Publications 2013

Number of records: 203

203 Characterization of [4Fe-4S] Cluster Vibrations and Structure in Nitrogenase Fe Protein at Three Oxidation Levels via Combined NRVS, EXAFS, and DFT Analyses D. Mitra, S. J. George, Y. Guo, S. Kamali, S. Keable, J. W. Peters, V. Pelmenschikov, D. A. Case, S. P. Cramer Journal of the American Chemical Society 2013, 135, 2530–2543, 10.1021/ja307027n

202 Future of Biosensors: A Personal View F. W. Scheller, A. Yaman, T. Bachmann, T. Hirsch, S. Kubick, R. Renneberg, S. Schumacher, U. Wollenberger, C. Teller, F. F. Bier Advances in Biochemical Engineering/Biotechnology 2013, 140, 1–28, 10.1007/10_2013_251

201 Effect of the Protonation Degree of a Self-Assembled Monolayer on the Immobilization Dynamics of a [NiFe] Hydrogenase T. Utesch, D. Millo, M. A. Castro, P. Hildebrandt, I. Zebger, M. A. Mroginski Langmuir 2013, 29, 673–682, 10.1021/la303635q

200 Unraveling the Interfacial Electron Transfer Dynamics of Electroactive Microbial Biofilms Using Surface-Enhanced Raman Spectroscopy H. K. Ly, F. Harnisch, S. F. Hong, U. Schröder, P. Hildebrandt, D. Millo ChemSusChem 2013, 6, 487–492, 10.1002/cssc.201200626

199 Disentangling Electron Tunneling and Protein Dynamics of Cytochrome through a Rationally Designed Surface Mutation D. Alvarez-Paggi, W. Meister, U. Kuhlmann, I. Weidinger, K. Tenger, L. Zimányi, G. Rákhely, P. Hildebrandt, D. H. Murgida The Journal of Physical Chemistry B 2013, 117, 6061–6068, 10.1021/jp400832m

198 Morphology and Luminescence of ZnO Films Grown on a Au(111) Support F. Stavale, L. Pascua, N. Nilius, H. J. Freund The Journal of Physical Chemistry C 2013, 117, 10552–10557, 10.1021/jp401939x

197 Identification of Crucial Amino Acids in Mouse Aldehyde Oxidase 3 That Determine Substrate Specificity M. Mahro, N. F. Brás, N. M. F. S. A. Cerqueira, C. Teutloff, C. Coelho, M. J. Romão, S. Leimkühler, A. Pastore PLoS ONE 2013, 8, 10.1371/journal.pone.0082285

196 Bis- -Heterocyclic Carbene (NHC) Stabilized η -Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity B. Blom, G. Tan, S. Enthaler, S. Inoue, J. D. Epping, M. Driess Journal of the American Chemical Society 2013, 135, 18108–18120, 10.1021/ja410234x

195 A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene Y. Xiong, S. Yao, G. Tan, S. Inoue, M. Driess Journal of the American Chemical Society 2013, 135, 5004–5007, 10.1021/ja402477w

194 N-Heterocyclic Silylene (NHSi) Rhodium and Iridium Complexes: Synthesis, Structure, Reactivity, and Catalytic Ability M. Stoelzel, C. Präsang, B. Blom, M. Driess Australian Journal of Chemistry 2013, 66, 1163–1170, 10.1071/CH13196

193 Dimensionally Stable Ru/Ir/TiO -Anodes with Tailored Mesoporosity for Efficient Electrochemical Chlorine Evolution N. Menzel, E. Ortel, K. Mette, R. Kraehnert, P. Strasser ACS Catalysis 2013, 3, 1324–1333, 10.1021/cs4000238

192 Micelle-Templated Oxides and Carbonates of Zinc, Cobalt, and Aluminum and a Generalized Strategy for Their Synthesis B. Eckhardt, E. Ortel, D. Bernsmeier, J. Polte, P. Strasser, U. Vainio, F. Emmerling, R. Kraehnert Chemistry of Materials 2013, 25, 2749–2758, 10.1021/cm400535d

191 Size-Controlled Synthesis of Colloidal Silver Nanoparticles Based on Mechanistic Understanding M. Wuithschick, B. Paul, R. Bienert, A. Sarfraz, U. Vainio, M. Sztucki, R. Kraehnert, P. Strasser, K. Rademann, F. Emmerling, J. Polte Chemistry of Materials 2013, 25, 4679–4689, 10.1021/cm401851g

190 Electrocatalytic Oxygen Evolution Reaction on Iridium Oxide Model Film Catalysts: Influence of Oxide Type and Catalyst Substrate Interactions T. Reier, I. Weidinger, P. Hildebrandt, R. Kraehnert, P. Strasser ECS Transaction ECS Transactions 2013, 58, 39–51, 10.1149/05802.0039ecst

189 Occurrence and biosynthesis of C-demethylactinomycins in actinomycin-producing Streptomyces chrysomallus and Streptomyces parvulus I. Crnovcic, J. Vater, U. Keller The Journal of Antibiotics 2013, 66, 211–218, 10.1038/ja.2012.120

188 Nitrogen- and phosphorus-co-doped carbons with tunable enhanced surface areas promoted by the doping additives J. P. Paraknowitsch, Y. Zhang, B. Wienert, A. Thomas Chemical Communications 2013, 49, 1208– 10.1039/c2cc37398j

187 Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications J. P. Paraknowitsch, A. Thomas Energy & Environmental Science 2013, 6, 2839– 10.1039/C3EE41444B

186 Covalent Triazine Frameworks Prepared from 1,3,5-Tricyanobenzene P. Katekomol, J. Roeser, M. Bojdys, J. Weber, A. Thomas Chemistry of Materials 2013, 25, 1542–1548, 10.1021/cm303751n

185 Dendritic Fluoroalcohols as Catalysts for Alkene Epoxidation with Hydrogen Peroxide A. Berkessel, J. Krämer, F. Mummy, J. M. Neudörfl, R. Haag Angewandte Chemie International Edition 2013, 52, 739–743, 10.1002/anie.201206003

184 Methane Coupling over Magnesium Oxide: How Doping Can Work P. Schwach, M. G. Willinger, A. Trunschke, R. Schlögl Angewandte Chemie International Edition 2013, 52, 11381–11384, 10.1002/anie.201305470

183 Effect of Exchange of the Cysteine Molybdenum Ligand with Selenocysteine on the Structure and Function of the Active Site in Human Sulfite Oxidase S. Reschke, D. Niks, H. Wilson, K. G. V. Sigfridsson, M. Haumann, K. V. Rajagopalan, R. Hille, S. Leimkühler Biochemistry 2013, 52, 8295–8303, 10.1021/bi4008512

182 A High-Valent Heterobimetallic [Cu(III) (μ-O) Ni(III)]2+ Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie International Edition 2013, 52, 5622–5626, 10.1002/anie.201300861

181 Active Mixed-Valent MnO Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles A. Indra, P. W. Menezes, I. Zaharieva, E. Baktash, J. Pfrommer, M. Schwarze, H. Dau, M. Driess Angewandte Chemie International Edition 2013, 52, 13206–13210, 10.1002/anie.201307543

180 Artificial photosynthesis as a frontier technology for energy sustainability T. Faunce, S. Styring, M. R. Wasielewski, G. W. Brudvig, A. W. Rutherford, J. Messinger, A. F. Lee, C. L. Hill, H. deGroot, M. Fontecave, D. R. MacFarlane, B. Hankamer, D. G. Nocera, D. M. Tiede, H. Dau, W. Hillier, L. Wang, R. Amal Energy & Environmental Science 2013, 6, 1074– 10.1039/C3ee40534f

