Publications 2012

Number of records: 213

213 Contributions of phase composition and defect structure to the long term stability of Li/MgO catalysts U. Simon, M. Harth, S. Arndt, A. Berthold, O. Görke, C. Hartmann, R. Schomäcker, H. Schubert International Journal of Materials Research 2012, 103, 1488–1498, 10.3139/146.110812

212 The Intimate Relationship between Bulk Electronic Conductivity and Selectivity in the Catalytic Oxidation of n-Butane M. Eichelbaum, M. Hävecker, C. Heine, A. Karpov, C. K. Dobner, F. Rosowski, A. Trunschke, R. Schlögl Angewandte Chemie International Edition 2012, 51, 6246–6250, 10.1002/anie.201201866

211 The microwave cavity perturbation technique for contact-free and in situ electrical conductivity measurements in catalysis and materials science M. Eichelbaum, R. Stößer, A. Karpov, C. K. Dobner, F. Rosowski, A. Trunschke, R. Schlögl Physical Chemistry Chemical Physics Phys. Chem. Chem. Phys. 2012, 14, 1302–1312, 10.1039/C1CP23462E

210 Resource-Efficient Alkane Selective Oxidation on New Crystalline Solids: Searching for Novel Catalyst Materials R. Glaum, C. Welker-Nieuwoudt, C. K. Dobner, M. Eichelbaum, F. Gruchow, C. Heine, A. Karpov, R. Kniep, F. Rosowski, R. Schlögl, S. A. Schunk, S. Titlbach, A. Trunschke Chemie Ingenieur Technik 2012, 84, 1766–1779, 10.1002/cite.201200078

209 Copper Complexes of “Superpodal” Amine Ligands and Reactivity Studies towards Dioxygen A. Jozwiuk, E. A. Ünal, S. Leopold, J. P. Boyd, M. Haryono, N. Kurowski, F. V. Escobar, P. Hildebrandt, J. Lach, F. W. Heinemann, D. Wiedemann, E. Irran, A. Grohmann European Journal of Inorganic Chemistry 2012, 2012, 3000–3013, 10.1002/ejic.201101265

208 Combined Electrochemistry and Surface-Enhanced Infrared Absorption Spectroscopy of Gramicidin A Incorporated into Tethered Bilayer Lipid Membranes J. Kozuch, C. Steinem, P. Hildebrandt, D. Millo Angewandte Chemie International Edition 2012, 51, 8114–8117, 10.1002/anie.201203214

207 Electric-Field Control of the pH-Dependent Redox Process of Cytochrome Immobilized on a Gold Electrode B. Jin, G. X. Wang, D. Millo, P. Hildebrandt, X. H. Xia The Journal of Physical Chemistry C 2012, 116, 13038–13044, 10.1021/jp303740e

206 Role of Met80 and Tyr67 in the Low-pH Conformational Equilibria of Cytochrome G. Battistuzzi, C. A. Bortolotti, M. Bellei, G. Di Rocco, J. Salewski, P. Hildebrandt, M. Sola Biochemistry 2012, 51, 5967–5978, 10.1021/bi3007302

205 Size-Dependent Morphology of Dealloyed Bimetallic Catalysts: Linking the Nano to the Macro Scale M. Oezaslan, M. Heggen, P. Strasser Journal of the American Chemical Society 2012, 134, 514–524, 10.1021/ja2088162

204 Two-step synthesis of Fe2O3 and Co3O4 nanoparticles: towards a general method for synthesizing nanocrystalline metal oxides with high surface area and thermal stability J. Zhu, X. Ouyang, M. Y. Lee, R. C. Davis, S. L. Scott, A. Fischer, A. Thomas RSC Advances 2012, 2, 121– 10.1039/c1ra00552a

203 Nitrogen-doped coatings on carbon nanotubes and their stabilizing effect on Pt nanoparticles X. Tuaev, J. P. Paraknowitsch, R. Illgen, A. Thomas, P. Strasser Physical Chemistry Chemical Physics 2012, 14, 6444– 10.1039/c2cp40760d

202 Influence of Periodic Nitrogen Functionality on the Selective Oxidation of Alcohols C. E. Chan-Thaw, A. Villa, G. M. Veith, K. Kailasam, L. A. Adamczyk, R. R. Unocic, L. Prati, A. Thomas Chemistry - An Asian Journal 2012, 7, 387–393, 10.1002/asia.201100565

201 One-Pot Synthesis of Metal-Doped Mesoporous Materials from (Dicyanamido)metallate Precursors J. P. Paraknowitsch, O. Sukhbat, Y. Zhang, A. Thomas European Journal of Inorganic Chemistry 2012, 2012, 4105–4116, 10.1002/ejic.201200680

200 Intrinsically Sulfur- and Nitrogen-Co-doped Carbons from Thiazolium Salts J. P. Paraknowitsch, B. Wienert, Y. Zhang, A. Thomas Chemistry - A European Journal 2012, 18, 15416–15423, 10.1002/chem.201202445

199 Dendritic HMPA as a Promoter for the Mukaiyama Aldol and Allylation Reaction F. Mummy, R. Haag Synlett 2012, 23, 2672–2676, 10.1055/s-0032-1317482

198 A Photochromic Histidine Kinase Rhodopsin (HKR1) That Is Bimodally Switched by Ultraviolet and Blue Light M. Luck, T. Mathes, S. Bruun, R. Fudim, R. Hagedorn, T. M. Tran Nguyen, S. Kateriya, J. T. M. Kennis, P. Hildebrandt, P. Hegemann Journal of Biological Chemistry 2012, 287, 40083–40090, 10.1074/jbc.M112.401604

197 Similarity recognition of molecular structures by optimal atomic matching and rotational superposition B. Helmich, M. Sierka Journal of Computational Chemistry 2012, 33, 134–140, 10.1002/jcc.21925

196 The Atomic Structure of a Metal-Supported Vitreous Thin Silica Film L. Lichtenstein, C. Büchner, B. Yang, S. Shaikhutdinov, M. Heyde, M. Sierka, R. Włodarczyk, J. Sauer, H. J. Freund Angewandte Chemie International Edition 2012, 51, 404–407, 10.1002/anie.201107097

195 Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films J. A. Boscoboinik, X. Yu, B. Yang, F. D. Fischer, R. Włodarczyk, M. Sierka, S. Shaikhutdinov, J. Sauer, H. J. Freund Angewandte Chemie International Edition 2012, 51, 6005–6008, 10.1002/anie.201201319

194 Thin silica films on Ru(0001): monolayer, bilayer and three-dimensional networks of [SiO4] tetrahedra B. Yang, W. E. Kaden, X. Yu, J. A. Boscoboinik, Y. Martynova, L. Lichtenstein, M. Heyde, M. Sterrer, R. Włodarczyk, M. Sierka, J. Sauer, S. Shaikhutdinov, H. J. Freund Physical Chemistry Chemical Physics 2012, 14, 11344–11351, 10.1039/C2CP41355H

193 Comparative investigations on thermostable pyrimidine nucleoside phosphorylases from Geobacillus thermoglucosidasius and Thermus thermophilus K. Szeker, X. Zhou, T. Schwab, A. Casanueva, D. Cowan, I. A. Mikhailopulo, P. Neubauer Journal of Molecular Catalysis B: Enzymatic 2012, 84, 27–34, 10.1016/j.molcatb.2012.02.006

192 Ab Initio Prediction of Adsorption Isotherms for Small Molecules in Metal–Organic Frameworks: The Effect of Lateral Interactions for Methane/CPO-27-Mg K. Sillar, J. Sauer Journal of the American Chemical Society 2012, 134, 18354–18365, 10.1021/ja307076t

191 Mesoporous Nitrogen-Doped Carbon for the Electrocatalytic Synthesis of Hydrogen Peroxide T. P. Fellinger, F. Hasché, P. Strasser, M. Antonietti Journal of the American Chemical Society 2012, 134, 4072–4075, 10.1021/ja300038p

