Publications 2016

Number of records: 177

177 Optimized immobilization of ZnO:Co electrocatalysts realizes 5% efficiency in photo-assisted splitting of water A. Azarpira, J. Pfrommer, K. Olech, C. Höhn, M. Driess, B. Stannowski, T. Schedel-Niedrig, M. Lublow Journal of Materials Chemistry A 2016, 4, 3082–3090, 10.1039/C5TA07329D

176 Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols T. L. Gianetti, S. P. Annen, G. Santiso-Quinones, M. Reiher, M. Driess, H. Grützmacher Angewandte Chemie International Edition 2016, 55, 1854–1858, 10.1002/anie.201509288

175 Morphology-Dependent Activities of Silver Phosphates: Visible-Light Water Oxidation and Dye Degradation P. W. Menezes, A. Indra, M. Schwarze, F. Schuster, M. Driess ChemPlusChem 2016, 81, 1068–1074, 10.1002/cplu.201500538

174 Yolk@Shell Nanoarchitectures with Bimetallic Nanocores–Synthesis and Electrocatalytic Applications A. Guiet, T. Unmüssig, C. Göbel, U. Vainio, M. Wollgarten, M. Driess, H. Schlaad, J. Polte, A. Fischer ACS Applied Materials & Interfaces 2016, 8, 28019–28029, 10.1021/acsami.6b06595

173 Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting P. W. Menezes, A. Indra, C. Das, C. Walter, C. Göbel, V. Gutkin, D. Schmeiβer, M. Driess ACS Catalysis 2016, 7, 103–109, 10.1021/acscatal.6b02666

172 Highly active promoters and native secretion signals for protein production during extremely low growth rates in Aspergillus niger F. Wanka, M. Arentshorst, T. C. Cairns, T. Jørgensen, A. F. J. Ram, V. Meyer Microbial Cell Factories 2016, 15, 10.1186/s12934-016-0543-2

171 Current challenges of research on filamentous fungi in relation to human welfare and a sustainable bio-economy: a white paper V. Meyer, M. R. Andersen, A. A. Brakhage, G. H. Braus, M. X. Caddick, T. C. Cairns, R. P. de Vries, T. Haarmann, K. Hansen, C. Hertz-Fowler, S. Krappmann, U. H. Mortensen, M. A. Peñalva, A. F. J. Ram, R. M. Head Fungal Biology and Biotechnology 2016, 3, 10.1186/s40694-016-0024-8

170 A Transcriptome Meta-Analysis Proposes Novel Biological Roles for the Antifungal Protein AnAFP in Aspergillus niger N. Paege, S. Jung, P. Schäpe, D. Müller-Hagen, J. P. Ouedraogo, C. Heiderich, J. Jedamzick, B. M. Nitsche, C. A. van den Hondel, A. F. Ram, V. Meyer PLOS ONE 2016, 11, 10.1371/journal.pone.0165755

169 Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C–F bond activation versus hydrogermylation T. Ahrens, M. Teltewskoi, M. Ahrens, T. Braun, R. Laubenstein Dalton Trans. 2016, 45, 17495–17507, 10.1039/C6DT03027K

168 Using Separable Nonnegative Matrix Factorization Techniques for the Analysis of Time-Resolved Raman Spectra R. Luce, P. Hildebrandt, U. Kuhlmann, J. Liesen Applied Spectroscopy 2016, 70, 1464–1475, 10.1177/0003702816662600

167 Monitoring the Transmembrane Proton Gradient Generated by Cytochromebo3in Tethered Bilayer Lipid Membranes Using SEIRA Spectroscopy S. Wiebalck, J. Kozuch, E. Forbrig, C. C. Tzschucke, L. J. C. Jeuken, P. Hildebrandt The Journal of Physical Chemistry B 2016, 120, 2249–2256, 10.1021/acs.jpcb.6b01435

166 Substrate–Protein Interactions of Type II NADH:Quinone Oxidoreductase fromEscherichia coli J. Salewski, A. P. Batista, F. V. Sena, D. Millo, I. Zebger, M. M. Pereira, P. Hildebrandt Biochemistry 2016, 55, 2722–2734, 10.1021/acs.biochem.6b00070

165 Domain motions and electron transfer dynamics in 2Fe-superoxide reductase M. Horch, T. Utesch, P. Hildebrandt, M. A. Mroginski, I. Zebger Phys. Chem. Chem. Phys. 2016, 18, 23053–23066, 10.1039/C6CP03666J

164 Gas-phase reactions of cationic molybdenum and tungsten monoxide with ethanol: a combined experimental/computational exercise P. González-Navarrete, M. Schlangen, H. Schwarz Structural Chemistry 2016, 28, 403–413, 10.1007/s11224-016-0862-2

163 MIPs and Aptamers for Recognition of Proteins in Biomimetic Sensing M. Menger, A. Yarman, J. Erdőssy, H. Yildiz, R. Gyurcsányi, F. Scheller Biosensors 2016, 6, 35– 10.3390/bios6030035

162 MIP-esterase/Tyrosinase Combinations for Paracetamol and Phenacetin A. Yarman, F. W. Scheller Electroanalysis 2016, 28, 2222–2227, 10.1002/elan.201600042

161 Light-Switchable Polymers of Intrinsic Microporosity D. Becker, N. Konnertz, M. Böhning, J. Schmidt, A. Thomas Chemistry of Materials 2016, 28, 8523–8529, 10.1021/acs.chemmater.6b02619

160 Copper-Free Sonogashira Coupling for High-Surface-Area Conjugated Microporous Poly(aryleneethynylene) Networks M. Trunk, A. Herrmann, H. Bildirir, A. Yassin, J. Schmidt, A. Thomas Chemistry - A European Journal 2016, 22, 7179–7183, 10.1002/chem.201600783

159 CH2Stabilized at Steps on Ru(0001) by Coadsorbates H. Kirsch, X. Zhao, Z. Ren, S. V. Levchenko, R. K. Campen The Journal of Physical Chemistry C 2016, 120, 24724–24733, 10.1021/acs.jpcc.6b07088

158 Ni Substitutional Defects in Bulk and at the (001) Surface of MgO from First-Principles Calculations A. Mazheika, S. V. Levchenko The Journal of Physical Chemistry C 2016, 120, 26934–26944, 10.1021/acs.jpcc.6b09505

157 Location of Trapped Electron Centers in the Bulk of Epitaxial MgO(001) Films Grown on Mo(001) Usingin situ W-band Electron Paramagnetic Resonance Spectroscopy D. Cornu, J. Rocker, A. Gonchar, T. Risse, H. J. Freund Physical Review Letters 2016, 117, 16801– 10.1103/PhysRevLett.117.016801

156 Evidence for Exchange Coupled Electrons and Holes in MgO after Oxidative Activation of CH4: A Multifrequency Transient Nutation EPR Study P. Schwach, M. Eichelbaum, R. Schlögl, T. Risse, K. P. Dinse The Journal of Physical Chemistry C 2016, 120, 3781–3790, 10.1021/acs.jpcc.5b11057

155 Hydration Structures of MgO, CaO, and SrO (001) Surfaces M. Ončák, R. Włodarczyk, J. Sauer The Journal of Physical Chemistry C 2016, 120, 24762–24769, 10.1021/acs.jpcc.6b07434

