Publications 2014

Number of records: 197

197 Tuning Spatial Distribution of Surface Hydroxyls on a Metal-Supported Single-Layer Silica B. Yang, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry Letters 2014, 5, 1701–1704, 10.1021/jz500689t

196 Applying thermo-destabilization of microemulsions as a new method for co-catalyst loading on mesoporous polymeric carbon nitride – towards large scale applications M. Schröder, K. Kailasam, S. Rudi, K. Fündling, J. Rieß, M. Lublow, A. Thomas, R. Schomäcker, M. Schwarze RSC Adv. 2014, 4, 50017–50026, 10.1039/C4RA10814K

195 Speciation of Molybdates under Hydrothermal Conditions J. Noack, F. Rosowski, R. Schlögl, A. Trunschke Zeitschrift für Anorganische und Allgemeine Chemie 2014, 640, 2730–2736, 10.1002/zaac.201400439

194 Ambient-Pressure Soft X-ray Absorption Spectroscopy of a Catalyst Surface in Action: Closing the Pressure Gap in the Selective n-Butane Oxidation over Vanadyl Pyrophosphate C. Heine, M. Hävecker, E. Stotz, F. Rosowski, A. Knop-Gericke, A. Trunschke, M. Eichelbaum, R. Schlögl The Journal of Physical Chemistry C 2014, 118, 20405–20412, 10.1021/jp506068x

193 Mechanisms of cell uptake and toxicity of the anticancer drug cisplatin N. D. Eljack, H. Y. M. Ma, J. Drucker, C. Shen, T. W. Hambley, E. J. New, T. Friedrich, R. J. Clarke Metallomics 2014, 6, 2126–2133, 10.1039/C4MT00238E

192 A missense variant of the ATP1A2 gene is associated with a novel phenotype of progressive sensorineural hearing loss associated with migraine S. K. Oh, J. I. Baek, K. M. Weigand, H. Venselaar, H. G. P. Swarts, S. H. Park, M. Hashim Raza, D. J. Jung, S. Y. Choi, S. H. Lee, T. Friedrich, G. Vriend, J. B. Koenderink, U. K. Kim, K. Y. Lee European Journal of Human Genetics 2014, 23, 639–645, 10.1038/ejhg.2014.154

191 A Single-Photon Avalanche Camera for Fluorescence Lifetime Imaging Microscopy and Correlation Spectroscopy M. Vitali, D. Bronzi, A. J. Krmpot, S. N. Nikolic, F. J. Schmitt, C. Junghans, S. Tisa, T. Friedrich, V. Vukojevic, L. Terenius, F. Zappa, R. Rigler IEEE Journal of Selected Topics in Quantum Electronics 2014, 20, 344–353, 10.1109/JSTQE.2014.2333238

190 Functional analysis of human Na(+)/K(+)-ATPase familial or sporadic hemiplegic migraine mutations expressed in Xenopus oocytes S. Spiller, T. Friedrich World Journal of Biological Chemistry 2014, 5, 240–253, 10.4331/wjbc.v5.i2.240

189 eGFP-pHsens as a highly sensitive fluorophore for cellular pH determination by fluorescence lifetime imaging microscopy (FLIM) F. J. Schmitt, B. Thaa, C. Junghans, M. Vitali, M. Veit, T. Friedrich Biochimica et Biophysica Acta (BBA) - Bioenergetics 2014, 1837, 1581–1593, 10.1016/j.bbabio.2014.04.003

188 The time course of non-photochemical quenching in phycobilisomes of Synechocystis sp. PCC6803 as revealed by picosecond time-resolved fluorimetry E. G. Maksimov, F. J. Schmitt, E. A. Shirshin, M. D. Svirin, I. V. Elanskaya, T. Friedrich, V. V. Fadeev, V. Z. Paschenko, A. B. Rubin Biochimica et Biophysica Acta (BBA) - Bioenergetics 2014, 1837, 1540–1547, 10.1016/j.bbabio.2014.01.010

187 The extended reductive acetyl-CoA pathway: ATPases in metal cluster maturation and reductive activation J. H. Jeoung, S. Goetzl, S. E. Hennig, J. Fesseler, C. Wörmann, J. Dendra, H. Dobbek Biological Chemistry 2014, 395, 10.1515/hsz-2013-0290

186 Structural basis for organohalide respiration M. Bommer, C. Kunze, J. Fesseler, T. Schubert, G. Diekert, H. Dobbek Science 2014, 346, 455–458, 10.1126/science.1258118

185 Carbon monoxide. Toxic gas and fuel for anaerobes and aerobes: carbon monoxide dehydrogenases. J. H. Jeoung, J. Fesseler, S. Götzl Met Ions Life Sci. 2014, 14, 37–69, 10.1007/978-94-017-9269-1_3

184 Antireflective Coatings with Adjustable Refractive Index and Porosity Synthesized by Micelle-Templated Deposition of MgF2 Sol Particles D. Bernsmeier, J. Polte, E. Ortel, T. Krahl, E. Kemnitz, R. Kraehnert ACS Applied Materials & Interfaces 2014, 6, 19559–19565, 10.1021/am5052685

183 Versatile control over size and spacing of small mesopores in metal oxide films and catalytic coatings via templating with hyperbranched core–multishell polymers D. Bernsmeier, E. Ortel, J. Polte, B. Eckhardt, S. Nowag, R. Haag, R. Kraehnert J. Mater. Chem. A 2014, 2, 13075–13082, 10.1039/C4TA01842G

182 Mechanical behavior of mesoporous titania thin films T. Rahman, R. Liu, E. Ortel, R. Kraehnert, A. Antoniou Applied Physics Letters 2014, 104, 241902– 10.1063/1.4883260

181 Electrocatalytic Oxygen Evolution on Iridium Oxide: Uncovering Catalyst-Substrate Interactions and Active Iridium Oxide Species T. Reier, D. Teschner, T. Lunkenbein, A. Bergmann, S. Selve, R. Kraehnert, R. Schlogl, P. Strasser Journal of the Electrochemical Society 2014, 161, 10.1149/2.0411409jes

180 Direct synthesis of nanosized-ZSM-5/SBA-15 analog composites from preformed ZSM-5 precursors for improved catalytic performance as cracking catalyst X. H. Vu, U. Bentrup, M. Hunger, R. Kraehnert, U. Armbruster, A. Martin Journal of Materials Science 2014, 49, 5676–5689, 10.1007/s10853-014-8287-z

179 Prototyping of catalyst pore-systems by a combined synthetic, analytical and computational approach: Application to mesoporous TiO2 V. Novák, E. Ortel, B. Winter, B. Butz, B. Paul, P. Kočí, M. Marek, E. Spiecker, R. Kraehnert Chemical Engineering Journal 2014, 248, 49–62, 10.1016/j.cej.2014.02.004

178 Dioxygen Activation by Siloxide Complexes of Chromium(II) and Chromium(IV) F. Schax, E. Bill, C. Herwig, C. Limberg Angewandte Chemie International Edition 2014, 53, 12741–12745, 10.1002/anie.201406313

177 A Cubic Fe4Mo4 Oxo Framework and Its Reversible Four-Electron Redox Chemistry J. P. Falkenhagen, B. Braun, E. Bill, D. Sattler, C. Limberg Inorganic Chemistry 2014, 53, 7294–7308, 10.1021/ic500584a

