Publications 2014

Number of records: 197

197 Cytotoxicity and genotoxicity of nano - and microparticulate copper oxide: role of solubility and intracellular bioavailability A. Semisch, J. Ohle, B. Witt, A. Hartwig Particle and Fibre Toxicology 2014, 1, 10– 10.1186/1743-8977-11-10

196 Tuning Spatial Distribution of Surface Hydroxyls on a Metal-Supported Single-Layer Silica B. Yang, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry Letters The Journal of Physical Chemistry Letters 2014, 10, 1701–1704, 10.1021/jz500689t

195 Applying thermo-destabilization of microemulsions as a new method for co-catalyst loading on mesoporous polymeric carbon nitride – towards large scale applications M. Schröder, K. Kailasam, S. Rudi, K. Fündling, J. Rieß, M. Lublow, A. Thomas, R. Schomäcker, M. Schwarze RSC Adv. RSC Adv. 2014, 91, 50017–50026, 10.1039/C4RA10814K

194 Speciation of Molybdates under Hydrothermal Conditions J. Noack, F. Rosowski, R. Schlögl, A. Trunschke Zeitschrift für anorganische und allgemeine Chemie Zeitschrift für Anorganische und Allgemeine Chemie 2014, 14, 2730–2736, 10.1002/zaac.201400439

193 Ambient-Pressure Soft X-ray Absorption Spectroscopy of a Catalyst Surface in Action: Closing the Pressure Gap in the Selective -Butane Oxidation over Vanadyl Pyrophosphate C. Heine, M. Hävecker, E. Stotz, F. Rosowski, A. Knop-Gericke, A. Trunschke, M. Eichelbaum, R. Schlögl The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2014, 35, 20405–20412, 10.1021/jp506068x

192 Mechanisms of cell uptake and toxicity of the anticancer drug cisplatin N. D. Eljack, H. Y. M. Ma, J. Drucker, C. Shen, T. W. Hambley, E. J. New, T. Friedrich, R. J. Clarke Metallomics Metallomics 2014, 11, 2126–2133, 10.1039/C4MT00238E

191 A missense variant of the ATP1A2 gene is associated with a novel phenotype of progressive sensorineural hearing loss associated with migraine S. K. Oh, J. I. Baek, K. M. Weigand, H. Venselaar, H. G. P. Swarts, S. H. Park, M. Hashim Raza, D. J. Jung, S. Y. Choi, S. H. Lee, T. Friedrich, G. Vriend, J. B. Koenderink, U. K. Kim, K. Y. Lee European Journal of Human Genetics European Journal of Human Genetics 2014, 5, 639–645, 10.1038/ejhg.2014.154

190 A Single-Photon Avalanche Camera for Fluorescence Lifetime Imaging Microscopy and Correlation Spectroscopy M. Vitali, L. Terenius, F. Zappa, R. Rigler, D. Bronzi, A. J. Krmpot, S. N. Nikolic, F. J. Schmitt, C. Junghans, S. Tisa, T. Friedrich, V. Vukojevic IEEE Journal of Selected Topics in Quantum Electronics IEEE Journal of Selected Topics in Quantum Electronics 2014, 6, 344–353, 10.1109/JSTQE.2014.2333238

189 Functional analysis of human Na(+)/K(+)-ATPase familial or sporadic hemiplegic migraine mutations expressed in Xenopus oocytes S. Spiller, T. Friedrich World Journal of Biological Chemistry 2014, 5, 240–253, 10.4331/wjbc.v5.i2.240

188 eGFP-pHsens as a highly sensitive fluorophore for cellular pH determination by fluorescence lifetime imaging microscopy (FLIM) F. J. Schmitt, B. Thaa, C. Junghans, M. Vitali, M. Veit, T. Friedrich Biochimica et Biophysica Acta (BBA) - Bioenergetics Biochimica et Biophysica Acta (BBA) - Bioenergetics 2014, 9, 1581–1593, 10.1016/j.bbabio.2014.04.003

187 The time course of non-photochemical quenching in phycobilisomes of Synechocystis sp. PCC6803 as revealed by picosecond time-resolved fluorimetry E. G. Maksimov, F. J. Schmitt, E. A. Shirshin, M. D. Svirin, I. V. Elanskaya, T. Friedrich, V. V. Fadeev, V. Z. Paschenko, A. B. Rubin Biochimica et Biophysica Acta (BBA) - Bioenergetics Biochimica et Biophysica Acta (BBA) - Bioenergetics 2014, 9, 1540–1547, 10.1016/j.bbabio.2014.01.010

186 The extended reductive acetyl-CoA pathway: ATPases in metal cluster maturation and reductive activation J. H. Jeoung, S. Goetzl, S. E. Hennig, J. Fesseler, C. Wörmann, J. Dendra, H. Dobbek Biological Chemistry Biological Chemistry 2014, 5, 545–558, 10.1515/hsz-2013-0290

185 Structural basis for organohalide respiration M. Bommer, C. Kunze, J. Fesseler, T. Schubert, G. Diekert, H. Dobbek Science 2014, 6208, 455–458, 10.1126/science.1258118

184 Carbon monoxide. Toxic gas and fuel for anaerobes and aerobes: carbon monoxide dehydrogenases. J. H. Jeoung, J. Fesseler, S. Götzl Met Ions Life Sci. 2014, 14, 37–69, 10.1007/978-94-017-9269-1_3

183 Antireflective Coatings with Adjustable Refractive Index and Porosity Synthesized by Micelle-Templated Deposition of MgF Sol Particles D. Bernsmeier, J. Polte, E. Ortel, T. Krahl, E. Kemnitz, R. Kraehnert ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces 2014, 22, 19559–19565, 10.1021/am5052685

182 Versatile control over size and spacing of small mesopores in metal oxide films and catalytic coatings via templating with hyperbranched core–multishell polymers D. Bernsmeier, E. Ortel, J. Polte, B. Eckhardt, S. Nowag, R. Haag, R. Kraehnert J. Mater. Chem. A J. Mater. Chem. A 2014, 32, 13075–13082, 10.1039/C4TA01842G

181 Mechanical behavior of mesoporous titania thin films T. Rahman, R. Liu, E. Ortel, R. Kraehnert, A. Antoniou Applied Physics Letters 2014, 24, 241902– 10.1063/1.4883260

180 Electrocatalytic Oxygen Evolution on Iridium Oxide: Uncovering Catalyst-Substrate Interactions and Active Iridium Oxide Species T. Reier, D. Teschner, T. Lunkenbein, A. Bergmann, S. Selve, R. Kraehnert, R. Schlögl, P. Strasser Journal of The Electrochemical Society 2014, 9, 10.1149/2.0411409jes

179 Direct synthesis of nanosized-ZSM-5/SBA-15 analog composites from preformed ZSM-5 precursors for improved catalytic performance as cracking catalyst X. H. Vu, U. Bentrup, M. Hunger, R. Kraehnert, U. Armbruster, A. Martin Journal of Materials Science Journal of Materials Science 2014, 16, 5676–5689, 10.1007/s10853-014-8287-z

178 Prototyping of catalyst pore-systems by a combined synthetic, analytical and computational approach: Application to mesoporous TiO2 V. Novák, E. Ortel, B. Winter, B. Butz, B. Paul, P. Kočí, M. Marek, E. Spiecker, R. Kraehnert Chemical Engineering Journal 2014, 49–62, 10.1016/j.cej.2014.02.004