154 Ab Initio Calculation of Rate Constants for Molecule-Surface Reactions with Chemical Accuracy G. Piccini, M. Alessio, J. Sauer Angewandte Chemie International Edition 2016, 55, 5235–5237, 10.1002/anie.201601534

153 Accurate adsorption energies for small molecules on oxide surfaces: CH4/MgO(001) and C2H6/MgO(001) A. D. Boese, J. Sauer Journal of Computational Chemistry 2016, 37, 2374–2385, 10.1002/jcc.24462

152 Ligands with Two Different Binding Sites and O2Reactivity of their Copper(I) Complexes S. T. Li, B. Braun-Cula, S. Hoof, M. Dürr, I. Ivanović-Burmazović, C. Limberg European Journal of Inorganic Chemistry 2016, 2016, 4017–4027, 10.1002/ejic.201600420

151 Cyclohexane oxidative dehydrogenation over copper oxide catalysts S. L. Nauert, F. Schax, C. Limberg, J. M. Notestein Journal of Catalysis 2016, 341, 180–190, 10.1016/j.jcat.2016.07.002

150 Modelling the production of soluble hydrogenase in Ralstonia eutropha by on-line optimal experimental design F. Neddermeyer, V. Marhold, C. Menzel, D. Krämer, R. King IFAC-PapersOnLine 2016, 49, 627–632, 10.1016/j.ifacol.2016.07.238

149 Modeling, Simulation, and Economic Evaluation of a Hybrid CO2 Capture Process for Oxidative Coupling of Methane A. Penteado, E. Esche, R. Wilhelm, H. R. Godini, D. Salerno, G. Tolksdorf, V. A. Merchan, G. Wozny Computer Aided Chemical Engineering 2016, 38, 1231–1236, 10.1016/B978-0-444-63428-3.50210-1

148 Solution of Chance-Constrained Mixed-Integer Nonlinear Programming Problems E. Esche, D. Müller, S. Werk, I. E. Grossmann, G. Wozny Computer Aided Chemical Engineering 2016, 38, 91–96, 10.1016/B978-0-444-63428-3.50020-5

147 Techno-Economic Evaluation of an Oxidative Coupling of Methane Process at Industrial Scale Production D. Salerno, H. R. Godini, A. Penteado, E. Esche, G. Wozny Computer Aided Chemical Engineering 2016, 38, 1785–1790, 10.1016/B978-0-444-63428-3.50302-7

146 Tailor-Made Modeling and Solution of Novel Process Units by Modular CAPE-OPEN-based Flowsheeting G. Tolksdorf, E. Esche, J. van Baten, G. Wozny Computer Aided Chemical Engineering 2016, 38, 787–792, 10.1016/B978-0-444-63428-3.50136-3

145 Computer-Aided Process and Plant Development. A Review of Common Software Tools and Methods and Comparison against an Integrated Collaborative Approach V. A. Merchan, E. Esche, S. Fillinger, G. Tolksdorf, G. Wozny Chemie Ingenieur Technik 2016, 88, 50–69, 10.1002/cite.201500099

144 Design and Assessment of a Membrane and Absorption Based Carbon Dioxide Removal Process for Oxidative Coupling of Methane A. Penteado, E. Esche, D. Salerno, H. R. Godini, G. Wozny Industrial & Engineering Chemistry Research 2016, 55, 7473–7483, 10.1021/acs.iecr.5b04910

143 Treated Nanolayered Mn Oxide by Oxidizable Compounds: A Strategy To Improve the Catalytic Activity toward Water Oxidation M. Mahdi Najafpour, D. Jafarian Sedigh, S. Maedeh Hosseini, I. Zaharieva Inorganic Chemistry 2016, 55, 8827–8832, 10.1021/acs.inorgchem.6b01334

142 Axial Ligation and Redox Changes at the Cobalt Ion in Cobalamin Bound to Corrinoid Iron-Sulfur Protein (CoFeSP) or in Solution Characterized by XAS and DFT P. Schrapers, S. Mebs, S. Goetzl, S. E. Hennig, H. Dau, H. Dobbek, M. Haumann PLOS ONE 2016, 11, 10.1371/journal.pone.0158681

141 Electrosynthesis of Biomimetic Manganese-Calcium Oxides for Water Oxidation Catalysis-Atomic Structure and Functionality D. González-Flores, I. Zaharieva, J. Heidkamp, P. Chernev, E. Martínez-Moreno, C. Pasquini, M. R. Mohammadi, K. Klingan, U. Gernet, A. Fischer, H. Dau ChemSusChem 2016, 9, 379–387, 10.1002/cssc.201501399

140 Water oxidation catalysis – role of redox and structural dynamics in biological photosynthesis and inorganic manganese oxides I. Zaharieva, D. González-Flores, B. Asfari, C. Pasquini, M. R. Mohammadi, K. Klingan, I. Zizak, S. Loos, P. Chernev, H. Dau Energy Environ. Sci. 2016, 9, 2433–2443, 10.1039/C6EE01222A

139 Wiring of the aldehyde oxidoreductase PaoABC to electrode surfaces via entrapment in low potential phenothiazine-modified redox polymers P. Pinyou, A. Ruff, S. Pöller, S. Alsaoub, S. Leimkühler, U. Wollenberger, W. Schuhmann Bioelectrochemistry 2016, 109, 24–30, 10.1016/j.bioelechem.2015.12.005

138 Construction of Giant-Spin Hamiltonians from Many-Spin Hamiltonians by Third-Order Perturbation Theory and Application to an Fe3Cr Single-Molecule Magnet S. G. Tabrizi, A. V. Arbuznikov, M. Kaupp Chemistry - A European Journal 2016, 22, 6853–6862, 10.1002/chem.201504896

137 Completing the Heterocubane Family [Cp*AlE]4(E = O, S, Se, and Te) by Selective Oxygenation and Sulfuration of [Cp*Al]4: Density Functional Theory Calculations of [Cp*AlE]4and Reactivity of [Cp*AlO]4toward Hydrolysis A. C. Stelzer, P. Hrobárik, T. Braun, M. Kaupp, B. Braun-Cula Inorganic Chemistry 2016, 55, 4915–4923, 10.1021/acs.inorgchem.6b00462

136 Understanding Thermodynamic and Spectroscopic Properties of Tetragonal Mn12Single-Molecule Magnets from Combined Density Functional Theory/Spin-Hamiltonian Calculations S. Ghassemi Tabrizi, A. V. Arbuznikov, M. Kaupp The Journal of Physical Chemistry A 2016, 120, 6864–6879, 10.1021/acs.jpca.6b06896

135 Tracking Transient Conformational States of T4 Lysozyme at Room Temperature Combining X-ray Crystallography and Site-Directed Spin Labeling P. Consentius, U. Gohlke, B. Loll, C. Alings, R. Müller, U. Heinemann, M. Kaupp, M. Wahl, T. Risse Journal of the American Chemical Society 2016, 138, 12868–12875, 10.1021/jacs.6b05507