176 Three-Coordinate Nickel(II) and Nickel(I) Thiolate Complexes Based on the β-Diketiminate Ligand System B. Horn, C. Limberg, C. Herwig, B. Braun Inorganic Chemistry 2014, 53, 6867–6874, 10.1021/ic500698v

175 Molecular CuII-O-CuII Complexes: Still Waters Run Deep P. Haack, C. Limberg Angewandte Chemie International Edition 2014, 53, 4282–4293, 10.1002/anie.201309505

174 A Tripodal Trisilanol Ligand and Its Complexation Behavior towards CuI, CuII, and ZnII F. Schax, B. Braun, C. Limberg European Journal of Inorganic Chemistry 2014, 2014, 2124–2130, 10.1002/ejic.201400088

173 A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O2 Reactivity R. Metzinger, S. Demeshko, C. Limberg Chemistry - A European Journal 2014, 20, 4721–4735, 10.1002/chem.201304535

172 Stability of nanostructured iridium oxide electrocatalysts during oxygen evolution reaction in acidic environment S. Cherevko, T. Reier, A. R. Zeradjanin, Z. Pawolek, P. Strasser, K. J. J. Mayrhofer Electrochemistry Communications 2014, 48, 81–85, 10.1016/j.elecom.2014.08.027

171 Water oxidation by manganese oxides formed from tetranuclear precursor complexes: the influence of phosphate on structure and activity D. Shevchenko, M. F. Anderlund, S. Styring, H. Dau, I. Zaharieva, A. Thapper Physical Chemistry Chemical Physics 2014, 16, 11965–11975, 10.1039/C3cp55125c

170 Biogenic Manganese-Calcium Oxides on the Cell Walls of the Algae : Elemental Composition, Atomic Structure, and Water-Oxidation Catalysis A. Schöler, I. Zaharieva, S. Zimmermann, M. Wiechen, A. M. Manke, P. Kurz, C. Plieth, H. Dau European Journal of Inorganic Chemistry 2014, 2014, 780–790, 10.1002/ejic.201300697

169 Fragments of Layered Manganese Oxide Are the Real Water Oxidation Catalyst after Transformation of Molecular Precursor on Clay M. M. Najafpour, A. N. Moghaddam, H. Dau, I. Zaharieva Journal of the American Chemical Society 2014, 136, 7245–7248, 10.1021/Ja5028716

168 Screen-Printed Calcium-Birnessite Electrodes for Water Oxidation at Neutral pH and an “Electrochemical Harriman Series” S. Y. Lee, D. González-Flores, J. Ohms, T. Trost, H. Dau, I. Zaharieva, P. Kurz ChemSusChem 2014, 7, 3442–3451, 10.1002/cssc.201402533

167 Molecular genetic analysis of vesicular transport in Aspergillus niger reveals partial conservation of the molecular mechanism of exocytosis in fungi M. J. Kwon, M. Arentshorst, M. Fiedler, F. L. M. de Groen, P. J. Punt, V. Meyer, A. F. J. Ram Microbiology 2014, 160, 316–329, 10.1099/mic.0.074252-0

166 A bifunctional enzyme from Rhodococcus erythropolis exhibiting secondary alcohol dehydrogenase-catalase activities E. Martinez-Rojas, T. Kurt, U. Schmidt, V. Meyer, L. A. Garbe Applied Microbiology and Biotechnology 2014, 98, 9249–9258, 10.1007/s00253-014-5808-2

165 The capacity of Aspergillus niger to sense and respond to cell wall stress requires at least three transcription factors: RlmA, MsnA and CrzA M. R. Fiedler, A. Lorenz, B. M. Nitsche, C. A. van den Hondel, A. F. Ram, V. Meyer Fungal Biology and Biotechnology 2014, 1, 10.1186/s40694-014-0005-8

164 Zinc-Catalyzed Depolymerization of End-of-Life Polysiloxanes S. Enthaler Angewandte Chemie International Edition 2014, 53, 2716–2721, 10.1002/anie.201309299

163 Low-Temperature Depolymerization of Polysiloxanes with Iron Catalysis S. Enthaler, R. Kretschmer ChemSusChem 2014, 7, 2030–2036, 10.1002/cssc.201301386

162 Coupling Bioorthogonal Chemistries with Artificial Metabolism: Intracellular Biosynthesis of Azidohomoalanine and Its Incorporation into Recombinant Proteins Y. Ma, H. Biava, R. Contestabile, N. Budisa, M. di Salvo Molecules 2014, 19, 1004–1022, 10.3390/molecules19011004

161 Sense codon emancipation for proteome-wide incorporation of noncanonical amino acids: rare isoleucine codon AUA as a target for genetic code expansion N. Bohlke, N. Budisa FEMS Microbiology Letters 2014, 351, 133–144, 10.1111/1574-6968.12371

160 Iron-catalyzed depolymerization of polysiloxanes to produce dichlorodimethylsilane, diacetoxydimethylsilane, or dimethoxydimethylsilane S. Enthaler Journal of Applied Polymer Science 2014, 132, 10.1002/app.41287

159 Evolution of fluorinated enzymes: An emerging trend for biocatalyst stabilization H. Biava, N. Budisa Engineering in Life Sciences 2014, 14, 340–351, 10.1002/elsc.201300049

158 Zinc-Catalyzed Depolymerization of Polyethers to Produce Valuable Building Blocks S. Enthaler Catalysis Letters 2014, 144, 850–859, 10.1007/s10562-014-1214-8

157 Synthesis of Ni(II) complexes with unsymmetric [O,N,O′]-pincer ligands and their use as precatalysts in carbon–carbon bond formations to access diarylmethanes C. I. Someya, E. Irran, S. Enthaler Inorganica Chimica Acta 2014, 421, 136–144, 10.1016/j.ica.2014.05.023

156 Exploring the coordination chemistry of 2-picolinic acid to zinc and application of the complexes in catalytic oxidation chemistry S. Enthaler, X. F. Wu, M. Weidauer, E. Irran, P. Döhlert Inorganic Chemistry Communications 2014, 46, 320–323, 10.1016/j.inoche.2014.06.020

155 Exploring the coordination chemistry of O,N,O′-ligands modified by 2-thienyl-substituents to nickel C. I. Someya, S. Inoue, E. Irran, S. Enthaler Inorganic Chemistry Communications 2014, 44, 114–118, 10.1016/j.inoche.2014.03.014

154 Zinc(II)-triflate as catalyst precursor for ring-closing depolymerization of end-of-life polytetrahydrofuran to produce tetrahydrofuran S. Enthaler Journal of Applied Polymer Science 2014, 131, 10.1002/app.39791

153 Bio-inspired carbon nitride mesoporous spheres for artificial photosynthesis: photocatalytic cofactor regeneration for sustainable enzymatic synthesis J. Huang, M. Antonietti, J. Liu Journal of Materials Chemistry A 2014, 2, 7686– 10.1039/c4ta00793j

152 The bioinspired construction of an ordered carbon nitride array for photocatalytic mediated enzymatic reduction J. Liu, R. Cazelles, Z. P. Chen, H. Zhou, A. Galarneau, M. Antonietti Physical Chemistry Chemical Physics 2014, 16, 14699– 10.1039/c4cp01348d