190 Building photoswitchable 3,4\'-AMPB peptides: Probing chemical ligation methods with reducible azobenzene thioesters G. Zeyat, K. Rück-Braun Beilstein Journal of Organic Chemistry 2012, 8, 890–896, 10.3762/bjoc.8.101

189 Concurrent Reactor Engineering, Separation Enhancement and Process Intensification; Comprehensive Unicat Approach for Oxidative Coupling f Methane (OCM) H. R. Godini, S. Jaso, W. Martini, S. Stünkel, D. Salerno, S. Nghiem Xuan, S. Song, S. Sadjadi, H. Trivedi, H. Arellano-Garcia, G. Wozny Technical Transactions 2012, 5, 63–74,

188 Oxidative Coupling of Methane: a new process concept for the improvement of the downstream processing by using adsorption S. Nghiem Xuan, H. Arellano-Garcia, G. Wozny, T. K. Tran Technical Transaction 2012, 109, 233–242,

187 Poly(ionic liquid) Complex with Spontaneous Micro-/Mesoporosity: Template-Free Synthesis and Application as Catalyst Support Q. Zhao, P. Zhang, M. Antonietti, J. Yuan Journal of the Electrochemical Society 2012, 134, 11852–11855, 10.1021/ja303552p

186 Solvent-Free and Metal-Free Oxidation of Toluene Using O2 and g-C3N4 with Nanopores: Nanostructure Boosts the Catalytic Selectivity X. H. Li, X. Wang, M. Antonietti ACS Nano 2012, 2, 2082–2086, 10.1021/cs300413x

185 Bioinspired hollow semiconductor nanospheres as photosynthetic nanoparticles J. Sun, J. Zhang, M. Zhang, M. Antonietti, X. Fu, X. Wang Nature Communications 2012, 1139, 10.1038/ncomms2152

184 Optimal Operation of a Membrane Reactor Network E. Esche, H. Arellano-Garcia, L. T. Biegler, G. Wozny Computer Aided Chemical Engineering 2012, 31, 1321–1325, 10.1016/B978-0-444-59506-5.50095-X

183 Chiral Tripodal Ligand Containing Three N-Heterocyclic Donor Functions and its Copper Complexes: Crystallization of [LCu(I)]2 2+ /[L2Cu(II)]2+ Stereoisomers and Tyrosinase Activity A. Arnold, C. Limberg, R. Metzinger Inorganic Chemistry Zeitschrift für anorganische und allgemeine Chemie 2012, 51, 12210–12217, 10.1021/ic301391s

182 IR-Monitored Photolysis of CO-Inhibited Nitrogenase: A Major EPR-Silent Species with Coupled Terminal CO Ligands L. Yan, V. Pelmenschikov, C. H. Dapper, A. D. Scott, W. E. Newton, S. P. Cramer Chemistry - A European Journal 2012, 18, 16349–16357, 10.1002/chem.201202072

181 Protein Rebinding to a Surface-Confined Imprint D. Dechtrirat, K. J. Jetzschmann, W. F. M. Stöcklein, F. W. Scheller, N. Gajovic-Eichelmann Advanced Functional Materials 2012, 22, 5231–5237, 10.1002/adfm.201201328

180 Peroxide-Dependent Analyte Conversion by the Heme Prosthetic Group, the Heme Peptide “Microperoxidase-11” and Cytochrome c on Chitosan Capped Gold Nanoparticles Modified Electrodes F. Scheller, N. Gajovic-Eichelmann, M. Bosserdt, B. Neumann, A. Yarman biosensors 2012, 2, 189–204, 10.3390/bios2020189

179 The aromatic peroxygenase from Marasmius rutola - a new enzyme for biosensor applications F. Scheller, K. Schreibner, R. Ullrich, M. Hofrichter, U. Wollenberger, N. Gajovic-Eichelmann, M. Kinne, B. Neumann, G. Gröbe, A. Yarman Analytical and Bioanalytical Chemistry 2012, 402, 405–412, 10.1007/s00216-011-5497-y

178 Resonance Raman and vibronic absorption spectra with Duschinsky rotation from a time-dependent perspective: Application to β-carotene P. Saalfrank, D. Kröner, S. Banerjee The Journal of Chemical Physics 2012, 137, 22A534–9 pages, 10.1063/1.4748147

177 Au_N clusters (N=1--6) supported on MgO(100) surfaces: Effect of exact exchange and dispersion interactions on adhesion energies L. O. Paz-Borbon, G. Barcaro, A. Fortunelli, S. Levchenko Physical Review B 2012, 85, 155409–155420, 10.1103/PhysRevB.85.155409

176 Direct and mediated electrochemical response of the Cytochrome P450 106A2 from Bacillus megaterium ATCC 13368 H. Colas, K. M. Ewen, F. Hannemann, N. Bistolas, U. Wollenberger, R. Bernhard, P. de Oliveira Bioelectrochemistry 2012, 87, 71–77, 10.1016/j.bioelechem.2012.01.006

175 The First Mammalian Aldehyde Oxidase Crystal Structure: Insights Into Substrate specificity C. Coelho, M. Mahro, J. Trincao, A. Carvalho, M. Ramos, M. Terao, E. Garattini, S. Leimkühler, M. Romao Journal of Biological Chemistry 2012, 287, 40690–40702, 10.1074/jbc.M112.390419

174 The Impact of Single Nucleiotide Plymorphisms on Human Aldehyde Oxidase T. Hartmann, M. Terao, E. Garattini, C. Teutloff, J. Alfaro, J. Jones, S. Leimkühler Drug Metabolism and Disposition 2012, 40, 856–864, 10.1124/dmd.111.043828

173 Human sulfite oxidase electrochemistry on gold nanoparticles modified electrode S. Frasca, O. Rojas, J. Salewski, B. Neumann, K. Stiba, I. Weidinger, B. Tiersch, S. Leimkühler, J. Koetz, U. Wollenberger Bioelectrochemistry 2012, 87, 33–41, 10.1016/j.bioelechem.2011.11.012

172 Low-Potential Amperometric Enzyme Biosensor for Xanthine and Hypoxanthine P. Kalimuthu, S. Leimkühler, P. Bernhardt Analytical Chemistry 2012, 84, 10359–10365, 10.1021/ac3025027

171 Catalytic electrochemistry of xanthine dehydrogenase P. Kalimuthu, S. Leimkühler, P. Bernhardt THe Journal of Physical Chemistry B 2012, 116, 11600–11607, 10.1021/jp307374z

170 Development of an EOS based on lattice cluster theory for pure components K. Langenbach, S. Enders Fluid Phase Equilibria 2012, 331, 58–79, 10.1016/j.fluid.2012.06.022

169 Phase Behavior of Hyperbranched Polymer in Demixed Solvent T. Zeiner, M. J. Puyan, P. Schrader, C. Browarzik, S. Enders Molecular Physics 2012, 110, 1359–1373, 10.1080/00268976.2011.648964

168 Liquid-liquid phase equilibria of hyperbranched polymers - experimental study and modelling C. Browarzik, D. Browarzik, S. Enders Fluid Phase Equilibria 2012, 328, 49–60, 10.1016/j.fluid.2012.05.018

167 Phase Diagrams for Systems Containing Hyperbranched Polymers S. Enders, K. Langenbach, P. Schrader, T. Zeiner Polymers 2012, 4, 72–115, 10.3390/polym4010072

166 Crossover from two- to three-dimensional gold particle shapes on CaO films of different thicknesses X. Shao, N. Nilius, H. J. Freund Physical Review B 2012, 85, 115444–115444, 10.1103/PhysRevB.85.115444

165 Probing the properties of metal–oxide interfaces: silica films on Mo and Ru supports L. Lichtenstein, M. Heyde, S. Ulrich, N. Nilius, H. J. Freund Journal of Physics: Condensed Matter 2012, 24, 351010–351017, 10.1088/0953-8984/24/35/354010

164 Tuning the electronic structure of ultrathin crystalline silica films on Ru(0001) R. Wlodarczyk, M. Sierka, J. Sauer, D. Löffler, J. J. Ulrich, X. Yu, B. Yang, I. M. N. Groot, S. Shaikhutdinov, H. J. Freund Physical Review B 2012, 85, 85403–85403, 10.1103/PhysRevB.85.085403