177 Dioxygen Activation by Siloxide Complexes of Chromium(II) and Chromium(IV) F. Schax, E. Bill, C. Herwig, C. Limberg Angewandte Chemie International Edition 2014, 47, 12741–12745, 10.1002/anie.201406313

176 A Cubic Fe Mo Oxo Framework and Its Reversible Four-Electron Redox Chemistry J. P. Falkenhagen, B. Braun, E. Bill, D. Sattler, C. Limberg Inorganic Chemistry 2014, 14, 7294–7308, 10.1021/ic500584a

175 Three-Coordinate Nickel(II) and Nickel(I) Thiolate Complexes Based on the β-Diketiminate Ligand System B. Horn, C. Limberg, C. Herwig, B. Braun Inorganic Chemistry 2014, 13, 6867–6874, 10.1021/ic500698v

174 Molecular Cu -O-Cu Complexes: Still Waters Run Deep P. Haack, C. Limberg Angewandte Chemie International Edition 2014, 17, 4282–4293, 10.1002/anie.201309505

173 A Tripodal Trisilanol Ligand and Its Complexation Behavior towards Cu , Cu , and Zn F. Schax, B. Braun, C. Limberg European Journal of Inorganic Chemistry 2014, 12, 2124–2130, 10.1002/ejic.201400088

172 A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O Reactivity R. Metzinger, S. Demeshko, C. Limberg Chemistry - A European Journal 2014, 16, 4721–4735, 10.1002/chem.201304535

171 Stability of nanostructured iridium oxide electrocatalysts during oxygen evolution reaction in acidic environment S. Cherevko, T. Reier, A. R. Zeradjanin, Z. Pawolek, P. Strasser, K. J. J. Mayrhofer Electrochemistry Communications Electrochemistry Communications 2014, 81–85, 10.1016/j.elecom.2014.08.027

170 Water oxidation by manganese oxides formed from tetranuclear precursor complexes: the influence of phosphate on structure and activity D. Shevchenko, M. F. Anderlund, S. Styring, H. Dau, I. Zaharieva, A. Thapper Physical Chemistry Chemical Physics 2014, 24, 11965– 10.1039/C3cp55125c

169 Biogenic Manganese-Calcium Oxides on the Cell Walls of the Algae : Elemental Composition, Atomic Structure, and Water-Oxidation Catalysis A. Schöler, I. Zaharieva, S. Zimmermann, M. Wiechen, A. M. Manke, P. Kurz, C. Plieth, H. Dau European Journal of Inorganic Chemistry 2014, 4, 780–790, 10.1002/ejic.201300697

168 Fragments of Layered Manganese Oxide Are the Real Water Oxidation Catalyst after Transformation of Molecular Precursor on Clay M. M. Najafpour, A. N. Moghaddam, H. Dau, I. Zaharieva Journal of the American Chemical Society 2014, 20, 7245–7248, 10.1021/Ja5028716

167 Screen-Printed Calcium-Birnessite Electrodes for Water Oxidation at Neutral pH and an “Electrochemical Harriman Series” S. Y. Lee, D. González-Flores, J. Ohms, T. Trost, H. Dau, I. Zaharieva, P. Kurz ChemSusChem 2014, 12, 3442–3451, 10.1002/cssc.201402533

166 Molecular genetic analysis of vesicular transport in Aspergillus niger reveals partial conservation of the molecular mechanism of exocytosis in fungi M. J. Kwon, M. Arentshorst, M. Fiedler, F. L. M. de Groen, P. J. Punt, V. Meyer, A. F. J. Ram Microbiology Microbiology 2014, 2, 316–329, 10.1099/mic.0.074252-0

165 A bifunctional enzyme from Rhodococcus erythropolis exhibiting secondary alcohol dehydrogenase-catalase activities E. Martinez-Rojas, T. Kurt, U. Schmidt, V. Meyer, L. A. Garbe Applied Microbiology and Biotechnology Applied Microbiology and Biotechnology 2014, 22, 9249–9258, 10.1007/s00253-014-5808-2

164 The capacity of Aspergillus niger to sense and respond to cell wall stress requires at least three transcription factors: RlmA, MsnA and CrzA M. R. Fiedler, A. Lorenz, B. M. Nitsche, C. A. van den Hondel, A. F. Ram, V. Meyer Fungal Biology and Biotechnology Fungal Biology and Biotechnology 2014, 1, 10.1186/s40694-014-0005-8

163 Recycling Concept for End-of-Life Silicones: Boron Trifluoride Diethyl Etherate as Depolymerization Reagent to Produce Difluorodimethylsilane as Useful Commodity P. Döhlert, J. Pfrommer, S. Enthaler ACS Sustainable Chemistry & Engineering ACS Sustainable Chemistry & Engineering 2014, 1, 163–169, 10.1021/sc500666d

162 Zinc-Catalyzed Depolymerization of End-of-Life Polysiloxanes S. Enthaler Angewandte Chemie International Edition 2014, 10, 2716–2721, 10.1002/anie.201309299

161 Low-Temperature Depolymerization of Polysiloxanes with Iron Catalysis S. Enthaler, R. Kretschmer ChemSusChem 2014, 7, 2030–2036, 10.1002/cssc.201301386

160 Coupling Bioorthogonal Chemistries with Artificial Metabolism: Intracellular Biosynthesis of Azidohomoalanine and Its Incorporation into Recombinant Proteins Y. Ma, H. Biava, R. Contestabile, N. Budisa, M. di Salvo Molecules Molecules 2014, 1, 1004–1022, 10.3390/molecules19011004

159 Sense codon emancipation for proteome-wide incorporation of noncanonical amino acids: rare isoleucine codon AUA as a target for genetic code expansion N. Bohlke, N. Budisa FEMS Microbiology Letters FEMS Microbiology Letters 2014, 2, 133–144, 10.1111/1574-6968.12371

158 Evolution of fluorinated enzymes: An emerging trend for biocatalyst stabilization H. Biava, N. Budisa Engineering in Life Sciences 2014, 4, 340–351, 10.1002/elsc.201300049

157 Zinc-Catalyzed Depolymerization of Polyethers to Produce Valuable Building Blocks S. Enthaler Catalysis Letters 2014, 5, 850–859, 10.1007/s10562-014-1214-8

156 Synthesis of Ni(II) complexes with unsymmetric [O,N,O′]-pincer ligands and their use as precatalysts in carbon–carbon bond formations to access diarylmethanes C. I. Someya, E. Irran, S. Enthaler Inorganica Chimica Acta Inorganica Chimica Acta 2014, 136–144, 10.1016/j.ica.2014.05.023

155 Exploring the coordination chemistry of 2-picolinic acid to zinc and application of the complexes in catalytic oxidation chemistry S. Enthaler, X. F. Wu, M. Weidauer, E. Irran, P. Döhlert Inorganic Chemistry Communications Inorganic Chemistry Communications 2014, 320–323, 10.1016/j.inoche.2014.06.020