179 Electrochemical water splitting by layered and 3D cross-linked manganese oxides: correlating structural motifs and catalytic activity A. Bergmann, I. Zaharieva, H. Dau, P. Strasser Energy & Environmental Science 2013, 6, 2745–2755, 10.1039/C3ee41194j

178 Cyanamide route to calcium–manganese oxide foams for water oxidation E. Baktash, I. Zaharieva, M. Schröder, C. Goebel, H. Dau, A. Thomas Dalton Transactions 2013, 42, 16920– 10.1039/c3dt51693h

177 Synthesis of Asymmetrically Substituted Terpyridines by Palladium-Catalyzed Direct C-H Arylation of Pyridine N-Oxides S. Duric, F. D. Sypaseuth, S. Hoof, E. Svensson, C. C. Tzschucke Chemistry - A European Journal 2013, 19, 17456–17463, 10.1002/chem.201302118

176 Stability and Metastability of Clusters in a Reactive Atmosphere: Theoretical Evidence for Unexpected Stoichiometries of Mg_{M}O_{x} S. Bhattacharya, S. V. Levchenko, L. M. Ghiringhelli, M. Scheffler Physical Review Letters 2013, 111, 135501–5, 10.1103/PhysRevLett.111.135501

175 Expanded genetic code for the engineering of ribosomally synthetized and post-translationally modified peptide natural products (RiPPs) N. Budisa Current Opinion in Biotechnology 2013, 24, 591–598, 10.1016/j.copbio.2013.02.026

174 Non-canonical amino acids as a useful synthetic biological tool for lipase-catalysed reactions in hostile environments C. G. Acevedo-Rocha, M. G. Hoesl, S. Nehring, M. Royter, C. Wolschner, B. Wiltschi, G. Antranikian, N. Budisa Catalysis Science & Technology 2013, 3, 1198– 10.1039/c3cy20712a

173 Biocatalytic synthesis of (2S)-5,5,5-trifluoroleucine and improved resolution into (2S,4S) and (2S,4R) diastereoisomers H. Biava, N. Budisa Tetrahedron Letters 2013, 54, 3662–3665, 10.1016/j.tetlet.2013.04.128

172 Obtention of enantiomerically pure 5,5,5-trifluoro-l-isoleucine and 5,5,5-trifluoro-l-alloisoleucine H. Biava, N. Budisa Journal of Fluorine Chemistry 2013, 156, 372–377, 10.1016/j.jfluchem.2013.07.021

171 Enhanced production of the nonribosomal peptide antibiotic valinomycin in Escherichia coli through small-scale high cell density fed-batch cultivation J. Li, J. Jaitzig, F. Hillig, R. Süssmuth, P. Neubauer Applied Microbiology and Biotechnology 2013, 98, 591–601, 10.1007/s00253-013-5309-8

170 Recombinant purine nucleoside phosphorylases from thermophiles: preparation, properties and activity towards purine and pyrimidine nucleosides X. Zhou, K. Szeker, B. Janocha, T. Böhme, D. Albrecht, I. A. Mikhailopulo, P. Neubauer FEBS Journal 2013, 280, 1475–1490, 10.1111/febs.12143

169 Systematic approaches for model derivation for optimization purposes E. Esche, D. Müller, R. Kraus, G. Wozny Chemical Engineering Science 2013, 10.1016/j.ces.2013.11.041

168 Simulations of the polarisation-dependent Raman intensity of -carotene in photosystem II crystals K. Brose, A. Zouni, F. Müh, M. A. Mroginski, J. Maultzsch Chemical Physics 2013, 418, 65–73, 10.1016/j.chemphys.2013.03.016

167 Modeling of the branching influence on liquid–liquid equilibrium of binary and ternary polymer solutions by lattice–cluster theory D. Browarzik, K. Langenbach, S. Enders, C. Browarzik The Journal of Chemical Thermodynamics 2013, 62, 56–63, 10.1016/j.jct.2013.02.018

166 The nonheme iron in photosystem II F. Müh, A. Zouni Photosynthesis Research 2013, 116, 295–314, 10.1007/s11120-013-9926-y

165 Structural Changes of the Oxygen-evolving Complex in Photosystem II during the Catalytic Cycle C. Glockner, J. Kern, M. Broser, A. Zouni, V. Yachandra, J. Yano Journal of Biological Chemistry 2013, 288, 22607–22620, 10.1074/jbc.M113.476622

164 Simultaneous Femtosecond X-ray Spectroscopy and Diffraction of Photosystem II at Room Temperature J. Kern, R. Alonso-Mori, R. Tran, J. Hattne, R. J. Gildea, N. Echols, C. Glockner, J. Hellmich, H. Laksmono, R. G. Sierra, B. Lassalle-Kaiser, S. Koroidov, A. Lampe, G. Han, S. Gul, D. DiFiore, D. Milathianaki, A. R. Fry, A. Miahnahri, D. W. Schafer, M. M Science 2013, 340, 491–495, 10.1126/Science.1234273

163 Synthesis of Rhodium(I) Boryl Complexes: Catalytic N-H Activation of Anilines and Ammonia M. Teltewskoi, S. I. Kalläne, T. Braun, R. Herrmann European Journal of Inorganic Chemistry 2013, 2013, 5762–5768, 10.1002/ejic.201300972

162 Zinc Complexes with the N-Donor-Functionalized Cyclopentadienyl Ligand C Me (CH ) NMe M. A. Chilleck, T. Braun, R. Herrmann, B. Braun Organometallics 2013, 32, 1067–1074, 10.1021/om301181e

161 Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species M. Ahrens, G. Scholz, T. Braun, E. Kemnitz Angewandte Chemie International Edition 2013, 52, 5328–5332, 10.1002/anie.201300608

160 Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions M. F. Kuehnel, D. Lentz, T. Braun Angewandte Chemie International Edition 2013, 52, 3328–3348, 10.1002/anie.201205260

159 Microcystin production revisited: conjugate formation makes a major contribution S. Meissner, J. Fastner, E. Dittmann Environmental Microbiology 2013, 15, 1810–1820, 10.1111/1462-2920.12072

158 Characterisation of paramagnetic Mo impurities on MgO(100) single-crystalline films grown on Mo(100) A. Gonchar, T. Risse Molecular Physics 2013, 111, 2708–2716, 10.1080/00268976.2013.811305

157 Measuring Cation Transport by Na,K- and H,K-ATPase in Xenopus Oocytes by Atomic Absorption Spectrophotometry: An Alternative to Radioisotope Assays K. L. Dürr, N. N. Tavraz, S. Spiller, T. Friedrich Journal of Visualized Experiments 2013, 10.3791/50201

156 The Linker Pivot in Ci-VSP: The Key to Unlock Catalysis K. Hobiger, T. Utesch, M. A. Mroginski, G. Seebohm, T. Friedrich, S. Barnes PLoS ONE 2013, 8, 10.1371/journal.pone.0070272

155 Voltage Dependence of Proton Pumping by Bacteriorhodopsin Mutants with Altered Lifetime of the M Intermediate S. Geibel, PLoS ONE 2013, 8, 10.1371/journal.pone.0073338

154 Functional characterization of a novel C-terminal ATP1A2 mutation causing hemiplegic migraine and epilepsy T. Pisano, S. Spiller, D. Mei, R. Guerrini, C. Cianchetti, T. Friedrich, D. Pruna Cephalalgia 2013, 33, 1302–1310, 10.1177/0333102413495116

153 A One-Pot Approach to Mesoporous Metal Oxide Ultrathin Film Electrodes Bearing One Metal Nanoparticle per Pore with Enhanced Electrocatalytic Properties A. Guiet, T. Reier, N. Heidary, D. Felkel, B. Johnson, U. Vainio, H. Schlaad, Y. Aksu, M. Driess, P. Strasser, A. Thomas, J. Polte, A. Fischer Chemistry of Materials 2013, 25, 4645–4652, 10.1021/cm401135z

