Publications 2016

Number of records: 174

174 Optimized immobilization of ZnO:Co electrocatalysts realizes 5% efficiency in photo-assisted splitting of water A. Azarpira, J. Pfrommer, K. Olech, C. Höhn, M. Driess, B. Stannowski, T. Schedel-Niedrig, M. Lublow Journal of Materials Chemistry A Journal of Materials Chemistry A 2016, 8, 3082–3090, 10.1039/C5TA07329D

173 Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols T. L. Gianetti, S. P. Annen, G. Santiso-Quinones, M. Reiher, M. Driess, H. Grützmacher Angewandte Chemie International Edition 2016, 5, 1854–1858, 10.1002/anie.201509288

172 Morphology-Dependent Activities of Silver Phosphates: Visible-Light Water Oxidation and Dye Degradation P. W. Menezes, A. Indra, M. Schwarze, F. Schuster, M. Driess ChemPlusChem ChemPlusChem 2016, 10, 1068–1074, 10.1002/cplu.201500538

171 Yolk@Shell Nanoarchitectures with Bimetallic Nanocores–Synthesis and Electrocatalytic Applications A. Guiet, T. Unmüssig, C. Göbel, U. Vainio, M. Wollgarten, M. Driess, H. Schlaad, J. Polte, A. Fischer ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces 2016, 41, 28019–28029, 10.1021/acsami.6b06595

170 Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting P. W. Menezes, A. Indra, C. Das, C. Walter, C. Göbel, V. Gutkin, D. Schmeiβer, M. Driess ACS Catalysis 2016, 1, 103–109, 10.1021/acscatal.6b02666

169 Highly active promoters and native secretion signals for protein production during extremely low growth rates in Aspergillus niger F. Wanka, M. Arentshorst, T. C. Cairns, T. Jørgensen, A. F. J. Ram, V. Meyer Microbial Cell Factories Microbial Cell Factories 2016, 1, 10.1186/s12934-016-0543-2

168 Current challenges of research on filamentous fungi in relation to human welfare and a sustainable bio-economy: a white paper V. Meyer, M. R. Andersen, A. A. Brakhage, G. H. Braus, M. X. Caddick, T. C. Cairns, R. P. de Vries, T. Haarmann, K. Hansen, C. Hertz-Fowler, S. Krappmann, U. H. Mortensen, M. A. Peñalva, A. F. J. Ram, R. M. Head Fungal Biology and Biotechnology Fungal Biology and Biotechnology 2016, 1, 10.1186/s40694-016-0024-8

167 A Transcriptome Meta-Analysis Proposes Novel Biological Roles for the Antifungal Protein AnAFP in Aspergillus niger N. Paege, S. Jung, P. Schäpe, D. Müller-Hagen, J. P. Ouedraogo, C. Heiderich, J. Jedamzick, B. M. Nitsche, C. A. van den Hondel, A. F. Ram, V. Meyer PLOS ONE PLOS ONE 2016, 11, 10.1371/journal.pone.0165755

166 Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C–F bond activation versus hydrogermylation T. Ahrens, M. Teltewskoi, M. Ahrens, T. Braun, R. Laubenstein Dalton Transactions Dalton Trans. 2016, 43, 17495–17507, 10.1039/C6DT03027K

165 Using Separable Nonnegative Matrix Factorization Techniques for the Analysis of Time-Resolved Raman Spectra R. Luce, P. Hildebrandt, U. Kuhlmann, J. Liesen Applied Spectroscopy Applied Spectroscopy 2016, 9, 1464–1475, 10.1177/0003702816662600

164 Monitoring the Transmembrane Proton Gradient Generated by Cytochrome in Tethered Bilayer Lipid Membranes Using SEIRA Spectroscopy S. Wiebalck, J. Kozuch, E. Forbrig, C. C. Tzschucke, L. J. C. Jeuken, P. Hildebrandt The Journal of Physical Chemistry B The Journal of Physical Chemistry B 2016, 9, 2249–2256, 10.1021/acs.jpcb.6b01435

163 Substrate–Protein Interactions of Type II NADH:Quinone Oxidoreductase from J. Salewski, A. P. Batista, F. V. Sena, D. Millo, I. Zebger, M. M. Pereira, P. Hildebrandt Biochemistry 2016, 19, 2722–2734, 10.1021/acs.biochem.6b00070

162 Domain motions and electron transfer dynamics in 2Fe-superoxide reductase M. Horch, T. Utesch, P. Hildebrandt, M. A. Mroginski, I. Zebger Physical Chemistry Chemical Physics Phys. Chem. Chem. Phys. 2016, 33, 23053–23066, 10.1039/C6CP03666J