163 Synthesis of Bi- and Tricyclic 1,2-Dihydroquinoline Derivatives from Arylamines and Alkynes by a Consecutive Zinc-Ammonium Salt Catalysis N. Purkait, S. Blechert Advanced Synthesis and Catalysis 2012, 354, 2079–2083, 10.1002/adsc.201200155

162 Stabilizing Gold Adatoms by Thiophenyl Derivatives: A Possible Route toward Metal Redispersion B. Yang, Y. Pan, X. Lin, N. Nilius, H. J. Freund, C. Hulot, A. Giraud, S. Blechert, S. Tosoni, J. Sauer Journal of the American Chemical Society 2012, 134, 11161–11167, 10.1021/ja300304s

161 A Microporous Binol-Derived Phosphoric Acid D. S. Kundu, J. Schmidt, C. Bleschke, A. Thomas, S. Blechert Angewandte Chemie International Edition 2012, 51, 5456–5459, 10.1002/anie.201109072

160 Comparison of Decamethyldizincocene [(η5-Cp*)2Zn2] versus Decamethylzincocene [Cp*2Zn] and Diethylzinc Et2Zn As Precatalysts for the Intermolecular Hydroamination Reaction A. Luehl, L. Hartenstein, S. Blechert, P. W. Roesky Organometallics 2012, 20, 7109–7116, 10.1021/om300649q

159 Effect of lattice-gas atoms on the adsorption behaviour of thioether molecules Y. Pan, B. Yang, C. Hulot, B. Siegfried, N. Nilius, H. J. Freund Physical Chemistry Chemical Physics 2012, 31, 10987–10993, 10.1039/C2CP41081H

158 Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis X. Wang, S. Blechert, M. Antonietti ACS Catalysis 2012, 2, 1596–1606, 10.1021/cs300240x

157 New catalysts with unsymmetrical N-heterocyclic carbene ligands J. Tornatzky, A. Kannenberg, S. Blechert Dalton Transactions 2012, 41, 8215–8225, 10.1039/C2DT30256J

156 Metal-free activation of H2O2 by g-C3N4 under visible light irradiation for the degradation of organic pollutants Y. Cui, Z. Ding, P. Liu, M. Antonietti, X. Fu, X. Wang Physical Chemistry Chemical Physics 2012, 14, 1455–1462, 10.1039/c1cp22820j

155 Photocatalytic oxidation of water by polymeric carbon nitride nanohybrids made of sustainable elements J. Zhang, M. Grzelczak, Y. Hou, K. Maeda, K. Domen, X. Fu, M. Antonietti, X. Wang Chemical Science 2012, 3, 443–446, 10.1039/c1sc00644d

154 Polymeric Graphitic Carbon Nitride as a Heterogeneous Organocatalyst: From Photochemistry to Multipurpose Catalysis to Sustainable Chemistry Y. Wang, X. Wang, M. Antonietti Angewandte Chemie International Edition 2012, 51, 68–89, 10.1002/anie.201101182

153 Co-Monomer Control of Carbon Nitride Semiconductors to Optimize Hydrogen Evolution with Visible Light J. Zhang, G. Zhang, X. Chen, S. Lin, L. Moehlmann, G. Dolega, G. Lipner, M. Antonietti, S. Blechert, X. Wang Angewandte Chemie International Edition 2012, 51, 3183–3187, 10.1002/anie.201106656

152 mpg-C3N4 as a solid base catalyst for Knoevenagel condensations and transesterification reactions F. Su, M. Antonietti, X. Wang Catal. Sci. Technol. 2012, 2, 1005–1009, 10.1039/c2cy00012a

151 A one-pot hydrothermal synthesis of sulfur and nitrogen doped carbon aerogels with enhanced electrocatalytic activity in the oxygen reduction reaction S. A. Wohlgemuth, R. J. White, M. G. Willinger, M. M. Titirici, M. Antonietti Green Chemistry 2012, 14, 1515–1523, 10.1039/c2gc35309a

150 Mesoporous g-C3N4 nanorods as multifunctional supports of ultrafine metal nanoparticles: hydrogen generation from water and reduction of nitrophenol with tandem catalysis in one step X. H. Li, X. Wang, M. Antonietti Chemical Science 2012, 3, 2170–2174, 10.1039/c2sc20289a

149 Metal-free oxidation of sulfides by carbon nitride with visible light illumination at room temperature P. Zhang, Y. Wang, H. Li, M. Antonietti Green Chemistry 2012, 14, 1904–1908, 10.1039/c2gc35148j

148 Synthesis of Monolayer-Patched Graphene from Glucose X. H. Li, S. Kurasch, U. Kaiser, M. Antonietti Angewandte Chemie International Edition 2012, 51, 9689–9692, 10.1002/anie.201203207

147 Template-Free One-Pot Synthesis of Porous Binary and Ternary Metal Nitride@N-Doped Carbon Composites from Ionic Liquids N. Fechler, T. P. Fellinger, M. Antonietti Chemistry of Materials 2012, 24, 713–719, 10.1021/cm203667g

146 Mesoporous Nitrogen Doped Carbon Supported Platinum PEM Fuel Cell Electrocatalyst Made From Ionic Liquids F. Hasche, T. P. Fellinger, M. Oezaslan, J. P. Paraknowitsch, M. Antonietti, P. Strasser ChemCatChem 2012, 4, 479–483, 10.1002/cctc.201100408

145 Conjugated porous polymers for energy applications F. Vilela, K. Zhang, M. Antonietti 2012, 5, 7819–7821, 10.1039/c2ee22002d

144 Carbon Nitride-Catalyzed Photoredox C-C Bond Formation with N-Aryltetrahydroisoquinolines L. Moehlmann, M. Baar, J. Riess, M. Antonietti, X. Wang, S. Blechert Advanced Synthesis and Catalysis 2012, 354, 1909–1913, 10.1002/adsc.201100894

143 First experimental proof for aberration correction in XPEEM: Resolution, transmission enhancement, and limitation by space charge effects T. Schmidt, A. Sala, H. Marchetto, E. Umbach, H. J. Freund Ultramicroscopy 2012, 126, 23–32, 10.1016/j.ultramic.2012.11.004

142 Nanoparticles for Heterogeneous Catalysis: New Mechanistic Insights S. Schauermann, N. Nilius, S. Shaikhutdinov, H. J. Freund Accounts of Chemical Research 2012, 46, 1673–1681, 10.1021/ar300225s

141 From embedded nanoislands to thin films: Topographic and optical properties of europium oxide on MgO(001) films F. Stavale, L. Pascua, N. Nilius, H. J. Freund Physical Review B 2012, 86, 85448–85448, 10.1103/PhysRevB.86.085448

140 Growth of Two-Dimensional Lithium Islands on CaO(001) Thin Films X. Shao, Y. Cui, W. D. Schneider, N. Nillius, H. J. Freund Journal of Physical Chemistry C 2012, 116, 17980–17984, 10.1021/jp306328c

139 Probing the luminescence of single Eu2O3 nano-islands on MgO(001) with scanning tunneling microscopy F. Stavale, N. Nilius, H. J. Freund Applied Physics Letters 2012, 101, 13109–13109, 10.1063/1.4731638

138 Donor Characteristics of Transition-Metal-Doped Oxides: Cr-Doped MgO versus Mo-Doped CaO F. Stavale, X. Shao, N. Nilius, H. J. Freund, S. Prada, L. Giordano, G. Paccioni Journal of the American Chemical Society 2012, 134, 11380–11383, 10.1021/ja304497n

137 Model oxide-supported metal catalysts - comparison of ultrahigh vacuum and solution based preparation of Pd nanoparticles on a single-crystalline oxide substrate H. F. Wang, W. E. Kaden, R. Dowler, M. Sterrer, H. J. Freund Physical Chemistry Chemical Physics 2012, 14, 11525–11533, 10.1039/c2cp41459g