152 Cytochrome P450 Interacts Directly with the Nonribosomal Peptide Synthetase to Generate Three Amino Acid Precursors in Skyllamycin Biosynthesis S. Uhlmann, R. D. Süssmuth, M. J. Cryle ACS Chemical Biology 2013, 8, 2586–2596, 10.1021/cb400555e

151 Champacyclin, a New Cyclic Octapeptide from Streptomyces Strain C42 Isolated from the Baltic Sea A. Pesic, H. Baumann, K. Kleinschmidt, P. Ensle, J. Wiese, R. Süssmuth, J. Imhoff Marine Drugs 2013, 11, 4834–4857, 10.3390/md11124834

150 Arg-Thz is a minimal substrate for the Nα,Nα-arginyl methyltransferase involved in the biosynthesis of plantazolicin N. A. Piwowarska, S. Banala, H. S. Overkleeft, R. D. Süssmuth Chemical Communications 2013, 49, 10703–10705, 10.1039/c3cc45898a

149 Reconstituted Biosynthesis of the Nonribosomal Macrolactone Antibiotic Valinomycin in J. Jaitzig, J. Li, R. D. Süssmuth, P. Neubauer ACS Synthetic Biology 2013, 131218130145008– 10.1021/sb400082j

148 Quantum Chemical Free Energies: Structure Optimization and Vibrational Frequencies in Normal Modes G. Piccini, J. Sauer Journal of Chemical Theory and Computation 2013, 9, 5038–5045, 10.1021/ct4005504

147 Accurate adsorption energies of small molecules on oxide surfaces: CO–MgO(001) A. D. Boese, J. Sauer Physical Chemistry Chemical Physics 2013, 15, 16481– 10.1039/C3CP52321G

146 Parameter optimization for the oxidative coupling of methane in a fixed bed reactor by combination of response surface methodology and computational fluid dynamics T. Eppinger, G. Wehinger, M. Kraume Chemical Engineering Research and Design 2013, 10.1016/j.cherd.2013.12.017

145 Numerische Untersuchung von Schüttungen sphärischer und nichtsphärischer Füllkörper mithilfe von DEM und CFD T. Eppinger, G. Wehinger, N. Jurtz, M. Kraume Chemie Ingenieur Technik 2013, 85, 1376–1377, 10.1002/cite.201250708

144 Anforderungen an eine OCM-Kinetik aus ingenieurstechnischer Sicht G. Chemie Ingenieur Technik 2013, 85, 1381–1381, 10.1002/cite.201250590

143 A Microgel Construction Kit for Bioorthogonal Encapsulation and pH-Controlled Release of Living Cells D. Steinhilber, T. Rossow, S. Wedepohl, F. Paulus, S. Seiffert, R. Haag Angewandte Chemie International Edition 2013, 52, 13538–13543, 10.1002/anie.201308005

142 A Rare Uranyl(VI)-Alkyl Ate Complex [Li(DME) ] [UO (CH SiMe ) ] and Its Comparison with a Homoleptic Uranium(VI)-Hexaalkyl L. A. Seaman, P. Hrobárik, M. F. Schettini, S. Fortier, M. Kaupp, T. W. Hayton Angewandte Chemie International Edition 2013, 52, 3259–3263, 10.1002/anie.201209611

141 Investigations in the phase system Li–MgO–Y–Zr with respect to defect forming and catalytic performance A. Berthold, R. Mitdank, U. Simon, S. Arndt, H. Schubert Journal of Physics and Chemistry of Solids 2013, 74, 997–1006, 10.1016/j.jpcs.2013.02.020

140 Facile synthesis of carbon nitride micro-/nanoclusters with photocatalytic activity for hydrogen evolution J. Liu, J. Huang, D. Dontosova, M. Antonietti RSC Advances 2013, 3, 22988– 10.1039/c3ra44490b

139 Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott–Schottky heterojunctions for catalysis X. H. Li, M. Antonietti Chemical Society Reviews 2013, 42, 6593– 10.1039/c3cs60067j

138 A Sustainable Route towards Imidazolium Building Blocks Based on Biomass Molecules D. Esposito, S. Kirchhecker, M. Antonietti Chemistry - A European Journal 2013, 19, 15097–15100, 10.1002/chem.201302806

137 Refining the Interpretation of Near-Infrared Band Shapes in a Polyynediyl Molecular Wire M. Parthey, J. B. G. Gluyas, P. A. Schauer, D. S. Yufit, J. A. K. Howard, M. Kaupp, P. J. Low Chemistry - A European Journal 2013, 19, 9780–9784, 10.1002/chem.201301747

136 Syntheses, Spectroelectrochemical Studies, and Molecular and Electronic Structures of Ferrocenyl Ene-diynes K. B. Vincent, Q. Zeng, M. Parthey, D. S. Yufit, J. A. K. Howard, F. Hartl, M. Kaupp, P. J. Low Organometallics 2013, 32, 6022–6032, 10.1021/om400535y

135 Synthesis and Bonding in Carbene Complexes of an Unsymmetrical Dilithio Methandiide: A Combined Experimental and Theoretical Study V. H. Gessner, F. Meier, D. Uhrich, M. Kaupp Chemistry - A European Journal 2013, 19, 16729–16739, 10.1002/chem.201303115

134 From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction D. Gallego, A. Brück, E. Irran, F. Meier, M. Kaupp, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2013, 135, 15617–15626, 10.1021/ja408137t

133 Does the environment around the H-cluster allow coordination of the pendant amine to the catalytic iron center in [FeFe] hydrogenases? Answers from theory T. Miyake, M. Bruschi, U. Cosentino, C. Baffert, V. Fourmond, C. Léger, G. Moro, L. Gioia, C. Greco JBIC Journal of Biological Inorganic Chemistry 2013, 18, 693–700, 10.1007/s00775-013-1014-4

132 Towards [NiFe]-hydrogenase biomimetic models that couple H2 binding with functionally relevant intramolecular electron transfers: a quantum chemical study C. Greco Dalton Transactions 2013, 42, 13845–13854, 10.1039/C3DT50836F

131 H2 Binding and Splitting on a New-Generation [FeFe]-Hydrogenase Model Featuring a Redox-Active Decamethylferrocenyl Phosphine Ligand: A Theoretical Investigation C. Greco Inorganic Chemistry 2013, 52, 1901–1908, 10.1021/ic302118h

130 Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11 K. Ray, F. Heims, F. F. Pfaff European Journal of Inorganic Chemistry 2013, 2013, 3784–3807, 10.1002/ejic.201300223

129 Frauenförderung zwischen heterogenen Logiken. Der Fall eines Nachwuchsförderprogramms in der deutschen Exzellenzinitiative G. Petschick, R. Schmidt, M. Norkus Swiss Journal of Sociology 2013, 39, 383–404,

128 Performance Analysis of a Porous Packed Bed Membrane Reactor for Oxidative Coupling of Methane: Structural and Operational Characteristics H. R. Godini, A. Gili, O. Görke, U. Simon, K. Hou, G. Wozny Energy & Fuels 2013, 131224152753003– 10.1021/ef402041b

127 Design and demonstration of an experimental membrane reactor set-up for oxidative coupling of methane H. R. Godini, H. Trivedi, A. G. de Villasante, O. Görke, S. Jašo, U. Simon, A. Berthold, W. Witt, G. Wozny Chemical Engineering Research and Design 2013, 91, 2671–2681, 10.1016/j.cherd.2013.05.025

