, 10.1021/ja504448v

1533 Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes B. L. Tran, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 136, 17292–17301, 10.1021/ja510093x

1532 Unification of Catalytic Water Oxidation and Oxygen Reduction Reactions: Amorphous Beat Crystalline Cobalt Iron Oxides A. Indra, P. W. Menezes, N. R. Sahraie, A. Bergmann, C. Das, M. Tallarida, D. Schmeißer, P. Strasser, M. Driess Journal of the American Chemical Society 2014, 136, 17530–17536, 10.1021/ja509348t

1531 Synthesis, Reactivity, and Electronic Structure of a Bioinspired Heterobimetallic [Ni(μ-S2)Fe] Complex with Disulfur Monoradical character R. Rudolph, B. Blom, S. Yao, F. Meier, E. Bill, M. van Gastel, N. Lindenmaier, M. Kaupp, M. Driess Organometallics 2014, 33, 3154–3162, 10.1021/om500381t

1530 From Unsymmetrically Substituted Benzamidinato and Guanidinato Dichlorohydridosilanes to Novel Hydrido N-Heterocyclic Silylene Iron Complexes B. Blom, M. Pohl, G. Tan, D. Gallego, M. Driess Organometallics 2014, 33, 5272–5282, 10.1021/om5005918

1529 Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity D. Gallego, S. Inoue, B. Blom, M. Driess Organometallics 2014, 33, 6885–6897, 10.1021/om500966t

1459 Nanostructured Manganese Oxides as Highly Active Water Oxidation Catalysts: A Boost from Manganese Precursor Chemistry P. W. Menezes, A. Indra, P. Littlewood, M. Schwarze, C. Göbel, R. Schomäcker, M. Driess ChemSusChem 2014, 7, 2202–2211, 10.1002/cssc.201402169

1440 A Molecular Approach to Self-Supported Cobalt-Substituted ZnO Materials as Remarkably Stable Electrocatalysts for Water Oxidation J. Pfrommer, M. Lublow, A. Azarpira, C. Göbel, M. Lücke, A. Steigert, M. Pogrzeba, P. W. Menezes, A. Fischer, T. Schedel-Niedrig, M. Driess Angewandte Chemie International Edition 2014, 53, 5183–5187, 10.1002/anie.201400243

1433 From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature Y. Xiong, S. Yao, R. Müller, M. Kaupp, M. Driess Nature Chemistry 2010, 2, 577–580, 10.1038/nchem.666

1390 Visible light driven non-sacrificial water oxidation and dye degradation with silver phosphates: multi-faceted morphology matters A. Indra, P. W. Menezes, M. Schwarze, M. Driess New Journal of Chemistry 2014, 10.1039/C3NJ01012K

1389 Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride G. Tan, W. Wang, B. Blom, M. Driess Dalton Transactions 2014, 10.1039/C3DT53321B

1388 N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field B. Blom, D. Gallego, M. Driess Inorganic Chemistry Frontiers 2014, 1, 134–148, 10.1039/C3QI00079F

1387 A Donor-Stabilized Zwitterionic “Half-Parent” Phosphasilene and Its Unusual Reactivity towards Small Molecules K. Hansen, T. Szilvási, B. Blom, E. Irran, M. Driess Chemistry - A European Journal 2014, 20, 1947–1956, 10.1002/chem.201303906

1386 Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes B. L. Tran, B. Li, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 136, 2555–2563, 10.1021/ja411912p

1385 Facile Access to Mono- and Dinuclear Heteroleptic N-Heterocyclic Silylene Copper Complexes G. Tan, B. Blom, D. Gallego, M. Driess Organometallics 2014, 33, 363–369, 10.1021/om4011033

1384 Bis- -Heterocyclic Carbene (NHC) Stabilized η -Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity B. Blom, G. Tan, S. Enthaler, S. Inoue, J. D. Epping, M. Driess Journal of the American Chemical Society 2013, 135, 18108–18120, 10.1021/ja410234x

1382 A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene Y. Xiong, S. Yao, G. Tan, S. Inoue, M. Driess Journal of the American Chemical Society 2013, 135, 5004–5007, 10.1021/ja402477w

