Publications 2017

Number of records: 162

162 Phylogenomic Analysis of the Microviridin Biosynthetic Pathway Coupled with Targeted Chemo-Enzymatic Synthesis Yields Potent Protease Inhibitors M. N. Ahmed, E. Reyna-González, B. Schmid, V. Wiebach, R. D. Süssmuth, E. Dittmann, D. P. Fewer ACS Chemical Biology 2017, 12, 1538–1546, 10.1021/acschembio.7b00124

161 Prerequisites of Isopeptide Bond Formation in Microcystin Biosynthesis S. Meyer, A. Mainz, J. C. Kehr, R. D. Süssmuth, E. Dittmann ChemBioChem 2017, 18, 2376–2379, 10.1002/cbic.201700389

160 Tuning Product Selectivity for Aqueous CO2Reduction with a Mn(bipyridine)-pyrene Catalyst Immobilized on a Carbon Nanotube Electrode B. Reuillard, K. H. Ly, T. E. Rosser, M. F. Kuehnel, I. Zebger, E. Reisner Journal of the American Chemical Society 2017, 139, 14425–14435, 10.1021/jacs.7b06269

159 Reaction dynamics of the chimeric channelrhodopsin C1C2 Y. Hontani, M. Marazzi, K. Stehfest, T. Mathes, I. H. M. van Stokkum, M. Elstner, P. Hegemann, J. T. M. Kennis Scientific Reports 2017, 7, 10.1038/s41598-017-07363-w

158 Molecular determinants of proton selectivity and gating in the red-light activated channelrhodopsin Chrimson J. Vierock, C. Grimm, N. Nitzan, P. Hegemann Scientific Reports 2017, 7, 10.1038/s41598-017-09600-8

157 The form and function of channelrhodopsin K. Deisseroth, P. Hegemann Science 2017, 357, 10.1126/science.aan5544

156 The two parallel photocycles of theChlamydomonassensory photoreceptor histidine kinase rhodopsin 1 M. Luck, P. Hegemann Journal of Plant Physiology 2017, 217, 77–84, 10.1016/j.jplph.2017.07.008

155 Proton transfer reactions in the red light-activatable channelrhodopsin variant ReaChR and their relevance for its function J. C. D. Kaufmann, B. S. Krause, C. Grimm, E. Ritter, P. Hegemann, F. J. Bartl Journal of Biological Chemistry 2017, 292, 14205–14216, 10.1074/jbc.M117.779629

154 Complex Photochemistry within the Green-Absorbing Channelrhodopsin ReaChR B. S. Krause, C. Grimm, J. C. D. Kaufmann, F. Schneider, T. P. Sakmar, F. J. Bartl, P. Hegemann Biophysical Journal 2017, 112, 1166–1175, 10.1016/j.bpj.2017.02.001

153 CODH-IV: A High-Efficiency CO-Scavenging CO Dehydrogenase with Resistance to O2 L. Domnik, M. Merrouch, S. Goetzl, J. H. Jeoung, C. Léger, S. Dementin, V. Fourmond, H. Dobbek Angewandte Chemie International Edition 2017, 56, 15466–15469, 10.1002/anie.201709261

152 A combined experimental and theoretical spectroscopic protocol for determination of the structure of heterogeneous catalysts: developing the information content of the resonance Raman spectra of M1 MoVOx A. Kubas, J. Noak, A. Trunschke, R. Schlögl, F. Neese, D. Maganas Chemical Science 2017, 8, 6338–6353, 10.1039/c7sc01771e

151 The Impact of the Bulk Structure on Surface Dynamics of Complex Mo–V-based Oxide Catalysts A. Trunschke, J. Noack, S. Trojanov, F. Girgsdies, T. Lunkenbein, V. Pfeifer, M. Hävecker, P. Kube, C. Sprung, F. Rosowski, R. Schlögl ACS Catalysis 2017, 7, 3061–3071, 10.1021/acscatal.7b00130

150 Isotope Studies in Oxidation of Propane over Vanadium Oxide P. Kube, B. Frank, R. Schlögl, A. Trunschke ChemCatChem 2017, 9, 3446–3455, 10.1002/cctc.201700847

149 Prospects of In vivo Incorporation of Non-canonical Amino Acids for the Chemical Diversification of Antimicrobial Peptides T. Baumann, J. H. Nickling, M. Bartholomae, A. Buivydas, O. P. Kuipers, N. Budisa Frontiers in Microbiology 2017, 8, 10.3389/fmicb.2017.00124

148 Global substitution of hemeproteins with noncanonical amino acids inEscherichia coliwith intact cofactor maturation machinery J. S. Völler, T. M. Thi To, H. Biava, B. Koksch, N. Budisa Enzyme and Microbial Technology 2017, 106, 55–59, 10.1016/j.enzmictec.2017.06.014

147 Peptidyl-Prolyl Model Study: How Does the Electronic Effect Influence the Amide Bond Conformation? P. K. Mykhailiuk, V. Kubyshkin, T. Bach, N. Budisa The Journal of Organic Chemistry 2017, 82, 8831–8841, 10.1021/acs.joc.7b00803

146 The Regioselective Synthesis of o-Nitrobenzyl DOPA Derivatives T. Schneider, J. Martin, P. Durkin, V. Kubyshkin, N. Budisa Synthesis 2017, 49, 2691–2699, 10.1055/s-0036-1588766

145 Hydrolysis, polarity, and conformational impact of C-terminal partially fluorinated ethyl esters in peptide models V. Kubyshkin, N. Budisa Beilstein Journal of Organic Chemistry 2017, 13, 2442–2457, 10.3762/bjoc.13.241

144 Amide rotation trajectories probed by symmetry V. Kubyshkin, N. Budisa Organic & Biomolecular Chemistry 2017, 15, 6764–6772, 10.1039/C7OB01421J

143 Selective19F-Labeling of Functionalized Carboxylic Acids with Difluoromethyl Diazomethane (CF2HCHN2) P. K. Mykhailiuk, I. Kishko, V. Kubyshkin, N. Budisa, J. Cossy Chemistry - A European Journal 2017, 23, 13279–13283, 10.1002/chem.201703446

142 Deciphering the Fluorine Code—The Many Hats Fluorine Wears in a Protein Environment A. A. Berger, J. S. Völler, N. Budisa, B. Koksch Accounts of Chemical Research 2017, 50, 2093–2103, 10.1021/acs.accounts.7b00226