126 Experimental and model-based analysis of membrane reactor performance for methane oxidative coupling: Effect of radial heat and mass transfer H. R. Godini, S. Xiao, M. Kim, N. Holst, S. Jašo, O. Görke, J. Steinbach, G. Wozny Journal of Industrial and Engineering Chemistry 2013, 10.1016/j.jiec.2013.09.022

125 Dual-membrane reactor for methane oxidative coupling and dry methane reforming: Reactor integration and process intensification H. R. Godini, S. Xiao, M. Kim, O. Görke, S. Song, G. Wozny Chemical Engineering and Processing: Process Intensification 2013, 74, 153–164, 10.1016/j.cep.2013.09.007

124 Exploring the reactivity of nickel complexes in hydrodecyanation reactions S. Enthaler, M. Weidauer, E. Irran, J. D. Epping, R. Kretschmer, C. I. Someya Journal of Organometallic Chemistry 2013, 745, 262–274, 10.1016/j.jorganchem.2013.07.068

123 Exploring the coordination chemistry of 1-benzoyl-4,5-dihydro-3,5-bis(trifluoromethyl)-1H-pyrazol-5-ol to copper C. I. Someya, S. Inoue, S. Enthaler Inorganic Chemistry Communications 2013, 38, 131–134, 10.1016/j.inoche.2013.10.016

122 Charge competition with oxygen molecules determines the growth of gold particles on doped CaO films Y. Cui, K. Huang, N. Nilius, H. J. Freund Faraday Discussions 2013, 162, 153– 10.1039/C3FD20130A

121 CO oxidation over ZnO films on Pt(111) at near-atmospheric pressures Y. Martynova, B. H. Liu, M. E. McBriarty, I. M. N. Groot, M. J. Bedzyk, S. Shaikhutdinov, H. J. Freund Journal of Catalysis 2013, 301, 227–232, 10.1016/j.jcat.2013.02.018

120 Towards Realistic Surface Science Models of Heterogeneous Catalysts: Influence of Support Hydroxylation and Catalyst Preparation Method M. Sterrer, H. J. Freund Catalysis Letters 2013, 143, 375–385, 10.1007/s10562-013-0987-5

119 STM Luminescence Spectroscopy of Intrinsic Defects in ZnO(0001̅) Thin Films F. Stavale, N. Nilius, H. J. Freund J. Phys. Chem. Lett. The Journal of Physical Chemistry Letters 2013, 4, 3972–3976, 10.1021/jz401823c

118 Preparation of Pd–MgO model catalysts by deposition of Pd from aqueous precursor solutions onto Ag(001)-supported MgO(001) thin films F. Ringleb, M. Sterrer, H. J. Freund Applied Catalysis A: General 2013, 10.1016/j.apcata.2013.05.031

117 CO Oxidation on Metal-Supported Ultrathin Oxide Films: What Makes Them Active? Y. Martynova, S. Shaikhutdinov, H. J. Freund ChemCatChem 2013, 5, 2162–2166, 10.1002/cctc.201300212

116 Adsorption, Activation, and Dissociation of Oxygen on Doped Oxides Y. Cui, X. Shao, M. Baldofski, J. Sauer, N. Nilius, H. J. Freund Angewandte Chemie International Edition 2013, 52, 11385–11387, 10.1002/anie.201305119

115 Well-Ordered Transition Metal Oxide Layers in Model Catalysis – A Series of Case Studies H. Kuhlenbeck, S. Shaikhutdinov, H. J. Freund Chemical Reviews 2013, 113, 3986–4034, 10.1021/cr300312n

114 Hydroxylation of Metal-Supported Sheet-Like Silica Films B. Yang, E. Emmez, W. E. Kaden, X. Yu, J. A. Boscoboinik, M. Sterrer, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C 2013, 117, 8336–8344, 10.1021/jp401935u

113 Patterned Defect Structures Predicted for Graphene Are Observed on Single-Layer Silica Films B. Yang, J. A. Boscoboinik, X. Yu, S. Shaikhutdinov, H. J. Freund Nano Letters 2013, 13, 4422–4427, 10.1021/nl402264k

112 A portable quartz micro balance for physical vapor deposition techniques S. Stuckenholz, C. Büchner, G. Thielsch, M. Heyde, H. J. Freund Review of Scientific Instruments 2013, 84, 85118– 10.1063/1.4819030

111 Model studies on heterogeneous catalysts at the atomic scale: From supported metal particles to two-dimensional zeolites H. J. Freund, M. Heyde, N. Nilius, S. Schauermann, S. Shaikhutdinov, M. Sterrer Journal of Catalysis 2013, 308, 154–167, 10.1016/j.jcat.2013.06.007

110 Electron quantization in arbitrarily shaped gold islands on MgO thin films C. Stiehler, Y. Pan, W. D. Schneider, P. Koskinen, H. Häkkinen, N. Nilius, H. J. Freund Physical Review Letters 2013, 88, 115415–115415, 10.1103/PhysRevB.88.115415

109 Controlling the charge state of single Mo dopants in a CaO film Y. Cui, N. Nilius, H. J. Freund, S. Prada, L. Giordano, G. Pacchioni Physical Review Letters 2013, 88, 205421–205425, 10.1103/PhysRevB.88.205421

108 Titration of Ce3+ Ions in the CeO2(111) Surface by Au Adatoms Y. Pan, N. Nilius, H. J. Freund, J. Paier, C. Penschke, J. Sauer Physical Review Letters 2013, 111, 206101–206105, 10.1103/PhysRevLett.111.206101

107 Gold Adsorption on CeO Thin Films Grown on Ru(0001) Y. Pan, Y. Cui, C. Stiehler, N. Nilius, H. J. Freund The Journal of Physical Chemistry C 2013, 117, 21879–21885, 10.1021/jp407605m

106 Exploring the Structure of Paramagnetic Centers in SBA-15 Supported Vanadia Catalysts with Pulsed One- and Two-Dimensional Electron Paramagnetic Resonance (EPR) and Electron Nuclear Double Resonance (ENDOR) A. Dinse, T. Wolfram, C. Carrero, R. Schlögl, R. Schomäcker, K. P. Dinse The Journal of Physical Chemistry C 2013, 117, 16921–16932, 10.1021/jp4042342

105 Anomalous reactivity of supported V2O5 nanoparticles for propane oxidative dehydrogenation: influence of the vanadium oxide precursor C. A. Carrero, C. J. Keturakis, A. Orrego, R. Schomäcker, I. E. Wachs Dalton Transactions 2013, 42, 12644–12653, 10.1039/c3dt50611h

104 Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism J. Hermeke, M. Mewald, M. Oestreich Journal of the American Chemical Society 2013, 135, 17537–17546, 10.1021/ja409344w

103 The Family of Ferrocene-Stabilized Silylium Ions: Synthesis, 29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum-Chemical Analyses K. Müther, P. Hrobárik, V. Hrobáriková, M. Kaupp, M. Oestreich Chemistry - A European Journal 2013, 19, 16579–16594, 10.1002/chem.201302885

102 Interaction of CO with Electron-Rich Defects on MgO(100) S. Sicolo, J. Sauer The Journal of Physical Chemistry C 2013, 117, 8365–8373, 10.1021/jp402546k

101 Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment J. Paier, C. Penschke, J. Sauer Chemical Reviews 2013, 113, 3949–3985, 10.1021/cr3004949

100 Analysis of the interaction of the molybdenum hydroxylase PaoABC from Escherichia coli with positively and negatively charged metal complexes A. Badalyan, E. G. Yoga, V. Schwuchow, S. Pöller, W. Schuhmann, S. Leimkühler, U. Wollenberger Electrochemistry Communications 2013, 37, 5–7, 10.1016/j.elecom.2013.09.017