134 Giant spin–orbit effects on1H and13C NMR shifts for uranium(vi) complexes revisited: role of the exchange–correlation response kernel, bonding analyses, and new predictions A. H. Greif, P. Hrobárik, J. Autschbach, M. Kaupp Phys. Chem. Chem. Phys. 2016, 18, 30462–30474, 10.1039/C6CP06129J

133 cistrans-Amide isomerism of the 3,4-dehydroproline residue, the ‘unpuckered’ proline V. Kubyshkin, N. Budisa Beilstein Journal of Organic Chemistry 2016, 12, 589–593, 10.3762/bjoc.12.57

132 Photochemical formation of quinone methides from peptides containing modified tyrosine A. Husak, B. P. Noichl, T. Šumanovac Ramljak, M. Sohora, Org. Biomol. Chem. 2016, 14, 10894–10905, 10.1039/C6OB02191C

131 Energetic contribution to both acidity and conformational stability in peptide models V. Kubyshkin, P. Durkin, N. Budisa New J. Chem. 2016, 40, 5209–5220, 10.1039/C5NJ03611A

130 Incorporation of Amino Acids with Long-Chain Terminal Olefins into Proteins M. Exner, S. Köhling, J. Rivollier, S. Gosling, P. Srivastava, Z. Palyancheva, P. Herdewijn, M. P. Heck, J. Rademann, N. Budisa Molecules 2016, 21, 287– 10.3390/molecules21030287

129 One-Pot Synthesis of Unprotected Anomeric Glycosyl Thiols in Water for Glycan Ligation Reactions with Highly Functionalized Sugars S. Köhling, M. P. Exner, S. Nojoumi, J. Schiller, N. Budisa, J. Rademann Angewandte Chemie International Edition 2016, 55, 15510–15514, 10.1002/anie.201607228

128 Design ofS-Allylcysteine in Situ Production and Incorporation Based on a Novel Pyrrolysyl-tRNA Synthetase Variant M. P. Exner, T. Kuenzl, T. M. T. To, Z. Ouyang, S. Schwagerus, M. G. Hoesl, C. P. R. Hackenberger, M. C. Lensen, S. Panke, N. Budisa ChemBioChem 2016, 18, 85–90, 10.1002/cbic.201600537

127 Optogenetic approaches addressing extracellular modulation of neural excitability E. A. Ferenczi, J. Vierock, K. Atsuta-Tsunoda, S. P. Tsunoda, C. Ramakrishnan, C. Gorini, K. Thompson, S. Y. Lee, A. Berndt, C. Perry, S. Minniberger, A. Vogt, J. Mattis, R. Prakash, S. Delp, K. Deisseroth, P. Hegemann Scientific Reports 2016, 6, 23947– 10.1038/srep23947

126 Structural foundations of optogenetics: Determinants of channelrhodopsin ion selectivity A. Berndt, S. Y. Lee, J. Wietek, C. Ramakrishnan, E. E. Steinberg, A. J. Rashid, H. Kim, S. Park, A. Santoro, P. W. Frankland, S. M. Iyer, S. Pak, S. Ährlund-Richter, S. L. Delp, R. C. Malenka, S. A. Josselyn, M. Carlén, P. Hegemann, K. Deisseroth Proceedings of the National Academy of Sciences 2016, 113, 822–829, 10.1073/pnas.1523341113

125 Unfolding of the C-Terminal Jα Helix in the LOV2 Photoreceptor Domain Observed by Time-Resolved Vibrational Spectroscopy P. E. Konold, T. Mathes, J. Weiβenborn, M. L. Groot, P. Hegemann, J. T. M. Kennis The Journal of Physical Chemistry Letters 2016, 7, 3472–3476, 10.1021/acs.jpclett.6b01484

124 Photoadduct Formation from the FMN Singlet Excited State in the LOV2 Domain ofChlamydomonas reinhardtiiPhototropin J. Zhu, T. Mathes, Y. Hontani, M. T. A. Alexandre, K. C. Toh, P. Hegemann, J. T. M. Kennis The Journal of Physical Chemistry Letters 2016, 7, 4380–4384, 10.1021/acs.jpclett.6b02075

123 Graphitic carbon nitride “reloaded”: emerging applications beyond (photo)catalysis J. Liu, H. Wang, M. Antonietti Chem. Soc. Rev. 2016, 45, 2308–2326, 10.1039/c5cs00767d

122 Activating Pd nanoparticles on sol–gel prepared porous g-C3N4/SiO2via enlarging the Schottky barrier for efficient dehydrogenation of formic acid H. H. Wang, B. Zhang, X. H. Li, M. Antonietti, J. S. Chen Inorg. Chem. Front. 2016, 3, 1124–1129, 10.1039/c6qi00151c

121 Mild Continuous Hydrogenolysis of Kraft Lignin over Titanium Nitride–Nickel Catalyst V. Molinari, G. Clavel, M. Graglia, M. Antonietti, D. Esposito ACS Catalysis 2016, 6, 1663–1670, 10.1021/acscatal.5b01926

120 Merging Single-Atom-Dispersed Silver and Carbon Nitride to a Joint Electronic SystemviaCopolymerization with Silver Tricyanomethanide Z. Chen, S. Pronkin, T. P. Fellinger, K. Kailasam, G. Vilé, D. Albani, F. Krumeich, R. Leary, J. Barnard, J. M. Thomas, J. Pérez-Ramírez, M. Antonietti, D. Dontsova ACS Nano 2016, 10, 3166–3175, 10.1021/acsnano.5b04210

119 Local Platinum Environments in a Solid Analogue of the Molecular Periana Catalyst M. Soorholtz, L. C. Jones, D. Samuelis, C. Weidenthaler, R. J. White, M. M. Titirici, D. A. Cullen, T. Zimmermann, M. Antonietti, J. Maier, R. Palkovits, B. F. Chmelka, F. Schüth ACS Catalysis 2016, 6, 2332–2340, 10.1021/acscatal.5b02305

118 Aerosol-Assisted Synthesis of Porous TiNxOy@C Nanocomposites V. Maurice, G. Clavel, M. Antonietti, C. Giordano Chemistry - A European Journal 2016, 22, 11624–11630, 10.1002/chem.201503768

117 Moving Graphitic Carbon Nitride from Electrocatalysis and Photocatalysis to a Potential Electrode Material for Photoelectric Devices J. Xu, M. Antonietti, M. Shalom Chemistry - An Asian Journal 2016, 11, 2499–2512, 10.1002/asia.201600857

116 Pd Supported on Carbon Nitride Boosts the Direct Hydrogen Peroxide Synthesis R. Arrigo, M. E. Schuster, S. Abate, G. Giorgianni, G. Centi, S. Perathoner, S. Wrabetz, V. Pfeifer, M. Antonietti, R. Schlögl ACS Catalysis 2016, 6, 6959–6966, 10.1021/acscatal.6b01889

115 Disclosing the High Activity of Ceramic Metallics in the Oxygen Evolution Reaction: Nickel Materials as a Case Study M. Ledendecker, X. Yang, M. Antonietti, M. Shalom ChemSusChem 2016, 9, 2928–2932, 10.1002/cssc.201601128