151 Adsorption and photocatalytic splitting of water on graphitic carbon nitride: a combined first principles and semiempirical study J. Wirth, R. Neumann, M. Antonietti, P. Saalfrank Physical Chemistry Chemical Physics 2014, 16, 15917– 10.1039/c4cp02021a

150 Mesoporous graphitic carbon nitride as a heterogeneous catalyst for photoinduced copper(I)-catalyzed azide-alkyne cycloaddition S. Dadashi-Silab, B. Kiskan, M. Antonietti, Y. Yagci RSC Adv. 2014, 4, 52170–52173, 10.1039/c4ra09954k

149 Sponge-like Nickel and Nickel Nitride Structures for Catalytic Applications M. Shalom, V. Molinari, D. Esposito, G. Clavel, D. Ressnig, C. Giordano, M. Antonietti Advanced Materials 2014, 26, 1272–1276, 10.1002/adma.201304288

148 Titanium Nitride-Nickel Nanocomposite as Heterogeneous Catalyst for the Hydrogenolysis of Aryl Ethers V. Molinari, C. Giordano, M. Antonietti, D. Esposito Journal of the American Chemical Society 2014, 136, 1758–1761, 10.1021/ja4119412

147 Uniform Graphitic Carbon Nitride Nanorod for Efficient Photocatalytic Hydrogen Evolution and Sustained Photoenzymatic Catalysis J. Liu, J. Huang, H. Zhou, M. Antonietti ACS Applied Materials & Interfaces 2014, 6, 8434–8440, 10.1021/am501319v

146 Ultrafast Syntheses of Silver Foams from Ag2NCN: Combustion Synthesis versus Chemical Reduction D. Ressnig, M. Antonietti Chemistry of Materials 2014, 26, 4064–4067, 10.1021/cm501475b

145 FeNi nanoparticles with carbon armor as sustainable hydrogenation catalysts: towards biorefineries G. Chieffi, C. Giordano, M. Antonietti, D. Esposito Journal of Materials Chemistry A 2014, 2, 11591– 10.1039/c4ta02457e

144 Upconversion-Agent Induced Improvement of g-C3N4 Photocatalyst under Visible Light J. Xu, T. J. K. Brenner, Z. Chen, D. Neher, M. Antonietti, M. Shalom ACS Applied Materials & Interfaces 2014, 6, 16481–16486, 10.1021/am5051263

143 In Situ Formation of Heterojunctions in Modified Graphitic Carbon Nitride: Synthesis and Noble Metal Free Photocatalysis M. Shalom, M. Guttentag, C. Fettkenhauer, S. Inal, D. Neher, A. Llobet, M. Antonietti Chemistry of Materials 2014, 26, 5812–5818, 10.1021/cm503258z

142 Metal-free ionic liquid-derived electrocatalyst for high-performance oxygen reduction in acidic and alkaline electrolytes K. Elumeeva, N. Fechler, T. P. Fellinger, M. Antonietti Mater. Horiz. 2014, 1, 588–594, 10.1039/C4MH00123K

141 Blood Ties: Co3O4 Decorated Blood Derived Carbon as a Superior Bifunctional Electrocatalyst C. Zhang, M. Antonietti, T. P. Fellinger Advanced Functional Materials 2014, 24, 7655–7665, 10.1002/adfm.201402770

140 Production of the Catechol Type Siderophore Bacillibactin by the Honey Bee Pathogen Paenibacillus larvae G. Hertlein, S. Müller, E. Garcia-Gonzalez, L. Poppinga, R. D. Süssmuth, E. Genersch, W. Blenau PLoS ONE 2014, 9, 10.1371/journal.pone.0108272

139 Synthesis and Crystal Structure of δ-TaON, a Metastable Polymorph of Tantalum Oxide Nitride T. Lüdtke, A. Schmidt, C. Göbel, A. Fischer, N. Becker, C. Reimann, T. Bredow, R. Dronskowski, M. Lerch Inorganic Chemistry 2014, 53, 11691–11698, 10.1021/ic501726m

138 Water Oxidation by Amorphous Cobalt-Based Oxides: Volume Activity and Proton Transfer to Electrolyte Bases K. Klingan, F. Ringleb, I. Zaharieva, J. Heidkamp, P. Chernev, D. Gonzalez-Flores, M. Risch, A. Fischer, H. Dau ChemSusChem 2014, 7, 1301–1310, 10.1002/cssc.201301019

137 Synthesis and Crystal Structure of Rutile-type ScTa2O5N S. Cosgun, M. Rohloff, C. Göbel, U. Gernert, A. Fischer, M. Lerch Zeitschrift für anorganische und allgemeine Chemie 2014, 640, 2771–2775, 10.1002/zaac.201400325

136 Bacillus subtilis as heterologous host for the secretory production of the non-ribosomal cyclodepsipeptide enniatin S. Zobel, J. Kumpfmüller, R. D. Süssmuth, T. Schweder Applied Microbiology and Biotechnology 2014, 99, 681–691, 10.1007/s00253-014-6199-0

135 Engineering of Aspergillus niger for the production of secondary metabolites L. Richter, F. Wanka, S. Boecker, D. Storm, T. Kurt, Ö. Vural, R. Süßmuth, V. Meyer Fungal Biology and Biotechnology 2014, 1, 1–13, 10.1186/s40694-014-0004-9

134 Dissecting Reactions of Nonlinear Precursor Peptide Processing of the Class III Lanthipeptide Curvopeptin N. A. Jungmann, B. Krawczyk, M. Tietzmann, P. Ensle, R. D. Süssmuth Journal of the American Chemical Society 2014, 136, 15222–15228, 10.1021/ja5062054

133 On Ammonia Binding to the Oxygen-Evolving Complex of Photosystem II: A Quantum Chemical Study J. Schraut, M. Kaupp Chemistry - A European Journal 2014, 20, 7300–7308, 10.1002/chem.201304464

132 Quantum-chemical insights into mixed-valence systems: within and beyond the Robin–Day scheme M. Parthey, M. Kaupp Chemical Society Reviews 2014, 43, 5067– 10.1039/C3CS60481K

131 Ligand spheres in asymmetric hetero Diels–Alder reactions catalyzed by Cu(II) box complexes: experiment and modeling V. Umamaheswari, P. Cias, A. Pöppl, M. Kaupp, G. Gescheidt Dalton Transactions 2014, 43, 698– 10.1039/c3dt51602d

130 Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic C—H Bonds Directed by a Secondary Amine Q. Li, M. Driess, J. F. Hartwig Angewandte Chemie International Edition 2014, 53, 8471–8474, 10.1002/anie.201404620

129 Elucidating the Effect of the Nucleophilicity of the Silyl Group in the Reduction of CO2 to CO Mediated by Silyl-Copper(I) Complexes G. Tan, B. Blom, D. Gallego, E. Irran, M. Driess Chemistry - A European Journal 2014, 20, 9400–9408, 10.1002/chem.201402017

128 High Catalytic Synergism between the Components of the Rhenium Complex@Silver Hybrid Material in Alkene Epoxidations A. Indra, M. Greiner, A. K. Gericke, R. Schlögl, D. Avnir, M. Driess ChemCatChem 2014, 6, 1935–1939, 10.1002/cctc.201402042