136 Li/Mo Codoping of CaO Films: A Means to Tailor the Equilibrium Shape of Au Deposits X. Shao, N. Nilius, H. J. Freund Journal of the American Society 2012, 134, 2532–2534, 10.1021/ja211396t

135 Main group chemistry: Breaking the limits with silylenes M. Driess Nature Chemistry 2012, 4, 525–526, 10.1038/nchem.1387

134 Heterotermetallic Indium Lithium Halostannates: Low-Temperature Single- Source Precursors for Tin-Rich Indium Tin Oxides and Their Application for Thin-Film Transistors M. Driess, K. Samedov, Y. Aksu Chemistry - A European Journal 2012, 18, 7766–7779, 10.1002/chem.201103594

133 Facile Metalation of Silicon and Germanium Analogues of Thiocarboxylic Acids with a Manganese(II) Hydride Precursor M. Driess, S. Yao, Y. Xiong Chemistry - A European Journal 2012, 18, 11356–11361, 10.1002/chem.201201335

132 Facile Access to Silicon-Functionalized Bis-Silylene Titanium(II) Complexes M. Driess, S. Inoue, B. Blom, D. Gallego Chemistry - A European Journal 2012, 18, 13355–13360, 10.1002/chem.201202399

131 Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis-(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands M. Driess, A. Brück, D. Gallego, W. Wang, E. Irran, J. F. Hartwig Angewandte Chemie International Edition 2012, 51, 11478–11482, 10.1002/anie.201205570

130 O-O Bond Formation Mediated by a Hexanuclear Iron Complex Supported on a Stannoxane Core S. Kundu, E. Matito, S. Walleck, F. F. Pfaff, F. Heims, B. Rabay, J. M. Luis, A. Company, B. Braun, T. Glaser, K. Ray Chemistry - A European Journal 2012, 10, 2787–2791, 10.1002/chem.201102326

129 Spectroscopic capture and reactivity of S = 1/2 nickel(III)–oxygen intermediates in the reaction of a NiII-salt with mCPBA F. F. Pfaff, F. Heims, S. Kundu, S. Mebs, K. Ray Chemical Communications 2012, 48, 3730–3732, 10.1039/C2CC30716B

128 The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes J. Hohenberger, K. Ray, K. Meyer Nature Communications 2012, 3, 720–733, 10.1038/ncomms1718

127 Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System F. Heims, V. Mereacre, A. Ciancetta, S. Mebs, A. K. Powell, C. Greco, K. Ray European Journal of Inorganic Chemistry 2012, 29, 4565–4569, 10.1002/ejic.201200156

126 Metal-oxo-mediated O-O bond formation reactions in chemistry and biology S. Kundu, M. Schwalbe, K. Ray Bioinorganic Reaction Mechanisms 2012, 8, 41–57, 10.1515/irm-2012-0004

125 Lewis-acid Trapping of an Elusive Copper-Tosylnitrene Intermediate Using Scandium Triflate S. Kundu, E. Miceli, E. Farquhar, F. F. Pfaff, U. Kuhlmann, P. Hildebrandt, B. Braun, C. Greco, K. Ray Journal of the American Chemical Society 2012, 134, 14710–14713, 10.1021/ja306674h

124 Cyanobacteria as source for natural products M. Welker, E. Dittmann, H. von Döhren Methods Enzymol 2012, 517, 23–46, 10.1016/B978-0-12-404634-4.00002-4

123 Surface science approach to catalyst preparation - Pd deposition onto thin Fe3O4(111) films from Pdcl2 precusor H. F. Wang, H. Ariga, R. Dowler, M. Sterrer, H. J. Freund Journal of Catalysis 2012, 286, 1–5, 10.1016/j.jcat.2011.09.026

122 Ultrathin Oxide Films on Metal Supports: Structure-Reactivity Relations S. Shaikhutdinov, H. J. Freund Annual Review of Physical Chemistry 2012, 63, 619–633, 10.1146/annurev-physchem-032511-143737

121 Formation of One-Dimensional Electronic States along the Step Edges of CeO2(111) N. Nilius, S. M. Kozlov, J. F. Jerratsch, M. Baron, X. Shao, F. Vines, S. Shaikhutdinov, K. M. Neyman, H. J. Freund ACS Nano 2012, 6, 1126–1133, 10.1021/nn2036472

120 Cathodoluminescence of near-surface centres in Cr-doped MgO(001) thin films probed by scanning tunnelling microscopy F. Stavale, N. Nilius, H. J. Freund New Journal of Physics 2012, 14, 33006–33006, 10.1088/1367-2630/14/3/033006

119 The contribution of lattice strain to core-level binding energy shifts in metal nanoparticles: Generality and origin of the shifts P. S. Bagus, A. Wieckowski, H. J. Freund Computational and Theoretical Chemistry 2012, 987, 22–24, 10.1016/j.comptc.2011.06.028

118 Scanning tunneling microscopy evidence for the Mars-van Krevelen type mechanism of low temperature CO oxidation on an FeO(1 1 1) film on Pt(1 1 1) M. Lewandowski, I. M. N. Groot, S. Shaikhutdinov, H. J. Freund Catalysis Today 2012, 181, 52–55, 10.1016/j.cattod.2011.08.033

117 CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate B. Horn, C. Limberg, C. Herwig, M. Feist, S. Mebs Chemical Communications 2012, 48, 8243–8245, 10.1039/c2cc33846g

116 Sulfur-linked Phenolates as Ligands for the Syntheses of Low-Nuclearity Iron(III) Complexes R. Metzinger, C. Limberg Zeitschrift für Anorganische und Allgemeine Chemie 2012, 638, 2225–2234, 10.1002/zaac.201200389

115 Copper(I) Siloxides – Aggregated solid state structures, Cu-Cu interactions and dynamic solution behavior F. Schax, C. Limberg, C. Mügge European Journal of Inorganic Chemistry 2012, 2012, 4661–4668, 10.1002/ejic.201200294

114 A Trispyrazolylborato-Iron-Cysteinato-Complex as a functional Model for the Cysteine-Dioxygenase M. Sallmann, I. Siewert, L. Fohlmeister, C. Limberg, C. Knispel Angewandte Chemie International Edition 2012, 51, 2234–2237, 10.1002/anie.201107345

113 Temperature-controlled activity of lipase B from Candida antarctica after immobilization within p-NIPAM microgel particles K. Gawlitza, C. Wu, R. Georgieva, D. Wang, M. Ansorge-Schumacher, R. von Klitzing Physical Chemistry Chemical Physics 2012, 226, 749–759, 10.1524/zpch.2012.0271

112 Efficient chemo-enzymatic epoxidation using silcoat-Novozym®435: Characterising the multiphase system S. Bhattacharya, A. Drews, E. Lyagin, M. Kraume, M. Ansorge-Schumacher Chemical Engineering and Technology 2012, 1448–1455, 10.1002/ceat.201100640

111 Stabilisation of the NAD+-reducing soluble [NiFe]-hydrogenase from Ralstonia eutropha H16 through modification with methoxy-poly(ethylene) glycol J. Ratzka, L. Lauterbach, O. Lenz, M. Ansorge-Schumacher Journal of Molecular Catalysis B: Enzymatic 2012, 74, 219–223, 10.1016/j.molcatb.2011.10.008

110 Radical detection in harsh environments by means of laserinduced fluorescence using a single bidirectional optical fiber H. Schwarz, R. Schlögl, R. Horn Applied Physics B 2012, 109, 19–26, 10.1007/s00340-012-5172-9

109 Suppression of electron transfer to dioxygen by charge transfer and electron transfer complexes in the FAD-dependent reductase component of toluene dioxygenase T. Y. Lin, T. Werther, J. H. Jeoung, H. Dobbek Journal of Biological Chemistry 2012, 287, 38338–38346, 10.1074/jbc.M112.374918

108 Complex formation with the activator RACo affects the corrinoid structure of CoFeSP W. Meister, S. E. Hennig, J. H. Jeoung, F. Lendzian, H. Dobbek, P. Hildebrandt Biochemistry 2012, 51, 7040–7042, 10.1021/bi300795n