114 New Organic Semiconducting Scaffolds by Supramolecular Preorganization: Dye Intercalation and Dye Oxidation and Reduction L. Li, Y. Zhao, M. Antonietti, M. Shalom Small 2016, 12, 6090–6097, 10.1002/smll.201602445

113 CO synthesized from the central one-carbon pool as source for the iron carbonyl in O2-tolerant [NiFe]-hydrogenase I. Bürstel, E. Siebert, S. Frielingsdorf, I. Zebger, B. Friedrich, O. Lenz Proceedings of the National Academy of Sciences 2016, 113, 14722–14726, 10.1073/pnas.1614656113

112 Impact of Carbon Nanotube Surface Chemistry on Hydrogen Oxidation by Membrane-Bound Oxygen-Tolerant Hydrogenases K. Monsalve, I. Mazurenko, C. Gutierrez-Sanchez, M. Ilbert, P. Infossi, S. Frielingsdorf, M. T. Giudici-Orticoni, O. Lenz, E. Lojou ChemElectroChem 2016, 3, 2179–2188, 10.1002/celc.201600460

111 Synchrotron-based Nickel Mössbauer Spectroscopy L. B. Gee, C. Y. Lin, F. E. Jenney, M. W. W. Adams, Y. Yoda, R. Masuda, M. Saito, Y. Kobayashi, K. Tamasaku, M. Lerche, M. Seto, C. G. Riordan, A. Ploskonka, P. P. Power, S. P. Cramer, L. Lauterbach Inorganic Chemistry 2016, 55, 6866–6872, 10.1021/acs.inorgchem.5b03004

110 Towards characterization of photo-excited electron transfer and catalysis in natural and artificial systems using XFELs R. Alonso-Mori, K. Asa, U. Bergmann, A. S. Brewster, R. Chatterjee, J. K. Cooper, H. M. Frei, F. D. Fuller, E. Goggins, S. Gul, H. Fukuzawa, D. Iablonskyi, M. Ibrahim, T. Katayama, T. Kroll, Y. Kumagai, B. A. McClure, J. Messinger, K. Motomura, K. Nagaya, T. Nishiyama, C. Saracini, Y. Sato, N. K. Sauter, D. Sokaras, T. Takanashi, T. Togashi, K. Ueda, W. W. Weare, T. C. Weng, M. Yabashi, V. K. Yachandra, I. D. Young, A. Zouni, J. F. Kern, J. Yano Faraday Discuss. 2016, 194, 621–638, 10.1039/c6fd00084c

109 Acoustic Injectors for Drop-On-Demand Serial Femtosecond Crystallography C. Roessler, R. Agarwal, M. Allaire, R. Alonso-Mori, B. Andi, J. R. Bachega, M. Bommer, A. Brewster, M. Browne, R. Chatterjee, E. Cho, A. Cohen, M. Cowan, S. Datwani, V. Davidson, J. Defever, B. Eaton, R. Ellson, Y. Feng, L. Ghislain, J. Glownia, G. Han, J. Hattne, J. Hellmich, A. Héroux, M. Ibrahim, J. Kern, A. Kuczewski, H. Lemke, P. Liu, L. Majlof, W. McClintock, S. Myers, S. Nelsen, J. Olechno, A. Orville, N. Sauter, A. Soares, S. Structure 2016, 24, 631–640, 10.1016/j.str.2016.02.007

108 Electrocatalytic investigation on the water oxidation ability of a hangman complex based on the [Ru(tpy)(bpy)(OH2)]2+ motif P. Wrzolek, S. Wahl, M. Schwalbe Catalysis Today 2016, 10.1016/j.cattod.2016.10.013

107 Ready to use bioinformatics analysis as a tool to predict immobilisation strategies for protein direct electron transfer (DET) R. Cazelles, N. Lalaoui, T. Hartmann, S. Leimkühler, U. Wollenberger, M. Antonietti, S. Cosnier Biosensors and Bioelectronics 2016, 85, 90–95, 10.1016/j.bios.2016.04.078

106 Nickel electrodes as a cheap and versatile platform for studying structure and function of immobilized redox proteins X. X. Han, J. Li, I. H. Öner, B. Zhao, S. Leimkühler, P. Hildebrandt, I. M. Weidinger Analytica Chimica Acta 2016, 941, 35–40, 10.1016/j.aca.2016.08.053

105 Role of Conductive Nanoparticles in the Direct Unmediated Bioelectrocatalysis of Immobilized Sulfite Oxidase T. Zeng, S. Frasca, J. Rumschöttel, J. Koetz, S. Leimkühler, U. Wollenberger Electroanalysis 2016, 28, 2303–2310, 10.1002/elan.201600246

104 The Molybdenum Active Site of Formate Dehydrogenase Is Capable of Catalyzing C–H Bond Cleavage and Oxygen Atom Transfer Reactions T. Hartmann, P. Schrapers, T. Utesch, M. Nimtz, Y. Rippers, H. Dau, M. A. Mroginski, M. Haumann, S. Leimkühler Biochemistry 2016, 55, 2381–2389, 10.1021/acs.biochem.6b00002

103 TheO-Carbamoyl-Transferase Alb15 Is Responsible for the Modification of Albicidin D. Petras, D. Kerwat, A. Pesic, B. F. Hempel, L. von Eckardstein, S. Semsary, J. Arasté, M. Marguerettaz, M. Royer, S. Cociancich, R. D. Süssmuth ACS Chemical Biology 2016, 11, 1198–1204, 10.1021/acschembio.5b01001

102 Top-down venomics of the East African green mamba, Dendroaspis angusticeps, and the black mamba, Dendroaspis polylepis, highlight the complexity of their toxin arsenals D. Petras, P. Heiss, R. A. Harrison, R. D. Süssmuth, J. J. Calvete Journal of Proteomics 2016, 146, 148–164, 10.1016/j.jprot.2016.06.018

101 Towards Biocontained Cell Factories: An Evolutionarily Adapted Escherichia coli Strain Produces a New-to-nature Bioactive Lantibiotic Containing Thienopyrrole-Alanine A. Kuthning, P. Durkin, S. Oehm, M. G. Hoesl, N. Budisa, R. D. Süssmuth Scientific Reports 2016, 6, 33447– 10.1038/srep33447

100 Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species T. Corona, L. Ribas, M. Rovira, E. R. Farquhar, X. Ribas, K. Ray, A. Company Angewandte Chemie International Edition 2016, 55, 14005–14008, 10.1002/anie.201607238

99 A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions S. Kundu, P. Chernev, X. Engelmann, C. S. Chung, H. Dau, E. Bill, J. England, W. Nam, K. Ray Dalton Trans. 2016, 45, 14538–14543, 10.1039/c6dt01815g

98 Changing the chemical and physical properties of high valent heterobimetallic bis-(μ-oxido) Cu–Ni complexes by ligand effects M. C. Kafentzi, M. Orio, M. Réglier, S. Yao, U. Kuhlmann, P. Hildebrandt, M. Driess, A. J. Simaan, K. Ray Dalton Trans. 2016, 45, 15994–16000, 10.1039/c6dt02391f

97 Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes S. Hong, Y. M. Lee, K. Ray, W. Nam Coordination Chemistry Reviews 2016, 10.1016/j.ccr.2016.07.006