161 Gas-phase reactions of cationic molybdenum and tungsten monoxide with ethanol: a combined experimental/computational exercise P. González-Navarrete, M. Schlangen, H. Schwarz Structural Chemistry Structural Chemistry 2016, 2, 403–413, 10.1007/s11224-016-0862-2

160 MIPs and Aptamers for Recognition of Proteins in Biomimetic Sensing M. Menger, A. Yarman, J. Erdőssy, H. Yildiz, R. Gyurcsányi, F. Scheller Biosensors Biosensors 2016, 3, 35– 10.3390/bios6030035

159 MIP-esterase/Tyrosinase Combinations for Paracetamol and Phenacetin A. Yarman, F. W. Scheller Electroanalysis 2016, 9, 2222–2227, 10.1002/elan.201600042

158 Light-Switchable Polymers of Intrinsic Microporosity D. Becker, N. Konnertz, M. Böhning, J. Schmidt, A. Thomas Chemistry of Materials 2016, 23, 8523–8529, 10.1021/acs.chemmater.6b02619

157 Copper-Free Sonogashira Coupling for High-Surface-Area Conjugated Microporous Poly(aryleneethynylene) Networks M. Trunk, A. Herrmann, H. Bildirir, A. Yassin, J. Schmidt, A. Thomas Chemistry - A European Journal 2016, 21, 7179–7183, 10.1002/chem.201600783

156 CH Stabilized at Steps on Ru(0001) by Coadsorbates H. Kirsch, X. Zhao, Z. Ren, S. V. Levchenko, R. K. Campen The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2016, 43, 24724–24733, 10.1021/acs.jpcc.6b07088

155 Ni Substitutional Defects in Bulk and at the (001) Surface of MgO from First-Principles Calculations A. Mazheika, S. V. Levchenko The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2016, 47, 26934–26944, 10.1021/acs.jpcc.6b09505

154 Location of Trapped Electron Centers in the Bulk of Epitaxial MgO(001) Films Grown on Mo(001) Using -band Electron Paramagnetic Resonance Spectroscopy D. Cornu, J. Rocker, A. Gonchar, T. Risse, H. J. Freund Physical Review Letters 2016, 1, 10.1103/PhysRevLett.117.016801

153 Evidence for Exchange Coupled Electrons and Holes in MgO after Oxidative Activation of CH : A Multifrequency Transient Nutation EPR Study P. Schwach, M. Eichelbaum, R. Schlögl, T. Risse, K. P. Dinse The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2016, 7, 3781–3790, 10.1021/acs.jpcc.5b11057

152 Hydration Structures of MgO, CaO, and SrO (001) Surfaces M. Ončák, R. Włodarczyk, J. Sauer The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2016, 43, 24762–24769, 10.1021/acs.jpcc.6b07434

151 Ab Initio Calculation of Rate Constants for Molecule-Surface Reactions with Chemical Accuracy G. Piccini, M. Alessio, J. Sauer Angewandte Chemie International Edition 2016, 17, 5235–5237, 10.1002/anie.201601534

150 Accurate adsorption energies for small molecules on oxide surfaces: CH /MgO(001) and C H /MgO(001) A. D. Boese, J. Sauer Journal of Computational Chemistry Journal of Computational Chemistry 2016, 26, 2374–2385, 10.1002/jcc.24462

149 Ligands with Two Different Binding Sites and O Reactivity of their Copper(I) Complexes S. T. Li, B. Braun-Cula, S. Hoof, M. Dürr, I. Ivanović-Burmazović, C. Limberg European Journal of Inorganic Chemistry 2016, 25, 4017–4027, 10.1002/ejic.201600420

148 Cyclohexane oxidative dehydrogenation over copper oxide catalysts S. L. Nauert, F. Schax, C. Limberg, J. M. Notestein Journal of Catalysis 2016, 180–190, 10.1016/j.jcat.2016.07.002

147 Discovery and Investigation of Natural Editing Function against Artificial Amino Acids in Protein Translation J. S. Völler, M. Dulic, U. I. M. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovulj, B. Koksch ACS Central Science ACS Central Science 2016, 1, 73–80, 10.1021/acscentsci.6b00339

146 Modelling the production of soluble hydrogenase in Ralstonia eutropha by on-line optimal experimental design**This work was supported by the DFG in the framework of the cluster of excellence UniCat. F. Neddermeyer, V. Marhold, C. Menzel, D. Krämer, R. King IFAC-PapersOnLine IFAC-PapersOnLine 2016, 7, 627–632, 10.1016/j.ifacol.2016.07.238

145 Contact Modifications for CFD Simulations of Fixed-Bed Reactors: Cylindrical Particles G. D. Wehinger, C. Fütterer, M. Kraume Industrial & Engineering Chemistry Research Industrial & Engineering Chemistry Research 2016, 1, 87–99, 10.1021/acs.iecr.6b03596