154 Exploring the coordination chemistry of O,N,O′-ligands modified by 2-thienyl-substituents to nickel C. I. Someya, S. Inoue, E. Irran, S. Enthaler Inorganic Chemistry Communications Inorganic Chemistry Communications 2014, 114–118, 10.1016/j.inoche.2014.03.014

153 Zinc(II)-triflate as catalyst precursor for ring-closing depolymerization of end-of-life polytetrahydrofuran to produce tetrahydrofuran S. Enthaler Journal of Applied Polymer Science Journal of Applied Polymer Science 2014, 2, 10.1002/app.39791

152 Bio-inspired carbon nitride mesoporous spheres for artificial photosynthesis: photocatalytic cofactor regeneration for sustainable enzymatic synthesis J. Huang, M. Antonietti, J. Liu J. Mater. Chem. A Journal of Materials Chemistry A 2014, 21, 7686–7693, 10.1039/c4ta00793j

151 The bioinspired construction of an ordered carbon nitride array for photocatalytic mediated enzymatic reduction J. Liu, R. Cazelles, Z. P. Chen, H. Zhou, A. Galarneau, M. Antonietti Phys. Chem. Chem. Phys. 2014, 28, 14699–14705, 10.1039/c4cp01348d

150 Adsorption and photocatalytic splitting of water on graphitic carbon nitride: a combined first principles and semiempirical study J. Wirth, R. Neumann, M. Antonietti, P. Saalfrank Phys. Chem. Chem. Phys. 2014, 30, 15917–15926, 10.1039/c4cp02021a

149 Mesoporous graphitic carbon nitride as a heterogeneous catalyst for photoinduced copper( )-catalyzed azide–alkyne cycloaddition S. Dadashi-Silab, B. Kiskan, M. Antonietti, Y. Yagci RSC Adv. RSC Adv. 2014, 94, 52170–52173, 10.1039/c4ra09954k

148 Sponge-like Nickel and Nickel Nitride Structures for Catalytic Applications M. Shalom, V. Molinari, D. Esposito, G. Clavel, D. Ressnig, C. Giordano, M. Antonietti Advanced Materials 2014, 8, 1272–1276, 10.1002/adma.201304288

147 Titanium Nitride-Nickel Nanocomposite as Heterogeneous Catalyst for the Hydrogenolysis of Aryl Ethers V. Molinari, C. Giordano, M. Antonietti, D. Esposito Journal of the American Chemical Society 2014, 5, 1758–1761, 10.1021/ja4119412

146 Uniform Graphitic Carbon Nitride Nanorod for Efficient Photocatalytic Hydrogen Evolution and Sustained Photoenzymatic Catalysis J. Liu, J. Huang, H. Zhou, M. Antonietti ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces 2014, 11, 8434–8440, 10.1021/am501319v

145 Ultrafast Syntheses of Silver Foams from Ag NCN: Combustion Synthesis versus Chemical Reduction D. Ressnig, M. Antonietti Chemistry of Materials 2014, 14, 4064–4067, 10.1021/cm501475b

144 FeNi nanoparticles with carbon armor as sustainable hydrogenation catalysts: towards biorefineries G. Chieffi, C. Giordano, M. Antonietti, D. Esposito Journal of Materials Chemistry A Journal of Materials Chemistry A 2014, 30, 11591– 10.1039/c4ta02457e

143 Upconversion-Agent Induced Improvement of g-C N Photocatalyst under Visible Light J. Xu, T. J. K. Brenner, Z. Chen, D. Neher, M. Antonietti, M. Shalom ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces 2014, 19, 16481–16486, 10.1021/am5051263

142 Formation of Heterojunctions in Modified Graphitic Carbon Nitride: Synthesis and Noble Metal Free Photocatalysis M. Shalom, M. Guttentag, C. Fettkenhauer, S. Inal, D. Neher, A. Llobet, M. Antonietti Chemistry of Materials 2014, 19, 5812–5818, 10.1021/cm503258z

141 Metal-free ionic liquid-derived electrocatalyst for high-performance oxygen reduction in acidic and alkaline electrolytes K. Elumeeva, N. Fechler, T. P. Fellinger, M. Antonietti Mater. Horiz. Mater. Horiz. 2014, 6, 588–594, 10.1039/C4MH00123K

140 Blood Ties: Co O Decorated Blood Derived Carbon as a Superior Bifunctional Electrocatalyst C. Zhang, M. Antonietti, T. P. Fellinger Advanced Functional Materials 2014, 48, 7655–7665, 10.1002/adfm.201402770

139 Production of the Catechol Type Siderophore Bacillibactin by the Honey Bee Pathogen Paenibacillus larvae G. Hertlein, S. Müller, E. Garcia-Gonzalez, L. Poppinga, R. D. Süssmuth, E. Genersch PLoS ONE 2014, 9, 10.1371/journal.pone.0108272

138 Synthesis and Crystal Structure of δ-TaON, a Metastable Polymorph of Tantalum Oxide Nitride T. Lüdtke, A. Schmidt, C. Göbel, A. Fischer, N. Becker, C. Reimann, T. Bredow, R. Dronskowski, M. Lerch Inorganic Chemistry 2014, 21, 11691–11698, 10.1021/ic501726m

137 Water Oxidation by Amorphous Cobalt-Based Oxides: Volume Activity and Proton Transfer to Electrolyte Bases K. Klingan, F. Ringleb, I. Zaharieva, J. Heidkamp, P. Chernev, D. Gonzalez-Flores, M. Risch, A. Fischer, H. Dau ChemSusChem 2014, 5, 1301–1310, 10.1002/cssc.201301019

136 Synthesis and Crystal Structure of Rutile-type ScTa O N S. Cosgun, M. Rohloff, C. Göbel, U. Gernert, A. Fischer, M. Lerch Zeitschrift für anorganische und allgemeine Chemie Zeitschrift für anorganische und allgemeine Chemie 2014, 14, 2771–2775, 10.1002/zaac.201400325

135 Bacillus subtilis as heterologous host for the secretory production of the non-ribosomal cyclodepsipeptide enniatin S. Zobel, J. Kumpfmüller, R. D. Süssmuth, T. Schweder Applied Microbiology and Biotechnology Applied Microbiology and Biotechnology 2014, 2, 681–691, 10.1007/s00253-014-6199-0

134 Engineering of Aspergillus niger for the production of secondary metabolites L. Richter, F. Wanka, S. Boecker, D. Storm, T. Kurt, Ö. Vural, R. Süßmuth, V. Meyer Fungal Biology and Biotechnology Fungal Biology and Biotechnology 2014, 1, 10.1186/s40694-014-0004-9

133 Dissecting Reactions of Nonlinear Precursor Peptide Processing of the Class III Lanthipeptide Curvopeptin N. A. Jungmann, B. Krawczyk, M. Tietzmann, P. Ensle, R. D. Süssmuth Journal of the American Chemical Society 2014, 43, 15222–15228, 10.1021/ja5062054

132 On Ammonia Binding to the Oxygen-Evolving Complex of Photosystem II: A Quantum Chemical Study J. Schraut, M. Kaupp Chemistry - A European Journal 2014, 24, 7300–7308, 10.1002/chem.201304464

131 Quantum-chemical insights into mixed-valence systems: within and beyond the Robin–Day scheme M. Parthey, M. Kaupp Chem. Soc. Rev. 2014, 14, 5067–5088, 10.1039/C3CS60481K