127 Hydride Binding to the Active Site of [FeFe]-Hydrogenase P. Chernev, C. Lambertz, A. Brünje, N. Leidel, K. G. V. Sigfridsson, R. Kositzki, C. H. Hsieh, S. Yao, R. Schiwon, M. Driess, C. Limberg, T. Happe, M. Haumann Inorganic Chemistry 2014, 53, 12164–12177, 10.1021/ic502047q

126 Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C–H Bonds for the Synthesis of 1,3-Diols B. Li, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 136, 6586–6589, 10.1021/ja5026479

125 An Elusive Hydridoaluminum(I) Complex for Facile C–H and C–O Bond Activation of Ethers and Access to Its Isolable Hydridogallium(I) Analogue: Syntheses, Structures, and Theoretical Studies G. Tan, T. Szilvási, S. Inoue, B. Blom, M. Driess Journal of the American Chemical Society 2014, 136, 9732–9742, 10.1021/ja504448v

124 Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes B. L. Tran, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 136, 17292–17301, 10.1021/ja510093x

123 Unification of Catalytic Water Oxidation and Oxygen Reduction Reactions: Amorphous Beat Crystalline Cobalt Iron Oxides A. Indra, P. W. Menezes, N. R. Sahraie, A. Bergmann, C. Das, M. Tallarida, D. Schmeißer, P. Strasser, M. Driess Journal of the American Chemical Society 2014, 136, 17530–17536, 10.1021/ja509348t

122 Synthesis, Reactivity, and Electronic Structure of a Bioinspired Heterobimetallic [Ni(μ-S2)Fe] Complex with Disulfur Monoradical character R. Rudolph, B. Blom, S. Yao, F. Meier, E. Bill, M. van Gastel, N. Lindenmaier, M. Kaupp, M. Driess Organometallics 2014, 33, 3154–3162, 10.1021/om500381t

121 From Unsymmetrically Substituted Benzamidinato and Guanidinato Dichlorohydridosilanes to Novel Hydrido N-Heterocyclic Silylene Iron Complexes B. Blom, M. Pohl, G. Tan, D. Gallego, M. Driess Organometallics 2014, 33, 5272–5282, 10.1021/om5005918

120 Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity D. Gallego, S. Inoue, B. Blom, M. Driess Organometallics 2014, 33, 6885–6897, 10.1021/om500966t

119 Dendritic Polyglycerol–Poly(ethylene glycol)-Based Polymer Networks for Biosensing Application P. Dey, M. Adamovski, S. Friebe, A. Badalyan, R. C. Mutihac, F. Paulus, S. Leimkühler, U. Wollenberger, R. Haag ACS Applied Materials & Interfaces 2014, 6, 8937–8941, 10.1021/am502018x

118 Ketoxime Coupling of p-Acetylphenylalanine at Neutral pH for Site-Directed Spin Labeling of Human Sulfite Oxidase A. Hahn, S. Reschke, S. Leimkühler, T. Risse The Journal of Physical Chemistry B 2014, 118, 7077–7084, 10.1021/jp503471j

117 The Biosynthesis of the Molybdenum Cofactor in Escherichia coli and Its Connection to FeS Cluster Assembly and the Thiolation of tRNA S. Leimkühler Advances in Biology 2014, 2014, 1–21, 10.1155/2014/808569

116 Catalytic bio–chemo and bio–bio tandem oxidation reactions for amide and carboxylic acid synthesis B. Bechi, S. Herter, S. McKenna, C. Riley, S. Leimkühler, N. J. Turner, A. J. Carnell Green Chem. 2014, 16, 4524–4529, 10.1039/c4gc01321b

115 Structural Data on the Periplasmic Aldehyde Oxidoreductase PaoABC from Escherichia coli: SAXS and Preliminary X-ray Crystallography Analysis A. Otrelo-Cardoso, M. da Silva Correia, V. Schwuchow, D. Svergun, M. Romão, S. Leimkühler, T. Santos-Silva International Journal of Molecular Sciences 2014, 15, 2223–2236, 10.3390/ijms15022223

114 Biochemical, Stabilization and Crystallization Studies on a Molecular Chaperone (PaoD) Involved in the Maturation of Molybdoenzymes A. R. Otrelo-Cardoso, V. Schwuchow, D. Rodrigues, E. J. Cabrita, S. Leimkühler, M. J. Romão, T. Santos-Silva, A. Pastore PLoS ONE 2014, 9, 10.1371/journal.pone.0087295

113 Pyranopterin Dithiolene Distortions Relevant to Electron Transfer in Xanthine Oxidase/Dehydrogenase C. Dong, J. Yang, S. Leimkühler, M. L. Kirk Inorganic Chemistry 2014, 53, 7077–7079, 10.1021/ic500873y

112 The biosynthesis of the molybdenum cofactors R. R. Mendel, S. Leimkühler JBIC Journal of Biological Inorganic Chemistry 2014, 10.1007/s00775-014-1173-y

111 The Reductive Half-reaction of Xanthine Dehydrogenase from Rhodobacter capsulatus: THE ROLE OF GLU232 IN CATALYSIS J. Hall, S. Reschke, H. Cao, S. Leimkuhler, R. Hille Journal of Biological Chemistry 2014, 289, 32121–32130, 10.1074/jbc.M114.603456

110 The role of FeS clusters for molybdenum cofactor biosynthesis and molybdoenzymes in bacteria K. Yokoyama, S. Leimkühler Biochimica et Biophysica Acta Biochimica et Biophysica Acta (BBA) - Molecular Cell Research 2014, 10.1016/j.bbamcr.2014.09.021

109 Electrical Wiring of the Aldehyde Oxidoreductase PaoABC with a Polymer Containing Osmium Redox Centers: Biosensors for Benzaldehyde and GABA A. Badalyan, M. Dierich, K. Stiba, V. Schwuchow, S. Leimkühler, U. Wollenberger Biosensors 2014, 4, 403–421, 10.3390/bios4040403

108 Assembly and catalysis of molybdenum or tungsten-containing formate dehydrogenases from bacteria T. Hartmann, N. Schwanhold, S. Leimkühler Biochimica et Biophysica Acta Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics 2014, 10.1016/j.bbapap.2014.12.006

107 [Ge(H)(2-C6H4PPh2)3] as Ligand Precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C6H4PPh2)3}] R. Herrmann, T. Braun, S. Mebs European Journal of Inorganic Chemistry 2014, 2014, 4826–4835, 10.1002/ejic.201402256

106 Electrochemical displacement sensor based on ferrocene boronic acid tracer and immobilized glycan for saccharide binding proteins and E. coli D. Dechtrirat, N. Gajovic-Eichelmann, F. Wojcik, L. Hartmann, F. F. Bier, F. W. Scheller Biosensors and Bioelectronics 2014, 58, 1–8, 10.1016/j.bios.2014.02.028

105 Hybrid Material for Protein Sensing Based on Electrosynthesized MIP on a Mannose Terminated Self-Assembled Monolayer D. Dechtrirat, N. Gajovic-Eichelmann, F. F. Bier, F. W. Scheller Advanced Functional Materials 2014, 24, 2233–2239, 10.1002/adfm.201303148