96 Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes X. Engelmann, I. Monte-Pérez, K. Ray Angewandte Chemie International Edition 2016, 55, 7632–7649, 10.1002/anie.201600507

95 A Single-Source Precursor Approach to Self-Supported Nickel-Manganese-Based Catalysts with Improved Stability for Effective Low-Temperature Dry Reforming of Methane P. W. Menezes, A. Indra, P. Littlewood, C. Göbel, R. Schomäcker, M. Driess ChemPlusChem 2016, 81, 370–377, 10.1002/cplu.201600064

94 Donor-Acceptor-Type Heptazine-Based Polymer Networks for Photocatalytic Hydrogen Evolution K. Kailasam, M. B. Mesch, L. Möhlmann, M. Baar, S. Blechert, M. Schwarze, M. Schröder, R. Schomäcker, J. Senker, A. Thomas Energy Technology 2016, 4, 744–750, 10.1002/ente.201500478

93 Activation of Chlorinated Methanes at the Surface of Nanoscopic Lewis Acidic Aluminium Fluorides T. Braun, E. Kemnitz, A. Siwek, M. Ahrens, M. Feist ChemCatChem 2016, 10.1002/cctc.201601238

92 Heterogeneous Catalytic Hydroarylation of Olefins at a Nanoscopic Aluminum Chlorofluoride B. Calvo, J. Wuttke, T. Braun, E. Kemnitz ChemCatChem 2016, 8, 1945–1950, 10.1002/cctc.201600257

91 The Inner Workings of Proton Slippage through the Sodium Pump T. Friedrich Biophysical Journal 2016, 111, 2342–2344, 10.1016/j.bpj.2016.10.026

90 ATP1A2 Mutations in Migraine: Seeing through the Facets of an Ion Pump onto the Neurobiology of Disease T. Friedrich, N. N. Tavraz, C. Junghans Frontiers in Physiology 2016, 7, 10.3389/fphys.2016.00239

89 The role of local and remote amino acid substitutions for optimizing fluorescence in bacteriophytochromes: A case study on iRFP D. Buhrke, F. Velazquez Escobar, L. Sauthof, S. Wilkening, N. Herder, N. N. Tavraz, M. Willoweit, A. Keidel, T. Utesch, M. A. Mroginski, F. J. Schmitt, P. Hildebrandt, T. Friedrich Scientific Reports 2016, 6, 28444– 10.1038/srep28444

88 Effects of project-based research work on the career paths of young academics M. Norkus, N. Baur, C. Besio Work Organisation, Labour & Globalisation 2016, 10, 1745–6428,

87 Synthesis and OER activity of NiO coatings with micelle-templated mesopore structure M. Bernicke, B. Eckhardt, A. Lippitz, E. Ortel, D. Bernsmeier, R. Schmack, R. Kraehnert ChemistrySelect 2016, 1, 482–489, 10.1002/slct.201600110

86 Oxygen Evolution Reaction Dynamics, Faradaic Charge Efficiency, and the Active Metal Redox States of Ni–Fe Oxide Water Splitting Electrocatalysts M. Görlin, P. Chernev, J. Ferreira de Araújo, T. Reier, S. Dresp, B. Paul, R. Krähnert, H. Dau, P. Strasser Journal of the American Chemical Society 2016, 138, 5603–5614, 10.1021/jacs.6b00332

85 Missing Piece of the Mechanism of the Turkevich Method: The Critical Role of Citrate Protonation F. Kettemann, A. Birnbaum, S. Witte, M. Wuithschick, N. Pinna, R. Kraehnert, K. Rademann, J. Polte Chemistry of Materials 2016, 28, 4072–4081, 10.1021/acs.chemmater.6b01796

84 Highly Active Binder-Free Catalytic Coatings for Heterogeneous Catalysis and Electrocatalysis: Pd on Mesoporous Carbon and Its Application in Butadiene Hydrogenation and Hydrogen Evolution D. Bernsmeier, L. Chuenchom, B. Paul, S. Rümmler, B. Smarsly, R. Kraehnert ACS Catalysis 2016, 6, 8255–8263, 10.1021/acscatal.6b02240

83 New Approach on Quantification of Porosity of Thin Films via Electron-Excited X-ray Spectra E. Ortel, A. Hertwig, D. Berger, P. Esposito, A. M. Rossi, R. Kraehnert, V. D. Hodoroaba Analytical Chemistry 2016, 88, 7083–7090, 10.1021/acs.analchem.6b00847

82 Nafion-Free Carbon-Supported Electrocatalysts with Superior Hydrogen Evolution Reaction Performance by Soft Templating D. Bernsmeier, M. Bernicke, E. Ortel, A. Bergmann, A. Lippitz, J. Nissen, R. Schmack, P. Strasser, J. Polte, R. Kraehnert ChemElectroChem 2016, 10.1002/celc.201600444

81 B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes D. Porwal, M. Oestreich European Journal of Organic Chemistry 2016, 2016, 3307–3309, 10.1002/ejoc.201600556

80 Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates I. Chatterjee, M. Oestreich Organic Letters 2016, 18, 2463–2466, 10.1021/acs.orglett.6b01016

79 Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations M. Mehta, I. Garcia de la Arada, M. Perez, D. Porwal, M. Oestreich, D. W. Stephan Organometallics 2016, 35, 1030–1035, 10.1021/acs.organomet.6b00158

78 Thermal Activation of Methane by [HfO].+and [XHfO]+(X=F, Cl, Br, I) and the Origin of a Remarkable Ligand Effect S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 7685–7688, 10.1002/anie.201602312

77 Lanthipeptides: chemical synthesis versus in vivo biosynthesis as tools for pharmaceutical production E. L. Ongey, P. Neubauer Microbial Cell Factories 2016, 15, 10.1186/s12934-016-0502-y

76 Structural and functional basis of phospholipid oxygenase activity of bacterial lipoxygenase from Pseudomonas aeruginosa S. Banthiya, J. Kalms, E. Galemou Yoga, I. Ivanov, X. Carpena, M. Hamberg, H. Kuhn, P. Scheerer Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids 2016, 1861, 1681–1692, 10.1016/j.bbalip.2016.08.002

75 Insights into Basal Signaling Regulation, Oligomerization, and Structural Organization of the Human G-Protein Coupled Receptor 83 A. Müller, J. C. Berkmann, P. Scheerer, H. Biebermann, G. Kleinau PLOS ONE 2016, 11, 10.1371/journal.pone.0168260

74 Models for heterogeneous catalysts: studies at the atomic level H. J. Freund Rendiconti Lincei 2016, 10.1007/s12210-016-0560-4

73 Nanoscale Patterns on Polar Oxide Surfaces M. Lewandowski, I. M. N. Groot, Z. H. Qin, T. Ossowski, T. Pabisiak, A. Kiejna, A. Pavlovska, S. Shaikhutdinov, H. J. Freund, E. Bauer Chemistry of Materials 2016, 28, 7433–7443, 10.1021/acs.chemmater.6b03040

72 A numerical optimization study on the catalytic dry reforming of methane in a spatially resolved fixed-bed reactor T. Eppinger, G. D. Wehinger, N. Jurtz, R. Aglave, M. Kraume Chemical Engineering Research and Design 2016, 115, 374–381, 10.1016/j.cherd.2016.09.007