141 Biocatalysis with Unnatural Amino Acids: Enzymology Meets Xenobiology F. Agostini, J. S. Völler, B. Koksch, C. G. Acevedo-Rocha, V. Kubyshkin, N. Budisa Angewandte Chemie International Edition 2017, 56, 9680–9703, 10.1002/anie.201610129

140 Synthesis and Structures of Gallium-β-Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex R. Laubenstein, M. Ahrens, T. Braun Zeitschrift für anorganische und allgemeine Chemie 2017, 643, 1723–1729, 10.1002/zaac.201700276

139 Synthesis and reactivity of a cationic palladium complex as possible intermediate in a Suzuki-Miyaura cross-coupling reaction J. Kohlmann, T. Braun Journal of Fluorine Chemistry 2017, 203, 140–145, 10.1016/j.jfluchem.2017.08.003

138 Et3GeH versus Et3SiH: controlling reaction pathways in catalytic C–F bond activations at a nanoscopic aluminum chlorofluoride G. Meißner, D. Dirican, C. Jäger, T. Braun, E. Kemnitz Catalysis Science & Technology 2017, 7, 3348–3354, 10.1039/c7cy00845g

137 Four-electron reduction of dioxygen to water by a trinuclear copper complex X. Engelmann, E. R. Farquhar, J. England, K. Ray Inorganica Chimica Acta 2017, 10.1016/j.ica.2017.11.014

136 Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex B. Wang, Y. M. Lee, W. Y. Tcho, S. Tussupbayev, S. T. Kim, Y. Kim, M. S. Seo, K. B. Cho, Y. Dede, B. C. Keegan, T. Ogura, S. H. Kim, T. Ohta, M. H. Baik, K. Ray, J. Shearer, W. Nam Nature Communications 2017, 8, 14839– 10.1038/ncomms14839

135 A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand I. Monte Pérez, X. Engelmann, Y. M. Lee, M. Yoo, E. Kumaran, E. R. Farquhar, E. Bill, J. England, W. Nam, M. Swart, K. Ray Angewandte Chemie International Edition 2017, 56, 14384–14388, 10.1002/anie.201707872

134 Multilayered lipid membrane stacks for biocatalysis using membrane enzymes G. R. Heath, M. Li, H. Rong, V. Radu, S. Frielingsdorf, O. Lenz, J. N. Butt, L. J. C. Jeuken Advanced Functional Materials 2017, 27, 1606265– 10.1002/adfm.201606265

133 A High-Throughput Composite Catalyst based on Nickel Carbon Cubes for the Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran C. M. Mani, M. Braun, V. Molinari, M. Antonietti, N. Fechler ChemCatChem 2017, 9, 3388–3394, 10.1002/cctc.201700506

132 Visible-Light-Irradiated Graphitic Carbon Nitride Photocatalyzed Diels-Alder Reactions with Dioxygen as Sustainable Mediator for Photoinduced Electrons Y. Zhao, M. Antonietti Angewandte Chemie International Edition 2017, 56, 9336–9340, 10.1002/anie.201703438

131 A continuous flow process for the production of 2,5-dimethylfuran from fructose using (non-noble metal based) heterogeneous catalysis M. Braun, M. Antonietti Green Chemistry 2017, 19, 3813–3819, 10.1039/C7GC01055A

130 Pharmacological and pharmacokinetic properties of lanthipeptides undergoing clinical studies E. L. Ongey, H. Yassi, S. Pflugmacher, P. Neubauer Biotechnology Letters 2017, 39, 473–482, 10.1007/s10529-016-2279-9

129 O2Activation on Ceria Catalysts-The Importance of Substrate Crystallographic Orientation C. Yang, X. Yu, S. Heißler, P. G. Weidler, A. Nefedov, Y. Wang, C. Wöll, T. Kropp, J. Paier, J. Sauer Angewandte Chemie International Edition 2017, 56, 16399–16404, 10.1002/anie.201709199

128 Activation of Small Molecules at Nickel(I) Moieties P. Zimmermann, C. Limberg Journal of the American Chemical Society 2017, 139, 4233–4242, 10.1021/jacs.6b12434

127 O2activation at a trispyrazolylborato nickel(ii) malonato complex S. Hoof, M. Sallmann, C. Herwig, B. Braun-Cula, C. Limberg Dalton Transactions 2017, 46, 16792–16795, 10.1039/c7dt04056c

126 Spectroscopic identification of active sites for the oxygen evolution reaction on iron-cobalt oxides R. D. L. Smith, C. Pasquini, S. Loos, P. Chernev, K. Klingan, P. Kubella, M. R. Mohammadi, D. Gonzalez-Flores, H. Dau Nature Communications 2017, 8, 10.1038/s41467-017-01949-8

125 Ligand binding at the A-cluster in full-length or truncated acetyl-CoA synthase studied by X-ray absorption spectroscopy P. Schrapers, J. Ilina, C. M. Gregg, S. Mebs, J. H. Jeoung, H. Dau, H. Dobbek, M. Haumann PLOS ONE 2017, 12, 10.1371/journal.pone.0171039

124 Photo-assisted water oxidation by high-nuclearity cobalt-oxo cores: tracing the catalyst fate during oxygen evolution turnover M. Natali, I. Bazzan, S. Goberna-Ferrón, R. Al-Oweini, M. Ibrahim, B. S. Bassil, H. Dau, F. Scandola, J. R. Galán-Mascarós, U. Kortz, A. Sartorel, I. Zaharieva, M. Bonchio Green Chemistry 2017, 19, 2416–2426, 10.1039/c7gc00052a

123 Tracking Catalyst Redox States and Reaction Dynamics in Ni–Fe Oxyhydroxide Oxygen Evolution Reaction Electrocatalysts: The Role of Catalyst Support and Electrolyte pH M. Görlin, J. Ferreira de Araújo, H. Schmies, D. Bernsmeier, S. Dresp, M. Gliech, Z. Jusys, P. Chernev, R. Kraehnert, H. Dau, P. Strasser Journal of the American Chemical Society 2017, 139, 2070–2082, 10.1021/jacs.6b12250

122 Dynamic real-time optimization under uncertainty of a hydroformylation mini-plant D. Müller, M. Illner, E. Esche, T. Pogrzeba, M. Schmidt, R. Schomäcker, L. T. Biegler, G. Wozny, J. U. Repke Computers & Chemical Engineering 2017, 106, 836–848, 10.1016/j.compchemeng.2017.01.041

121 Synthesis and Granulation of a 5A Zeolite-Based Molecular Sieve and Adsorption Equilibrium of the Oxidative Coupling of Methane Gases L. Garcı́a, Y. A. Poveda, M. Khadivi, G. Rodríguez, O. Görke, E. Esche, H. R. Godini, G. Wozny, A. Orjuela Journal of Chemical & Engineering Data 2017, 62, 1550–1557, 10.1021/acs.jced.7b00061