144 Modeling, Simulation, and Economic Evaluation of a Hybrid CO2 Capture Process for Oxidative Coupling of Methane A. Penteado, E. Esche, R. Wilhelm, H. R. Godini, D. Salerno, G. Tolksdorf, V. A. Merchan, G. Wozny Computer Aided Chemical Engineering 2016, 38, 1231–1236, 10.1016/B978-0-444-63428-3.50210-1

143 Solution of Chance-Constrained Mixed-Integer Nonlinear Programming Problems E. Esche, D. Müller, S. Werk, I. E. Grossmann, G. Wozny Computer Aided Chemical Engineering 2016, 38, 91–96, 10.1016/B978-0-444-63428-3.50020-5

142 Techno-Economic Evaluation of an Oxidative Coupling of Methane Process at Industrial Scale Production D. Salerno, H. R. Godini, A. Penteado, E. Esche, G. Wozny Computer Aided Chemical Engineering 2016, 38, 1785–1790, 10.1016/B978-0-444-63428-3.50302-7

141 Tailor-Made Modeling and Solution of Novel Process Units by Modular CAPE-OPEN-based Flowsheeting G. Tolksdorf, E. Esche, J. van Baten, G. Wozny Computer Aided Chemical Engineering 2016, 38, 787–792, 10.1016/B978-0-444-63428-3.50136-3

140 Computer-Aided Process and Plant Development. A Review of Common Software Tools and Methods and Comparison against an Integrated Collaborative Approach V. A. Merchan, E. Esche, S. Fillinger, G. Tolksdorf, G. Wozny Chemie Ingenieur Technik Chemie Ingenieur Technik 2016, 1, 50–69, 10.1002/cite.201500099

139 Design and Assessment of a Membrane and Absorption Based Carbon Dioxide Removal Process for Oxidative Coupling of Methane A. Penteado, E. Esche, D. Salerno, H. R. Godini, G. Wozny Industrial & Engineering Chemistry Research Industrial & Engineering Chemistry Research 2016, 27, 7473–7483, 10.1021/acs.iecr.5b04910

138 Treated Nanolayered Mn Oxide by Oxidizable Compounds: A Strategy To Improve the Catalytic Activity toward Water Oxidation M. Mahdi Najafpour, D. Jafarian Sedigh, S. Maedeh Hosseini, I. Zaharieva Inorganic Chemistry 2016, 17, 8827–8832, 10.1021/acs.inorgchem.6b01334

137 Axial Ligation and Redox Changes at the Cobalt Ion in Cobalamin Bound to Corrinoid Iron-Sulfur Protein (CoFeSP) or in Solution Characterized by XAS and DFT P. Schrapers, S. Mebs, S. Goetzl, S. E. Hennig, H. Dau, H. Dobbek, M. Haumann PLOS ONE PLOS ONE 2016, 7, 10.1371/journal.pone.0158681

136 Electrosynthesis of Biomimetic Manganese-Calcium Oxides for Water Oxidation Catalysis-Atomic Structure and Functionality D. González-Flores, I. Zaharieva, J. Heidkamp, P. Chernev, E. Martínez-Moreno, C. Pasquini, M. R. Mohammadi, K. Klingan, U. Gernet, A. Fischer, H. Dau ChemSusChem 2016, 4, 379–387, 10.1002/cssc.201501399

135 Water oxidation catalysis – role of redox and structural dynamics in biological photosynthesis and inorganic manganese oxides I. Zaharieva, D. González-Flores, B. Asfari, C. Pasquini, M. R. Mohammadi, K. Klingan, I. Zizak, S. Loos, P. Chernev, H. Dau Energy & Environmental Science Energy Environ. Sci. 2016, 7, 2433–2443, 10.1039/C6EE01222A

134 Wiring of the aldehyde oxidoreductase PaoABC to electrode surfaces via entrapment in low potential phenothiazine-modified redox polymers P. Pinyou, A. Ruff, S. Pöller, S. Alsaoub, S. Leimkühler, U. Wollenberger, W. Schuhmann Bioelectrochemistry 2016, 24–30, 10.1016/j.bioelechem.2015.12.005

133 Construction of Giant-Spin Hamiltonians from Many-Spin Hamiltonians by Third-Order Perturbation Theory and Application to an Fe Cr Single-Molecule Magnet S. G. Tabrizi, A. V. Arbuznikov, M. Kaupp Chemistry - A European Journal 2016, 20, 6853–6862, 10.1002/chem.201504896