99 Sensors based on cytochrome P450 and CYP mimicking systems A. Yarman, U. Wollenberger, F. W. Scheller Electrochimica Acta 2013, 110, 63–72, 10.1016/j.electacta.2013.03.154

98 Electrochemically driven biocatalysis of the oxygenase domain of neuronal nitric oxide synthase in indium tin oxide nanoparticles/polyvinyl alcohol nanocomposite X. Xu, U. Wollenberger, J. Qian, K. Lettau, C. Jung, S. Liu Bioelectrochemistry 2013, 94, 7–12, 10.1016/j.bioelechem.2013.04.005

97 Concentration of Vacancies at Metal-Oxide Surfaces: Case Study of MgO(100) N. A. Richter, S. Sicolo, S. V. Levchenko, J. Sauer, M. Scheffler Physical Review Letters 2013, 111, 045502–5 pages, 10.1103/PhysRevLett.111.045502

96 Catalytic production of hydrogen peroxide and water by oxygen-tolerant [NiFe]-hydrogenase during H2 cycling in the presence of O2 L. Lauterbach, O. Lenz Journal of the American Chemical Society 2013, 135, 17897–17905, 10.1021/ja408420d

95 Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution A. J. Healy, P. A. Ash, O. Lenz, K. A. Vincent Physical Chemistry Chemical Physics 2013, 15, 7055– 10.1039/c3cp00119a

94 Stability enhancement of an O2-tolerant NAD+-reducing [NiFe]-hydrogenase by a combination of immobilisation and chemical modification N. Herr, J. Ratzka, L. Lauterbach, O. Lenz, M. B. Ansorge-Schumacher Journal of Molecular Catalysis B: Enzymatic 2013, 97, 169–174, 10.1016/j.molcatb.2013.06.009

93 H2-driven cofactor regeneration with NAD(P)+-reducing hydrogenases L. Lauterbach, O. Lenz, K. A. Vincent FEBS Journal 2013, 280, 3058–3068, 10.1111/febs.12245

92 Novel, Oxygen-Insensitive Group 5 [NiFe]-Hydrogenase in Ralstonia eutropha C. Schafer, B. Friedrich, O. Lenz Applied and Environmental Microbiology 2013, 79, 5137–5145, 10.1128/AEM.01576-13

91 Resonance Raman Spectroscopy as a Tool to Monitor the Active Site of Hydrogenases E. Siebert, M. Horch, Y. Rippers, J. Fritsch, S. Frielingsdorf, O. Lenz, F. Velazquez Escobar, F. Siebert, L. Paasche, U. Kuhlmann, F. Lendzian, M. A. Mroginski, I. Zebger, P. Hildebrandt Angewandte Chemie International Edition 2013, 52, 5162–5165, 10.1002/anie.201209732

90 Coupling Biocatalysis with Molecular Imprinting in a Biomimetic Sensor A. Yarman, F. W. Scheller Angewandte Chemie International Edition 2013, 52, 11521–11525, 10.1002/anie.201305368

89 Genome mining reveals the genus Xanthomonas to be a promising reservoir for new bioactive non-ribosomally synthesized peptides M. Royer, R. Koebnik, M. Marguerettaz, V. Barbe, G. P. Robin, C. Brin, S. Carrere, C. Gomez, M. Hügelland, G. H. Völler, J. Noëll, I. Pieretti, S. Rausch, V. Verdier, S. Poussier, P. Rott, R. D. Süssmuth, S. Cociancich BMC Genomics 2013, 14, 658– 10.1186/1471-2164-14-658

88 Elimination Reactions of Esters in the Biosynthesis of Polyketides and Ribosomal Peptides B. Krawczyk, E. F. van Herwerden, H. S. Overkleeft, R. D. Süssmuth Angewandte Chemie International Edition 2013, 52, 9082–9084, 10.1002/anie.201304851

87 Biotransformation of the Fungal Phytotoxin Fomannoxin by Soil Streptomycetes N. Horlacher, J. Nachtigall, D. Schulz, R. D. Süssmuth, R. Hampp, H. P. Fiedler, S. D. Schrey Journal of Chemical Ecology 2013, 39, 931–941, 10.1007/s10886-013-0290-3

86 Involvement and Unusual Substrate Specificity of a Prolyl Oligopeptidase in Class III Lanthipeptide Maturation G. H. Völler, B. Krawczyk, P. Ensle, R. D. Süssmuth Journal of the American Chemical Society 2013, 135, 7426–7429, 10.1021/ja402296m

85 Conformational investigation of antibiotic proximicin by X-ray structure analysis and quantum studies suggest a stretched conformation of this type of γ-peptide A. Denisiuk, V. Schubert, F. E. Wolter, E. Irran, P. Trouillas, R. D. Süssmuth Bioorganic & Medicinal Chemistry 2013, 21, 3582–3589, 10.1016/j.bmc.2013.02.051

84 Alanine Scan of the Peptide Antibiotic Feglymycin: Assessment of Amino Acid Side Chains Contributing to Antimicrobial Activity A. Hänchen, S. Rausch, B. Landmann, L. Toti, A. Nusser, R. D. Süssmuth ChemBioChem 2013, 14, 625–632, 10.1002/cbic.201300032

83 Characterization of the Biosynthetic Genes for 10,11-Dehydrocurvularin, a Heat Shock Response-Modulating Anticancer Fungal Polyketide from Aspergillus terreus Y. Xu, P. Espinosa-Artiles, V. Schubert, Y. M. Xu, W. Zhang, M. Lin, A. A. L. Gunatilaka, R. Sussmuth, I. Molnar Applied and Environmental Microbiology 2013, 79, 2038–2047, 10.1128/AEM.03334-12

82 Total Synthesis of the Ribosomally Synthesized Linear Azole-Containing Peptide Plantazolicin A from Bacillus amyloliquefaciens S. Banala, P. Ensle, R. D. Süssmuth Angewandte Chemie International Edition 2013, 52, 9518–9523, 10.1002/anie.201302266

81 The Lantibiotic Peptide Labyrinthopeptin A1 Demonstrates Broad Anti-HIV and Anti-HSV Activity with Potential for Microbicidal Applications G. Férir, M. I. Petrova, G. Andrei, D. Huskens, B. Hoorelbeke, R. Snoeck, J. Vanderleyden, J. Balzarini, S. Bartoschek, M. Brönstrup, R. D. Süssmuth, D. Schols, H. Favoreel PLoS ONE 2013, 8, 10.1371/journal.pone.0064010

80 Nickel(i)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO2 generating NiICO, NiIICO3 and NiIIC2O4NiII entities B. Horn, C. Limberg, C. Herwig, B. Braun Chemical Communications 2013, 49, 10923–10925, 10.1039/c3cc45407j

79 Access to a CuII–O–CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity P. Haack, A. Kärgel, C. Greco, J. Dokic, B. Braun, F. F. Pfaff, S. Mebs, K. Ray, C. Limberg Journal of the American Chemical Society 2013, 135, 16148–16160, 10.1021/ja406721a

78 Synthesis of a Chiral, Polydentate Ligand System Setting Out from L-Cysteine and First Nickel Complexes Thereof D. S. Warner, C. Limberg, S. Mebs Zeitschrift für anorganische und allgemeine Chemie 2013, 639, 1577–1583, 10.1002/zaac.201300071

77 Redox-Dependent Structural Transformations of the [4Fe-3S] Proximal Cluster in O2-Tolerant Membrane-Bound [NiFe]-Hydrogenase: A DFT Study V. Pelmenschikov, M. Kaupp Journal of the American Chemical Society 2013, 135, 11809–11823, 10.1021/ja402159u