120 MOSAIC - Enabling Large-Scale Equation-Based Flow Sheet Optimization E. Esche, C. Hoffmann, M. Illner, D. Müller, S. Fillinger, G. Tolksdorf, H. Bonart, G. Wozny, J. U. Repke Chemie Ingenieur Technik 2017, 89, 620–635, 10.1002/cite.201600114

119 Improving Interoperability of Engineering Tools - Data Exchange in Plant Design S. Fillinger, H. Bonart, W. Welscher, E. Esche, J. U. Repke Chemie Ingenieur Technik 2017, 89, 1454–1463, 10.1002/cite.201700032

118 Analysis and Decomposition for Improved Convergence of Nonlinear Process Models in Chemical Engineering S. Bublitz, E. Esche, G. Tolksdorf, V. Mehrmann, J. U. Repke Chemie Ingenieur Technik 2017, 89, 1503–1514, 10.1002/cite.201700041

117 Eco-fabrication of hierarchical porous silica monoliths by ice-templating of rice husk ash A. Bahrami, U. Simon, N. Soltani, S. Zavareh, J. Schmidt, M. I. Pech-Canul, A. Gurlo Green Chemistry 2017, 19, 188–195, 10.1039/c6gc02153k

116 Macroporous polymer-derived SiO 2 /SiOC monoliths freeze-cast from polysiloxane and amorphous silica derived from rice husk N. Soltani, U. Simon, A. Bahrami, X. Wang, S. Selve, J. D. Epping, M. I. Pech-Canul, M. F. Bekheet, A. Gurlo Journal of the European Ceramic Society 2017, 37, 4809–4820, 10.1016/j.jeurceramsoc.2017.06.023

115 Iron Exsolution Phenomena in Lanthanum Strontium Ferrite SOFC Anodes T. Götsch, C. Praty, M. Grünbacher, L. Schlicker, M. F. Bekheet, A. Doran, A. Gurlo, M. Tada, H. Matsui, N. Ishiguro, B. Kloetzer, S. Penner ECS Transactions 2017, 78, 1327–1341, 10.1149/07801.1327ecst

114 Surface chemistry and stability of metastable corundum-type In2O3 E. M. Köck, M. Kogler, C. Zhuo, L. Schlicker, M. F. Bekheet, A. Doran, A. Gurlo, S. Penner Physical Chemistry Chemical Physics 2017, 19, 19407–19419, 10.1039/c7cp03632a

113 Surface chemistry of pure tetragonal ZrO2and gas-phase dependence of the tetragonal-to-monoclinic ZrO2transformation E. M. Köck, M. Kogler, T. Götsch, L. Schlicker, M. F. Bekheet, A. Doran, A. Gurlo, B. Klötzer, B. Petermüller, D. Schildhammer, N. Yigit, S. Penner Dalton Transactions 2017, 46, 4554–4570, 10.1039/c6dt04847a

112 Protein Dynamics in the Reductive Activation of a B12-Containing Enzyme S. Goetzl, C. Teutloff, T. Werther, S. E. Hennig, J. H. Jeoung, R. Bittl, H. Dobbek Biochemistry 2017, 56, 5496–5502, 10.1021/acs.biochem.7b00477

111 Theoretical evidence for unexpected O-rich phases at corners of MgO surfaces S. Bhattacharya, D. Berger, K. Reuter, L. M. Ghiringhelli, S. V. Levchenko Physical Review Materials 2017, 1, 10.1103/PhysRevMaterials.1.071601

110 Effective intermediate-spin iron in O2-transporting heme proteins N. Schuth, S. Mebs, D. Huwald, P. Wrzolek, M. Schwalbe, A. Hemschemeier, M. Haumann Proceedings of the National Academy of Sciences 2017, 114, 8556–8561, 10.1073/pnas.1706527114

109 Surface enhanced resonance Raman spectroscopy of iron Hangman complexes on electrodes during electrocatalytic oxygen reduction: advantages and problems of common drycast methods R. Götz, H. K. Ly, P. Wrzolek, M. Schwalbe, I. M. Weidinger Dalton Transactions Dalton Transactions 2017, 46, 13220–13228, 10.1039/C7DT01174A

108 Trends and challenges for microporous polymers N. Chaoui, M. Trunk, R. Dawson, J. Schmidt, A. Thomas Chemical Society Reviews 2017, 46, 3302–3321, 10.1039/C7CS00071E

107 2D Porous Carbons prepared from Layered Organic-Inorganic Hybrids and their Use as Oxygen-Reduction Electrocatalysts S. Li, C. Cheng, H. W. Liang, X. Feng, A. Thomas Advanced Materials 2017, 29, 1700707– 10.1002/adma.201700707

106 Boosting electrochemical water oxidation through replacement of OhCo sites in cobalt oxide spinel with manganese P. W. Menezes, A. Indra, V. Gutkin, M. Driess Chemical Communications 2017, 53, 8018–8021, 10.1039/C7CC03749J

105 Stereoselective Transfer Semi-Hydrogenation of Alkynes toE-Olefins withN-Heterocyclic Silylene-Manganese Catalysts Y. P. Zhou, Z. Mo, M. P. Luecke, M. Driess Chemistry - A European Journal 2017, 23, 10.1002/chem.201705745

104 N-heterocyclic silylenes as powerful steering ligands in catalysis S. Raoufmoghaddam, Y. P. Zhou, Y. Wang, M. Driess Journal of Organometallic Chemistry 2017, 829, 2–10, 10.1016/j.jorganchem.2016.07.014

103 Boosting Visible-Light-Driven Photocatalytic Hydrogen Evolution with an Integrated Nickel Phosphide-Carbon Nitride System A. Indra, A. Acharjya, P. W. Menezes, C. Merschjann, D. Hollmann, M. Schwarze, M. Aktas, A. Friedrich, S. Lochbrunner, A. Thomas, M. Driess Angewandte Chemie International Edition 2017, 56, 1653–1657, 10.1002/anie.201611605

102 A facile corrosion approach to the synthesis of highly active CoOxwater oxidation catalysts A. Indra, P. W. Menezes, C. Das, C. Göbel, M. Tallarida, D. Schmeiβer, M. Driess Journal of Materials Chemistry A 2017, 5, 5171–5177, 10.1039/C6TA10650A