132 Completing the Heterocubane Family [Cp*AlE] (E = O, S, Se, and Te) by Selective Oxygenation and Sulfuration of [Cp*Al] : Density Functional Theory Calculations of [Cp*AlE] and Reactivity of [Cp*AlO] toward Hydrolysis A. C. Stelzer, P. Hrobárik, T. Braun, M. Kaupp, B. Braun-Cula Inorganic Chemistry 2016, 10, 4915–4923, 10.1021/acs.inorgchem.6b00462

131 Understanding Thermodynamic and Spectroscopic Properties of Tetragonal Mn Single-Molecule Magnets from Combined Density Functional Theory/Spin-Hamiltonian Calculations S. Ghassemi Tabrizi, A. V. Arbuznikov, M. Kaupp The Journal of Physical Chemistry A 2016, 34, 6864–6879, 10.1021/acs.jpca.6b06896

130 Tracking Transient Conformational States of T4 Lysozyme at Room Temperature Combining X-ray Crystallography and Site-Directed Spin Labeling P. Consentius, U. Gohlke, B. Loll, C. Alings, R. Müller, U. Heinemann, M. Kaupp, M. Wahl, T. Risse Journal of the American Chemical Society 2016, 39, 12868–12875, 10.1021/jacs.6b05507

129 Giant spin–orbit effects on H and C NMR shifts for uranium( ) complexes revisited: role of the exchange–correlation response kernel, bonding analyses, and new predictions A. H. Greif, P. Hrobárik, J. Autschbach, M. Kaupp Physical Chemistry Chemical Physics Phys. Chem. Chem. Phys. 2016, 44, 30462–30474, 10.1039/C6CP06129J

128 – -Amide isomerism of the 3,4-dehydroproline residue, the ‘unpuckered’ proline V. Kubyshkin, N. Budisa Beilstein Journal of Organic Chemistry 2016, 589–593, 10.3762/bjoc.12.57

127 Photochemical formation of quinone methides from peptides containing modified tyrosine A. Husak, B. P. Noichl, T. Šumanovac Ramljak, M. Sohora, Đ. Škalamera, N. Budiša, N. Basarić Organic & Biomolecular Chemistry Org. Biomol. Chem. 2016, 46, 10894–10905, 10.1039/C6OB02191C

126 Energetic contribution to both acidity and conformational stability in peptide models V. Kubyshkin, P. Durkin, N. Budisa New Journal of Chemistry New J. Chem. 2016, 6, 5209–5220, 10.1039/C5NJ03611A

125 Incorporation of Amino Acids with Long-Chain Terminal Olefins into Proteins M. Exner, S. Köhling, J. Rivollier, S. Gosling, P. Srivastava, Z. Palyancheva, P. Herdewijn, M. P. Heck, J. Rademann, N. Budisa Molecules Molecules 2016, 3, 287– 10.3390/molecules21030287

124 One-Pot Synthesis of Unprotected Anomeric Glycosyl Thiols in Water for Glycan Ligation Reactions with Highly Functionalized Sugars S. Köhling, M. P. Exner, S. Nojoumi, J. Schiller, N. Budisa, J. Rademann Angewandte Chemie International Edition 2016, 50, 15510–15514, 10.1002/anie.201607228

123 Optogenetic approaches addressing extracellular modulation of neural excitability E. A. Ferenczi, J. Vierock, K. Atsuta-Tsunoda, S. P. Tsunoda, C. Ramakrishnan, C. Gorini, K. Thompson, S. Y. Lee, A. Berndt, C. Perry, S. Minniberger, A. Vogt, J. Mattis, R. Prakash, S. Delp, K. Deisseroth, P. Hegemann Scientific Reports Scientific Reports 2016, 1, 10.1038/srep23947

122 Structural foundations of optogenetics: Determinants of channelrhodopsin ion selectivity A. Berndt, S. Y. Lee, J. Wietek, C. Ramakrishnan, E. E. Steinberg, A. J. Rashid, H. Kim, S. Park, A. Santoro, P. W. Frankland, S. M. Iyer, S. Pak, S. Ährlund-Richter, S. L. Delp, R. C. Malenka, S. A. Josselyn, M. Carlén, P. Hegemann, K. Deisseroth Proceedings of the National Academy of Sciences Proceedings of the National Academy of Sciences 2016, 4, 822–829, 10.1073/pnas.1523341113

121 Unfolding of the C-Terminal Jα Helix in the LOV2 Photoreceptor Domain Observed by Time-Resolved Vibrational Spectroscopy P. E. Konold, T. Mathes, J. Weiβenborn, M. L. Groot, P. Hegemann, J. T. M. Kennis The Journal of Physical Chemistry Letters The Journal of Physical Chemistry Letters 2016, 17, 3472–3476, 10.1021/acs.jpclett.6b01484