107 Redox-dependent complex formation by an ATP-dependent activator of the corrinoid/iron-sulfur Protein. S. E. Hennig, J. H. Jeoung, S. Götzl, H. Dobbek Proceedings of the National Academy of Sciences of the United States of America 2012, 109, 5235–5240, 10.1073/pnas.1117126109

106 The Fe(II)/α-ketoglutarate-dependent taurine dioxygenases from Pseudomonas putida and Escherichia coli are tetramers. S. H. Knauer, O. Hartl-Spiegelhauer, S. Schwarzinger, P. Hänzelmann, H. Dobbek FEBS Journal 2012, 279, 816–831, 10.1111/j.1742-4658.2012.08473.x

105 n-Butyl isocyanide oxidation at the [NiFe4S4OHx] cluster of CO dehydrogenase J. H. Jeoung, H. Dobbek Journal of Biological Inorganic Chemistry 2012, 17, 167–173, 10.1007/s00775-011-0839-y

104 Activation of Oxygen on MgO: O2.- Radical Ion Formation on Thin, Metal-Supported MgO(001) Films A. Gonchar, T. Risse, H. J. Freund, L. Giordano, C. diValentin, G. Pacchioni Angewandte Chemie International Edition 2012, 50, 2635–2638, 10.1002/anie.201005729

103 Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi Pincerlike Arene to Palladium M. Driess, S. Inoue, W. Wang, E. Irran Angewandte Chemie International Edition 2012, 51, 3691–3694, 10.1002/anie.201200632

102 Facile Molecular Approach to Transparent Thin-Film Field-Effect Transistors with High-Performance Using New Homo- and Heteroleptic Indium(III)–Tin(II) Single-Source Precursors M. Driess, K. Samedov, Y. Aksu Chemistry of Materials 2012, 24, 2078–2090, 10.1021/cm300510y

101 Electrosynthesis, functional, and structural characterization of a water-oxidizing manganese oxide I. Zaharieva, P. Chernev, M. Risch, K. Klingan, M. Kohlhoff, A. Fischer, H. Dau Energy & Environmental Science 2012, 5, 7081–7089, 10.1039/c2ee21191b

100 Layered manganese oxides for water-oxidation: alkaline earth cations influence catalytic activity in a photosystem II-like fashion M. Wiechen, I. Zaharieva, H. Dau, P. Kurz Chemical Science 2012, 3, 2330–2339, 10.1039/c2sc20226c

99 Atomic structure of cobalt-oxide nanoparticles active in light-driven catalysis of water oxidation M. Risch, D. Shevchenko, M. Anderlund, S. Styring, J. Heidkamp, K. Lange, A. Thapper, I. Zaharieva Int. J. Hydrogen Energy 2012, 37, 8878–8888, 10.1016/j.ijhydene.2012.01.138

98 Water oxidation by electrodeposited cobalt oxides - role of anions and redox-inert cations in structure and function of the amorphous catalyst M. Risch, K. Klingan, F. Ringleb, P. Chernev, I. Zaharieva, A. Fischer, H. Dau ChemSusChem 2012, 5, 542–549, 10.1002/cssc.201100574

97 High-valent [MnFe] and [FeFe] cofactors in ribonucleotide reductases N. Leidel, A. Popović-Bijelić, K. Havelius, P. Chernev, N. Voevodskaya, A. Gräslund, M. Haumann Biochimica et Biophysica Acta 2012, 1817, 430–444, 10.1016/j.bbabio.2011.12.008

96 Electronic structure of an [FeFe] hydrogenase model complex in solution revealed by X-ray absorption spectroscopy using narrow-band emission detection N. Leidel, P. Chernev, K. Havelius, L. Schwartz, S. Ott, M. Haumann Journal of the American Chemical Society 2012, 134, 14142–14157, 10.1021/ja304970p

95 Site-selective X-ray spectroscopy on an asymmetric model complex of the [FeFe] hydrogenase active site N. Leidel, P. Chernev, K. Havelius, S. Ezzaher, S. Ott, M. Haumann Inorganic Chemistry 2012, 51, 4546–4559, 10.1021/ic2024154

94 Alternating electron and proton transfer steps in photosynthetic water oxidation A. Klauss, M. Haumann, H. Dau Proc Natl Acad Sci U S A 2012, 109, 16035–16040, 10.1073/pnas.1206266109

93 Structural models of the manganese complex of photosystem II and mechanistic implications A. Grundmeier, H. Dau Biochimica et Biophysica Acta 2012, 1817, 88–105, 10.1016/j.bbabio.2011.07.004

92 Recent developments in research on water oxidation by photosystem II H. Dau, I. Zaharieva, M. Haumann Current Opinion in Chemical Biology 2012, 16, 3–10, 10.1016/j.cbpa.2012.02.011

91 A Janus cobalt-based catalytic material for electro-splitting of water S. Cobo, J. Heidkamp, P. A. Jacques, J. Fize, V. Fourmond, L. Guetaz, B. Jousselme, V. Ivanova, H. Dau, S. Palacin, M. Fontecave, V. Artero Nature Materials 2012, 11, 802–807, 10.1038/NMAT3385

90 Fast high-pressure freezing of protein crystals in their mother liquor A. Burkhardt, M. Warmer, C. Glöckner, A. Zouni, A. Meents Acta Cryst Sec F 2012, 495–500, 10.1107/S1744309112009670

89 Room temperature fentosecond X-ray diffraction of photosystem II microcrystals J. Kern, J. Hellmich, C. Glöckner, D. DiFiore, A. Zouni, V. Yachandra Proceedings of the National Academy of Sciences of the United States of America 2012, 109, 9721–9726, 10.1073/pnas.1204598109

88 Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode R. Alonso-Mori, J. Hellmich, C. Glöckner, A. Zouni, V. Yachandra Proceedings of the National Academy of Sciences of the United States of America 2012, 109, 19103–19107, 10.1073/pnas.1211384109

87 Nanoflow electrospinning serial femtosecond crystallography R. G. Sierra, H. Laksmono, J. Kern, J. Hellmich, C. Glöckner, A. Zouni, M. Bogan, R. Tran, J. Hattne, R. Alonso-Mori, B. Lassalle-Kaiser, D. W. Schafer, N. Echols, R. J. Gildea, R. W. Grosse-Kunstleve, J. Sellberg, T. A. McQueen, A. R. Fry, M. Messerschmi Acta Crystallographica Section D 2012, 1584–1587, 10.1107/S0907444912038152

86 Feglymycin, a unique natural bacterial antibiotic peptide, inhibits HIV entry by targeting the viral envelope protein gp120 G. Ferir, A. Hänchen, K. O. Francois, B. Hoorelbeke, D. Huskens, F. Dettner, R. D. Süssmuth, D. Schols Virology 2012, 433, 308–319, 10.1016/j.virol.2012.08.007

85 Curvopeptin: a new lanthionine-containing class III lantibiotic and its co-substrate promiscuous synthetase B. Krawczyk, G. H. Völler, J. Völler, P. Ensle, R. D. Süssmuth ChemBioChem 2012, 13, 2065–2071, 10.1002/cbic.201200417

84 Deuterium labeled peptides give insights into the directionality of class III lantibiotic synthetase LabKC B. Krawczyk, P. Ensle, W. Müller, R. D. Süssmuth Journal of the American Chemical Society 2012, 134, 9922–9925, 10.1021/ja3040224

83 Silvalactam, a 24-membered macrolactam antibiotic produced by Streptomyces sp. Tü 6392* D. Schulz, J. Nachtigall, U. Geisen, H. Kalthoff, J. F. Imhoff, H. P. Fiedler, R. D. Süssmuth The Journal of Antibiotics 2012, 65, 369–372, 10.1038/ja.2012.33

82 Complementary surface-enhanced resonance raman spectroscopic biodetection of mixed protein solutions by chitosan- and silica-coated plasmon-tuned silver nanoparticles A. Sivanesan, G. Kalaivani, A. Fischer, K. Stiba, S. Leimkühler, I. M. Weidinger Analytical Chemistry 2012, 84, 5759–5764, 10.1021/ac301001a