76 Charge Separation Promoted Activation of Molecular Oxygen by Neutral Gold Clusters A. P. Woodham, G. Meijer, A. Fielicke Journal of the American Chemical Society 2013, 135, 1727–1730, 10.1021/ja312223t

75 Not so loosely bound rare gas atoms: finite-temperature vibrational fingerprints of neutral gold-cluster complexes L. M. Ghiringhelli, P. Gruene, J. T. Lyon, D. M. Rayner, G. Meijer, A. Fielicke, M. Scheffler New Journal of Physics 2013, 15, 83003– 10.1088/1367-2630/15/8/083003

74 Zero-field splittings in metHb and metMb with aquo and fluoro ligands: a FD-FT THz-EPR study J. Nehrkorn, B. M. Martins, K. Holldack, S. Stoll, H. Dobbek, R. Bittl, A. Schnegg Molecular Physics 2013, 111, 2696–2707, 10.1080/00268976.2013.809806

73 Visualizing the substrate-, superoxo-, alkylperoxo-, and product-bound states at the nonheme Fe(II) site of homogentisate dioxygenase J. H. Jeoung, M. Bommer, T. Y. Lin, H. Dobbek Proceedings of the National Academy of Sciences 2013, 110, 12625–12630, 10.1073/pnas.1302144110

72 Frontiers, Opportunities and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation A. Apple, J. Bercaw, A. Bocarly, H. Dobbek, D. Dubois, M. Dupuis, J. Ferry, E. Fujita, R. Hille, P. Kenis, C. Kerfeld, R. Morris, C. Peden, A. Portis, S. Ragsdale, T. Rauchfuss, J. Reek, L. Seefeldt, R. Thauer, G. Waldrop Chemical Reviews 2013, 113, 6621–6658, 10.1021/cr300463y

71 Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates L. Zámostná, M. Ahrens, T. Braun Journal of Fluorine Chemistry 2013, 155, 132–142, 10.1016/j.jfluchem.2013.05.021

70 α-Dialdimine Complexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen and Dihydrogen A. Eiβler, P. Kläring, F. Emmerling, T. Braun European Journal of Inorganic Chemistry 2013, 2013, 4775–4788, 10.1002/ejic.201300625

69 Hybrid hierarchical patterns of gold nanoparticles and poly(ethylene glycol) microstructures J. Chen, M. Arafeh, A. Guiet, D. Felkel, A. Loebus, S. M. Kelleher, A. Fischer, M. C. Lensen Journal of Materials Chemistry C 2013, 1, 7709–7715, 10.1039/C3TC30811A

68 Energy, Equipment and Dost Savings by Using a Membrane Unit in an Amine-Based Absorption Process for CO2 Removal S. Song, E. Esche, S. Stünkel, T. Brinkmann, J. Wind, S. Shishatskiy, G. Wozny Chemical Engineering and Technology 2013, 85, 1221–1227, 10.1002/cite.201200242

67 Resonance Raman Characterization of the Ammonia-Generated Oxo Intermediate of Cytochrome c Oxidase from Paracoccus denitrificans J. Kozuch, I. von der Hocht, F. Hilbers, H. Michel, I. M. Weidinger Biochemistry 2013, 52, 6197–6202, 10.1021/bi400535m

66 Potential-Dependent Surface-Enhanced Resonance Raman Spectroscopy at Nanostructured TiO2: A Case Study on Cytochrome b5 X. X. Han, C. Köhler, J. Kozuch, U. Kuhlmann, L. Paasche, A. Sivanesan, I. M. Weidinger, P. Hildebrandt Small 2013, 10.1002/smll.201301070

65 Modulation of direct electron transfer of cytochrome c by use of a molecularly imprinted thin film M. Bosserdt, N. Gajovic-Eichelman, F. W. Scheller Analytical and Bioanalytical Chemistry 2013, 405, 6437–6444, 10.1007/s00216-013-7009-8

64 A Biosensor for Aromatic Aldehydes Comprising the Mediator Dependent PaoABC-Aldehyde Oxidoreductase A. Badalyan, M. Neumann-Schaal, S. Leimkühler, U. Wollenberger Electroanalysis The Journal of Physical Chemistry C 2013, 25, 101–108, 10.1002/elan.201200362

63 Tunable Electric Field Enhancement and Redox Chemistry on TiO2 Island Films via Covalent Attachment to Ag or Au Nanostructures A. Sivanesan, K. H. Ly, W. Adamkiewicz, K. Stiba, S. Leimkühler, I. M. Weidinger The Journal of Physical Chemistry C 2013, 117, 11866–11872, 10.1021/jp4032578

62 Bioelectrocatalysis at mesoporous antimony doped tin oxide electrodes-Electrochemical characterization and direct enzyme communication S. Frasca, A. Molero Milan, A. Guiet, C. Goebel, F. Pérez-Caballero, K. Stiba, S. Leimkühler, A. Fischer, U. Wollenberger Electrochimica Acta Biochimica et Biophysica Acta (BBA) - Bioenergetics 2013, 110, 172–180, 10.1016/j.electacta.2013.03.144

61 Molybdenum enzymes, their maturation and molybdenum cofactor biosynthesis in Escherichia coli C. Iobbi-Nivol, S. Leimkühler Biochimica et Biophysica Acta (BBA) - Bioenergetics 2013, 1827, 1086–1101, 10.1016/j.bbabio.2012.11.007

60 The oxygen-tolerant and NAD+-dependent formate dehydrogenase from is able to catalyze the reduction of CO2 to formate T. Hartmann, S. Leimkühler FEBS Journal 2013, 280, 6083–6096, 10.1111/febs.12528

59 Identification of a bis-molybdopterin intermediate in molybdenum cofactor biosynthesis in Escherichia coli S. Reschke, K. G. V. Sigfridsson, P. Kaufmann, N. Leidel, S. Horn, K. Gast, C. Schulzke, M. Haumann, S. Leimkuehler Journal of Biological Chemistry 2013, 288, 29736–29745, 10.1074/jbc.M113.497453

58 Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations R. Kretschmer, M. Schlangen, H. Schwarz ChemPlusChem 2013, 78, 952–958, 10.1002/cplu.201300138

57 Towards an Understanding of Channelrhodopsin Function: Simulations Lead to Novel Insights of the Channel Mechanism H. C. Watanabe, K. Welke, D. J. Sindhikara, P. Hegemann, M. Elstner Journal of Molecular Biology 2013, 425, 1795–1814, 10.1016/j.jmb.2013.01.033

56 Genetically encoded calcium indicators for multi-color neural activity imaging and combination with optogenetics J. Akerboom, N. Carreras Calderón, L. Tian, S. Wabnig, M. Prigge, J. Tolö, A. Gordus, M. B. Orger, K. E. Severi, J. J. Macklin, R. Patel, S. R. Pulver, T. J. Wardill, E. Fischer, C. Schüler, T. W. Chen, K. S. Sarkisyan, J. S. Marvin, C. I. Bargmann, D. S. Frontiers in Molecular Neuroscience 2013, 6, 1–29, 10.3389/fnmol.2013.00002

55 From channelrhodopsins to optogenetics P. Hegemann, G. Nagel EMBO Molecular Medicine 2013, 5, 173–176, 10.1002/emmm.201202387

54 Optogenetic Modulation of an Adenylate Cyclase in Toxoplasma gondii Demonstrates a Requirement of the Parasite cAMP for Host-Cell Invasion and Stage Differentiation A. Hartmann, R. D. Arroyo-Olarte, K. Imkeller, P. Hegemann, R. Lucius, N. Gupta Journal of Biological Chemistry 2013, 288, 13705–13717, 10.1074/jbc.M113.465583