101 Cobalt-Catalyzed Regioselective Borylation of Arenes: N-Heterocyclic Silylene as an Electron Donor in the Metal-Mediated Activation of C−H Bonds H. Ren, Y. P. Zhou, Y. Bai, C. Cui, M. Driess Chemistry - A European Journal 2017, 23, 5663–5667, 10.1002/chem.201605937

100 Taming Silicon Congeners of CO and CO2: Synthesis of Monomeric SiIIand SiIVChalcogenide Complexes A. Burchert, R. Müller, S. Yao, C. Schattenberg, Y. Xiong, M. Kaupp, M. Driess Angewandte Chemie International Edition 2017, 56, 6298–6301, 10.1002/anie.201700530

99 From a Molecular 2Fe-2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting C. Panda, P. W. Menezes, C. Walter, S. Yao, M. E. Miehlich, V. Gutkin, K. Meyer, M. Driess Angewandte Chemie International Edition 2017, 56, 10506–10510, 10.1002/anie.201706196

98 Silylene-Nickel Promoted Cleavage of B−O Bonds: From Catechol Borane to the Hydroborylene Ligand T. J. Hadlington, T. Szilvási, M. Driess Angewandte Chemie International Edition 2017, 56, 7470–7474, 10.1002/anie.201702772

97 Alkaline electrochemical water oxidation with multi-shelled cobalt manganese oxide hollow spheres A. Indra, P. W. Menezes, C. Das, D. Schmeißer, M. Driess Chemical Communications 2017, 53, 8641–8644, 10.1039/C7CC03566G

96 Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application M. P. Luecke, D. Porwal, A. Kostenko, Y. P. Zhou, S. Yao, M. Keck, C. Limberg, M. Oestreich, M. Driess Dalton Transactions 2017, 46, 16412–16418, 10.1039/C7DT03301J

95 Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins Y. Wang, A. Kostenko, S. Yao, M. Driess Journal of the American Chemical Society 2017, 139, 13499–13506, 10.1021/jacs.7b07167

94 Insights intotrans-Ligand and Spin-Orbit Effects on Electronic Structure and Ligand NMR Shifts in Transition-Metal Complexes A. H. Greif, P. Hrobárik, M. Kaupp Chemistry - A European Journal 2017, 23, 9790–9803, 10.1002/chem.201700844

93 Four-Component Relativistic Density Functional Calculations of EPR Parameters for Model Complexes of Tungstoenzymes S. Gohr, P. Hrobárik, M. Kaupp The Journal of Physical Chemistry A 2017, 121, 9106–9117, 10.1021/acs.jpca.7b08768

92 The photocycle of orange carotenoid protein conceals distinct intermediates and asynchronous changes in the carotenoid and protein components E. G. Maksimov, N. N. Sluchanko, Y. B. Slonimskiy, E. A. Slutskaya, A. V. Stepanov, A. M. Argentova-Stevens, E. A. Shirshin, G. V. Tsoraev, K. E. Klementiev, O. V. Slatinskaya, E. P. Lukashev, T. Friedrich, V. Z. Paschenko, A. B. Rubin Scientific Reports 2017, 7, 10.1038/s41598-017-15520-4

91 Characterization of Frex as an NADH sensor for in vivo applications in the presence of NAD+ and at various pH values S. Wilkening, F. J. Schmitt, M. Horch, I. Zebger, O. Lenz, T. Friedrich Photosynthesis Research 2017, 133, 305–315, 10.1007/s11120-017-0348-0

90 Biophysical modeling of in vitro and in vivo processes underlying regulated photoprotective mechanism in cyanobacteria E. A. Shirshin, E. E. Nikonova, F. I. Kuzminov, N. N. Sluchanko, I. V. Elanskaya, M. Y. Gorbunov, V. V. Fadeev, T. Friedrich, E. G. Maksimov Photosynthesis Research 2017, 133, 261–271, 10.1007/s11120-017-0377-8

89 Deletion of the short N-terminal extension in OCP reveals the main site for FRP binding N. N. Sluchanko, Y. B. Slonimskiy, M. Moldenhauer, T. Friedrich, E. G. Maksimov FEBS Letters 2017, 591, 1667–1676, 10.1002/1873-3468.12680

88 Assembly of photoactive orange carotenoid protein from its domains unravels a carotenoid shuttle mechanism M. Moldenhauer, N. N. Sluchanko, D. Buhrke, D. V. Zlenko, N. N. Tavraz, F. J. Schmitt, P. Hildebrandt, E. G. Maksimov, T. Friedrich Photosynthesis Research 2017, 133, 327–341, 10.1007/s11120-017-0353-3

87 Interaction of the signaling state analog and the apoprotein form of the orange carotenoid protein with the fluorescence recovery protein M. Moldenhauer, N. N. Sluchanko, N. N. Tavraz, C. Junghans, D. Buhrke, M. Willoweit, L. Chiappisi, F. J. Schmitt, V. Vukojević, E. A. Shirshin, V. Y. Ponomarev, V. Z. Paschenko, M. Gradzielski, E. G. Maksimov, T. Friedrich Photosynthesis Research 2017, 135, 125–139, 10.1007/s11120-017-0346-2

86 Retinoschisin is linked to retinal Na/K-ATPase signaling and localization K. Plössl, M. Royer, S. Bernklau, N. N. Tavraz, T. Friedrich, J. Wild, B. H. F. Weber, U. Friedrich Molecular Biology of the Cell 2017, 28, 2178–2189, 10.1091/mbc.e17-01-0064

85 Fluorescent Labeling Preserving OCP Photoactivity Reveals Its Reorganization during the Photocycle E. G. Maksimov, N. N. Sluchanko, K. S. Mironov, E. A. Shirshin, K. E. Klementiev, G. V. Tsoraev, M. Moldenhauer, T. Friedrich, D. A. Los, S. I. Allakhverdiev, V. Z. Paschenko, A. B. Rubin Biophysical Journal 2017, 112, 46–56, 10.1016/j.bpj.2016.11.3193

84 The Unique Protein-to-Protein Carotenoid Transfer Mechanism E. G. Maksimov, N. N. Sluchanko, Y. B. Slonimskiy, K. S. Mironov, K. E. Klementiev, M. Moldenhauer, T. Friedrich, D. A. Los, V. Z. Paschenko, A. B. Rubin Biophysical Journal 2017, 113, 402–414, 10.1016/j.bpj.2017.06.002

83 Disruption of Ankyrin B and Caveolin-1 Interaction Sites Alters Na + ,K + -ATPase Membrane Diffusion C. Junghans, V. Vukojević, N. N. Tavraz, E. G. Maksimov, W. Zuschratter, F. J. Schmitt, T. Friedrich Biophysical Journal 2017, 113, 2249–2260, 10.1016/j.bpj.2017.08.053