120 Photoadduct Formation from the FMN Singlet Excited State in the LOV2 Domain of Phototropin J. Zhu, T. Mathes, Y. Hontani, M. T. A. Alexandre, K. C. Toh, P. Hegemann, J. T. M. Kennis The Journal of Physical Chemistry Letters The Journal of Physical Chemistry Letters 2016, 21, 4380–4384, 10.1021/acs.jpclett.6b02075

119 Graphitic carbon nitride “reloaded”: emerging applications beyond (photo)catalysis J. Liu, H. Wang, M. Antonietti Chemical Society Reviews Chem. Soc. Rev. 2016, 8, 2308–2326, 10.1039/c5cs00767d

118 Activating Pd nanoparticles on sol–gel prepared porous g-C N /SiO via enlarging the Schottky barrier for efficient dehydrogenation of formic acid H. H. Wang, B. Zhang, X. H. Li, M. Antonietti, J. S. Chen Inorganic Chemistry Frontiers Inorg. Chem. Front. 2016, 9, 1124–1129, 10.1039/c6qi00151c

117 Mild Continuous Hydrogenolysis of Kraft Lignin over Titanium Nitride–Nickel Catalyst V. Molinari, G. Clavel, M. Graglia, M. Antonietti, D. Esposito ACS Catalysis 2016, 3, 1663–1670, 10.1021/acscatal.5b01926

116 Merging Single-Atom-Dispersed Silver and Carbon Nitride to a Joint Electronic System Copolymerization with Silver Tricyanomethanide Z. Chen, S. Pronkin, T. P. Fellinger, K. Kailasam, G. Vilé, D. Albani, F. Krumeich, R. Leary, J. Barnard, J. M. Thomas, J. Pérez-Ramírez, M. Antonietti, D. Dontsova ACS Nano 2016, 3, 3166–3175, 10.1021/acsnano.5b04210

115 Local Platinum Environments in a Solid Analogue of the Molecular Periana Catalyst M. Soorholtz, L. C. Jones, D. Samuelis, C. Weidenthaler, R. J. White, M. M. Titirici, D. A. Cullen, T. Zimmermann, M. Antonietti, J. Maier, R. Palkovits, B. F. Chmelka, F. Schüth ACS Catalysis 2016, 4, 2332–2340, 10.1021/acscatal.5b02305

114 Aerosol-Assisted Synthesis of Porous TiN O @C Nanocomposites V. Maurice, G. Clavel, M. Antonietti, C. Giordano Chemistry - A European Journal 2016, 33, 11624–11630, 10.1002/chem.201503768

113 Moving Graphitic Carbon Nitride from Electrocatalysis and Photocatalysis to a Potential Electrode Material for Photoelectric Devices J. Xu, M. Antonietti, M. Shalom Chemistry - An Asian Journal 2016, 18, 2499–2512, 10.1002/asia.201600857

112 Pd Supported on Carbon Nitride Boosts the Direct Hydrogen Peroxide Synthesis R. Arrigo, M. E. Schuster, S. Abate, G. Giorgianni, G. Centi, S. Perathoner, S. Wrabetz, V. Pfeifer, M. Antonietti, R. Schlögl ACS Catalysis 2016, 10, 6959–6966, 10.1021/acscatal.6b01889

111 Disclosing the High Activity of Ceramic Metallics in the Oxygen Evolution Reaction: Nickel Materials as a Case Study M. Ledendecker, X. Yang, M. Antonietti, M. Shalom ChemSusChem 2016, 20, 2928–2932, 10.1002/cssc.201601128

110 New Organic Semiconducting Scaffolds by Supramolecular Preorganization: Dye Intercalation and Dye Oxidation and Reduction L. Li, Y. Zhao, M. Antonietti, M. Shalom Small 2016, 44, 6090–6097, 10.1002/smll.201602445

109 CO synthesized from the central one-carbon pool as source for the iron carbonyl in O -tolerant [NiFe]-hydrogenase I. Bürstel, E. Siebert, S. Frielingsdorf, I. Zebger, B. Friedrich, O. Lenz Proceedings of the National Academy of Sciences Proceedings of the National Academy of Sciences 2016, 51, 14722–14726, 10.1073/pnas.1614656113

108 Impact of Carbon Nanotube Surface Chemistry on Hydrogen Oxidation by Membrane-Bound Oxygen-Tolerant Hydrogenases K. Monsalve, I. Mazurenko, C. Gutierrez-Sanchez, M. Ilbert, P. Infossi, S. Frielingsdorf, M. T. Giudici-Orticoni, O. Lenz, E. Lojou ChemElectroChem ChemElectroChem 2016, 12, 2179–2188, 10.1002/celc.201600460