130 Ligand spheres in asymmetric hetero Diels–Alder reactions catalyzed by Cu( ) box complexes: experiment and modeling V. Umamaheswari, P. Cias, A. Pöppl, M. Kaupp, G. Gescheidt Dalton Trans. Dalton Transactions 2014, 2, 698–705, 10.1039/c3dt51602d

129 Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic CH Bonds Directed by a Secondary Amine Q. Li, M. Driess, J. F. Hartwig Angewandte Chemie International Edition 2014, 32, 8471–8474, 10.1002/anie.201404620

128 Elucidating the Effect of the Nucleophilicity of the Silyl Group in the Reduction of CO to CO Mediated by Silyl-Copper(I) Complexes G. Tan, B. Blom, D. Gallego, E. Irran, M. Driess Chemistry - A European Journal 2014, 30, 9400–9408, 10.1002/chem.201402017

127 High Catalytic Synergism between the Components of the Rhenium Complex@Silver Hybrid Material in Alkene Epoxidations A. Indra, M. Greiner, A. K. Gericke, R. Schlögl, D. Avnir, M. Driess ChemCatChem 2014, 7, 1935–1939, 10.1002/cctc.201402042

126 Hydride Binding to the Active Site of [FeFe]-Hydrogenase P. Chernev, C. Lambertz, A. Brünje, N. Leidel, K. G. V. Sigfridsson, R. Kositzki, C. H. Hsieh, S. Yao, R. Schiwon, M. Driess, C. Limberg, T. Happe, M. Haumann Inorganic Chemistry 2014, 22, 12164–12177, 10.1021/ic502047q

125 Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C–H Bonds for the Synthesis of 1,3-Diols B. Li, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 18, 6586–6589, 10.1021/ja5026479

124 An Elusive Hydridoaluminum(I) Complex for Facile C–H and C–O Bond Activation of Ethers and Access to Its Isolable Hydridogallium(I) Analogue: Syntheses, Structures, and Theoretical Studies G. Tan, T. Szilvási, S. Inoue, B. Blom, M. Driess Journal of the American Chemical Society 2014, 27, 9732–9742, 10.1021/ja504448v

123 Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes B. L. Tran, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 49, 17292–17301, 10.1021/ja510093x

122 Unification of Catalytic Water Oxidation and Oxygen Reduction Reactions: Amorphous Beat Crystalline Cobalt Iron Oxides A. Indra, P. W. Menezes, N. R. Sahraie, A. Bergmann, C. Das, M. Tallarida, D. Schmeißer, P. Strasser, M. Driess Journal of the American Chemical Society 2014, 50, 17530–17536, 10.1021/ja509348t

121 Synthesis, Reactivity, and Electronic Structure of a Bioinspired Heterobimetallic [Ni(μ-S )Fe] Complex with Disulfur Monoradical character R. Rudolph, B. Blom, S. Yao, F. Meier, E. Bill, M. van Gastel, N. Lindenmaier, M. Kaupp, M. Driess Organometallics 2014, 12, 3154–3162, 10.1021/om500381t

120 From Unsymmetrically Substituted Benzamidinato and Guanidinato Dichlorohydridosilanes to Novel Hydrido N-Heterocyclic Silylene Iron Complexes B. Blom, M. Pohl, G. Tan, D. Gallego, M. Driess Organometallics 2014, 19, 5272–5282, 10.1021/om5005918

119 Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity D. Gallego, S. Inoue, B. Blom, M. Driess Organometallics 2014, 23, 6885–6897, 10.1021/om500966t

118 Dendritic Polyglycerol–Poly(ethylene glycol)-Based Polymer Networks for Biosensing Application P. Dey, M. Adamovski, S. Friebe, A. Badalyan, R. C. Mutihac, F. Paulus, S. Leimkühler, U. Wollenberger, R. Haag ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces 2014, 12, 8937–8941, 10.1021/am502018x

117 Ketoxime Coupling of -Acetylphenylalanine at Neutral pH for Site-Directed Spin Labeling of Human Sulfite Oxidase A. Hahn, S. Reschke, S. Leimkühler, T. Risse The Journal of Physical Chemistry B The Journal of Physical Chemistry B 2014, 25, 7077–7084, 10.1021/jp503471j

116 The Biosynthesis of the Molybdenum Cofactor in and Its Connection to FeS Cluster Assembly and the Thiolation of tRNA S. Leimkühler Advances in Biology Advances in Biology 2014, 1–21, 10.1155/2014/808569

115 Catalytic bio–chemo and bio–bio tandem oxidation reactions for amide and carboxylic acid synthesis B. Bechi, S. Herter, S. McKenna, C. Riley, S. Leimkühler, N. J. Turner, A. J. Carnell Green Chem. Green Chem. 2014, 10, 4524–4529, 10.1039/c4gc01321b

114 Structural Data on the Periplasmic Aldehyde Oxidoreductase PaoABC from Escherichia coli: SAXS and Preliminary X-ray Crystallography Analysis A. Otrelo-Cardoso, M. da Silva Correia, V. Schwuchow, D. Svergun, M. Romão, S. Leimkühler, T. Santos-Silva International Journal of Molecular Sciences International Journal of Molecular Sciences 2014, 2, 2223–2236, 10.3390/ijms15022223

113 Biochemical, Stabilization and Crystallization Studies on a Molecular Chaperone (PaoD) Involved in the Maturation of Molybdoenzymes A. R. Otrelo-Cardoso, V. Schwuchow, D. Rodrigues, E. J. Cabrita, S. Leimkühler, M. J. Romão, T. Santos-Silva PLoS ONE 2014, 1, 10.1371/journal.pone.0087295

112 Pyranopterin Dithiolene Distortions Relevant to Electron Transfer in Xanthine Oxidase/Dehydrogenase C. Dong, J. Yang, S. Leimkühler, M. L. Kirk Inorganic Chemistry 2014, 14, 7077–7079, 10.1021/ic500873y

111 The biosynthesis of the molybdenum cofactors R. R. Mendel, S. Leimkühler JBIC Journal of Biological Inorganic Chemistry JBIC Journal of Biological Inorganic Chemistry 2014, 2, 337–347, 10.1007/s00775-014-1173-y

110 The Reductive Half-reaction of Xanthine Dehydrogenase from J. Hall, S. Reschke, H. Cao, S. Leimkühler, R. Hille Journal of Biological Chemistry 2014, 46, 32121–32130, 10.1074/jbc.M114.603456

109 Electrical Wiring of the Aldehyde Oxidoreductase PaoABC with a Polymer Containing Osmium Redox Centers: Biosensors for Benzaldehyde and GABA A. Badalyan, M. Dierich, K. Stiba, V. Schwuchow, S. Leimkühler, U. Wollenberger Biosensors Biosensors 2014, 4, 403–421, 10.3390/bios4040403

108 [Ge(H)(2-C H PPh ) ] as Ligand Precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C H PPh ) }] R. Herrmann, T. Braun, S. Mebs European Journal of Inorganic Chemistry 2014, 28, 4826–4835, 10.1002/ejic.201402256

107 Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks T. Ahrens, J. Kohlmann, M. Ahrens, T. Braun Chemical Reviews Chemical Reviews 2014, 2, 931–972, 10.1021/cr500257c