71 Investigating dry reforming of methane with spatial reactor profiles and particle-resolved CFD simulations G. D. Wehinger, M. Kraume, V. Berg, O. Korup, K. Mette, R. Schlögl, M. Behrens, R. Horn AIChE Journal 2016, 62, 4436–4452, 10.1002/aic.15520

70 A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2M′] Complexes in Oxidation Reactions X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray Angewandte Chemie International Edition 2016, 10.1002/anie.201607611

69 Structure of photosystem II and substrate binding at room temperature I. D. Young, M. Ibrahim, R. Chatterjee, S. Gul, F. D. Fuller, S. Koroidov, A. S. Brewster, R. Tran, R. Alonso-Mori, T. Kroll, T. Michels-Clark, H. Laksmono, R. G. Sierra, C. A. Stan, R. Hussein, M. Zhang, L. Douthit, M. Kubin, C. de Lichtenberg, L. Vo Pham, H. Nilsson, M. H. Cheah, D. Shevela, C. Saracini, M. A. Bean, I. Seuffert, D. Sokaras, T. C. Weng, E. Pastor, C. Weninger, T. Fransson, L. Lassalle, P. Bräuer, P. Aller, P. T. Docker, B. Andi, A. M. Orville, J. M. Glownia, S. Nelson, M. Sikorski, D. Zhu, M. S. Hunter, T. J. Lane, A. Aquila, J. E. Koglin, J. Robinson, M. Liang, S. Boutet, A. Y. Lyubimov, M. Uervirojnangkoorn, N. W. Moriarty, D. Liebschner, P. V. Afonine, D. G. Waterman, G. Evans, P. Wernet, H. Dobbek, W. I. Weis, A. T. Brunger, P. H. Zwart, P. D. Adams, A. Zouni, J. Messinger, U. Bergmann, N. K. Sauter, J. Kern, V. K. Yachandra, J. Yano Nature 2016, 540, 453–457, 10.1038/nature20161

68 Pseudo-Contact NMR Shifts over the Paramagnetic Metalloprotein CoMMP-12 from First Principles L. Benda, J. Mareš, E. Ravera, G. Parigi, C. Luchinat, M. Kaupp, J. Vaara Angewandte Chemie International Edition 2016, 55, 14713–14717, 10.1002/anie.201608829

67 Thermal Dehydrogenation of Methane by [ReN]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 14863–14866, 10.1002/anie.201607960

66 The Origin of the Efficient, Thermal Chemisorption of Methane by the Heteronuclear Metal-Oxide Cluster [Al2TaO5]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 14867–14871, 10.1002/anie.201608999

65 Mechanistic aspects of CO2 activation mediated by phenyl yttrium cation: A combined experimental/theoretical study M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Journal of Catalysis 2016, 343, 68–74, 10.1016/j.jcat.2015.09.012

64 A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes Y. P. Zhou, S. Raoufmoghaddam, T. Szilvási, M. Driess Angewandte Chemie International Edition 2016, 55, 12868–12872, 10.1002/anie.201606979

63 Uncovering the prominent role of metal ions in octahedral versus tetrahedral sites of cobalt–zinc oxide catalysts for efficient oxidation of water P. W. Menezes, A. Indra, A. Bergmann, P. Chernev, C. Walter, H. Dau, P. Strasser, M. Driess J. Mater. Chem. A 2016, 4, 10014–10022, 10.1039/C6TA03644A

62 Thermal Methane Activation by [Si2O5].+and [Si2O5H2].+: Reactivity Enhancement by Hydrogenation X. Sun, S. Zhou, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 13345–13348, 10.1002/anie.201607864

61 Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC]+with Methane under Ambient Conditions J. Li, S. Zhou, M. Schlangen, T. Weiske, H. Schwarz Angewandte Chemie International Edition 2016, 55, 13072–13075, 10.1002/anie.201606707

60 Efficient Room-Temperature Methane Activation by the Closed-Shell, Metal-Free Cluster [OSiOH]+: A Novel Mechanistic Variant X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 14257–14263, 10.1002/chem.201601981

59 Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions J. Li, S. Zhou, J. Zhang, M. Schlangen, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 138, 11368–11377, 10.1021/jacs.6b07246

58 Efficient Room-Temperature Activation of Methane by TaN+under C−N Coupling S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 11678–11681, 10.1002/anie.201606259

57 The Unique Gas-Phase Chemistry of the [AuO]+/CH4Couple: Selective Oxygen-Atom Transfer to, Rather than Hydrogen-Atom Abstraction from, Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 10877–10880, 10.1002/anie.201605259

56 Chemical looping as reactor concept for the oxidative coupling of methane over a Na2WO4/Mn/SiO2 catalyst V. Fleischer, P. Littlewood, S. Parishan, R. Schomäcker Chemical Engineering Journal 2016, 306, 646–654, 10.1016/j.cej.2016.07.094

55 Investigation of the surface reaction network of the oxidative coupling of methane over Na2WO4/Mn/SiO2 catalyst by temperature programmed and dynamic experiments V. Fleischer, R. Steuer, S. Parishan, R. Schomäcker Journal of Catalysis 2016, 341, 91–103, 10.1016/j.jcat.2016.06.014

54 Silica material variation for the MnxOy-Na2WO4/SiO2 M. Yildiz, Y. Aksu, U. Simon, T. Otremba, K. Kailasam, C. Göbel, F. Girgsdies, O. Görke, F. Rosowski, A. Thomas, R. Schomäcker, S. Arndt Applied Catalysis A: General 2016, 525, 168–179, 10.1016/j.apcata.2016.06.034

53 Oxidative coupling of methane on the Na2WO4-MnxOy catalyst: COK-12 as an inexpensive alternative to SBA-15 M. G. Colmenares, U. Simon, M. Yildiz, S. Arndt, R. Schomaecker, A. Thomas, F. Rosowski, A. Gurlo, O. Goerke Catalysis Communications 2016, 85, 75–78, 10.1016/j.catcom.2016.06.025

52 Vibrational spectroscopy reveals the initial steps of biological hydrogen evolution S. Katz, J. Noth, M. Horch, H. S. Shafaat, T. Happe, P. Hildebrandt, I. Zebger Chem. Sci. 2016, 7, 6746–6752, 10.1039/C6SC01098A

51 On the Activation of Methane and Carbon Dioxide by [HTaO]+and [TaOH]+in the Gas Phase: A Mechanistic Study M. Firouzbakht, N. J. Rijs, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2016, 22, 10581–10589, 10.1002/chem.201601339

50 The Mössbauer Parameters of the Proximal Cluster of Membrane-Bound Hydrogenase Revisited: A Density Functional Theory Study S. G. Tabrizi, V. Pelmenschikov, L. Noodleman, M. Kaupp Journal of Chemical Theory and Computation 2016, 12, 174–187, 10.1021/acs.jctc.5b00854

49 Characterization of the [3Fe–4S]0/1+ cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses L. Lauterbach, L. B. Gee, V. Pelmenschikov, F. E. Jenney, S. Kamali, Y. Yoda, M. W. W. Adams, S. P. Cramer Dalton Trans. 2016, 45, 7215–7219, 10.1039/C5DT04760A