53 Direct methane oxidation over Pt-modified nitrogen-doped carbons M. Soorholtz, R. J. White, T. Zimmermann, M. M. Titirici, M. Antonietti, R. Palkovits, F. Schüth Chemical Communications Journal of Materials Chemistry A 2013, 49, 240–242, 10.1039/c2cc36232e

52 Mesoporous nitrogen-doped carbon for copper-mediated Ullmann-type C-O/-N/-S cross-coupling reactions P. Zhang, J. Yuan, H. Li, X. Liu, X. Xu, M. Antonietti, Y. Wang RSC Advances Journal of Materials Chemistry A 2013, 3, 1890–1895, 10.1039/c2ra22559j

51 On the Way to Artificial Photosynthesis: Simple Materials and System Designs for Photoelectrodes M. Antonietti Angewandte Chemie International Edition Journal of Materials Chemistry A 2013, 52, 1086–1087, 10.1002/anie.201207937

50 Surface Area Control and Photocatalytic Activity of Conjugated Microporous Poly(benzothiadiazole) Networks K. Zhang, D. Kopetzki, P. H. Seeberger, M. Antonietti, F. Vilela Angewandte Chemie International Edition Journal of Materials Chemistry A 2013, 52, 1432–1436, 10.1002/anie.201207163

49 Tunable nitrogen-doped carbon aerogels as sustainable electrocatalysts in the oxygen reduction reaction S. A. Wohlgemuth, T. P. Fellinger, P. Jäker, M. Antonietti Journal of Materials Chemistry A 2013, 1, 4002–4009, 10.1039/c3ta10352h

48 “Salt Templating”: A Simple and Sustainable Pathway toward Highly Porous Functional Carbons from Ionic Liquids N. Fechler, T. P. Fellinger, M. Antonietti Advanced Materials Scientific Reports 2013, 25, 75–79, 10.1002/adma.201203422

47 Electro- and Photochemical Water Oxidation on Ligand-free Co3O4 Nanoparticles with Tunable Sizes M. Grzelczak, J. Zhang, J. Pfrommer, J. Hartmann, M. Driess, M. Antonietti, X. Wang ACS Catalysis Scientific Reports 2013, 3, 383–388, 10.1021/cs3007523

46 Facilitating room-temperature Suzuki coupling reaction with light: Mott-Schottky photocatalyst for C-C-coupling X. H. Li, M. Baar, S. Blechert, M. Antonietti Scientific Reports 2013, 3, 10.1038/srep01743

45 Bio-inspired NADH regeneration by carbon nitride photocatalysis using diatom templates J. Liu, M. Antonietti Energy & Environmental Science 2013, 6, 1486–1493, 10.1039/c3ee40696b

44 Improving Carbon Nitride Photocatalysis by Supramolecular Preorganization of Monomers M. Shalom, S. Inal, C. Fettkenhauer, D. Neher, M. Antonietti Journal of the American Chemical Society 2013, 135, 7118–7121, 10.1021/ja402521s

43 Chemical Conversion of Sugars to Lactic Acid by Alkaline Hydrothermal Processes D. Esposito, M. Antonietti ChemSusChem 2013, 6, 989–992, 10.1002/cssc.201300092

42 Iron-Catalyzed Ring-Closing Depolymerization of Poly(tetrahydrofuran) S. Enthaler, A. Trautner ChemSusChem 2013, 6, 1334–1336, 10.1002/cssc.201300380

41 Dual functionality of formamidine polymers, as ligands and as bases, in ruthenium-catalysed hydrogen evolution from formic acid S. Enthaler, H. Junge, A. Fischer, A. Kammer, S. Krackl, J. D. Epping Polymer Chemistry 2013, 4, 2741– 10.1039/C3PY00120B

40 Nickel-catalyzed hydrodehalogenation of aryl halides M. Weidauer, E. Irran, C. I. Someya, M. Haberberger, S. Enthaler Journal of Organometallic Chemistry 2013, 729, 53–59, 10.1016/j.jorganchem.2013.01.014

39 Nickel-catalyzed Hydrodecyanation of Carbon-Cyano Bonds M. Weidauer, C. I. Someya, E. Irran, S. Enthaler Asian Journal of Organic Chemistry 2013, 2, 150–156, 10.1002/ajoc.201200185

38 Nickel-catalyzed C(sp2)-C(sp2) Cross Coupling Reactions of Sulfur-Functionalities and Grignard Reagents C. I. Someya, M. Weidauer, S. Enthaler Catalysis Letters 2013, 143, 424–431, 10.1007/s10562-013-0979-5

37 Application of a Bis(silylene) Nickel Complex as Precatalyst in C-C Bond Formation Reactions C. I. Someya, M. Haberberger, W. Wang, S. Enthaler, S. Inoue Chemistry Letters 2013, 42, 286–288, 10.1246/cl.2013.286

36 Application of fatty acid chlorides in the iron-catalyzed depolymerization of polyethers S. Enthaler European Journal of Lipid Science and Technology 2013, 115, 239–245, 10.1002/ejlt.201200301

35 Single and Double N-H Bond Activation of Ammonia by [Al2O3 ].+ : Room Temperature Formation of the Aminyl Radical and Nitrene R. Kretschmer, Z. C. Wang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 52, 9513–9517, 10.1002/anie.201302506

34 Thermal Methane Activation by a Binary V-Nb Transition-Metal Oxide Cluster Cation: A Further Example for the Crucial Role of Oxygen-Centered Radicals Z. C. Wang, J. W. Liu, M. Schlangen, T. Weiske, D. Schröder, J. Sauer, H. Schwarz Chemistry - A European Journal 2013, 19, 11496–11501, 10.1002/chem.201302133

33 Isomer-Selective Thermal Activation of Methane in the Gas Phase by [HMO]+ and [M(OH)]+ (M=Ti and V) R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 52, 6097–6101, 10.1002/anie.201300900

32 Particle shape optimization by changing from an isotropic to an anisotropic nanostructure: preparation of highly active and stable supported Pt catalysts in microemulsions R. Y. Parapat, M. Wijaya, M. Schwarze, S. Selve, M. Willinger, R. Schomäcker Nanoscale 2013, 5, 796–805, 10.1039/c2nr32122j

31 Interaction of Probe Molecules with Bridging Hydroxyls of Two-Dimensional Zeolites: A Surface Science Approach A. Boscoboinik, X. Yu, E. Emmez, B. Yang, S. Shaikhutdinov, F. D. Fischer, J. Sauer, H. J. Freund J. Phys. Chem. Lett. J. Phys. Chem. C 2013, 117, 13547–13556, 10.1021/jp405533s

30 Full-Length Structure of a Sensor Histidine Kinase Pinpoints Coaxial Coiled Coils as Signal Transducers and Modulators R. P. Diensthuber, M. Bommer, T. Gleichmann, A. Möglich Structure 2013, 21, 1127–1136, 10.1016/j.str.2013.04.024

29 Magnetic Silver Hybrid Nanoparticles for Surface-Enhanced Resonance Raman Spectroscopic Detection and Decontamination of Small Toxic Molecules X. X. Han, A. M. Schmidt, G. Marten, A. Fischer, I. M. Weidinger, P. Hildebrandt ACS Nano 2013, 7, 3212–3220, 10.1021/nn305892j

28 Parallelisiertes System zum Screening und zur Charakterisierung von Biokatalysatoren E. Lyagin, A. Drews, M. Kraume GIT Labor-Fachzeitschrift 2013, 5, 322–324,

27 Crystal structure of pre-activated arrestin p44 Y. J. Kim, K. P. Hofmann, O. P. Ernst, P. Scheerer, H. W. Choe, M. E. Sommer Nature 2013, 497, 142–146, 10.1038/nature12133