106 Electrochemical displacement sensor based on ferrocene boronic acid tracer and immobilized glycan for saccharide binding proteins and E. coli D. Dechtrirat, N. Gajovic-Eichelmann, F. Wojcik, L. Hartmann, F. F. Bier, F. W. Scheller Biosensors and Bioelectronics 2014, 1–8, 10.1016/j.bios.2014.02.028

105 Hybrid Material for Protein Sensing Based on Electrosynthesized MIP on a Mannose Terminated Self-Assembled Monolayer D. Dechtrirat, N. Gajovic-Eichelmann, F. F. Bier, F. W. Scheller Advanced Functional Materials 2014, 15, 2233–2239, 10.1002/adfm.201303148

104 Third Generation ATP Sensor with Enzymatic Analyte Recycling A. Yarman, C. Schulz, C. Sygmund, R. Ludwig, L. Gorton, U. Wollenberger, F. W. Scheller Electroanalysis 2014, 9, 2043–2048, 10.1002/elan.201400231

103 Characterization of the enhanced peroxidatic activity of amyloid β peptide–hemin complexes towards neurotransmitters B. Neumann, A. Yarman, U. Wollenberger, F. Scheller Analytical and Bioanalytical Chemistry 2014, 14, 3359–3364, 10.1007/s00216-014-7822-8

102 The First Electrochemical MIP Sensor for Tamoxifen A. Yarman, F. Scheller Sensors Sensors 2014, 5, 7647–7654, 10.3390/s140507647

101 Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper–nitrene complexes S. L. Abram, I. Monte-Pérez, F. F. Pfaff, E. R. Farquhar, K. Ray Chem. Commun. 2014, 69, 9852–9854, 10.1039/C4CC03754E

100 Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups S. Kundu, E. Miceli, E. R. Farquhar, K. Ray Dalton Trans. Dalton Transactions 2014, 11, 4264–4267, 10.1039/C3DT52644E

99 Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions S. Hong, F. F. Pfaff, E. Kwon, Y. Wang, M. S. Seo, E. Bill, K. Ray, W. Nam Angewandte Chemie International Edition 2014, 39, 10403–10407, 10.1002/anie.201405874

98 Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions K. Ray, F. F. Pfaff, B. Wang, W. Nam Journal of the American Chemical Society 2014, 40, 13942–13958, 10.1021/ja507807v

97 Models in Catalysis J. Sauer, H. J. Freund Catalysis Letters 2014, 1, 109–125, 10.1007/s10562-014-1387-1

96 Support Effect in Oxide Catalysis: Methanol Oxidation on Vanadia/Ceria T. Kropp, J. Paier, J. Sauer Journal of the American Chemical Society 2014, 41, 14616–14625, 10.1021/ja508657c

95 Effect of Anharmonicity on Adsorption Thermodynamics G. Piccini, J. Sauer Journal of Chemical Theory and Computation 2014, 6, 2479–2487, 10.1021/ct500291x

94 Tuning porosity and activity of microporous polymer network organocatalysts by co-polymerisation J. Schmidt, D. S. Kundu, S. Blechert, A. Thomas Chem. Commun. 2014, 25, 3347–3349, 10.1039/C3CC49220F

93 Mechanism of NO reduction by CO over Pt/SBA-15 P. Xiao, R. C. Davis, X. Ouyang, J. Li, A. Thomas, S. L. Scott, J. Zhu Catalysis Communications 2014, 69–72, 10.1016/j.catcom.2014.02.027

92 Noble-Metal-Free Electrocatalysts with Enhanced ORR Performance by Task-Specific Functionalization of Carbon using Ionic Liquid Precursor Systems N. Ranjbar Sahraie, J. P. Paraknowitsch, C. Göbel, A. Thomas, P. Strasser Journal of the American Chemical Society 2014, 41, 14486–14497, 10.1021/ja506553r

91 A Self-Improved Water-Oxidation Catalyst: Is One Site Really Enough? I. López, M. Z. Ertem, S. Maji, J. Benet-Buchholz, A. Keidel, U. Kuhlmann, P. Hildebrandt, C. J. Cramer, V. S. Batista, A. Llobet Angewandte Chemie International Edition 2014, 1, 205–209, 10.1002/anie.201307509

90 Escherichia coli RIC Is Able to Donate Iron to Iron-Sulfur Clusters L. S. Nobre, R. Garcia-Serres, S. Todorovic, P. Hildebrandt, M. Teixeira, J. M. Latour, L. M. Saraiva PLoS ONE 2014, 4, 10.1371/journal.pone.0095222

89 Voltage-dependent structural changes of the membrane-bound anion channel hVDAC1 probed by SEIRA and electrochemical impedance spectroscopy J. Kozuch, C. Weichbrodt, D. Millo, K. Giller, S. Becker, P. Hildebrandt, C. Steinem Phys. Chem. Chem. Phys. 2014, 20, 9546–9555, 10.1039/C4CP00167B

88 Reductive activation and structural rearrangement in superoxide reductase: a combined infrared spectroscopic and computational study M. Horch, A. F. Pinto, T. Utesch, M. A. Mroginski, C. V. Romão, M. Teixeira, P. Hildebrandt, I. Zebger Phys. Chem. Chem. Phys. Phys. Chem. Chem. Phys. 2014, 27, 14220–14230, 10.1039/C4CP00884G

87 Metal-induced histidine deprotonation in biocatalysis? Experimental and theoretical insights into superoxide reductase M. Horch, A. F. Pinto, M. A. Mroginski, M. Teixeira, P. Hildebrandt, I. Zebger RSC Adv. RSC Adv. 2014, 96, 54091–54095, 10.1039/C4RA11976B

86 More than fine tuning P. Hildebrandt Science 2014, 6216, 1456–1457, 10.1126/science.aaa2878

85 NirN Protein from is a Novel Electron-bifurcating Dehydrogenase Catalyzing the Last Step of Heme Biosynthesis J. Adamczack, M. Hoffmann, U. Papke, K. Haufschildt, T. Nicke, M. Bröring, M. Sezer, R. Weimar, U. Kuhlmann, P. Hildebrandt, G. Layer Journal of Biological Chemistry 2014, 44, 30753–30762, 10.1074/jbc.M114.603886

84 Cellular Metabolites Enhance the Light Sensitivity of Cryptochrome through Alternate Electron Transfer Pathways C. Engelhard, X. Wang, D. Robles, J. Moldt, L. O. Essen, A. Batschauer, R. Bittl, M. Ahmad The Plant Cell The Plant Cell Online 2014, 11, 4519–4531, 10.1105/tpc.114.129809

83 Structural Transformations of Zinc Oxide Layers on Pt(111) B. H. Liu, M. E. McBriarty, M. J. Bedzyk, S. Shaikhutdinov, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2014, 49, 28725–28729, 10.1021/jp510069q

82 Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State T. T. Metsänen, M. Oestreich Organometallics 2014, 3, 543–546, 10.1021/om501279a

81 Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom J. Hermeke, M. Mewald, E. Irran, M. Oestreich Organometallics 2014, 19, 5097–5100, 10.1021/om500851r