82 Structural insights into the light-driven auto-assembly process of the water-oxidizing Mn4CaO5-cluster in photosystem II M. Zhang, M. Bommer, R. Chatterjee, R. Hussein, J. Yano, H. Dau, J. Kern, H. Dobbek, A. Zouni eLife 2017, 6, 10.7554/eLife.26933

81 Role of missing carotenoid in reducing the fluorescence of single monomeric photosystem II core complexes S. Skandary, F. Müh, I. Ashraf, M. Ibrahim, M. Metzger, A. Zouni, A. J. Meixner, M. Brecht Physical Chemistry Chemical Physics 2017, 19, 13189–13194, 10.1039/c6cp07748j

80 Drop-on-demand sample delivery for studying biocatalysts in action at X-ray free-electron lasers F. D. Fuller, S. Gul, R. Chatterjee, E. S. Burgie, I. D. Young, H. Lebrette, V. Srinivas, A. S. Brewster, T. Michels-Clark, J. A. Clinger, B. Andi, M. Ibrahim, E. Pastor, C. de Lichtenberg, R. Hussein, C. J. Pollock, M. Zhang, C. A. Stan, T. Kroll, T. Fransson, C. Weninger, M. Kubin, P. Aller, L. Lassalle, P. Bräuer, M. D. Miller, M. Amin, S. Koroidov, C. G. Roessler, M. Allaire, R. G. Sierra, P. T. Docker, J. M. Glownia, S. Nelson, J. E. Koglin, D. Zhu, M. Chollet, S. Song, H. Lemke, M. Liang, D. Sokaras, R. Alonso-Mori, A. Zouni, J. Messinger, U. Bergmann, A. K. Boal, J. M. Bollinger, C. Krebs, M. Högbom, G. N. Phillips, R. D. Vierstra, N. K. Sauter, A. M. Orville, J. Kern, V. K. Yachandra, J. Yano Nature Methods 2017, 14, 443–449, 10.1038/nmeth.4195

79 Protonation and Sulfido versus Oxo Ligation Changes at the Molybdenum Cofactor in Xanthine Dehydrogenase (XDH) Variants Studied by X-ray Absorption Spectroscopy S. Reschke, S. Mebs, K. G. V. Sigfridsson-Clauss, R. Kositzki, S. Leimkühler, M. Haumann Inorganic Chemistry 2017, 56, 2165–2176, 10.1021/acs.inorgchem.6b02846

78 Copper(i)-catalysed transfer hydrogenations with ammonia borane E. Korytiaková, N. O. Thiel, F. Pape, J. F. Teichert Chemical Communications 2017, 53, 732–735, 10.1039/C6CC09067B

77 Tethered NHC Ligands for Stereoselective Alkyne Semihydrogenations F. Pape, J. Teichert Synthesis 2017, 49, 2470–2482, 10.1055/s-0036-1590112

76 The 1,6,7,12-Tetraazaperylene Bridging Ligand as an Electron Reservoir and Its Disulfonato Derivative as Redox Mediator in an Enzyme-Electrode Process T. Brietzke, T. Dietz, A. Kelling, U. Schilde, J. Bois, H. Kelm, M. Reh, M. Schmitz, T. Körzdörfer, S. Leimkühler, U. Wollenberger, H. J. Krüger, H. J. Holdt Chemistry - A European Journal 2017, 23, 15583–15587, 10.1002/chem.201703639

75 Dealing at Arm's Length: Catalysis with N-Heterocyclic Carbene Ligands Bearing Anionic Tethers F. Pape, J. F. Teichert European Journal of Organic Chemistry 2017, 2017, 4206–4229, 10.1002/ejoc.201700124

74 Internal Dynamics of the 3-Pyrroline-N-Oxide Ring in Spin-Labeled Proteins P. Consentius, B. Loll, U. Gohlke, C. Alings, C. Müller, R. Müller, C. Teutloff, U. Heinemann, M. Kaupp, M. C. Wahl, T. Risse The Journal of Physical Chemistry Letters 2017, 8, 1113–1117, 10.1021/acs.jpclett.6b02971

73 Combining EPR spectroscopy and X-ray crystallography to elucidate the structure and dynamics of conformationally constrained spin labels in T4 lysozyme single crystals P. Consentius, U. Gohlke, B. Loll, C. Alings, U. Heinemann, M. C. Wahl, T. Risse Physical Chemistry Chemical Physics 2017, 19, 20723–20734, 10.1039/C7CP03144K

72 High Performance Reduction of H2O2with an Electron Transport Decaheme Cytochrome on a Porous ITO Electrode B. Reuillard, K. H. Ly, P. Hildebrandt, L. J. C. Jeuken, J. N. Butt, E. Reisner Journal of the American Chemical Society 2017, 139, 3324–3327, 10.1021/jacs.6b12437

71 Reversible light-dependent molecular switches on Ag/AgCl nanostructures W. Song, C. J. Querebillo, R. Götz, S. Katz, U. Kuhlmann, U. Gernert, I. M. Weidinger, P. Hildebrandt Nanoscale 2017, 9, 8380–8387, 10.1039/C7NR02760E

70 An expanded genetic code for probing the role of electrostatics in enzyme catalysis by vibrational Stark spectroscopy J. S. Völler, H. Biava, P. Hildebrandt, N. Budisa Biochimica et Biophysica Acta (BBA) - General Subjects 2017, 1861, 3053–3059, 10.1016/j.bbagen.2017.02.009

69 Characterization of anisotropically shaped silver nanoparticle arrays via spectroscopic ellipsometry supported by numerical optical modeling D. Gkogkou, T. Shaykhutdinov, T. W. H. Oates, U. Gernert, B. Schreiber, S. Facsko, P. Hildebrandt, I. M. Weidinger, N. Esser, K. Hinrichs Applied Surface Science 2017, 421, 460–464, 10.1016/j.apsusc.2016.10.105

68 Electrochemical and Resonance Raman Spectroscopic Studies of Water-Oxidizing Ruthenium Terpyridyl-Bipyridyl Complexes A. Keidel, I. López, J. Staffa, U. Kuhlmann, F. Bozoglian, C. Gimbert-Suriñach, J. Benet-Buchholz, P. Hildebrandt, A. Llobet ChemSusChem 2017, 10, 551–561, 10.1002/cssc.201601221