1381 N-Heterocyclic Silylene (NHSi) Rhodium and Iridium Complexes: Synthesis, Structure, Reactivity, and Catalytic Ability M. Stoelzel, C. Präsang, B. Blom, M. Driess Australian Journal of Chemistry 2013, 66, 1163–1170, 10.1071/CH13196

1353 A High-Valent Heterobimetallic [Cu(III) (μ-O) Ni(III)]2+ Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie International Edition 2013, 52, 5622–5626, 10.1002/anie.201300861

1352 Active Mixed-Valent MnO Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles A. Indra, P. W. Menezes, I. Zaharieva, E. Baktash, J. Pfrommer, M. Schwarze, H. Dau, M. Driess Angewandte Chemie International Edition 2013, 52, 13206–13210, 10.1002/anie.201307543

1312 A One-Pot Approach to Mesoporous Metal Oxide Ultrathin Film Electrodes Bearing One Metal Nanoparticle per Pore with Enhanced Electrocatalytic Properties A. Guiet, T. Reier, N. Heidary, D. Felkel, B. Johnson, U. Vainio, H. Schlaad, Y. Aksu, M. Driess, P. Strasser, A. Thomas, J. Polte, A. Fischer Chemistry of Materials 2013, 25, 4645–4652, 10.1021/cm401135z

1288 From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction D. Gallego, A. Brück, E. Irran, F. Meier, M. Kaupp, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2013, 135, 15617–15626, 10.1021/ja408137t

1280 A High-Valent Heterobimetallic [Cu (μ-O) Ni ] Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie 2013, 125, 5732–5736, 10.1002/ange.201300861

1110 Electro- and Photochemical Water Oxidation on Ligand-free Co3O4 Nanoparticles with Tunable Sizes M. Grzelczak, J. Zhang, J. Pfrommer, J. Hartmann, M. Driess, M. Antonietti, X. Wang ACS Catalysis Scientific Reports 2013, 3, 383–388, 10.1021/cs3007523

993 From a Stable Silanone Complex to Isolable, Donor-Supported Silicoxonium Halides [LSi(dmap) O SiMe3]+X− M. Driess, Y. Xiong, S. Yao, E. Irran Chemistry - A European Journal 2011, 17, 11274–11279, 10.1002/chem.201101610

992 Reactivity of N-Heterocyclic Germylene Toward Ammonia and Water M. Driess, W. Wang, S. Inoue, S. Yao Organometallics 2011, 30, 6490–6494, 10.1021/om200970s

991 Synthesis of Stannyl-Substituted Zn4O4 Cubanes as Single-Source Precursors for Amorphous Tin-Doped ZnO and Zn2SnO4 Nanocrystals and Their Potential for Thin Film Field Effect Transistor Applications M. Driess, M. Tsaroucha, Y. Aksu, E. Irran Chemistry of Materials 2011, 23, 2428–2438, 10.1021/cm200282w

990 Main group chemistry: Breaking the limits with silylenes M. Driess Nature Chemistry 2012, 4, 525–526, 10.1038/nchem.1387

989 Heterotermetallic Indium Lithium Halostannates: Low-Temperature Single- Source Precursors for Tin-Rich Indium Tin Oxides and Their Application for Thin-Film Transistors M. Driess, K. Samedov, Y. Aksu Chemistry - A European Journal 2012, 18, 7766–7779, 10.1002/chem.201103594

988 Facile Metalation of Silicon and Germanium Analogues of Thiocarboxylic Acids with a Manganese(II) Hydride Precursor M. Driess, S. Yao, Y. Xiong Chemistry - A European Journal 2012, 18, 11356–11361, 10.1002/chem.201201335

987 Facile Access to Silicon-Functionalized Bis-Silylene Titanium(II) Complexes M. Driess, S. Inoue, B. Blom, D. Gallego Chemistry - A European Journal 2012, 18, 13355–13360, 10.1002/chem.201202399

986 Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis-(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands M. Driess, A. Brück, D. Gallego, W. Wang, E. Irran, J. F. Hartwig Angewandte Chemie International Edition 2012, 51, 11478–11482, 10.1002/anie.201205570

985 Facile Low-Temperature Approach to Tin-Containing ZnO Nanocrystals with Tunable Tin Concentrations Using Heterobimetallic Sn/Zn Single-Source Precursors M. Driess, M. Tsaroucha, Y. Aksu, J. D. Epping ChemPlusChem 2013, 78, 62–69, 10.1002/cplu.201200259