107 Synchrotron-based Nickel Mössbauer Spectroscopy L. B. Gee, C. Y. Lin, F. E. Jenney, M. W. W. Adams, Y. Yoda, R. Masuda, M. Saito, Y. Kobayashi, K. Tamasaku, M. Lerche, M. Seto, C. G. Riordan, A. Ploskonka, P. P. Power, S. P. Cramer, L. Lauterbach Inorganic Chemistry 2016, 14, 6866–6872, 10.1021/acs.inorgchem.5b03004

106 Towards characterization of photo-excited electron transfer and catalysis in natural and artificial systems using XFELs R. Alonso-Mori, K. Asa, U. Bergmann, A. S. Brewster, R. Chatterjee, J. K. Cooper, H. M. Frei, F. D. Fuller, E. Goggins, S. Gul, H. Fukuzawa, D. Iablonskyi, M. Ibrahim, T. Katayama, T. Kroll, Y. Kumagai, B. A. McClure, J. Messinger, K. Motomura, K. Nagaya, T. Nishiyama, C. Saracini, Y. Sato, N. K. Sauter, D. Sokaras, T. Takanashi, T. Togashi, K. Ueda, W. W. Weare, T. C. Weng, M. Yabashi, V. K. Yachandra, I. D. Young, A. Zouni, J. F. Kern, J. Yano Faraday Discussions Faraday Discuss. 2016, 621–638, 10.1039/c6fd00084c

105 Acoustic Injectors for Drop-On-Demand Serial Femtosecond Crystallography C. G. Roessler, R. Agarwal, M. Allaire, R. Alonso-Mori, B. Andi, J. F. R. Bachega, M. Bommer, A. S. Brewster, M. C. Browne, R. Chatterjee, E. Cho, A. E. Cohen, M. Cowan, S. Datwani, V. L. Davidson, J. Defever, B. Eaton, R. Ellson, Y. Feng, L. P. Ghislain, J. M. Glownia, G. Han, J. Hattne, J. Hellmich, A. Héroux, M. Ibrahim, J. Kern, A. Kuczewski, H. T. Lemke, P. Liu, L. Majlof, W. M. McClintock, S. Myers, S. Nelsen, J. Olechno, A. M. Orville, N. K. Sauter, A. S. Soares, S. M. Soltis, H. Song, R. G. Stearns, R. Tran, Y. Tsai, M. Uervirojnangkoorn, C. M. Wilmot, V. Yachandra, J. Yano, E. T. Yukl, D. Zhu, A. Zouni Structure 2016, 4, 631–640, 10.1016/j.str.2016.02.007

104 Ready to use bioinformatics analysis as a tool to predict immobilisation strategies for protein direct electron transfer (DET) R. Cazelles, N. Lalaoui, T. Hartmann, S. Leimkühler, U. Wollenberger, M. Antonietti, S. Cosnier Biosensors and Bioelectronics 2016, 90–95, 10.1016/j.bios.2016.04.078

103 Nickel electrodes as a cheap and versatile platform for studying structure and function of immobilized redox proteins X. X. Han, J. Li, I. H. Öner, B. Zhao, S. Leimkühler, P. Hildebrandt, I. M. Weidinger Analytica Chimica Acta Analytica Chimica Acta 2016, 35–40, 10.1016/j.aca.2016.08.053

102 Role of Conductive Nanoparticles in the Direct Unmediated Bioelectrocatalysis of Immobilized Sulfite Oxidase T. Zeng, S. Frasca, J. Rumschöttel, J. Koetz, S. Leimkühler, U. Wollenberger Electroanalysis 2016, 10, 2303–2310, 10.1002/elan.201600246

101 The Molybdenum Active Site of Formate Dehydrogenase Is Capable of Catalyzing C–H Bond Cleavage and Oxygen Atom Transfer Reactions T. Hartmann, P. Schrapers, T. Utesch, M. Nimtz, Y. Rippers, H. Dau, M. A. Mroginski, M. Haumann, S. Leimkühler Biochemistry 2016, 16, 2381–2389, 10.1021/acs.biochem.6b00002

100 The -Carbamoyl-Transferase Alb15 Is Responsible for the Modification of Albicidin D. Petras, D. Kerwat, A. Pesic, B. F. Hempel, L. von Eckardstein, S. Semsary, J. Arasté, M. Marguerettaz, M. Royer, S. Cociancich, R. D. Süssmuth ACS Chemical Biology ACS Chemical Biology 2016, 5, 1198–1204, 10.1021/acschembio.5b01001

99 Top-down venomics of the East African green mamba, Dendroaspis angusticeps , and the black mamba, Dendroaspis polylepis , highlight the complexity of their toxin arsenals D. Petras, P. Heiss, R. A. Harrison, R. D. Süssmuth, J. J. Calvete Journal of Proteomics Journal of Proteomics 2016, 148–164, 10.1016/j.jprot.2016.06.018