67 Switchable Redox Chemistry of the Hexameric Tyrosine-Coordinated Heme Protein P. Kielb, T. Utesch, J. Kozuch, J. H. Jeoung, H. Dobbek, M. A. Mroginski, P. Hildebrandt, I. Weidinger The Journal of Physical Chemistry B 2017, 121, 3955–3964, 10.1021/acs.jpcb.7b01286

66 Carbon Monoxide Dehydrogenase Reduces Cyanate to Cyanide A. Ciaccafava, D. Tombolelli, L. Domnik, J. H. Jeoung, H. Dobbek, M. A. Mroginski, I. Zebger, P. Hildebrandt Angewandte Chemie International Edition 2017, 56, 7398–7401, 10.1002/anie.201703225

65 Redox-dependent substrate-cofactor interactions in the Michaelis-complex of a flavin-dependent oxidoreductase T. Werther, S. Wahlefeld, J. Salewski, U. Kuhlmann, I. Zebger, P. Hildebrandt, H. Dobbek Nature Communications 2017, 8, 16084– 10.1038/ncomms16084

64 Determination of the Local Electric Field at Au/SAM Interfaces Using the Vibrational Stark Effect J. K. Staffa, L. Lorenz, M. Stolarski, D. H. Murgida, I. Zebger, T. Utesch, J. Kozuch, P. Hildebrandt The Journal of Physical Chemistry C 2017, 121, 22274–22285, 10.1021/acs.jpcc.7b08434

63 Temperature Dependence of the Catalytic Two- versus Four-Electron Reduction of Dioxygen by a Hexanuclear Cobalt Complex I. Monte-Pérez, S. Kundu, A. Chandra, K. E. Craigo, P. Chernev, U. Kuhlmann, H. Dau, P. Hildebrandt, C. Greco, C. Van Stappen, N. Lehnert, K. Ray Journal of the American Chemical Society 2017, 139, 15033–15042, 10.1021/jacs.7b07127

62 Ultrathin Zn and ZnO films on Cu(111) as model catalysts B. H. Liu, I. M. N. Groot, Q. Pan, S. Shaikhutdinov, H. J. Freund Applied Catalysis A: General 2017, 548, 16–23, 10.1016/j.apcata.2017.06.043

61 Li/MgO Catalysts Doped with Alio-valent Ions. Part II: Local Topology Unraveled by EPR/NMR and DFT Modeling U. Simon, S. Alarcón Villaseca, H. Shang, S. V. Levchenko, S. Arndt, J. D. Epping, O. Görke, M. Scheffler, R. Schomäcker, J. van Tol, A. Ozarowski, K. P. Dinse ChemCatChem 2017, 9, 3597–3610, 10.1002/cctc.201700610

60 Li/MgO Catalysts Doped with Alio-valent Ions. Part I: Structure, Composition, and Catalytic Properties S. Arndt, U. Simon, K. Kiefer, T. Otremba, K. Siemensmeyer, M. Wollgarten, A. Berthold, F. Schmidt, O. Görke, R. Schomäcker, K. P. Dinse ChemCatChem 2017, 9, 3583–3596, 10.1002/cctc.201700611

59 Fast tuning of covalent triazine frameworks for photocatalytic hydrogen evolution S. Kuecken, A. Acharjya, L. Zhi, M. Schwarze, R. Schomäcker, A. Thomas Chemical Communications 2017, 53, 5854–5857, 10.1039/c7cc01827d

58 Improving the Catalytic Activity in the Rhodium-Mediated Hydroformylation of Styrene by a Bis(N-heterocyclic silylene) Ligand M. Schmidt, B. Blom, T. Szilvási, R. Schomäcker, M. Driess European Journal of Inorganic Chemistry 2017, 2017, 1284–1291, 10.1002/ejic.201700148

57 Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation F. Forster, T. T. Metsänen, E. Irran, P. Hrobárik, M. Oestreich Journal of the American Chemical Society 2017, 139, 16334–16342, 10.1021/jacs.7b09444

56 Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst J. Fuchs, H. F. T. Klare, M. Oestreich ACS Catalysis 2017, 7, 8338–8342, 10.1021/acscatal.7b03336

55 Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes W. Yuan, P. Orecchia, M. Oestreich Chemical Communications 2017, 53, 10390–10393, 10.1039/c7cc06195a

54 B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes D. Porwal, M. Oestreich Synthesis 2017, 49, 4698–4702, 10.1055/s-0036-1588476

53 BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base Q. Yin, Y. Soltani, R. L. Melen, M. Oestreich Organometallics 2017, 36, 2381–2384, 10.1021/acs.organomet.7b00381

52 B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes I. Chatterjee, D. Porwal, M. Oestreich Angewandte Chemie International Edition 2017, 56, 3389–3391, 10.1002/anie.201611813

51 Spin-Selective, Competitive Hydrogen-Atom Transfer versus CH2O-Generation from the CH4/[ReO4]+Couple at Ambient Conditions S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2017, 23, 17469–17472, 10.1002/chem.201704892

50 Electronic Effects on Room-Temperature, Gas-Phase C–H Bond Activations by Cluster Oxides and Metal Carbides: The Methane Challenge H. Schwarz, S. Shaik, J. Li Journal of the American Chemical Society 2017, 139, 17201–17212, 10.1021/jacs.7b10139

49 Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory V. Pelmenschikov, J. A. Birrell, C. C. Pham, N. Mishra, H. Wang, C. Sommer, E. Reijerse, C. P. Richers, K. Tamasaku, Y. Yoda, T. B. Rauchfuss, W. Lubitz, S. P. Cramer Journal of the American Chemical Society 2017, 10.1021/jacs.7b09751

48 Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2ZnO4].+ S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 14297–14300, 10.1002/anie.201704979

47 On the Electronic Origin of Remarkable Ligand Effects on the Reactivities of [NiL]+Complexes (L=C6H5, C5H4N, CN) towards Methane S. Zhou, M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2017, 23, 14430–14433, 10.1002/chem.201703767

46 Ménage-à-trois: single-atom catalysis, mass spectrometry, and computational chemistry H. Schwarz Catal. Sci. Technol. 2017, 7, 43–4314, 10.1039/c6cy02658c

45 Anionic silicate organic frameworks constructed from hexacoordinate silicon centres J. Roeser, D. Prill, M. J. Bojdys, P. Fayon, A. Trewin, A. N. Fitch, M. U. Schmidt, A. Thomas Nature Chemistry 2017, 9, 977–982, 10.1038/nchem.2771

44 Metal-Dependent Strengthening and Weakening of M−H and M−C Bonds by an Oxo Ligand: Thermal Gas-Phase Activation of Methane by [OMH]+and [MH]+(M=Mo, Ti) M. Firouzbakht, S. Zhou, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2017, 23, 12346–12352, 10.1002/chem.201701615