984 New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules M. Driess, B. Blom, M. Stoelzel Chemistry - A European Journal 2013, 19, 40–62, 10.1002/chem.201203072

934 Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi Pincerlike Arene to Palladium M. Driess, S. Inoue, W. Wang, E. Irran Angewandte Chemie International Edition 2012, 51, 3691–3694, 10.1002/anie.201200632

933 Facile Molecular Approach to Transparent Thin-Film Field-Effect Transistors with High-Performance Using New Homo- and Heteroleptic Indium(III)–Tin(II) Single-Source Precursors M. Driess, K. Samedov, Y. Aksu Chemistry of Materials 2012, 24, 2078–2090, 10.1021/cm300510y

878 A Neutral, Monomeric Germanium (I) Radical W. D. Woodul, E. Carter, R. Müller, A. F. Richards, A. Stasch, M. Kaupp, D. M. Murphy, M. Driess, C. Jones Journal of the American Chemical Society 2011, 3, 10074–10077, 10.1021/ja204344e

874 A Heterobimetallic Approach To Stabilize the Elusive Disulfur Radical Trianion ("Subsulfide") S. Yao, P. Hrobárik, F. Meier, R. Rudolph, E. Bill, E. Irran, M. Kaupp, M. Driess Chemistry - A European Journal 2013, 3, 1246–1253, 10.1002/chem.201203642

858 Bis(silylenyl)- and Bis(germylenyl)-Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)–Cobalt Complexes W. Wang, S. Inoue, S. Enthaler, M. Driess Angewandte Chemie International Edition 2012, 51, 6167–6171, 10.1002/anie.201202175

850 Supported ZnO Catalysts for the Conversion of Alkanes: About the Metamorphosis of a heterogeneous Catalyst. S. Arndt, B. Uysal, A. Berthold, T. Otremba, Y. Aksu, M. Driess, R. Schomäcker Journal of Natural Gas Chemistry 2012, 21, 581–594, 10.1016/S1003-9953(11)60407-6

669 Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride M. Stoelzel, C. Präsang, S. Inoue, S. Enthaler, M. Driess Angewandte Chemie International Edition 2012, 51, 339–403, 10.1002/anie.201105722

658 Li-doped MgO From Different Preparative Routes for the Oxidative Coupling of Methane S. Arndt, U. Simon, S. Heitz, A. Berthold, B. Beck, O. Görke, J. D. Epping, T. Otremba, Y. Aksu, E. Irran, G. Laugel, M. Driess, H. Schubert, R. Schomäcker Topics in Catalysis 2011, 54, 1266–2285, 10.1007/s11244-011-9749-z

657 Lessons from isolable nickel(I) precursor complexes for small molecule activation S. Yao, M. Driess Accounts of Chemical Research 2012, 45, 276–287, 10.1021/ar200156r

627 Low-Valent Molybdenum-Based Dual Pre-Catalysts for Highly Efficient Catalytic Epoxidation of Alkenes and Deoxygenation of Sulfoxides M. Driess, S. Enthaler, S. Krackl, A. Company Casadevall ChemCatChem 2011, 3, 1186–1192, 10.1002/cctc.201100007

623 Molecular Heterobimetallic Approach to Li-Containing MgO Nanoparticles with Variable Li-Concentrations Using Lithium-Methylmagnesium Alkoxide Clusters S. Heitz, J. D. Epping, Y. Aksu, M. Driess Chemistry of Materials 2010, 22, 4563–4571, 10.1021/cm100415m

525 Monooxygenase-Like Reactivity of an Unprecedented Heterobimetallic {FeO2Ni} Moiety S. Yao, C. Herwig, Y. Xiong, A. Company, E. Bill, C. Limberg, M. Driess Angewandte Chemie International Edition 2010, 49, 7054–7058, 10.1002/anie.201001914

519 Intermolecular Hydrogen-Fluorine-Interaction in Dimolybdenum Triply Bonded Complexes Modified by Fluorinated Formamidine Ligands for the Construction of 2D- and 3D-Networks S. Enthaler, S. Kragl, S. Inoue, M. Drieß European Journal of Inorganic Chemistry 2011, 2011, 2103–2111, 10.1002/ejic.201001357