104 Third Generation ATP Sensor with Enzymatic Analyte Recycling A. Yarman, C. Schulz, C. Sygmund, R. Ludwig, L. Gorton, U. Wollenberger, F. W. Scheller Electroanalysis 2014, 26, 2043–2048, 10.1002/elan.201400231

103 Characterization of the enhanced peroxidatic activity of amyloid β peptide–hemin complexes towards neurotransmitters B. Neumann, A. Yarman, U. Wollenberger, F. Scheller Analytical and Bioanalytical Chemistry 2014, 406, 3359–3364, 10.1007/s00216-014-7822-8

102 The First Electrochemical MIP Sensor for Tamoxifen A. Yarman, F. Scheller Sensors 2014, 14, 7647–7654, 10.3390/s140507647

101 Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper–nitrene complexes S. L. Abram, I. Monte-Pérez, F. F. Pfaff, E. R. Farquhar, K. Ray Chemical Communications 2014, 50, 9852– 10.1039/C4CC03754E

100 Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups S. Kundu, E. Miceli, E. R. Farquhar, K. Ray Dalton Transactions 2014, 43, 4264– 10.1039/C3DT52644E

99 Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions S. Hong, F. F. Pfaff, E. Kwon, Y. Wang, M. S. Seo, E. Bill, K. Ray, W. Nam Angewandte Chemie International Edition 2014, 53, 10403–10407, 10.1002/anie.201405874

98 Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions K. Ray, F. F. Pfaff, B. Wang, W. Nam Journal of the American Chemical Society 2014, 136, 13942–13958, 10.1021/ja507807v

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96 Support Effect in Oxide Catalysis: Methanol Oxidation on Vanadia/Ceria T. Kropp, J. Paier, J. Sauer Journal of the American Chemical Society 2014, 136, 14616–14625, 10.1021/ja508657c

95 Effect of Anharmonicity on Adsorption Thermodynamics G. Piccini, J. Sauer Journal of Chemical Theory and Computation 2014, 10, 2479–2487, 10.1021/ct500291x

94 Tuning porosity and activity of microporous polymer network organocatalysts by co-polymerisation J. Schmidt, D. S. Kundu, S. Blechert, A. Thomas Chemical Communications 2014, 50, 3347– 10.1039/C3CC49220F

93 Mechanism of NO reduction by CO over Pt/SBA-15 P. Xiao, R. C. Davis, X. Ouyang, J. Li, A. Thomas, S. L. Scott, J. Zhu Catalysis Communications 2014, 50, 69–72, 10.1016/j.catcom.2014.02.027

92 Noble-Metal-Free Electrocatalysts with Enhanced ORR Performance by Task-Specific Functionalization of Carbon using Ionic Liquid Precursor Systems N. Ranjbar Sahraie, J. P. Paraknowitsch, C. Göbel, A. Thomas, P. Strasser Journal of the American Chemical Society 2014, 136, 14486–14497, 10.1021/ja506553r

91 A Self-Improved Water-Oxidation Catalyst: Is One Site Really Enough? I. López, M. Z. Ertem, S. Maji, J. Benet-Buchholz, A. Keidel, U. Kuhlmann, P. Hildebrandt, C. J. Cramer, V. S. Batista, A. Llobet Angewandte Chemie International Edition 2014, 53, 205–209, 10.1002/anie.201307509

90 Escherichia coli RIC Is Able to Donate Iron to Iron-Sulfur Clusters L. S. Nobre, R. Garcia-Serres, S. Todorovic, P. Hildebrandt, M. Teixeira, J. M. Latour, L. M. Saraiva, A. Giuffrè PLoS ONE 2014, 9, 10.1371/journal.pone.0095222

89 Voltage-dependent structural changes of the membrane-bound anion channel hVDAC1 probed by SEIRA and electrochemical impedance spectroscopy J. Kozuch, C. Weichbrodt, D. Millo, K. Giller, S. Becker, P. Hildebrandt, C. Steinem Physical Chemistry Chemical Physics 2014, 16, 9546– 10.1039/C4CP00167B

88 Reductive activation and structural rearrangement in superoxide reductase: a combined infrared spectroscopic and computational study M. Horch, A. F. Pinto, T. Utesch, M. A. Mroginski, C. V. Romão, M. Teixeira, P. Hildebrandt, I. Zebger Phys. Chem. Chem. Phys. 2014, 16, 14220–14230, 10.1039/C4CP00884G

87 Metal-induced histidine deprotonation in biocatalysis? Experimental and theoretical insights into superoxide reductase M. Horch, A. F. Pinto, M. A. Mroginski, M. Teixeira, P. Hildebrandt, I. Zebger RSC Adv. 2014, 4, 54091–54095, 10.1039/C4RA11976B

86 More than fine tuning P. Hildebrandt Science 2014, 346, 1456–1457, 10.1126/science.aaa2878

85 NirN Protein from Pseudomonas aeruginosa is a Novel Electron-bifurcating Dehydrogenase Catalyzing the Last Step of Heme d1 Biosynthesis J. Adamczack, M. Hoffmann, U. Papke, K. Haufschildt, T. Nicke, M. Broring, M. Sezer, R. Weimar, U. Kuhlmann, P. Hildebrandt, G. Layer Journal of Biological Chemistry 2014, 289, 30753–30762, 10.1074/jbc.M114.603886

84 Cellular Metabolites Enhance the Light Sensitivity of Arabidopsis Cryptochrome through Alternate Electron Transfer Pathways C. Engelhard, X. Wang, D. Robles, J. Moldt, L. O. Essen, A. Batschauer, R. Bittl, M. Ahmad The Plant Cell Online 2014, 26, 4519–4531, 10.1105/tpc.114.129809

83 Structural Transformations of Zinc Oxide Layers on Pt(111) B. H. Liu, M. E. McBriarty, M. J. Bedzyk, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C 2014, 118, 28725–28729, 10.1021/jp510069q

82 Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom J. Hermeke, M. Mewald, E. Irran, M. Oestreich Organometallics 2014, 33, 5097–5100, 10.1021/om500851r

81 Support effect in the preparation of supported metal catalysts via microemulsion R. Y. Parapat, O. H. I. Saputra, A. P. Ang, M. Schwarze, R. Schomäcker RSC Adv. 2014, 4, 50955–50963, 10.1039/C4RA10736E

80 Enhanced catalytic performance of MnxOy–Na2WO4/SiO2 for the oxidative coupling of methane using an ordered mesoporous silica support M. Yildiz, Y. Aksu, U. Simon, K. Kailasam, O. Goerke, F. Rosowski, R. Schomäcker, A. Thomas, S. Arndt Chem. Commun. 2014, 50, 14440–14442, 10.1039/C4CC06561A

79 Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts C. A. Carrero, R. Schloegl, I. E. Wachs, R. Schomaecker ACS Catalysis 2014, 4, 3357–3380, 10.1021/cs5003417

78 Nanostructured Manganese Oxides as Highly Active Water Oxidation Catalysts: A Boost from Manganese Precursor Chemistry P. W. Menezes, A. Indra, P. Littlewood, M. Schwarze, C. Göbel, R. Schomäcker, M. Driess ChemSusChem 2014, 7, 2202–2211, 10.1002/cssc.201402169