81 In vitro chemoenzymatic and in vivo biocatalytic syntheses of new beauvericin analogues D. Matthes, L. Richter, J. Müller, A. Denisiuk, S. C. Feifel, Y. Xu, P. Espinosa-Artiles, R. D. Süssmuth, I. Molnar Chemical Communications 2012, 48, 5674–5676, 10.1039/C2CC31669B

80 Multikriterielle Aspekte der Modularisierung bei der Planung verfahrenstechnischer Anlagen L. Hady, G. Wozny Chemie Ingenieur Technik 2012, 84, 597–614, 10.1002/cite.201100175

79 Nickel Complexes Modified by O,N,O'-Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for C-C Bond Formations C. I. Someya, E. Irran, S. Enthaler Asian Journal of Organic Chemistry 2012, 1, 322–326, 10.1002/ajoc.201200089

78 Investigation on membrane-assisted CO2 removal process for oxidative coupling of methane in mini-plant scale S. Song, S. Stünkel, H. R. Godini, X. N. Son, G. Wozny, J. Yuan Czasopismo Techniczne Mechanika 2012, 109, 223–232,

77 New triblock copolymer templates, PEO-PB-PEO, for the synthesis of Titania films with controlled mesopore size, wall thickness, and bimodal porosity E. Ortel, A. Fischer, L. Chuenchom, J. Polte, F. Emerling, B. Smarsly, R. Kraehnert Small 2012, 8, 298–309, 10.1002/smll.201101520

76 Electrocatalysis using porous nanostructured materials N. Menzel, E. Ortel, R. Kraehnert, P. Strasser ChemPhysChem 2012, 13, 1385–1394, 10.1002/cphc.201100984

75 Micelle-templated Mesoporous Films of Magnesium Carbonate and Magnesium Oxide B. Eckhardt, E. Ortel, J. Polte, D. Bernsmeier, O. Goerke, P. Strasser, R. Kraehnert Advanced Materials 2012, 24, 3115–3119, 10.1002/adma.201104984

74 Recent progress in soft-templating of porous carbon materials L. Chuenchom, R. Kraehnert, B. Smarsly Soft Matter 2012, 8, 10801–10812, 10.1039/C2SM07448F

73 Supported Mesoporous and Hierarchical Porous Pd/TiO 2 Catalytic Coatings with Controlled Particle Size and Pore Structure E. Ortel, S. Sokolov, C. Zielke, Iver Lauermann, Soeren Selve, K. Weh, B. Paul, J. Polte, R. Kraehnert Chemistry of Materials 2012, 24, 3828–3838, 10.1021/cm301081w

72 Experimental investigation of fluidized-bed reactor performance for oxidative coupling of methane S. Jaso, S. Sadjadi, H. R. Godini, U. Simon, S. Arndt, O. Görke, A. Berthold, H. Arellano-Garcia, H. Schubert, R. Schomäcker, G. Wozny Journal of Natural Gas Chemistry 2012, 21, 534–543, 10.1016/S1003-9953(11)60402-7

71 Two-Dimensional Model for Oxidative Coupling of Methane in a Packed-Bed Membrane Reactor N. Holst, S. Jaso, H. R. Godini, S. Glöser, H. Arellano-Garcia, G. Wozny, J. Steinbach Chemical Engineering and Technology 2012, 35, 294–301, 10.1002/ceat.201100473

70 Methane Oxidative Coupling: Synthesis of Membrane Reactor Networks H. R. Godini, S. Jaso, H. Arellano-Garcia, M. Omidkhah, G. Wozny Industrial and Engineering Chemistry Research 2012, 51, 7747–7761, 10.1021/ie202877r

69 Energy, Equipment, and Cost Savings by Application of Membranes in Amine-Based Absorption-Desorption Processes for CO2 Removal S. Stünkel, E. Esche, S. Song, T. Brinkmann, J. Wind, S. Shishatskiy, G. Wozny Proceedings of 14th Aachener Membran Kolloquium 2012, 10 pages,

68 Oxidative Coupling of Methane: Process Design, Development and Operation in a Mini-Plant Scale S. Stünkel, H. Trivedi, H. R. Godini, S. Jaso, N. Holst, S. Arndt, J. Steinbach, R. Schomäcker Chemie Ingenieur Technik 2012, 84, 1989–1996, 10.1002/cite.201200052

67 Process Development in a Miniplant scale - A multilevel - multiscale PSE Approach for developing an improved Oxidative Coupling of Methane Process S. Stünkel, K. Bittig, H. R. Godini, S. Jaso, W. Martini, G. Wozny Computer Aided Chemical Engineering 2012, 31, 1692–1696, 10.1016/B978-0-444-59506-5.50169-3Digital Object Identifier

66 Two-Dimensional Modeling of a Packed-Bed Membrane Reactor for the Oxidative Coupling of Methane E. Esche, H. Arellano-Garcia, L. Biegler, G. Wozny Chemical Engineering Transactions 2012, 29, 1537–1542, 10.3303/CET1229257

65 Oxidative Coupling of Methane: Optimal Operating Policies for a Membrane Reactor Network E. Lenhart, E. Esche, H. Arellano-Garcia, L. Biegler Chemie Ingenieur Technik 2012, 84, 1980–1988, 10.1002/cite.201200073

64 Giant Spin-Orbit Effects on NMR Shifts in Diamagnetic Actinide Complexes: Guiding the Search of Uranium (VI) Hydride Complexex in the Correct Spectral Range P. Hrobárik, V. Hrobárikova, A. H. Greif, M. Kaupp Angewandte Communications 2012, 3, 10884–10888, 10.1002/anie.201204634

63 Predicting the Localized/Delocalized Character of Mixed-Valence Diquinone Radical Anions. Toward the Right Answer for the Right Reason M. Renz, M. Kaupp The Journal of Physical Chemistry A 2012, 2, 10629–10637, 10.1021/jp308294r

62 Parallel reactor system for screening and characterisation of biocatalysts E. Lyagin, A. Drews, M. Kraume Czasopismo Techniczne Mechanika 2012, 5, 149–154,

61 Revealing the Absolute Configuration of the CO and CN- Ligands at the Active Site of a [NiFe] Hydrogenase Y. Rippers, M. Horch, P. Hildebrandt, I. Zebger, M. A. Mroginski ChemPhysChem 2012, 13, 3852–3856, 10.1002/cphc.201200562

60 A Universal Scaffold for Synthesis of the Fe(CN)(2)(CO) Moiety of [NiFe] Hydrogenase I. Buerstel, E. Siebert, G. Winter, P. Hummel, I. Zebger, B. Friedrich, O. Lenz Journal of Biological Chemistry 2012, 287, 38845–38853, 10.1074/jbc.M112.376947

59 Vibrational Stark Effect of the Electric-Field Reporter 4-Mercaptobenzonitrile as a Tool for Investigating Electrostatics at Electrode/SAM/Solution Interfaces G. Schkolnik, J. Salewski, D. Millo, I. Zebger, S. Franzen, P. Hildebrandt International Journal of Molecular Science 2012, 13, 7466–7482, 10.3390/ijms13067466

58 Analyzing the catalytic processes of immobilized redox enzymes by vibrational spectroscopies M. Sezer, D. Millo, I. M. Weidinger, I. Zebger, P. Hildebrandt IUBMB LIFE 2012, 64, 455–464, 10.1002/iub.1020

57 Characterization and Quantification of Reduced Sites on Supported Vanadium Oxide Catalysts using High-Frequencey Electron Paramagnetic Resonance A. Dinse, C. Carrero, A. Ozarowski, R. Schomäcker, R. Schlögl, K. P. Dinse ChemCatChem 2012, 4, 641–652, 10.1002/cctc.201100412

56 Reductive Cleavage of Amides to Alcohols and Amines Catalyzed by Well-defined Bimetallic Molybdenum Complexes S. Krackl, C. I. Someya, S. Enthaler Chemistry - A European Journal 2012, 18, 15267–15271, 10.1002/chem.201202857