509 A Molecular Precursor Approach to Tunable Porous Tin-Rich Indium Tin Oxide with Durable High Electrical Conductivity for Bioelectronic Devices M. Driess, A. Thomas, Y. Aksu, S. Frasca, U. Wollenberger Chemistry of Materials 2011, 23, 1798–1804, 10.1021/cm103087p

508 Facile Access to Homo- and Heteroleptic, Triply Bonded Dimolybdenum Hexaalkoxides with Unsaturated Alkoxide Ligands M. Driess, S. Krackl, J. G. Ma, Y. Aksu European Journal of Inorganic Chemistry 2011, 11, 1725–1732, 10.1002/ejic.201001236

507 Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules M. Driess, S. Yao, Y. Xiong Organometallics 2011, 30, 1748–1767, 10.1021/om200017h

506 Unprecedented Alkylzinc--Magnesium Alkoxide Clusters as Suitable Organometallic Precursors for Magnesium-Containing ZnO Nanoparticles M. Driess, S. Heitz, Y. Aksu, C. Merschjann Chemistry - A European Journal 2011, 17, 3904–3910, 10.1002/chem.201002743

505 Entrapment of Heteropolyacids in Metallic Silver Matrices: Unique Heterogenized Acid Catalysts M.Driess, S. Krackl, A. Company Casadevall, Y. Aksu, D. Avnir ChemCatChem 2011, 3, 227–232, 10.1002/cctc.201000239

416 High Efficiency in Catalytic Hydrosilylation of Ketones with Zinc-Based Precatalysts Featuring Hard and Soft Tridentate O,S,O-Ligands N. Marinos, S. Enthaler, M. Drieß ChemCatChem 2010, 2, 846–853, 10.1002/cctc.201000036

410 Facile and Efficient Reduction of Ketones in the Presence of Zinc Catalysts Modified by Phenol Ligands S. Enthaler, B. Eckhardt, S. Inoue, E. Irran, M. Drieß Chemistry - An Asian Journal 2010, 5, 2027–2035, 10.1002/asia.201000317

409 Formamidines - Versatile Ligands for Zinc-Catalyzed Hydrosilylation and Iron-Catalyzed Epoxidation Reactions S. Enthaler, K. Schröder, S. Inoue, B. Eckhardt, K. Junge, M. Beller, M. Drieß European Journal of Organic Chemistry 2010, 25, 4893–4901, 10.1002/ejoc.201000648

407 Isomerization of an N-Heterocyclic Germylene to an Azagermabenzen-1-ylidene and Its Coupling to a Unique Bis(germylene) S. Yao, X. Zhang, Y. Xiong, H. Schwarz, M. Driess Organometallics 2010, 29, 5353–5357, 10.1021/om100383y

362 Addition of [(Eta5-C5Me5)IrH4] to a Zwitterionic Silylene: Stepwise Formation of Iridium(V)-Silyl and Iridium(III)-Silylene Complexes T. Braun, M. Driess, A. K. Jungton, A. Meltzer, C. Präsang, A. Penner Dalton Transactions 2010, 39, 5436–5438, 10.1039/c0dt00236d

306 Steering S-H and N-H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)-Ni(CO)3 Complex A. Meltzer, S. Inoue, C. Präsang, M. Driess Journal of the American Chemical Society 2010, 132, 3038–3046, 10.1021/ja910305p

305 Methylmagesium Alkoxide Clusters with Mg4O4 Cubane- and Mg7O8 Biscubane-Like Cores: Organometallic Precursors for Low-Temperature Formation of MgO Nanoparticles with Variable Surface Defects S. Heitz, Y. Aksu, C. Merschjann, M. Driess Chemistry of Materials 2010, 22, 1376–1385, 10.1021/cm9021535

294 Synthesis and Rearrangement of Stable NHC - Silylene Adducts and Their Unique Reactivity towards Cyclohexylisocyanide Y. Xiong, S. Yao, M. Driess Chemistry - An Asian Journal 2010, 5, 322–327, 10.1002/asia.200900434

293 Reversible P4 Activation with Nickel(I) and an Eta3-Coordinated Tetraphosphorus Ligand between Two NiI Centers S. Yao, Y. Xiong, C. Milsmann, E. Bill, S. Pfirrmann, C. Limberg, M. Driess Chemistry - A European Journal 2010, 16, 436–439, 10.1002/chem.200902820