98 Towards Biocontained Cell Factories: An Evolutionarily Adapted Escherichia coliStrain Produces a New-to-nature Bioactive Lantibiotic ContainingThienopyrrole-Alanine A. Kuthning, P. Durkin, S. Oehm, M. G. Hoesl, N. Budisa, R. D. Süssmuth Scientific Reports Scientific Reports 2016, 1, 10.1038/srep33447

97 Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species T. Corona, L. Ribas, M. Rovira, E. R. Farquhar, X. Ribas, K. Ray, A. Company Angewandte Chemie International Edition 2016, 45, 14005–14008, 10.1002/anie.201607238

96 A cobalt( ) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions S. Kundu, P. Chernev, X. Engelmann, C. S. Chung, H. Dau, E. Bill, J. England, W. Nam, K. Ray Dalton Transactions Dalton Trans. 2016, 37, 14538–14543, 10.1039/c6dt01815g

95 Changing the chemical and physical properties of high valent heterobimetallic bis-(μ-oxido) Cu–Ni complexes by ligand effects M. C. Kafentzi, M. Orio, M. Réglier, S. Yao, U. Kuhlmann, P. Hildebrandt, M. Driess, A. J. Simaan, K. Ray Dalton Transactions Dalton Trans. 2016, 40, 15994–16000, 10.1039/c6dt02391f

94 Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes X. Engelmann, I. Monte-Pérez, K. Ray Angewandte Chemie International Edition 2016, 27, 7632–7649, 10.1002/anie.201600507

93 A Single‐Source Precursor Approach to Self‐Supported Nickel–Manganese‐Based Catalysts with Improved Stability for Effective Low‐Temperature Dry Reforming of Methane P. W. Menezes, A. Indra, P. Littlewood, C. Göbel, R. Schomäcker, M. Driess ChemPlusChem ChemPlusChem 2016, 4, 370–377, 10.1002/cplu.201600064

92 Donor-Acceptor-Type Heptazine-Based Polymer Networks for Photocatalytic Hydrogen Evolution K. Kailasam, M. B. Mesch, L. Möhlmann, M. Baar, S. Blechert, M. Schwarze, M. Schröder, R. Schomäcker, J. Senker, A. Thomas Energy Technology Energy Technology 2016, 6, 744–750, 10.1002/ente.201500478

91 Heterogeneous Catalytic Hydroarylation of Olefins at a Nanoscopic Aluminum Chlorofluoride B. Calvo, J. Wuttke, T. Braun, E. Kemnitz ChemCatChem 2016, 11, 1945–1950, 10.1002/cctc.201600257

90 The Inner Workings of Proton Slippage through the Sodium Pump T. Friedrich Biophysical Journal 2016, 11, 2342–2344, 10.1016/j.bpj.2016.10.026

89 ATP1A2 Mutations in Migraine: Seeing through the Facets of an Ion Pump onto the Neurobiology of Disease T. Friedrich, N. N. Tavraz, C. Junghans Frontiers in Physiology Frontiers in Physiology 2016, 10.3389/fphys.2016.00239

88 The role of local and remote amino acid substitutions for optimizing fluorescence in bacteriophytochromes: A case study on iRFP D. Buhrke, F. Velazquez Escobar, L. Sauthof, S. Wilkening, N. Herder, N. N. Tavraz, M. Willoweit, A. Keidel, T. Utesch, M. A. Mroginski, F. J. Schmitt, P. Hildebrandt, T. Friedrich Scientific Reports Scientific Reports 2016, 1, 10.1038/srep28444

87 Effects of project-based research work on the career paths of young academics M. Norkus, N. Baur, C. Besio Work Organisation, Labour & Globalisation 2016, 10, 1745–6428,

86 Synthesis and OER activity of NiO coatings with micelle-templated mesopore structure M. Bernicke, B. Eckhardt, A. Lippitz, E. Ortel, D. Bernsmeier, R. Schmack, R. Kraehnert ChemistrySelect ChemistrySelect 2016, 3, 482–489, 10.1002/slct.201600110

85 Oxygen Evolution Reaction Dynamics, Faradaic Charge Efficiency, and the Active Metal Redox States of Ni–Fe Oxide Water Splitting Electrocatalysts M. Görlin, P. Chernev, J. Ferreira de Araújo, T. Reier, S. Dresp, B. Paul, R. Krähnert, H. Dau, P. Strasser Journal of the American Chemical Society 2016, 17, 5603–5614, 10.1021/jacs.6b00332