48 Supports and modified nano-particles for designing model catalysts C. P. O'Brien, K. H. Dostert, M. Hollerer, C. Stiehler, F. Calaza, S. Schauermann, S. Shaikhutdinov, M. Sterrer, H. J. Freund Faraday Discuss. 2016, 188, 309–321, 10.1039/c5fd00143a

47 Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO2]+(X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer J. Li, S. Zhou, J. Zhang, M. Schlangen, T. Weiske, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 138, 7973–7981, 10.1021/jacs.6b03798

46 Leader Peptide-Free In Vitro Reconstitution of Microviridin Biosynthesis Enables Design of Synthetic Protease-Targeted Libraries E. Reyna-González, B. Schmid, D. Petras, R. D. Süssmuth, E. Dittmann Angewandte Chemie International Edition 2016, 55, 9398–9401, 10.1002/anie.201604345

45 Spin-Selective Thermal Activation of Methane by Closed-Shell [TaO3]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 7257–7260, 10.1002/anie.201601965

44 Modelling the production of soluble hydrogenase in Ralstonia eutropha by on-line optimal experimental design F. Neddermeyer, V. Marhold, C. Menzel, D. Krämer, R. King IFAC Symposium on Dynamics and Control of Process Systems including Biosystems Proceedings 2016, 11, 627–632,

43 Apparatus for low temperature thermal desorption spectroscopy of portable samples S. Stuckenholz, C. Büchner, H. Ronneburg, G. Thielsch, M. Heyde, H. J. Freund Review of Scientific Instruments 2016, 87, 45103– 10.1063/1.4945265

42 Differences and Commonalities in the Gas-Phase Reactions of Closed-Shell Metal Dioxide Clusters [MO2]+(M=V, Nb, and Ta) with Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 7225–7228, 10.1002/chem.201600498

41 Palladium-mediated borylation of pentafluorosulfanyl functionalized compounds: the crucial role of metal fluorido complexes C. Berg, T. Braun, R. Laubenstein, B. Braun Chem. Commun. 2016, 52, 3931–3934, 10.1039/C5CC10219G

40 Is it all in the hinge? A kryptoracemate and three of its alternative racemic polymorphs of an aminonitrile R. Laubenstein, M. D. Şerb, U. Englert, G. Raabe, T. Braun, B. Braun Chem. Commun. 2016, 52, 1214–1217, 10.1039/C5CC08992A

39 Polarization- and Wavelength-Dependent Surface-Enhanced Raman Spectroscopy Using Optically Anisotropic Rippled Substrates for Sensing D. Gkogkou, B. Schreiber, T. Shaykhutdinov, H. K. Ly, U. Kuhlmann, U. Gernert, S. Facsko, P. Hildebrandt, N. Esser, K. Hinrichs, I. M. Weidinger, T. W. H. Oates ACS Sensors 2016, 1, 318–323, 10.1021/acssensors.5b00176

38 Biochemical Dissection of the Natural Diversification of Microcystin Provides Lessons for Synthetic Biology of NRPS S. Meyer, J. C. Kehr, A. Mainz, D. Dehm, D. Petras, R. Süssmuth, E. Dittmann Cell Chemical Biology 2016, 23, 462–471, 10.1016/j.chembiol.2016.03.011

37 Krypton Derivatization of an O2-Tolerant Membrane-Bound [NiFe] Hydrogenase Reveals a Hydrophobic Tunnel Network for Gas Transport J. Kalms, A. Schmidt, S. Frielingsdorf, P. van der Linden, D. von Stetten, O. Lenz, P. Carpentier, P. Scheerer Angewandte Chemie International Edition 2016, 55, 5586–5590, 10.1002/anie.201508976

36 Structures of ribosome-bound initiation factor 2 reveal the mechanism of subunit association T. Sprink, D. J. F. Ramrath, H. Yamamoto, K. Yamamoto, J. Loerke, J. Ismer, P. W. Hildebrand, P. Scheerer, J. Bu rger, T. Mielke, C. M. T. Spahn Science Advances 2016, 2, 10.1126/sciadv.1501502

35 Interaction of Water with the CaO(001) Surface Y. Fujimori, X. Zhao, X. Shao, S. V. Levchenko, N. Nilius, M. Sterrer, H. J. Freund The Journal of Physical Chemistry C 2016, 120, 5565–5576, 10.1021/acs.jpcc.6b00433

34 Enantioselective Nanoporous Carbon Based on Chiral Ionic Liquids I. Fuchs, N. Fechler, M. Antonietti, Y. Mastai Angewandte Chemie International Edition 2016, 55, 408–412, 10.1002/anie.201505922

33 1,2,4-Triazole-Based Approach to Noble-Metal-Free Visible-Light Driven Water Splitting over Carbon Nitrides D. Dontsova, C. Fettkenhauer, V. Papaefthimiou, J. Schmidt, M. Antonietti Chemistry of Materials 2016, 28, 772–778, 10.1021/acs.chemmater.5b03722

32 Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content N. Fechler, N. P. Zussblatt, R. Rothe, R. Schlögl, M. G. Willinger, B. F. Chmelka, M. Antonietti Advanced Materials 2016, 28, 1287–1294, 10.1002/adma.201501503

31 When the inhibitor tells more than the substrate: the cyanide-bound state of a carbon monoxide dehydrogenase A. Ciaccafava, D. Tombolelli, L. Domnik, J. Fesseler, J. H. Jeoung, H. Dobbek, M. A. Mroginski, I. Zebger, P. Hildebrandt Chem. Sci. 2016, 7, 3162–3171, 10.1039/C5SC04554A

30 A Fluorometric Activity Assay for Light-Regulated Cyclic-Nucleotide-Monophosphate Actuators C. H. Schumacher, H. G. Körschen, C. Nicol, C. Gasser, R. Seifert, M. Schwärzel, A. Möglich Methods in Molecular Biology 2016, 1408, 93–105, 10.1007/978-1-4939-3512-3_7

29 Library-aided probing of linker determinants in hybrid photoreceptors R. Ohlendorf, C. H. Schumacher, F. Richter, A. Möglich ACS Synthetic Biology 2016, 5, 1117–1126, 10.1021/acssynbio.6b00028

28 Hydrothermal synthesis of bi-functional nanostructured manganese tungstate catalysts for selective oxidation X. Li, T. Lunkenbein, J. Kröhnert, V. Pfeifer, F. Girgsdies, F. Rosowski, R. Schlögl, A. Trunschke Faraday Discuss. 2016, 188, 99–113, 10.1039/C5FD00191A

27 Enhancing of catalytic properties of vanadia via surface doping with phosphorus using atomic layer deposition V. E. Strempel, D. Löffler, J. Kröhnert, K. Skorupska, B. Johnson, R. N. d'Alnoncourt, M. Driess, F. Rosowski Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 2016, 34, 1– 10.1116/1.4936390

26 Selective Alkane Oxidation by Manganese Oxide: Site Isolation of MnOxChains at the Surface of MnWO4Nanorods X. Li, T. Lunkenbein, V. Pfeifer, M. Jastak, P. K. Nielsen, F. Girgsdies, A. Knop-Gericke, F. Rosowski, R. Schlögl, A. Trunschke Angewandte Chemie International Edition 2016, 55, 4092–4096, 10.1002/anie.201510201