292 Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein O. Sanganas, S. Löscher, S. Pfirrmann, N. Marinos, P. Glatzel, T. C. Weng, C. Limberg, M. Driess, H. Dau, M. Haumann Journal of Physics: Conference Series 2009, 190, 12199–12199, 10.1088/1742-6596/190/1/012199

291 Striking lessons from nickel-superoxides and related systems S. Yao, M. Driess, C. Milsmann, E. Bill, K. Wieghardt Journal of Biological Inorganic Chemistry 2009, 14, 33–44, 10.1007/s00775-009-0526-4

289 The Catalytic Activity of Zinc Oxides from Single Source Precursors with Additives for the C-H Acitivation of Lower Alkanes S. Arndt, Y. Aksu, M. Driess, R. Schomäcker Catalysis Letters 2009, 131, 258–265, 10.1007/s10562-009-0055-3

284 O-O Bond Activation in Heterobimetallic Peroxides: Synthesis of the Peroxide [LNi(My,Eta2:Eta2-O2)K] and its Conversion into a Bis(My-Hydroxo) Nickel Zinc Complex S. Yao, Y. Xiong, M. Vogt, H. Grützmacher, C. Herwig, C. Limberg, M. Driess Angewandte Chemie International Edition 2009, 48, 8107–8110, 10.1002/anie.200903772

282 Side-on Coordination of a P-P Bond in Heterobinuclear Tetraphosphorus Complexes with a [Si(My,Eta2.2-P4)Ni] Core and Nickel(I) Centers Y. Xiong, S. Yao, E. Bill, M. Driess Inorganic Chemistry 2009, 48, 7522–7524, 10.1021/ic901088c

279 Striking Reactivity of a Stable, Zwitterionic Silylene Towards Substituted Diazomethanes, Azides, and Isocyanides Y. Xiong, S. Yao, M. Driess Chemistry - A European Journal 2009, 15, 8542–8547, 10.1002/chem.200901337

278 Isolable Metallo-Germylene and Metallo-Stannylene Sigma-Complexes with Iron S. Inoue, M. Driess Organometallics 2009, 28, 5032–5035, 10.1021/om9005802

276 From an N-Heterocyclic Silacyclopropene to Donor-Supported Silacyclopropenylium Cations S. Yao, Y. Xiong, C. van Wüllen, M. Driess Organometallics 2009, 28, 1610–1612, 10.1021/om801178g

274 Lithium related deep and shallow acceptors in Li-doped ZnO nanocrystals C. Rauch, W. Gelhoff, M. Wagner, E. Malguth, G. Callsen, R. Kirste, B. Salameh, A. Hoffmann, S. Polarz, Y. Aksu, M. Driess Journal of Applied Physics 2010, 107, 24311–24311, 10.1063/1.3275889

273 A Systematic Study on Zinc Oxide Materials Containing Group I Metals (Li, Na, K)-Synthesis from Organometallic Precursors, Characterization, and Properties S. Polarz, A. Orlov, A. Hoffmann, M. Wagner, C. Rauch, R. Kirste, W. Gelhoff, Y. Aksu, M. Driess, M. W. E. van der Berg, M. Lehmann Chemistry of Materials 2009, 21, 3889–3897, 10.1021/cm9014223

272 Beta-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing For H2 and N2 Activation C. Limberg, S. Pfirrmann, S. Yao, B. Ziemer, R. Stößer, M. Driess Organometallics 2009, 28, 6855–6860, 10.1021/om9007983

268 Facile Dissociation of [(LNiII)2E2] Dichalcogenides: Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution M. Driess, S. Yao, Y. Xiong, X. Zhang, M. Schlangen, H. Schwarz, C. Milsmann Angewandte Chemie International Edition 2009, 48, 4551–4455, 10.1002/anie.200901132

245 Activation of C-H bonds mediated by Mo=Mo moieties in heterobimetallic Zn/O/Mo Clusters J. G. Ma, Y. Aksu, L. J. Gregoriades, J. Sauer, M. Driess Dalton Transactions 2010, 39, 103–106, 10.1039/b917585g