43 Oxygen Scrambling of CO2Adsorbed on CaO(001) B. H. Solis, J. Sauer, Y. Cui, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C 2017, 121, 18625–18634, 10.1021/acs.jpcc.7b05293

42 Enzymes as Tools in MIP-Sensors A. Yarman, K. Jetzschmann, B. Neumann, X. Zhang, U. Wollenberger, A. Cordin, K. Haupt, F. Scheller Chemosensors 2017, 5, 11– 10.3390/chemosensors5020011

41 Bioelectrocatalytic Reduction of Hydrogen Peroxide by Microperoxidase-11 Immobilized on Mesoporous Antimony-Doped Tin Oxide B. Neumann, P. Kielb, L. Rustam, A. Fischer, I. M. Weidinger, U. Wollenberger ChemElectroChem 2017, 4, 913–919, 10.1002/celc.201600776

40 Transient Catalytic Voltammetry of Sulfite Oxidase Reveals Rate Limiting Conformational Changes T. Zeng, S. Leimkühler, U. Wollenberger, V. Fourmond Journal of the American Chemical Society 2017, 139, 11559–11567, 10.1021/jacs.7b05480

39 Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane L. Yue, J. Li, S. Zhou, X. Sun, M. Schlangen, S. Shaik, H. Schwarz Angewandte Chemie International Edition 2017, 56, 10219–10223, 10.1002/anie.201703485

38 Metal-Free, Room-Temperature Oxygen-Atom Transfer in the N2O/CO Redox Couple as Catalyzed by [Si2Ox].+(x=2-5) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 9990–9993, 10.1002/anie.201703453

37 Structural mechanism of arrestin activation P. Scheerer, M. E. Sommer Current Opinion in Structural Biology 2017, 45, 160–169, 10.1016/

36 Structural–Functional Features of the Thyrotropin Receptor: A Class A G-Protein-Coupled Receptor at Work G. Kleinau, C. L. Worth, A. Kreuchwig, H. Biebermann, P. Marcinkowski, P. Scheerer, G. Krause Frontiers in Endocrinology 2017, 8, 1–25, 10.3389/fendo.2017.00086

35 Carbon Dioxide Adsorption on V2O3(0001) M. A. Haija, Y. Romanyshyn, A. Uhl, H. Kuhlenbeck, H. J. Freund Topics in Catalysis 2017, 60, 413–419, 10.1007/s11244-017-0810-4

34 CFD als Designtool für Festbettreaktoren mit kleinem Rohr-zu-Pelletdurchmesser-Verhältnis: Heute oder in Zukunft? G. D. Wehinger, M. Kraume Chemie Ingenieur Technik 2017, 89, 447–453, 10.1002/cite.201600155

33 Blue-light reception through quaternary transitions C. Engelhard, R. P. Diensthuber, A. Möglich, R. Bittl Scientific Reports 2017, 7, 1–10, 10.1038/s41598-017-01497-7

32 Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks M. Trunk, J. F. Teichert, A. Thomas Journal of the American Chemical Society 2017, 139, 3615–3618, 10.1021/jacs.6b13147

31 Carbon-Based Microbial-Fuel-Cell Electrodes: From Conductive Supports to Active Catalysts S. Li, C. Cheng, A. Thomas Advanced Materials 2017, 29, 1602547– 10.1002/adma.201602547

30 Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy E. J. Reijerse, C. C. Pham, V. Pelmenschikov, R. Gilbert-Wilson, A. Adamska-Venkatesh, J. F. Siebel, L. B. Gee, Y. Yoda, K. Tamasaku, W. Lubitz, T. B. Rauchfuss, S. P. Cramer Journal of the American Chemical Society 2017, 139, 4306–4309, 10.1021/jacs.7b00686

29 Sequential Gas-Phase Activation of Carbon Dioxide and Methane by [Re(CO)2]+: The Sequence of Events Matters! S. Zhou, J. Li, M. Firouzbakht, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2017, 139, 6169–6176, 10.1021/jacs.7b01255

28 Activation of CS2and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes T. Ahrens, B. Schmiedecke, T. Braun, R. Herrmann, R. Laubenstein European Journal of Inorganic Chemistry 2017, 2017, 713–722, 10.1002/ejic.201601122

27 Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step J. Kohlmann, T. Braun, R. Laubenstein, R. Herrmann Chemistry - A European Journal 2017, 10.1002/chem.201700549

26 Modeling pore processes for particle-resolved CFD simulations of catalytic fixed-bed reactors G. D. Wehinger, F. Klippel, M. Kraume Computers & Chemical Engineering 2017, 101, 11–22, 10.1016/j.compchemeng.2017.02.029

25 Tuning the oxidative power of free iron–sulfur clusters S. M. Lang, S. Zhou, H. Schwarz Phys. Chem. Chem. Phys. 2017, 19, 8055–8060, 10.1039/c7cp00023e

24 Double-flow focused liquid injector for efficient serial femtosecond crystallography D. Oberthuer, J. Knoška, M. O. Wiedorn, K. R. Beyerlein, D. A. Bushnell, E. G. Kovaleva, M. Heymann, L. Gumprecht, R. A. Kirian, A. Barty, V. Mariani, A. Tolstikova, L. Adriano, S. Awel, M. Barthelmess, K. Dörner, P. L. Xavier, O. Yefanov, D. R. James, G. Nelson, D. Wang, G. Calvey, Y. Chen, A. Schmidt, M. Szczepek, S. Frielingsdorf, O. Lenz, E. Snell, P. J. Robinson, B. Šarler, G. Belšak, M. Maček, F. Wilde, A. Aquila, S. Boutet, M. Liang, M. S. Hunter, P. Scheerer, J. D. Lipscomb, U. Weierstall, R. D. Kornberg, J. C. H. Spence, L. Pollack, H. N. Chapman, S. Bajt Scientific Reports 2017, 7, 44628– 10.1038/srep44628

23 On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO)x]+/CH4(x=0-3) Couples S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 2951–2954, 10.1002/anie.201611826

22 An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water Z. Mo, T. Szilvási, Y. P. Zhou, S. Yao, M. Driess Angewandte Chemie International Edition 2017, 56, 3699–3702, 10.1002/anie.201700625

21 Divalent Cations Increase DNA Repair Activities of Bacterial (6-4) Photolyases H. Ma, F. Zhang, E. Ignatz, M. Suehnel, P. Xue, P. Scheerer, L. O. Essen, N. Krauß, T. Lamparter Photochemistry and Photobiology 2017, 93, 323–330, 10.1111/php.12698