77 Catalytic Activity of Mono- and Bi-Metallic Nanoparticles Synthesized via Microemulsions R. König, M. Schwarze, R. Schomäcker, C. Stubenrauch Catalysts 2014, 4, 256–275, 10.3390/catal4030256

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75 Sol–gel method for synthesis of Mn–Na2WO4/SiO2 catalyst for methane oxidative coupling H. R. Godini, A. Gili, O. Görke, S. Arndt, U. Simon, A. Thomas, R. Schomäcker, G. Wozny Catalysis Today 2014, 236, 12–22, 10.1016/j.cattod.2014.01.005

74 Thermal Reaction Analysis of Oxidative Coupling of Methane H. Godini, V. Fleischer, O. Görke, S. Jaso, R. Schomäcker, G. Wozny Chemie Ingenieur Technik 2014, 86, 1906–1915, 10.1002/cite.201400080

73 Autocatalytic growth of ZnO nanorods from flat Au(111)-supported ZnO films L. Pascua, F. Stavale, N. Nilius, H. J. Freund Phys. Chem. Chem. Phys. 2014, 16, 26741–26745, 10.1039/c4cp03730h

72 Reactivity of Ultra-Thin ZnO Films Supported by Ag(111) and Cu(111): A Comparison to ZnO/Pt(111) Q. Pan, B. H. Liu, M. E. McBriarty, Y. Martynova, I. M. N. Groot, S. Wang, M. J. Bedzyk, S. Shaikhutdinov, H. J. Freund Catalysis Letters 2014, 144, 648–655, 10.1007/s10562-014-1191-y

71 Ceria Nanocrystals Exposing Wide (100) Facets: Structure and Polarity Compensation Y. Pan, N. Nilius, C. Stiehler, H. J. Freund, J. Goniakowski, C. Noguera Advanced Materials Interfaces 2014, 1, 1400404– 10.1002/admi.201400404

70 The role of exposed silver in CO oxidation over MgO(001)/Ag(001) thin films F. Ringleb, Y. Fujimori, M. A. Brown, W. E. Kaden, F. Calaza, H. Kuhlenbeck, M. Sterrer, H. J. Freund Catalysis Today 2014, 240, 206–213, 10.1016/j.cattod.2014.04.025

69 Interconversion of α-Fe2O3 and Fe3O4 Thin Films: Mechanisms, Morphology, and Evidence for Unexpected Substrate Participation F. Genuzio, A. Sala, T. Schmidt, D. Menzel, H. J. Freund The Journal of Physical Chemistry C 2014, 118, 29068–29076, 10.1021/jp504020a

68 Platinum Group Metal Clusters: From Gas-Phase Structures and Reactivities towards Model Catalysts D. J. Harding, A. Fielicke Chemistry - A European Journal 2014, 20, 3258–3267, 10.1002/chem.201304586

67 Far-IR Spectra of Small Neutral Gold Clusters in the Gas Phase P. Gruene, B. Butschke, J. T. Lyon, D. M. Rayner, A. Fielicke Zeitschrift für Physikalische Chemie 2014, 228, 337–350, 10.1515/zpch-2014-0480

66 Superoxide Formation on Isolated Cationic Gold Clusters A. P. Woodham, A. Fielicke Angewandte Chemie International Edition 2014, 53, 6554–6557, 10.1002/anie.201402783

65 Highly regioselective hydride transfer, oxidative dehydrogenation, and hydrogen-atom abstraction in the thermal gas-phase chemistry of [Zn(OH)]+/C3H8 X. N. Wu, H. T. Zhao, J. Li, M. Schlangen, H. Schwarz Phys. Chem. Chem. Phys. 2014, 16, 26617–26623, 10.1039/c4cp02139h

64 Structural Characterization of CO-Inhibited Mo-Nitrogenase by Combined Application of Nuclear Resonance Vibrational Spectroscopy, Extended X-ray Absorption Fine Structure, and Density Functional Theory: New Insights into the Effects of CO Binding and the Role of the Interstitial Atom A. D. Scott, V. Pelmenschikov, Y. Guo, L. Yan, H. Wang, S. J. George, C. H. Dapper, W. E. Newton, Y. Yoda, Y. Tanaka, S. P. Cramer Journal of the American Chemical Society 2014, 136, 15942–15954, 10.1021/ja505720m

63 Native-like Photosystem II Superstructure at 2.44 Å Resolution through Detergent Extraction from the Protein Crystal J. Hellmich, M. Bommer, A. Burkhardt, M. Ibrahim, J. Kern, A. Meents, F. Müh, H. Dobbek, A. Zouni Structure 2014, 22, 1607–1615, 10.1016/j.str.2014.09.007

62 Taking snapshots of photosynthetic water oxidation using femtosecond X-ray diffraction and spectroscopy J. Kern, R. Tran, R. Alonso-Mori, S. Koroidov, N. Echols, J. Hattne, M. Ibrahim, S. Gul, H. Laksmono, R. G. Sierra, R. J. Gildea, G. Han, J. Hellmich, B. Lassalle-Kaiser, R. Chatterjee, A. S. Brewster, C. A. Stan, C. Glöckner, A. Lampe, D. DiFiore, D. Mil Nature Communications 2014, 5, 10.1038/ncomms5371

61 A Molecular Approach to Self-Supported Cobalt-Substituted ZnO Materials as Remarkably Stable Electrocatalysts for Water Oxidation J. Pfrommer, M. Lublow, A. Azarpira, C. Göbel, M. Lücke, A. Steigert, M. Pogrzeba, P. W. Menezes, A. Fischer, T. Schedel-Niedrig, M. Driess Angewandte Chemie International Edition 2014, 53, 5183–5187, 10.1002/anie.201400243

60 ATP-induced electron transfer by redox-selective partner recognition S. E. Hennig, S. Goetzl, J. H. Jeoung, M. Bommer, F. Lendzian, P. Hildebrandt, H. Dobbek Nature Communications 2014, 5, 10.1038/ncomms5626

59 Sites for Methane Activation on Lithium-Doped Magnesium Oxide Surfaces K. Kwapien, J. Paier, J. Sauer, M. Geske, U. Zavyalova, R. Horn, P. Schwach, A. Trunschke, R. Schlögl Angewandte Chemie International Edition 2014, 53, 8774–8778, 10.1002/anie.201310632

58 Surface defects and their impact on the electronic structure of Mo-doped CaO films: an STM and DFT study Y. Cui, X. Shao, S. Prada, L. Giordano, G. Pacchioni, H. J. Freund, N. Nilius Physical Chemistry Chemical Physics 2014, 16, 12764– 10.1039/C4CP01565G

57 Nature of active sites in Ni2P hydrotreating catalysts as probed by iron substitution H. Zhao, S. T. Oyama, H. J. Freund, R. Włodarczyk, M. Sierka Applied Catalysis B: Environmental 2014, 164, 204–216, 10.1016/j.apcatb.2014.09.010

56 Synthesis and vibrational spectroscopy of 57Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction D. Schilter, V. Pelmenschikov, H. Wang, F. Meier, L. B. Gee, Y. Yoda, M. Kaupp, T. B. Rauchfuss, S. P. Cramer Chemical Communications Chem. Commun. 2014, 50, 13469–13472, 10.1039/C4CC04572F