55 Zinc-catalyzed Deoxygenation of Sulfoxides to Sulfides applying [B(Pin)]2 as Deoxygenation Reagents S. Enthaler Catalysis Letters 2012, 142, 1306–1311, 10.1007/s10562-012-0897-y

54 Bis(silylenyl)- and Bis(germylenyl)-Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)–Cobalt Complexes W. Wang, S. Inoue, S. Enthaler, M. Driess Angewandte Chemie International Edition 2012, 51, 6167–6171, 10.1002/anie.201202175

53 Deoxygenation of Sulfoxides to Sulfides in the Presence of Zinc Catalysts and Boranes as Reducing Reagents S. Enthaler, S. Krackl, E. Irran, S. Inoue Catalysis Letters 2012, 142, 1003–1010, 10.1007/s10562-012-0862-9

52 Application of a Nickel-bispidine complex as Pre-catalysts for C(sp2)-C(sp3) Bond Formations S. Enthaler, M. Haberberger, C. I. Someya, A. Company, E. Irran Catalysis Letters 2012, 142, 557–565, 10.1007/s10562-012-0806-4

51 Effects of Ligands, Cluster Size, and Charge State in Gas-Phase Catalysis: A Happy Marriage of Experimental and Computational Studies H. Schwarz, M. Schlangen Catalysis Letters 2012, 142, 1265–1278, 10.1007/s10562-012-0892-3

50 Mechanistic Studies on the Gas-Phase Dehydrogenation of Alkanes at Cyclometalated Platinum Complexes H. Schwarz, B. Butschke Chemistry - A European Journal 2012, 18, 14055–14062, 10.1002/chem.201201652

49 Cryo-EM structure of gastric H+,K+-ATPase with a single occupied cation-binding site K. Abe, K. Tania, T. Friedrich, Y. Fujiyoshia Proceedings of the National Academy of Sciences of the United States of America 2012, 109, 18401–18406, 10.1073/pnas.1212294109

48 Supported ZnO Catalysts for the Conversion of Alkanes: About the Metamorphosis of a heterogeneous Catalyst. S. Arndt, B. Uysal, A. Berthold, T. Otremba, Y. Aksu, M. Driess, R. Schomäcker Journal of Natural Gas Chemistry 2012, 21, 581–594, 10.1016/S1003-9953(11)60407-6

47 Activation and Coordination of Ammonia at [Cp*Ir(H)2]: NMR and Matrix Isolation Studies T. Braun, C. Limberg, A. K. Jungton, C. Herwig Chemistry - A European Journal 2012, 18, 10009–10013, 10.1002/chem.201201295

46 Gas-phase structures of neutral silicon clusters M. Haertelt, J. T. Lyon, P. Claes, J. de Haeck, P. Lievens, A. Fielicke The Journal of Chemical Physics 2012, 136, 64301– 10.1063/1.3682323

45 Structure determination of neutral MgO clusters - hexagonal nanotubes and cages M. Haertelt, A. Fielicke, G. Meijer, K. Kwapien, M. Sierka, J. Sauer Physical Chemistry Chemical Physics 2012, 14, 2849–2856, 10.1039/C2CP23432G

44 Activation of molecular oxygen by anionic gold clusters A. Woodham, G. Meijer, A. Fielicke Angewandte Chemie International Edition 2012, 51, 4444–4447, 10.1002/anie.201108958

43 Activated Methane on Small Cationic Platinum Clusters D. J. Harding, C. Kerpal, G. Meijer, A. Fielicke Angewandte Chemie International Edition 2012, 51, 817–819, 10.1002/anie.201107042

42 Low-Temperature Iron-Catalyzed Depolymerization of Polyethers S. Enthaler, M. Weidauer ChemSusChem 2012, 5, 1195–1198, 10.1002/cssc.201200125

41 Characterization of New Class III Lantibiotics-Erythreapeptin, Avermipeptin and Griseopeptin from Saccharopolyspora erythraea, Streptomyces avermitilis and Streptomyces griseus Demonstrates Stepwise N-Terminal Leader Processing G. H. Völler, J. M. Krawczyk, A. Pesic, B. Krawczyk, J. Nachtigall, R. D. Süssmuth ChemBioChem 2012, 13, 1174–1183, 10.1002/cbic.201200118

40 Congeneric Lantibiotics from Ribosomal In Vivo Peptide Synthesis with Noncanonical Amino Acids** F. Oldach, R. Al Toma, A. Kuthning, T. Caetano, S. Mendo, N. Budisa, R. Süssmuth Angewandte Chemie International Edition 2012, 51, 415–418, 10.1002/anie.201106154

39 A new method to synthesize very active and stable supported metal Pt catalysts: thermo-destabilization of microemulsions R. Parapat, V. Parwoto, M. Schwarze, B. Zhang, D. S. Su, R. Schomäcker Journal of Materials Chemistry 2012, 22, 11606–11614, 10.1039/c2jm15468d

38 Multifunctional Dendritic Architectures: An Investigation of their Mechanical Properties H. Zhou, M. Richter, R. v. Klitzing, R. Haag MRS Proceedings 2012, 1403, 10.1557/opl.2012.370

37 Tunable Plasmon Coupling in Distance-Controlled Gold Nanoparticles H. Lange, N. G. Bastús, A. Carl, M. Richter, H. Weller, B. H. Juárez, C. Thomsen, R. v. Klitzing, A. Knorr Langmuir 2012, 28, 8862–8866, 10.1021/la3001575

36 Immobilization of lipase B within micron-sized poly-N-isopropylacrylamide hydrogel particles by solvent exchange K. Gawlitza, C. Wu, R. Georgieva, D. Wang, M. B. Ansorge-Schumacher, R. v. Klitzing Physical Chemistry Chemical Physics 2012, 14, 9594–9600, 10.1039/C2CP40624A

35 One-Step Formulation of Protein Microparticles with Tailored Properties: Hard Templating at Soft Conditions D. V. Volodkin, S. Schmidt, P. Fernandez, N. I. Larionova, G. B. Sukhorukov, C. Duschl, H. Möhwald, R. v. Klitzing Advanced Materials 2012, 9, 1914–1922, 10.1002/adfm.201103007

34 Thermal Reactions of YAlO3+• with Methane: Increasing the Reactivity of Y2O3+• and the Selectivity of Al2O3+• by Doping H. Schwarz, J. B. Ma, Z. C. Wang, M. Schlangen, S. G. He Angewandte Chemie International Edition 2012, 51, 5991–5994, 10.1002/anie.201201698

33 A computational study on the intriguing mechanisms of the gas-phase thermal activation of methane by bare [Ni(H)(OH)]+ O. Lakuntza, J. M. Matxain, F. Ruipérez, M. Besora, F. Maseras, J. M. Ugalde, M. Schlangen, H. Schwarz Physical Chemistry Chemical Physics 2012, 14, 9306–9310, 10.1039/c2cp23502a

32 Synthesis, reactivity and structures of iridium tetrafluoropyridyl complexes: Ammonia coordination and activation T. Braun, A. K. Jungton, P. Kläring, A. Eißler Zeitschrift für Anorganische und Allgemeine Chemie 2012, 638, 505–511, 10.1002/zaac.201100440

31 Process development of an energy and cost efficient carbon capture process for the oxidative coupling of methane in a mini plant scale S. Stünkel, K. Bittig, G. Wozny Proceeding on 243rd ACS National Meeting and Exposition 2012, 534,

30 Thermal Ammonia Activation by Cationic Transition-Metal Hydrides of the First Row – Small but Mighty H. Schwarz, R. Kretschmer, M. Schlangen Chemistry - An Asian Journal 2012, 7, 1214–1220, 10.1002/asia.201101045

29 Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry H. Schwarz, N. Dietl, M. Schlangen Angewandte Chemie International Edition 2012, 51, 5544–5555, 10.1002/anie.201108363