20 The crystal structure of Pseudomonas aeruginosa lipoxygenase Ala420Gly mutant explains the improved oxygen affinity and the altered reaction specificity J. Kalms, S. Banthiya, E. Galemou Yoga, M. Hamberg, H. G. Holzhutter, H. Kuhn, P. Scheerer Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids 2017, 1862, 463–473, 10.1016/j.bbalip.2017.01.003

19 Crystal Structures of Bacterial (6-4) Photolyase Mutants with Impaired DNA Repair Activity F. Zhang, H. Ma, K. Bowatte, D. Kwiatkowski, E. Mittmann, H. Qasem, N. Krauß, X. Zeng, Z. Ren, P. Scheerer, X. Yang, T. Lamparter Photochemistry and Photobiology 2017, 93, 304–314, 10.1111/php.12699

18 Support Effects on CO Oxidation on Metal-supported Ultrathin FeO(1 1 1) Films X. Weng, K. Zhang, Q. Pan, Y. Martynova, S. Shaikhutdinov, H. J. Freund ChemCatChem 2017, 10.1002/cctc.201601447

17 An S-Oxygenated [NiFe] Complex Modelling Sulfenate Intermediates of an O2-Tolerant Hydrogenase N. J. Lindenmaier, S. Wahlefeld, E. Bill, T. Szilvási, C. Eberle, S. Yao, P. Hildebrandt, M. Horch, I. Zebger, M. Driess Angewandte Chemie International Edition 2017, 56, 2208–2211, 10.1002/anie.201611069

16 Functional Graphene Nanomaterials Based Architectures: Biointeractions, Fabrications, and Emerging Biological Applications C. Cheng, S. Li, A. Thomas, N. A. Kotov, R. Haag Chemical Reviews 2017, 117, 1826–1914, 10.1021/acs.chemrev.6b00520

15 Activation of Dioxygen at a Lewis Acidic Nickel(II) Complex: Characterization of a Metastable Organoperoxide Complex P. Holze, T. Corona, N. Frank, B. Braun-Cula, C. Herwig, A. Company, C. Limberg Angewandte Chemie International Edition 2017, 10.1002/anie.201609526

14 Discovery and Investigation of Natural Editing Function against Artificial Amino Acids in Protein Translation J. S. Völler, M. Dulic, U. I. M. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovulj, B. Koksch ACS Central Science 2017, 3, 73–80, 10.1021/acscentsci.6b00339

13 Contact Modifications for CFD Simulations of Fixed-Bed Reactors: Cylindrical Particles G. D. Wehinger, C. Fütterer, M. Kraume Industrial & Engineering Chemistry Research 2017, 56, 87–99, 10.1021/acs.iecr.6b03596

12 Thermal Methane Activation by the Metal-Free Cluster Cation [Si2O4].+ X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2017, 23, 1498–1501, 10.1002/chem.201605496

11 Metal-mediated activation of carbon dioxide in the gas phase: Mechanistic insight derived from a combined experimental/computational approach H. Schwarz Coordination Chemistry Reviews 2017, 334, 112–123, 10.1016/j.ccr.2016.03.009

10 Electrostatic and Charge-Induced Methane Activation by a Concerted Double C–H Bond Insertion C. Geng, J. Li, T. Weiske, M. Schlangen, S. Shaik, H. Schwarz Journal of the American Chemical Society 2017, 139, 1684–1689, 10.1021/jacs.6b12514

9 Striking Doping Effects on Thermal Methane Activation Mediated by the Heteronuclear Metal Oxides [XAlO4].+(X=V, Nb, and Ta) X. N. Wu, J. Li, M. Schlangen, S. Zhou, P. González-Navarrete, H. Schwarz Chemistry - A European Journal 2017, 23, 788–792, 10.1002/chem.201605226

8 Solid-State Ion-Exchanged Cu/Mordenite Catalysts for the Direct Conversion of Methane to Methanol H. V. Le, S. Parishan, A. Sagaltchik, C. Göbel, C. Schlesiger, W. Malzer, A. Trunschke, R. Schomäcker, A. Thomas ACS Catalysis 2017, 1403–1412, 10.1021/acscatal.6b02372

7 Construction of a polyproline structure with hydrophobic exterior using octahydroindole-2-carboxylic acid V. Kubyshkin, N. Budisa Org. Biomol. Chem. 2017, 15, 619–627, 10.1039/C6OB02306A

6 Enzymes as modular catalysts for redox half-reactions in H2-powered chemical synthesis: from biology to technology H. A. Reeve, P. A. Ash, H. Park, A. Huang, M. Posidias, C. Tomlinson, O. Lenz, K. A. Vincent Biochemical Journal 2017, 474, 215–230, 10.1042/BCJ20160513

5 The purple Trp288Ala mutant of Synechocystis OCP persistently quenches phycobilisome fluorescence and tightly interacts with FRP N. N. Sluchanko, K. E. Klementiev, E. A. Shirshin, G. V. Tsoraev, T. Friedrich, E. G. Maksimov Biochimica et Biophysica Acta Biochimica et Biophysica Acta (BBA) - Bioenergetics 2017, 1858, 1–11, 10.1016/j.bbabio.2016.10.005

4 Investigation of the NADH/NAD+ ratio in Ralstonia eutropha using the fluorescence reporter protein Peredox V. Tejwani, F. J. Schmitt, S. Wilkening, I. Zebger, M. Horch, O. Lenz, T. Friedrich Biochimica et Biophysica Acta Biochimica et Biophysica Acta (BBA) - Bioenergetics 2017, 1858, 86–94, 10.1016/j.bbabio.2016.11.001

3 Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane H. Schwarz, P. González-Navarrete, J. Li, M. Schlangen, X. Sun, T. Weiske, S. Zhou Organometallics 2017, 36, 8–17, 10.1021/acs.organomet.6b00372

2 On the Origin of the Remarkably Variable Reactivities of [AlCeOx]+(x=2-4) towards Methane as a Function of Oxygen Content S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 413–416, 10.1002/anie.201610424

1 Active and Stable Nickel-Based Electrocatalysts Based on the ZnO:Ni System for Water Oxidation in Alkaline Media J. Pfrommer, A. Azarpira, A. Steigert, K. Olech, P. W. Menezes, R. F. Duarte, X. Liao, R. G. Wilks, M. Bär, T. Schedel-Niedrig, M. Driess ChemCatChem 2017, 9, 672–676, 10.1002/cctc.201600922