55 How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane? H. Schwarz Israel Journal of Chemistry 2014, 54, 1413–1431, 10.1002/ijch.201300134

54 Detailed numerical simulations of catalytic fixed-bed reactors: Heterogeneous dry reforming of methane G. D. Wehinger, T. Eppinger, M. Kraume Chemical Engineering Science 2014, 122, 197–209, 10.1016/j.ces.2014.09.007

53 Catalytic Borylation of SCF3-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective C-H Activation at the ortho-Position S. I. Kalläne, T. Braun Angewandte Chemie International Edition 2014, 53, 9311–9315, 10.1002/anie.201406424

52 Synthesis and Structures of Fluorinated (β-Diketiminato)rhodium Complexes: Si-H Activation of Silanes at a Carbonyl Complex G. Meier, V. Steck, B. Braun, A. Eißler, R. Herrmann, M. Ahrens, R. Laubenstein, T. Braun European Journal of Inorganic Chemistry 2014, 2014, 2793–2808, 10.1002/ejic.201402087

51 Crystal structure of a common GPCR-binding interface for G protein and arrestin M. Szczepek, F. Beyrière, K. P. Hofmann, M. Elgeti, R. Kazmin, A. Rose, F. J. Bartl, D. von Stetten, M. Heck, M. E. Sommer, P. W. Hildebrand, P. Scheerer Nature Communications 2014, 5, 4801– 10.1038/ncomms5801

50 Oxygen activation on oxide surfaces: A perspective at the atomic level H. J. Freund Catalysis Today 2014, 10.1016/j.cattod.2014.05.037

49 Luminescence Properties of Nitrogen-Doped ZnO F. Stavale, L. Pascua, N. Nilius, H. J. Freund The Journal of Physical Chemistry C 2014, 118, 13693–13696, 10.1021/jp5035536

48 Position of Transmembrane Helix 6 Determines Receptor G Protein Coupling Specificity A. S. Rose, M. Elgeti, U. Zachariae, H. Grubmüller, K. P. Hofmann, P. Scheerer, P. W. Hildebrand Journal of the American Chemical Society 2014, 136, 11244–11247, 10.1021/ja5055109

47 Resonance Raman spectroscopy on [NiFe] hydrogenase provides structural insights into catalytic intermediates and reactions M. Horch, J. Schoknecht, M. A. Mroginski, O. Lenz, P. Hildebrandt, I. Zebger Journal of the American Chemical Society 2014, 136, 9870–9873, 10.1021/ja505119q

46 Enhanced oxygen-tolerance of the full heterotrimeric membrane-bound [NiFe]-hydrogenase of Ralstonia eutropha V. Radu, S. Frielingsdorf, S. D. Evans, O. Lenz, L. J. C. Jeuken Journal of the American Chemical Society 2014, 136, 8512–8515, 10.1021/ja503138p

45 Rubredoxin-related maturation factor guarantees metal cofactor integrity during aerobic biosynthesis of membrane-bound [NiFe] hydrogenase J. Fritsch, E. Siebert, J. Priebe, I. Zebger, F. Lendzian, C. Teutloff, B. Friedrich, O. Lenz Journal of Biological Chemistry 2014, 289, 7982–7993, 10.1074/jbc.M113.544668

44 The Structure of a Transient Complex of a Nonribosomal Peptide Synthetase and a Cytochrome P450 Monooxygenase K. Haslinger, C. Brieke, S. Uhlmann, L. Sieverling, R. D. Süssmuth, M. J. Cryle Angewandte Chemie International Edition 2014, 53, 8518–8522, 10.1002/anie.201404977

43 Paenilamicin: Structure and Biosynthesis of a Hybrid Nonribosomal Peptide/Polyketide Antibiotic from the Bee Pathogen Paenibacillus larvae S. Müller, E. Garcia-Gonzalez, A. Mainz, G. Hertlein, N. C. Heid, E. Mösker, H. van den Elst, H. S. Overkleeft, E. Genersch, R. D. Süssmuth Angewandte Chemie International Edition 2014, 10.1002/anie.201404572

42 Isolation and structure elucidation of the nucleoside antibiotic strepturidin from Streptomyces albus DSM 40763 A. Pesic, B. Steinhaus, S. Kemper, J. Nachtigall, H. J. Kutzner, G. Höfle, R. D. Süssmuth The Journal of Antibiotics 2014, 67, 471–477, 10.1038/ja.2014.16

41 Elucidation of sevadicin, a novel non-ribosomal peptide secondary metabolite produced by the honey bee pathogenic bacterium Paenibacillus larvae E. Garcia-Gonzalez, S. Müller, P. Ensle, R. D. Süssmuth, E. Genersch Environmental Microbiology 2014, 16, 1297–1309, 10.1111/1462-2920.12417

40 Stereochemistry and Conformation of Skyllamycin, a Non-Ribosomally Synthesized Peptide from Streptomyces sp. Acta 2897 V. Schubert, F. Di Meo, P. L. Saaidi, S. Bartoschek, H. P. Fiedler, P. Trouillas, R. D. Süssmuth Chemistry - A European Journal 2014, 20, 4948–4955, 10.1002/chem.201304562

39 Biological effects of paenilamicin, a secondary metabolite antibiotic produced by the honey bee pathogenic bacterium Paenibacillus larvae E. Garcia-Gonzalez, S. Müller, G. Hertlein, N. Heid, R. D. Süssmuth, E. Genersch MicrobiologyOpen 2014, 10.1002/mbo3.195

38 On divorcing isomers, dissecting reactivity, and resolving mechanisms of propane C—H and aryl C—X (X = halogen) bond activations mediated by a ligated copper(III) oxo complex N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Chemical Physics Letters 2014, 608, 408–424, 10.1016/j.cplett.2014.05.005

37 Adsorption of thioether molecules on an alumina thin film Y. Pan, N. Nilius, W. D. Schneider, H. J. Freund Surface Science 2014, 628, 111–115, 10.1016/j.susc.2014.05.021

36 Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative Si–N Coupling J. Hermeke, H. F. T. Klare, M. Oestreich Chemistry - A European Journal 2014, 20, 9250–9254, 10.1002/chem.201402866

35 Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex T. T. Metsänen, P. Hrobárik, H. F. T. Klare, M. Kaupp, M. Oestreich Journal of the American Chemical Society 2014, 136, 6912–6915, 10.1021/ja503254f

34 Engineering of a red-light-activated human cAMP/cGMP-specific phosphodiesterase C. Gasser, S. Taiber, C. M. Yeh, C. H. Wittig, P. Hegemann, S. Ryu, F. Wunder, A. Möglich Proceedings of the National Academy of Sciences 2014, 10.1073/pnas.1321600111

33 Thermal Ethane Activation by Bare [V2O5]+ and [Nb2O5]+ Cluster Cations: on the Origin of Their Different Reactivities X. N. Wu, S. Y. Tang, H. T. Zhao, T. Weiske, M. Schlangen, H. Schwarz Chemistry - A European Journal 2014, 20, 6672–6677, 10.1002/chem.201402055