25 Effect of the catalyst pore structure on fixed-bed reactor performance of partial oxidation of n-butane: A simulation study Y. Dong, F. J. Keil, O. Korup, F. Rosowski, R. Horn Chemical Engineering Science 2016, 142, 299–309, 10.1016/j.ces.2015.12.004

24 Bond Activation by Metal–Carbene Complexes in the Gas Phase S. Zhou, J. Li, M. Schlangen, H. Schwarz Accounts of Chemical Research 2016, 49, 494–502, 10.1021/acs.accounts.5b00023

23 Mechanistic Aspects of the Holmium-mediated, Reciprocal Hydrogen/Sulfur Exchange in the Gas Phase: C₆H₅CH₃ + CH₂S → C₆H₅CHS + CH₄ S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 4336–4339, 10.1002/chem.201600061

22 An iron(II) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity H. Gehring, R. Metzinger, B. Braun, C. Herwig, S. Harder, K. Ray, C. Limberg Dalton Trans. 2016, 45, 2989–2996, 10.1039/C5DT04266F

21 On the Origin of Room-temperature, Au+-mediated Coupling of a Methylene Ligand with H2. Implications for the Mechanism of Methane Dehydrogenation. J. Li , S. Zhou, M. Schlangen, T. Weiske, H. Schwarz ChemistrySelect 2016, 1, 444–447, 10.1002/slct.201600073

20 Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO]+Complexes with Fluoromethanes (CH(4–n)Fn,n= 1–3) N. J. Rijs, P. González-Navarrete, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2016, 138, 3125–3135, 10.1021/jacs.5b12972

19 Bacterial molybdoenzymes: old enzymes for new purposes S. Leimkühler, C. Iobbi-Nivol FEMS Microbiology Reviews 2016, 40, 1–18, 10.1093/femsre/fuv043

18 Sustainable Process Design for Oxidative Coupling of Methane (OCM): Comprehensive Reactor Engineering via Computational Fluid Dynamics (CFD) Analysis of OCM Packed-Bed Membrane Reactors M. S. Salehi, M. Askarishahi, H. R. Godini, O. Görke, G. Wozny Industrial & Engineering Chemistry Research 2016, 55, 3287–3299, 10.1021/acs.iecr.5b03292

17 CFD Simulation of Oxidative Coupling of Methane in Fluidized-Bed Reactors: A Detailed Analysis of Flow-Reaction Characteristics and Operating Conditions M. S. Salehi, M. Askarishahi, H. R. Godini, R. Schomäcker, G. Wozny Industrial & Engineering Chemistry Research 2016, 55, 1149–1163, 10.1021/acs.iecr.5b02433

16 Rational biosynthetic approaches for the production of new-to-nature compounds in fungi S. Boecker, S. Zobel, V. Meyer, R. D. Süssmuth Fungal Genetics and Biology 2016, 10.1016/j.fgb.2016.02.003

15 Molecularly Imprinted Electropolymer for a Hexameric Heme Protein with Direct Electron Transfer and Peroxide Electrocatalysis L. Peng, A. Yarman, K. Jetzschmann, J. H. Jeoung, D. Schad, H. Dobbek, U. Wollenberger, F. W. Scheller Sensors 2016, 16, 272– 10.3390/s16030272

14 Electrosynthesized molecularly imprinted polymers for protein recognition J. Erdőssy, V. Horváth, A. Yarman, F. W. Scheller, R. E. Gyurcsányi TrAC Trends in Analytical Chemistry 2016, 79, 179–190, 10.1016/j.trac.2015.12.018

13 The Supersized Class III Lanthipeptide Stackepeptin Displays Motif Multiplication in the Core Peptide N. A. Jungmann, E. F. van Herwerden, M. Hügelland, R. D. Süssmuth ACS Chemical Biology 2016, 11, 69–76, 10.1021/acschembio.5b00651

12 Reprogramming the Biosynthesis of Cyclodepsipeptide Synthetases to Obtain New Enniatins and Beauvericins S. Zobel, S. Boecker, D. Kulke, D. Heimbach, V. Meyer, R. D. Süssmuth ChemBioChem 2016, 17, 283–287, 10.1002/cbic.201500649

11 ZnO Coatings with Controlled Pore Size, Crystallinity and Electrical Conductivity R. Schmack, B. Eckhardt, G. Koch, E. Ortel, R. Kraehnert Materials Science 2016, 22, 74–81, 10.5755/j01.ms.22.1.8634

10 Quercetin 2,4-Dioxygenase Activates Dioxygen in a Side-On O2-Ni Complex J. H. Jeoung, D. Nianios, S. Fetzner, H. Dobbek Angewandte Chemie International Edition 2016, 10.1002/anie.201510741

9 Reactivation from the Ni–B state in [NiFe] hydrogenase of Ralstonia eutropha is controlled by reduction of the superoxidised proximal cluster V. Radu, S. Frielingsdorf, O. Lenz, L. J. C. Jeuken Chem. Commun. 2016, 52, 2632–2635, 10.1039/C5CC10382G

8 Structure of an Actinobacterial-Type [NiFe]-Hydrogenase Reveals Insight into O2-Tolerant H2 Oxidation C. Schäfer, M. Bommer, S. Hennig, J. H. Jeoung, H. Dobbek, O. Lenz Structure 2016, 24, 285–292, 10.1016/j.str.2015.11.010

7 Breaking and Making of Carbon-Carbon Bonds by Lanthanides and Third-Row Transition Metals S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 3073–3076, 10.1002/chem.201504571

6 Unravelling Mechanistic Aspects of the Gas-Phase Ethanol Conversion: An Experimental and Computational Study on the Thermal Reactions of MO2+(M=Mo, W) with Ethanol P. González-Navarrete, M. Schlangen, X. N. Wu, H. Schwarz Chemistry - A European Journal 2016, 22, 3077–3083, 10.1002/chem.201504929

5 Methanol adsorption on monocrystalline ceria surfaces C. Yang, F. Bebensee, A. Nefedov, C. Wöll, T. Kropp, L. Komissarov, C. Penschke, R. Moerer, J. Paier, J. Sauer Journal of Catalysis 2016, 336, 116–125, 10.1016/j.jcat.2016.01.003

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3 Efficient Room-Temperature, Au+ -Mediated Coupling of a Carbene Ligand with Methane To Generate C2Hx (x=4, 6) S. Zhou, J. Li, X. N. Wu, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 441–444, 10.1002/anie.201509320

2 An artificial structure modeler for 3D CFD simulations of catalytic foams G. D. Wehinger, H. Heitmann, M. Kraume Chemical Engineering Journal 2016, 284, 543–556, 10.1016/j.cej.2015.09.014

1 Nickel as a co-catalyst for photocatalytic hydrogen evolution on graphitic-carbon nitride (sg-CN): what is the nature of the active species? A. Indra, P. W. Menezes, K. Kailasam, D. Hollmann, M. Schröder, A. Thomas, A. Brückner, M. Driess Chem. Commun. 2016, 52, 104–107, 10.1039/C5CC07936E