132 A Low-Temperature Molecular Approach to Highly Conductive Indium Tin Oxide Thin Films with Durable Electro-Optical Performance Y. Aksu, A. Prodi-Schwab, M. Driess Angewandte Chemie International Edition 2009, 48, 7778–7782, 10.1002/anie.200901204

117 Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0) A. Meltzer, C. Präsang, M. Driess Journal of the American Chemical Society 2009, 131, 7232–7233, 10.1021/ja9026727

116 A Zwitterionic Silylene as Reactive Intermediate and its Unusual Dimerization to an NHeterobicyclic Disilane Y. Xiong, S. Yao, M. Driess Chemistry - An Asian Journal 2009, 4, 1323–1328, 10.1002/asia.200900127

114 Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective C-H Activation Y. Xiong, S. Yao, M. Driess Chemistry - A European Journal 2009, 15, 5545–5551, 10.1002/chem.200900318

113 The Striking Stabilization of Ni0(η6-Arene) Complexes by an Ylide- Like Silylene Ligand A. Meltzer, C. Präsang, M. Driess Angewandte Chemie International Edition 2009, 48, 3170–3173, 10.1002/anie.200900290

112 Bridging the Materials Gap in Catalysis: Entrapment of Molecular Catalysts in Functional Supports and Beyond A. Thomas, M. Driess Angewandte Chemie International Edition 2009, 48, 1890–1892, 10.1002/anie.200805136

111 Twice silicon-induced C-H activation and tautomerisation of a b-diketiminato ligand and formation of new types of N-heterocyclic silanes Y. Xiong, S. Yao, M. Driess Dalton Transactions 2009, 3, 421–423, 10.1039/b820285k

110 Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C-H bond activation S. Yao, C. van Wüllen, M. Driess Chemical Communications 2008, 42, 5393–5395, 10.1039/b811952j

109 One-pot synthesis of lithium alkylzinc alkoxo heterocubanes with a LiZn3O4 core as suitable organometallic precursors for Li-containing ZnO nanocrystals S. Jana, Y. Aksu, M. Brym, M. Driess Dalton Transactions 2009, 9, 1516–1521, 10.1039/b816623d

108 From a Paramagnetic, Mononuclear Supersulfidonickel(II) Complex to a Diamagnetic Dimer with a Four-Sulfur Two-Electron Bond S. Yao, C. Milsmann, E. Bill, K. Wieghardt, M. Driess Journal of the American Chemical Society 2008, 130, 13536–13537, 10.1021/ja806101h

107 An Isolable "Side-on" Superoxonickel Complex [LNi(O2)] with a Square-Planar Tetracoordinate Nickel(II) Center and Its Conversion into [LNi(My-OH)2NiL] S. Yao, C. Milsmann, E. Bill, K. Wieghardt, M. Driess Angewandte Chemie International Edition 2008, 37, 7110–7113, 10.1002/anie.200802234

106 Dichotomic Reactivity of a Stable Silylene toward Terminal Alkynes: Facile C-H Bond Insertion versus Autocatalytic Formation of Silacycloprop-3-ene S. Yao, C. van Wüllen, X. Y. Sun, M. Driess Angewandte Chemie International Edition 2008, 47, 3250–3253, 10.1002/anie.200704939

105 Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxide clusters K. Merz, M. Moreno, E. Löffler, L. Khodeir, A. Rittermeier, K. Fink, K. Kotsis, M. Muhler, M. Driess Chemical Communications 2008, 1, 73–75, 10.1039/b714806b

104 Structure-Property-Function Relationships in Nanoscale Oxide Sensors: A Case Study Based on Zinc Oxide S. Polarz, A. Roy, M. Lehmann, M. Driess, F. E. Kruis Advanced Functional Materials 2007, 17, 1385–1391, 10.1002/adfm.200700139

97 Organometallics Meet Colloid Chemistry: A Case Study in Three Phases Based on Molecular Carbonyl Precursors Containing Zinc and Manganese S. Polarz, M. Driess, A. Roy, M. Lehmann, A. Orlov Journal of the American Chemical Society 2007, 129, 371–375, 10.1021/ja0659626

96 From Metal-Organic Precursors to Functional Ceramics and Related Nanoscaled Materials S. Mathur, M. Driess Comprehensive Organometallic Chemistry III Eds. Robert H. Crabtree, D. Michael P. Mingos Elsevier 2007, 35–70,