32 High performance (VOx)n–(TiOx)m/SBA-15 catalysts for the oxidative dehydrogenation of propane C. Carrero, M. Kauer, A. Dinse, T. Wolfram, N. Hamilton, A. Trunschke, R. Schlögl, R. Schomäcker Catalysis Science & Technology 2014, 4, 786– 10.1039/c3cy00625e

31 Oxidative coupling of methane—A complex surface/gas phase mechanism with strong impact on the reaction engineering B. Beck, V. Fleischer, S. Arndt, M. G. Hevia, A. Urakawa, P. Hugo, R. Schomäcker Catalysis Today 2014, 228, 212–218, 10.1016/j.cattod.2013.11.059

30 Reversible [4Fe-3S] cluster morphing in an O2-tolerant [NiFe] hydrogenase S. Frielingsdorf, J. Fritsch, A. Schmidt, M. Hammer, J. Löwenstein, E. Siebert, V. Pelmenschikov, T. Jaenicke, J. Kalms, Y. Rippers, F. Lendzian, I. Zebger, C. Teutloff, M. Kaupp, R. Bittl, P. Hildebrandt, B. Friedrich, O. Lenz, P. Scheerer Nature Chemical Biology 2014, 10, 378–385, 10.1038/nchembio.1500

29 Versatile reactivity of a rhodium(I) boryl complex towards ketones and imines S. I. Kalläne, T. Braun, B. Braun, S. Mebs Dalton Transactions 2014, 43, 6786– 10.1039/c4dt00080c

28 Hyperbranched polyglycerol supported ruthenium catalysts for ring-closing metathesis V. S. Thengarai, J. Keilitz, R. Haag Inorganica Chimica Acta 2014, 409, 179–184, 10.1016/j.ica.2013.06.031

27 The chaperone FdsC for Rhodobacter capsulatus formate dehydrogenase binds the bis-molybdopterin guanine dinucleotide cofactor N. Böhmer, T. Hartmann, S. Leimkühler FEBS Letters 2014, 588, 531–537, 10.1016/j.febslet.2013.12.033

26 Fluidic Effects on Kinetic Parameter Estimation in Lab-scale Catalysis Testing - A Critical Evaluation Based on Computational Fluid Dynamics G. D. Wehinger, T. Eppinger, M. Kraume Chemical Engineering Science 2014, 111, 220–230, 10.1016/j.ces.2014.02.025

25 Visible light driven non-sacrificial water oxidation and dye degradation with silver phosphates: multi-faceted morphology matters A. Indra, P. W. Menezes, M. Schwarze, M. Driess New Journal of Chemistry 2014, 10.1039/C3NJ01012K

24 Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride G. Tan, W. Wang, B. Blom, M. Driess Dalton Transactions 2014, 10.1039/C3DT53321B

23 N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field B. Blom, D. Gallego, M. Driess Inorganic Chemistry Frontiers 2014, 1, 134–148, 10.1039/C3QI00079F

22 A Donor-Stabilized Zwitterionic “Half-Parent” Phosphasilene and Its Unusual Reactivity towards Small Molecules K. Hansen, T. Szilvási, B. Blom, E. Irran, M. Driess Chemistry - A European Journal 2014, 20, 1947–1956, 10.1002/chem.201303906

21 Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes B. L. Tran, B. Li, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 136, 2555–2563, 10.1021/ja411912p

20 Facile Access to Mono- and Dinuclear Heteroleptic N-Heterocyclic Silylene Copper Complexes G. Tan, B. Blom, D. Gallego, M. Driess Organometallics 2014, 33, 363–369, 10.1021/om4011033

19 Harnessing the Evolvability of Tricyclic Microviridins To Dissect Protease-Inhibitor Interactions A. R. Weiz, K. Ishida, F. Quitterer, S. Meyer, J. C. Kehr, K. M. Müller, M. Groll, C. Hertweck, E. Dittmann Angewandte Chemie International Edition 2014, 53, 3735–3738, 10.1002/anie.201309721

18 Biosynthetic rivalry of o-aminophenol-carboxylic acids initiates production of hemi-actinomycins in Streptomyces antibioticus I. Crnovcic, S. Semsary, J. Vater, U. Keller RSC Advances 2014, 4, 5065–5074, 10.1039/C3RA45661G

17 MALDI-TOF mass spectrometry, an efficient technique for in situ detection and characterization of actinomycins J. Vater, I. Crnovcic, S. Semsary, U. Keller Journal of Mass Spectrometry 2014, 49, 210–222, 10.1002/jms.3329

16 Cyclolization of D-Lysergic Acid Alkaloid Peptides J. Havemann, D. Vogel, B. Loll, U. Keller Chemistry & Biology 2014, 21, 146–155, 10.1016/j.chembiol.2013.11.008

15 Polymeric Carbon Nitride/Mesoporous Silica Composites as Catalyst Support for Au and Pt Nanoparticles P. Xiao, Y. Zhao, T. Wang, Y. Zhan, H. Wang, J. Li, A. Thomas, J. Zhu Chemistry - A European Journal 2014, 20, 2872–2878, 10.1002/chem.201303741

14 A Sustainable Template for Mesoporous Zeolite Synthesis R. J. White, A. Fischer, C. Goebel, A. Thomas Journal of the American Chemical Society 2014, 136, 2715–2718, 10.1021/ja411586h

13 Experimentelle Validierung von robuster Prozessplanung und -regelung mit Gauß'schen Mischdichten N. Rossner, R. King at – Automatisierungstechnik 2014, 62, 10.1515/auto-2014-1016

12 Biophysical, mutational and functional investigation of the chromophore-binding pocket of light-oxygen-voltage photoreceptors R. P. Diensthuber, C. Engelhard, N. Lemke, T. Gleichmann, R. Ohlendorf, R. Bittl, A. Möglich ACS Synthetic Biology 2014, 140220144111007– 10.1021/sb400205x

11 Neutral and Cationic Zinc Complexes with N- and S-Donor-Functionalized Cyclopentadienyl Ligands M. A. Chilleck, T. Braun, B. Braun, S. Mebs Organometallics 2014, 33, 551–560, 10.1021/om401076g

10 Functional Analysis of Environmental DNA-Derived Microviridins Provides New Insights into the Diversity of the Tricyclic Peptide Family D. Gatte-Picchi, A. Weiz, K. Ishida, C. Hertweck, E. Dittmann Applied and Environmental Microbiology 2014, 80, 1380–1387, 10.1128/AEM.03502-13

9 Redox Non-Innocence of a N-Heterocyclic Nitrenium Cation Bound to a Nickel–Cyclam Core F. Heims, F. F. Pfaff, S. L. Abram, E. R. Farquhar, M. Bruschi, C. Greco, K. Ray Journal of the American Chemical Society 2014, 136, 582–585, 10.1021/ja4099559

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7 Shining light on integrity of a tetracobalt-polyoxometalate water oxidation catalyst by X-ray spectroscopy before and after catalysis R. Schiwon, K. Klingan, H. Dau, C. Limberg Chemical Communications 2014, 50, 100– 10.1039/C3CC46629A

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1 Optimal operation of a membrane reactor network E. Esche, H. Arellano-Garcia, L. T. Biegler AIChE Journal 2014, 1, 170–180, 10.1002/aic.14252