80 Support effect in the preparation of supported metal catalysts microemulsion R. Y. Parapat, O. H. I. Saputra, A. P. Ang, M. Schwarze, R. Schomäcker RSC Adv. RSC Adv. 2014, 92, 50955–50963, 10.1039/C4RA10736E

79 Enhanced catalytic performance of Mn O –Na WO /SiO for the oxidative coupling of methane using an ordered mesoporous silica support M. Yildiz, Y. Aksu, U. Simon, K. Kailasam, O. Goerke, F. Rosowski, R. Schomäcker, A. Thomas, S. Arndt Chem. Commun. 2014, 92, 14440–14442, 10.1039/c4cc06561a

78 Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts C. A. Carrero, R. Schloegl, I. E. Wachs, R. Schomaecker ACS Catalysis 2014, 10, 3357–3380, 10.1021/cs5003417

77 Nanostructured Manganese Oxides as Highly Active Water Oxidation Catalysts: A Boost from Manganese Precursor Chemistry P. W. Menezes, A. Indra, P. Littlewood, M. Schwarze, C. Göbel, R. Schomäcker, M. Driess ChemSusChem 2014, 8, 2202–2211, 10.1002/cssc.201402169

76 Catalytic Activity of Mono- and Bi-Metallic Nanoparticles Synthesized via Microemulsions R. König, M. Schwarze, R. Schomäcker, C. Stubenrauch Catalysts Catalysts 2014, 3, 256–275, 10.3390/catal4030256

75 Methane Activation S. Arndt, R. Schomäcker Molecular Sciences and Chemical Engineering 2014, 2, 1–13, 10.1016/B978-0-12-409547-2.10948-5

74 Sol–gel method for synthesis of Mn–Na2WO4/SiO2 catalyst for methane oxidative coupling H. R. Godini, A. Gili, O. Görke, S. Arndt, U. Simon, A. Thomas, R. Schomäcker, G. Wozny Catalysis Today 2014, 12–22, 10.1016/j.cattod.2014.01.005

73 Thermal Reaction Analysis of Oxidative Coupling of Methane H. R. Godini, V. Fleischer, O. Görke, S. Jaso, R. Schomäcker, G. Wozny Chemie Ingenieur Technik Chemie Ingenieur Technik 2014, 11, 1906–1915, 10.1002/cite.201400080

72 Autocatalytic growth of ZnO nanorods from flat Au(111)-supported ZnO films L. Pascua, F. Stavale, N. Nilius, H. J. Freund Phys. Chem. Chem. Phys. Phys. Chem. Chem. Phys. 2014, 48, 26741–26745, 10.1039/c4cp03730h

71 Reactivity of Ultra-Thin ZnO Films Supported by Ag(111) and Cu(111): A Comparison to ZnO/Pt(111) Q. Pan, B. H. Liu, M. E. McBriarty, Y. Martynova, I. M. N. Groot, S. Wang, M. J. Bedzyk, S. Shaikhutdinov, H. J. Freund Catalysis Letters 2014, 4, 648–655, 10.1007/s10562-014-1191-y

70 Ceria Nanocrystals Exposing Wide (100) Facets: Structure and Polarity Compensation Y. Pan, N. Nilius, C. Stiehler, H. J. Freund, J. Goniakowski, C. Noguera Advanced Materials Interfaces Advanced Materials Interfaces 2014, 9, 1400404– 10.1002/admi.201400404

69 Interconversion of α-Fe O and Fe O Thin Films: Mechanisms, Morphology, and Evidence for Unexpected Substrate Participation F. Genuzio, A. Sala, T. Schmidt, D. Menzel, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2014, 50, 29068–29076, 10.1021/jp504020a

68 Platinum Group Metal Clusters: From Gas-Phase Structures and Reactivities towards Model Catalysts D. J. Harding, A. Fielicke Chemistry - A European Journal 2014, 12, 3258–3267, 10.1002/chem.201304586

67 Far-IR Spectra of Small Neutral Gold Clusters in the Gas Phase P. Gruene, B. Butschke, J. T. Lyon, D. M. Rayner, A. Fielicke Zeitschrift für Physikalische Chemie 2014, 4, 10.1515/zpch-2014-0480

66 Superoxide Formation on Isolated Cationic Gold Clusters A. P. Woodham, A. Fielicke Angewandte Chemie International Edition 2014, 25, 6554–6557, 10.1002/anie.201402783

65 Highly regioselective hydride transfer, oxidative dehydrogenation, and hydrogen-atom abstraction in the thermal gas-phase chemistry of [Zn(OH)] /C H X. N. Wu, H. T. Zhao, J. Li, M. Schlangen, H. Schwarz Phys. Chem. Chem. Phys. Phys. Chem. Chem. Phys. 2014, 48, 26617–26623, 10.1039/c4cp02139h

64 Structural Characterization of CO-Inhibited Mo-Nitrogenase by Combined Application of Nuclear Resonance Vibrational Spectroscopy, Extended X-ray Absorption Fine Structure, and Density Functional Theory: New Insights into the Effects of CO Binding and the Role of the Interstitial Atom A. D. Scott, V. Pelmenschikov, Y. Guo, L. Yan, H. Wang, S. J. George, C. H. Dapper, W. E. Newton, Y. Yoda, Y. Tanaka, S. P. Cramer Journal of the American Chemical Society 2014, 45, 15942–15954, 10.1021/ja505720m

63 Native-like Photosystem II Superstructure at 2.44 Å Resolution through Detergent Extraction from the Protein Crystal J. Hellmich, M. Bommer, A. Burkhardt, M. Ibrahim, J. Kern, A. Meents, F. Müh, H. Dobbek, A. Zouni Structure 2014, 11, 1607–1615, 10.1016/j.str.2014.09.007

62 Taking snapshots of photosynthetic water oxidation using femtosecond X-ray diffraction and spectroscopy J. Kern, R. Tran, R. Alonso-Mori, S. Koroidov, N. Echols, J. Hattne, M. Ibrahim, S. Gul, H. Laksmono, R. G. Sierra, R. J. Gildea, G. Han, J. Hellmich, B. Lassalle-Kaiser, R. Chatterjee, A. S. Brewster, C. A. Stan, C. Glöckner, A. Lampe, D. DiFiore, D. Milathianaki, A. R. Fry, M. M. Seibert, J. E. Koglin, E. Gallo, J. Uhlig, D. Sokaras, T. C. Weng, P. H. Zwart, D. E. Skinner, M. J. Bogan, M. Messerschmidt, P. Glatzel, G. J. Williams, S. Boutet, P. D. Adams, A. Zouni, J. Messinger, N. K. Sauter, U. Bergmann, J. Yano, V. K. Yachandra Nature Communications Nature Communications 2014, 1, 10.1038/ncomms5371

61 A Molecular Approach to Self-Supported Cobalt-Substituted ZnO Materials as Remarkably Stable Electrocatalysts for Water Oxidation J. Pfrommer, M. Lublow, A. Azarpira, C. Göbel, M. Lücke, A. Steigert, M. Pogrzeba, P. W. Menezes, A. Fischer, T. Schedel-Niedrig, M. Driess Angewandte Chemie International Edition 2014, 10.1002/anie.201400243

60 ATP-induced electron transfer by redox-selective partner recognition S. E. Hennig, S. Goetzl, J. H. Jeoung, M. Bommer, F. Lendzian, P. Hildebrandt, H. Dobbek Nature Communications Nature Communications 2014, 1, 10.1038/ncomms5626