26 Photolytic C-H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent T. Braun, B. Rabay, J. Falkenhagen Dalton Transactions 2013, 42, 8058–8065, 10.1039/c3dt33022b

25 Crystal structure of a prokaryotic (6-4) photolyase with an Fe-S cluster and a 6,7-dimethyl-8-ribityllumazine antenna chromophore F. Zhang, P. Scheerer, I. Oberpichler, T. Lamparter, N. Krauß Proceedings of the National Academy of Sciences of the United States of America 2013, 110, 7217–7222, 10.1073/pnas.1302377110

24 Mechanistic Aspects of Gas-Phase Hydrogen-Atom Transfer from Methane to [CO].+ and [SiO].+: Why Do They Differ? H. Schwarz, N. Dietl, A. Troiani, M. Schlangen, O. Ursini, G. Angelini, Y. Apeloig, G. de Petris Chemistry - A European Journal 2013, 19, 6662–6669, 10.1002/chem.201204157

23 Structure, function and biosynthesis of O2-tolerant hydrogenases J. Fritsch, O. Lenz, B. Friedrich Nature Reviews Microbiology 2013, 11, 106–114, 10.1038/nrmicro2940

22 Calculation of the high pressure phase equilibrium in hyperbranched polymer systems with the Lattice-Cluster Theory K. Langenbach, S. Enders, C. Browarzik, D. Browarzik Journal of Chemical Thermodynamics 2013, 59, 107–113, 10.1016/j.jct.2012.12.002

21 Structure and Chemistry of the Heteronuclear Oxo-Cluster [VPO4].+: A Model System for the Gas-Phase Oxidation of Small Hydrocarbons H. Schwarz, N. Dietls, T. Wende, K. Chen, L. Jiang, M. Schlangen, X. Zhao, K. R. Asmis Journal of the American Chemical Society 2013, 135, 3711–3721, 10.1021/ja400198y

20 Lithium-molybdate nanostructures grown on the Mo(001) surface F. Stavale, N. Nilius, H. J. Freund Surface Science 2013, 609, 78–84, 10.1016/j.susc.2012.11.007

19 Steering the Growth of Metal Ad-particles via Interface Interactions Between a MgO Thin Film and a Mo Support S. Benedetti, F. Stavale, S. Valeri, C. Noguera, H. J. Freund, J. Goniakowski, N. Nilius Advanced Functional Materials 2013, 23, 78–80, 10.1002/adfm.201201502

18 Facile Low-Temperature Approach to Tin-Containing ZnO Nanocrystals with Tunable Tin Concentrations Using Heterobimetallic Sn/Zn Single-Source Precursors M. Driess, M. Tsaroucha, Y. Aksu, J. D. Epping ChemPlusChem 2013, 78, 62–69, 10.1002/cplu.201200259

17 New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules M. Driess, B. Blom, M. Stoelzel Chemistry - A European Journal 2013, 19, 40–62, 10.1002/chem.201203072

16 Nonheme oxoiron( IV ) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity D. Wang, K. Ray, M. J. Collins, E. R. Farquhar, J. R. Frisch, L. Gomez, T. A. Jackson, M. Kerscher, A. Waleska, P. Comba, M. Costas, L. Que, Jr. Chemical Science 2013, 4, 282–291, 10.1039/C2SC21318D

15 Ribosomally synthesized and posttranslationally modified natural products: overview and recommendations for a universal nomenclature E. Dittmann, R. Süssmuth Natural Product Reports 2013, 30, 108–160, 10.1039/c2np20085f

14 Cyanobacterial Toxins: Biosynthetic Routes and Evolutionary Routes E. Dittmann FEMS Microbiologial Reviews 2013, 37, 23–43, 10.1111/1574-6976.12000

13 Hydride Reactivity of NiII-X-NiII-Entities: Mixed-valent Hydrido Complexes and Reversible Metal Reduction H. Gehring, R. Metzinger, C. Herwig, J. Intemann, S. Harder, C. Limberg Chemistry - A European Journal 2013, 19, 1629–1636, 10.1002/chem.201203201

12 Resolving kinetics and dynamics of a catalytic reaction inside a fixed bed reactor by combined kinetic and spectroscopic profiling M. Geske, O. Korup, R. Horn Catalysis Science and Technology 2013, 3, 169–175, 10.1039/c2cy20489d

11 Catalytic partial oxidation of methane on platinum investigated by spatial reactor profiles, spatially resolved spectroscopy, and microkinetic modeling O. Korup, C. F. Goldsmith, G. Weinberg, M. Geske, T. Kandemir, R. Schlögl, R. Horn Journal of Catalysis 2013, 297, 1–16, 10.1016/j.jcat.2012.08.022

10 C-N coupling in the gas-phase reactions of ammonia and [M(CH)]+ (M = Ni, Pd, Pt): a combined experimental/computational exercise H. Schwarz, R. Kretschmer, M. Schlangen Dalton Transactions 2013, 42, 4153–4162, 10.1039/c3dt32596b

9 Heterologous expression and engineering studies of labyrinthopeptins, new class III lantibiotics from Actinomadura namibiensis J. M. Krawczyk, G. H. Völler, B. Krawczyk, J. Kretz, M. Broenstrup, R. D. Süssmuth Chemistry & Biology 2013, 20, 111–122, 10.1016/j.chembiol.2012.10.023

8 Gas-Phase Reactions of Cationic Vanadium-Phosphorus Oxide Clusters with C2Hx (x = 4, 6): A DFT-Based Analysis of Reactivity Patterns N. Dietl, X. Zhang, C. van der Linde, M. K. Beyer, M. Schlangen Chemistry - A European Journal 2013, 19, 3017–3028, 10.1002/chem.201203050

7 One-Pot Synthesis of Supported, Nanochristalline Nickel Manganese Oxide for Dry Reforming of Methane X. Xie, T. Otremba, P. Littlewood, R. Schomäcker, A. Thomas ACS Catalysis 2013, 3, 224–229, 10.1021/cs3003963

6 The rise of the zinc age in homogeneous catalysis? S. Enthaler ACS Catalysis 2013, 3, 150–158, 10.1021/cs300685q

5 Straightforward Iron-catalyzed Synthesis of Vinylboronates by the Hydroboration of Alkynes M. Haberberger, S. Enthaler Chemistry - An Asian Journal 2013, 8, 50–54, 10.1002/asia.201200931

4 Techno-economic analysis of integrating the methane oxidative coupling and methane reforming processes H. R. Godini, S. Xiao, S. Jaso, S. Stünkel, D. Salerno, S. Nghiem Xuan, S. Song, G. Wozny Fuel Processing Technology 2013, 106, 684–694, 10.1016/j.fuproc.2012.10.002

3 A Heterobimetallic Approach To Stabilize the Elusive Disulfur Radical Trianion ("Subsulfide") S. Yao, P. Hrobárik, F. Meier, R. Rudolph, E. Bill, E. Irran, M. Kaupp, M. Driess Chemistry - A European Journal 2013, 3, 1246–1253, 10.1002/chem.201203642

2 Combining Spectroscopy and Theory to Evaluate Structural Models of Metalloenzymes: A Case Study on the Soluble [NiFe] Hydrogenase from Ralstonia eutropha M. Horch, Y. Rippers, M. A. Mroginski, P. Hildebrandt, I. Zebger ChemPhysChem 2013, 14, 185–191, 10.1002/cphc.201200853

1 On the Origin of the Surprisingly Sluggish Redox Reaction of the N2O/CO Couple Mediated by [Y2O2]+. and [YAlO2]+. Cluster Ions in the Gas Phase H. Schwarz, J. B. Ma, Z. C. Wang, M. Schlangen, S. G. He Angewandte Chemie International Edition 2013, 52, 1226–1230, 10.1002/anie.201208559