28 Neutral Metal Atoms Acting as a Leaving Group in Gas-Phase SN2 Reactions: M(CH3)+ + NH3 -> CH3NH3+ + M (M = Zn, C, Hg) H. Schwarz, R. Kretschmer, M. Schlangen, M. Kaupp Organometallics 2012, 31, 3816–3824, 10.1021/om300116c

27 Membrane Reactor System for Parallel Continuous Screening and Characterisation of Biocatalysts E. Lyagin, A. Drews, S. Bhattacharya, M. Kraume Chemical Engineering Transactions 2012, 27, 319–324, 10.3303/cet1227054

26 Tailored silica coated Ag nanoparticles for non-invasive surface enhanced Raman spectroscopy of biomolecular targets A. Sivanesan, J. Kozuch , H. K. Ly, G. Kalaivani, A. Fischer, I. M. Weidinger RSC Advances 2012, 2, 805–808, 10.1039/C1RA00781E

25 Induced Surface Enhancement in Coral Pt Island Films Attached to Nanostructured Ag Electrodes H. K. Ly, C. Köhler, A. Fischer, J. Kabuss, F. Schlosser, M. Schoth, A. Knorr, I. M. Weidinger Langmuir 2012, 28, 5819–5825, 10.1021/la205139g

24 Mn-Na2WO4/SiO2 as Catalyst for the Oxidative Coupling of Methane. What is really known? S. Arndt, T. Otremba, U. Simon, M. Yildiz, H. Schubert, R. Schomäcker Applied Catalysis A: General 2012, 425, 53–61, 10.1016/j.apcata.2012.02.046

23 Direct Conversion of Methane into Formaldehyde Mediated by [Al2O3]•+ at Room Temperature H. Schwarz, Z. C. Wang, N. Dietl, R. Kretschmer, J. B. Ma, T. Weiske, M. Schlangen Angewandte Chemie International Edition 2012, 51, 3703–3707, 10.1002/anie.201200015

22 Coupling of Ci-VSP Modules Requires a Combination of Structure and Electrostatics within the Linker K. Hobiger, T. Utesch, M. A. Mroginski, T. Friedrich Biophysical Journal 2012, 102, 1313–1322, 10.1016/j.bpj.2012.02.027

21 C-N and C-C Bond Formations in the Thermal Reactions of "Bare" Ni(NH2)+ with C2H4: Mechanistic Insight on the Metal-Mediated Hydroamination of an Unactivated Olefin H. Schwarz, R. Kretschmer, M. Schlangen Angewandte Chemie International Edition 2012, 51, 3483–3488, 10.1002/anie.201104433

20 Control of Gastric H,K-ATPase Activity by Cations, Voltage and Intracellular pH Analyzed by Voltage Clamp Fluorometry in Xenopus Oocytes K. L. Dürr, N. N. Tavraz, T. Friedrich PLoS ONE 2012, 7, 10.1371/journal.pone.0033645

19 Application of Nickel Complexes Modified by Tridentate O,N,O'-Ligands as Precatalysts in Nickel-Catalyzed C(sp2)-C(sp3) Bond Formations S. Enthaler, C. I. Someya, S. Inoue, S. Krackl, E. Irran European Journal of Inorganic Chemistry 2012, 2012, 1269–1277, 10.1002/ejic.201101253

18 The Rise of the Iron Age in Hydrogen Evolution? B. Loges, S. Enthaler ChemCatChem 2012, 4, 323–325, 10.1002/cctc.201100391

17 Mapping local electric fields in proteins at biomimetic interfaces G. Schkolnik, T. Utesch, J. Salewski, K. Tenger, D. Millo, A. Kranich, I. Zebger, C. Schulz, L. Zimanyi, G. Rakhely, M. A. Mroginski, P. Hildebrandt Chemical Communications 2012, 48, 70–72, 10.1039/c1cc13186a

16 NAD(H)-coupled hydrogen cycling - structure-function relationships of bidirectional [NiFe] hydrogenases M. Horch, L. Lauterbach, O. Lenz, P. Hildebrandt, I. Zebger FEBS letters 2012, 586, 545–556, 10.1016/j.febslet.2011.10.010

15 Iron-based pre-catalyst supported on polyformamidine for C-C bond formation S. Enthaler, S. Krackl, J. D. Epping, B. Eckhardt, S. M. Weidner, A. Fischer Polym. Chem. 2012, 3, 751–756, 10.1039/c2py00540a

14 Zinc-catalyzed Depolymerization of Artificial Polyethers S. Enthaler, M. Weidauer Chemistry - A European Journal 2012, 18, 1910–1913, 10.1002/chem.201103677

13 Synthesis of delta- and epsilon-Cyanoesters by Zinc-catalyzed Ring-opening of Cyclic Ethers with Acid Chlorides and Subsequent Cyanation S. Enthaler, M. Weidauer Catalysis Letters 2012, 142, 168–175, 10.1007/s10562-011-0744-6

12 Partition Coefficients of Itaconates in Aqueous-Micellar Solutions: Measurements and Predictions with COSMO-RS M. Schwarze, I. Volovych, S. Wille, L. Mukrushina, W. Arlt, R. Schomäcker Industrial and Engineering Chemistry Research 2012, 51, 1846–1852, 10.1021/ie2006565

11 Influence of the wall structure on the void fraction distribution in packed beds N. Zobel, T. Eppinger, F. Behrendt, M. Kraume Chemical Engineering Science 2012, 212–219, 10.1016/j.ces.2011.12.029

10 Li/MgO with Spin Sensors as Catalyst for the Oxidative Coupling of Methane U. Simon, S. Arndt, T. Otremba, T. Schlingmann, K. P. Dinse, R. Schomäcker, H. Schubert Catalysis Communications 2012, 18, 132–136, 10.1016/j.catcom.2011.11.021

9 Comparison of oxidizing agents for the oxidative coupling of methane over state-of-the-art catalysts K. Langfeld, B. Frank, V. E. Strempel, C. Berger-Karin, G. Weinberg, E. V. Kondratenko, R. Schomäcker Applied Catalysis A: General 2012, 417-418, 145–152, 10.1016/j.apcata.2011.12.035

8 A modular system for regeneration of NAD cofactors using graphite particles modified with hydrogenase and diaphorase moieties H. A. Reeve, L. Lauterbach, P. A. Ash, O. Lenz, K. A. Vincent Chemical Communications 2012, 48, 1589–1591, 10.1039/C1CC14826E

7 "Rollover" cyclometalation - early history, recent developments, mechanistic insights and application aspects H. Schwarz, B. Butschke Chemical Science 2012, 3, 308–326, 10.1039/c1sc00651g

6 Mechanistic Aspects and Elementary Steps of N-H Bond Activation of Ammonia and C-N Coupling Induced by Gas-Phase Ions: A Combined Experimental/Computational Exercise H. Schwarz, R. Kretschmer, M. Schlangen Chemistry - A European Journal 2012, 18, 40–49, 10.1002/chem.201102494

5 An Efficient Zinc-Catalyzed Dehydration of Primary Amides to Nitriles S. Enthaler, S. Inoue Chemistry - An Asian Journal 2012, 7, 169–175, 10.1002/asia.201100493

4 Non-adiabatic excited state dynamics of riboflavin after photoexcitation B. Klaumünzer, H. Lischka, D. Kröner, P. Saalfrank Physical Chemistry Chemical Physics 2012, 14, 8693–8703, 10.1039/C2CP40978J

3 Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride M. Stoelzel, C. Präsang, S. Inoue, S. Enthaler, M. Driess Angewandte Chemie International Edition 2012, 51, 339–403, 10.1002/anie.201105722

2 Lessons from isolable nickel(I) precursor complexes for small molecule activation S. Yao, M. Driess Accounts of Chemical Research 2012, 45, 276–287, 10.1021/ar200156r

1 BLUF Hydrogen network dynamics and UV/Vis spectra: A combined molecular dynamics and quantum chemical study J. Götze, C. Greco, V. Bonacic-Koutecky, P. Saalfrank Journal of Photochemistry and Photobiology B: Biology 2012, 33, 2233–2242, 10.1002/jcc.23056