59 Sites for Methane Activation on Lithium-Doped Magnesium Oxide Surfaces K. Kwapien, J. Paier, J. Sauer, M. Geske, U. Zavyalova, R. Horn, P. Schwach, A. Trunschke, R. Schlögl Angewandte Chemie International Edition 2014, 33, 8774–8778, 10.1002/anie.201310632

58 Surface defects and their impact on the electronic structure of Mo-doped CaO films: an STM and DFT study Y. Cui, X. Shao, S. Prada, L. Giordano, G. Pacchioni, H. J. Freund, N. Nilius Phys. Chem. Chem. Phys. 2014, 25, 12764–12772, 10.1039/C4CP01565G

57 Synthesis and vibrational spectroscopy of Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction D. Schilter, V. Pelmenschikov, H. Wang, F. Meier, L. B. Gee, Y. Yoda, M. Kaupp, T. B. Rauchfuss, S. P. Cramer Chem. Commun. Chem. Commun. 2014, 88, 13469–13472, 10.1039/C4CC04572F

56 How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane? H. Schwarz Israel Journal of Chemistry Israel Journal of Chemistry 2014, 10, 1413–1431, 10.1002/ijch.201300134

55 Catalytic Borylation of SCF -Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective CH Activation at the -Position S. I. Kalläne, T. Braun Angewandte Chemie International Edition 2014, 35, 9311–9315, 10.1002/anie.201406424

54 Synthesis and Structures of Fluorinated (β-Diketiminato)rhodium Complexes: Si-H Activation of Silanes at a Carbonyl Complex G. Meier, V. Steck, B. Braun, A. Eißler, R. Herrmann, M. Ahrens, R. Laubenstein, T. Braun European Journal of Inorganic Chemistry 2014, 17, 2793–2808, 10.1002/ejic.201402087

53 Crystal structure of a common GPCR-binding interface for G protein and arrestin M. Szczepek, F. Beyrière, K. P. Hofmann, M. Elgeti, R. Kazmin, A. Rose, F. J. Bartl, D. von Stetten, M. Heck, M. E. Sommer, P. W. Hildebrand, P. Scheerer Nature Communications Nature Communications 2014, 1, 10.1038/ncomms5801

52 Oxygen activation on oxide surfaces: A perspective at the atomic level H. J. Freund Catalysis Today 2014, 2–9, 10.1016/j.cattod.2014.05.037

51 Luminescence Properties of Nitrogen-Doped ZnO F. Stavale, L. Pascua, N. Nilius, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2014, 25, 13693–13696, 10.1021/jp5035536

50 Position of Transmembrane Helix 6 Determines Receptor G Protein Coupling Specificity A. S. Rose, M. Elgeti, U. Zachariae, H. Grubmüller, K. P. Hofmann, P. Scheerer, P. W. Hildebrand Journal of the American Chemical Society 2014, 32, 11244–11247, 10.1021/ja5055109

49 Resonance Raman Spectroscopy on [NiFe] Hydrogenase Provides Structural Insights into Catalytic Intermediates and Reactions M. Horch, J. Schoknecht, M. A. Mroginski, O. Lenz, P. Hildebrandt, I. Zebger Journal of the American Chemical Society 2014, 28, 9870–9873, 10.1021/ja505119q

48 Enhanced Oxygen-Tolerance of the Full Heterotrimeric Membrane-Bound [NiFe]-Hydrogenase of V. Radu, S. Frielingsdorf, S. D. Evans, O. Lenz, L. J. C. Jeuken Journal of the American Chemical Society 2014, 24, 8512–8515, 10.1021/ja503138p

47 Rubredoxin-related Maturation Factor Guarantees Metal Cofactor Integrity during Aerobic Biosynthesis of Membrane-bound [NiFe] Hydrogenase J. Fritsch, E. Siebert, J. Priebe, I. Zebger, F. Lendzian, C. Teutloff, B. Friedrich, O. Lenz Journal of Biological Chemistry 2014, 11, 7982–7993, 10.1074/jbc.M113.544668

46 The Structure of a Transient Complex of a Nonribosomal Peptide Synthetase and a Cytochrome P450 Monooxygenase K. Haslinger, C. Brieke, S. Uhlmann, L. Sieverling, R. D. Süssmuth, M. J. Cryle Angewandte Chemie International Edition 2014, 32, 8518–8522, 10.1002/anie.201404977

45 Paenilamicin: Structure and Biosynthesis of a Hybrid Nonribosomal Peptide/Polyketide Antibiotic from the Bee Pathogen S. Müller, E. Garcia-Gonzalez, A. Mainz, G. Hertlein, N. C. Heid, E. Mösker, H. van den Elst, H. S. Overkleeft, E. Genersch, R. D. Süssmuth Angewandte Chemie International Edition 2014, 40, 10821–10825, 10.1002/anie.201404572

44 Isolation and structure elucidation of the nucleoside antibiotic strepturidin from Streptomyces albus DSM 40763 A. Pesic, B. Steinhaus, S. Kemper, J. Nachtigall, H. J. Kutzner, G. Höfle, R. D. Süssmuth The Journal of Antibiotics 2014, 6, 471–477, 10.1038/ja.2014.16

43 Elucidation of sevadicin, a novel non-ribosomal peptide secondary metabolite produced by the honey bee pathogenic bacterium E. Garcia-Gonzalez, S. Müller, P. Ensle, R. D. Süssmuth, E. Genersch Environmental Microbiology Environmental Microbiology 2014, 5, 1297–1309, 10.1111/1462-2920.12417

42 Stereochemistry and Conformation of Skyllamycin, a Non-Ribosomally Synthesized Peptide from sp. Acta 2897 V. Schubert, F. Di Meo, P. L. Saaidi, S. Bartoschek, H. P. Fiedler, P. Trouillas, R. D. Süssmuth Chemistry - A European Journal 2014, 17, 4948–4955, 10.1002/chem.201304562

41 Biological effects of paenilamicin, a secondary metabolite antibiotic produced by the honey bee pathogenic bacterium E. Garcia-Gonzalez, S. Müller, G. Hertlein, N. Heid, R. D. Süssmuth, E. Genersch MicrobiologyOpen MicrobiologyOpen 2014, 5, 642–656, 10.1002/mbo3.195

40 On divorcing isomers, dissecting reactivity, and resolving mechanisms of propane CH and aryl CX (X=halogen) bond activations mediated by a ligated copper(III) oxo complex N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Chemical Physics Letters 2014, 408–424, 10.1016/j.cplett.2014.05.005

39 Adsorption of thioether molecules on an alumina thin film Y. Pan, N. Nilius, W. D. Schneider, H. J. Freund Surface Science 2014, 111–115, 10.1016/j.susc.2014.05.021

38 Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling J. Hermeke, H. F. T. Klare, M. Oestreich Chemistry - A European Journal 2014, 30, 9250–9254, 10.1002/chem.201402866

37 Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex T. T. Metsänen, P. Hrobárik, H. F. T. Klare, M. Kaupp, M. Oestreich Journal of the American Chemical Society 2014, 19, 6912–6915, 10.1021/ja503254f

36 Engineering of a red-light-activated human cAMP/cGMP-specific phosphodiesterase C. Gasser, S. Taiber, C. M. Yeh, C. H. Wittig, P. Hegemann, S. Ryu, F. Wunder, A. Moglich Proceedings of the National Academy of Sciences Proceedings of the National Academy of Sciences 2014, 24, 8803–8808, 10.1073/pnas.1321600111

35 Thermal Ethane Activation by Bare [V O ] and [Nb O ] Cluster Cations: on the Origin of Their Different Reactivities X. N. Wu, S. Y. Tang, H. T. Zhao, T. Weiske, M. Schlangen, H. Schwarz Chemistry - A European Journal 2014, 22, 6672–6677, 10.1002/chem.201402055

34 High performance (VOx)n–(TiOx)m/SBA-15 catalysts for the oxidative dehydrogenation of propane C. Carrero, M. Kauer, A. Dinse, T. Wolfram, N. Hamilton, A. Trunschke, R. Schlögl, R. Schomäcker Catalysis Science & Technology Catalysis Science & Technology 2014, 3, 786– 10.1039/c3cy00625e

33 Oxidative coupling of methane—A complex surface/gas phase mechanism with strong impact on the reaction engineering B. Beck, V. Fleischer, S. Arndt, M. G. Hevia, A. Urakawa, P. Hugo, R. Schomäcker Catalysis Today 2014, 212–218, 10.1016/j.cattod.2013.11.059

32 Reversible [4Fe-3S] cluster morphing in an O2-tolerant [NiFe] hydrogenase S. Frielingsdorf, J. Fritsch, A. Schmidt, M. Hammer, J. Löwenstein, E. Siebert, V. Pelmenschikov, T. Jaenicke, J. Kalms, Y. Rippers, F. Lendzian, I. Zebger, C. Teutloff, M. Kaupp, R. Bittl, P. Hildebrandt, B. Friedrich, O. Lenz, P. Scheerer Nature Chemical Biology 2014, 5, 378–385, 10.1038/nchembio.1500

31 Versatile reactivity of a rhodium(i) boryl complex towards ketones and imines S. I. Kalläne, T. Braun, B. Braun, S. Mebs Dalton Transactions Dalton Transactions 2014, 18, 6786– 10.1039/c4dt00080c

30 Hyperbranched polyglycerol supported ruthenium catalysts for ring-closing metathesis V. S. Thengarai, J. Keilitz, R. Haag Inorganica Chimica Acta Inorganica Chimica Acta 2014, 179–184, 10.1016/j.ica.2013.06.031

29 The chaperone FdsC for formate dehydrogenase binds the bis-molybdopterin guanine dinucleotide cofactor N. Böhmer, T. Hartmann, S. Leimkühler FEBS Letters FEBS Letters 2014, 4, 531–537, 10.1016/j.febslet.2013.12.033

28 Fluidic effects on kinetic parameter estimation in lab-scale catalysis testing – A critical evaluation based on computational fluid dynamics G. D. Wehinger, T. Eppinger, M. Kraume Chemical Engineering Science 2014, 220–230, 10.1016/j.ces.2014.02.025

27 Visible light driven non-sacrificial water oxidation and dye degradation with silver phosphates: multi-faceted morphology matters A. Indra, P. W. Menezes, M. Schwarze, M. Driess New J. Chem. 2014, 5, 1942–1945, 10.1039/C3NJ01012K

26 Mechanistic studies of CO reduction to methanol mediated by an N-heterocyclic germylene hydride G. Tan, W. Wang, B. Blom, M. Driess Dalton Trans. Dalton Transactions 2014, 16, 6006–6011, 10.1039/C3DT53321B

25 N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field B. Blom, D. Gallego, M. Driess Inorg. Chem. Front. Inorganic Chemistry Frontiers 2014, 2, 134–148, 10.1039/C3QI00079F

24 A Donor-Stabilized Zwitterionic “Half-Parent” Phosphasilene and Its Unusual Reactivity towards Small Molecules K. Hansen, T. Szilvási, B. Blom, E. Irran, M. Driess Chemistry - A European Journal 2014, 7, 1947–1956, 10.1002/chem.201303906

23 Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes B. L. Tran, B. Li, M. Driess, J. F. Hartwig Journal of the American Chemical Society 2014, 6, 2555–2563, 10.1021/ja411912p

22 Harnessing the Evolvability of Tricyclic Microviridins To Dissect Protease-Inhibitor Interactions A. R. Weiz, K. Ishida, F. Quitterer, S. Meyer, J. C. Kehr, K. M. Müller, M. Groll, C. Hertweck, E. Dittmann Angewandte Chemie International Edition 2014, 14, 3735–3738, 10.1002/anie.201309721

21 Biosynthetic rivalry of o-aminophenol-carboxylic acids initiates production of hemi-actinomycins in Streptomyces antibioticus I. Crnovčić, S. Semsary, J. Vater, U. Keller RSC Advances 2014, 10, 5065– 10.1039/C3RA45661G

20 MALDI-TOF mass spectrometry, an efficient technique for detection and characterization of actinomycins J. Vater, I. Crnovčić, S. Semsary, U. Keller Journal of Mass Spectrometry Journal of Mass Spectrometry 2014, 3, 210–222, 10.1002/jms.3329

19 Cyclolization of D-Lysergic Acid Alkaloid Peptides J. Havemann, D. Vogel, B. Loll, U. Keller Chemistry & Biology 2014, 1, 146–155, 10.1016/j.chembiol.2013.11.008

18 Polymeric Carbon Nitride/Mesoporous Silica Composites as Catalyst Support for Au and Pt Nanoparticles P. Xiao, Y. Zhao, T. Wang, Y. Zhan, H. Wang, J. Li, A. Thomas, J. Zhu Chemistry - A European Journal 2014, 10, 2872–2878, 10.1002/chem.201303741

17 A Sustainable Template for Mesoporous Zeolite Synthesis R. J. White, A. Fischer, C. Goebel, A. Thomas Journal of the American Chemical Society 2014, 7, 2715–2718, 10.1021/ja411586h

16 Experimentelle Validierung von robuster Prozessplanung und -regelung mit Gauß\'schen Mischdichten N. Rossner, R. King at – Automatisierungstechnik at – Automatisierungstechnik 2014, 2, 10.1515/auto-2014-1016

15 Biophysical, Mutational, and Functional Investigation of the Chromophore-Binding Pocket of Light-Oxygen-Voltage Photoreceptors R. P. Diensthuber, C. Engelhard, N. Lemke, T. Gleichmann, R. Ohlendorf, R. Bittl, A. Möglich ACS Synthetic Biology ACS Synthetic Biology 2014, 11, 811–819, 10.1021/sb400205x

14 Systematic approaches for model derivation for optimization purposes E. Esche, D. Müller, R. Kraus, G. Wozny Chemical Engineering Science 2014, 215–224, 10.1016/j.ces.2013.11.041

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12 Functional Analysis of Environmental DNA-Derived Microviridins Provides New Insights into the Diversity of the Tricyclic Peptide Family D. Gatte-Picchi, A. Weiz, K. Ishida, C. Hertweck, E. Dittmann Applied and Environmental Microbiology 2014, 4, 1380–1387, 10.1128/AEM.03502-13

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