84 Missing Piece of the Mechanism of the Turkevich Method: The Critical Role of Citrate Protonation F. Kettemann, A. Birnbaum, S. Witte, M. Wuithschick, N. Pinna, R. Kraehnert, K. Rademann, J. Polte Chemistry of Materials 2016, 11, 4072–4081, 10.1021/acs.chemmater.6b01796

83 Highly Active Binder-Free Catalytic Coatings for Heterogeneous Catalysis and Electrocatalysis: Pd on Mesoporous Carbon and Its Application in Butadiene Hydrogenation and Hydrogen Evolution D. Bernsmeier, L. Chuenchom, B. Paul, S. Rümmler, B. Smarsly, R. Kraehnert ACS Catalysis 2016, 12, 8255–8263, 10.1021/acscatal.6b02240

82 New Approach on Quantification of Porosity of Thin Films via Electron-Excited X-ray Spectra E. Ortel, A. Hertwig, D. Berger, P. Esposito, A. M. Rossi, R. Kraehnert, V. D. Hodoroaba Analytical Chemistry 2016, 14, 7083–7090, 10.1021/acs.analchem.6b00847

81 B(C F ) -Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes D. Porwal, M. Oestreich European Journal of Organic Chemistry 2016, 20, 3307–3309, 10.1002/ejoc.201600556

80 Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates I. Chatterjee, M. Oestreich Organic Letters 2016, 10, 2463–2466, 10.1021/acs.orglett.6b01016

79 Metal-Free Phosphine Oxide Reductions Catalyzed by B(C F ) and Electrophilic Fluorophosphonium Cations M. Mehta, I. Garcia de la Arada, M. Perez, D. Porwal, M. Oestreich, D. W. Stephan Organometallics 2016, 7, 1030–1035, 10.1021/acs.organomet.6b00158

78 Thermal Activation of Methane by [HfO] and [XHfO] (X=F, Cl, Br, I) and the Origin of a Remarkable Ligand Effect S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 27, 7685–7688, 10.1002/anie.201602312

77 Lanthipeptides: chemical synthesis versus in vivo biosynthesis as tools for pharmaceutical production E. L. Ongey, P. Neubauer Microbial Cell Factories Microbial Cell Factories 2016, 1, 10.1186/s12934-016-0502-y

76 Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane H. Schwarz, P. González-Navarrete, J. Li, M. Schlangen, X. Sun, T. Weiske, S. Zhou Organometallics 2016, 1, 8–17, 10.1021/acs.organomet.6b00372

75 Structural and functional basis of phospholipid oxygenase activity of bacterial lipoxygenase from Pseudomonas aeruginosa S. Banthiya, J. Kalms, E. Galemou Yoga, I. Ivanov, X. Carpena, M. Hamberg, H. Kuhn, P. Scheerer Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids 2016, 11, 1681–1692, 10.1016/j.bbalip.2016.08.002

74 Insights into Basal Signaling Regulation, Oligomerization, and Structural Organization of the Human G-Protein Coupled Receptor 83 A. Müller, J. C. Berkmann, P. Scheerer, H. Biebermann, G. Kleinau PLOS ONE PLOS ONE 2016, 12, 10.1371/journal.pone.0168260

73 Models for heterogeneous catalysts: studies at the atomic level H. J. Freund Rendiconti Lincei Rendiconti Lincei 2016, 5–18, 10.1007/s12210-016-0560-4

72 Nanoscale Patterns on Polar Oxide Surfaces M. Lewandowski, I. M. N. Groot, Z. H. Qin, T. Ossowski, T. Pabisiak, A. Kiejna, A. Pavlovska, S. Shaikhutdinov, H. J. Freund, E. Bauer Chemistry of Materials 2016, 20, 7433–7443, 10.1021/acs.chemmater.6b03040

71 A numerical optimization study on the catalytic dry reforming of methane in a spatially resolved fixed-bed reactor T. Eppinger, G. D. Wehinger, N. Jurtz, R. Aglave, M. Kraume Chemical Engineering Research and Design Chemical Engineering Research and Design 2016, 374–381, 10.1016/j.cherd.2016.09.007

70 Investigating dry reforming of methane with spatial reactor profiles and particle-resolved CFD simulations G. D. Wehinger, M. Kraume, V. Berg, O. Korup, K. Mette, R. Schlögl, M. Behrens, R. Horn AIChE Journal AIChE Journal 2016, 12, 4436–4452, 10.1002/aic.15520

69 Structure of photosystem II and substrate binding at room temperature I. D. Young, M. Ibrahim, R. Chatterjee, S. Gul, F. D. Fuller, S. Koroidov, A. S. Brewster, R. Tran, R. Alonso-Mori, T. Kroll, T. Michels-Clark, H. Laksmono, R. G. Sierra, C. A. Stan, R. Hussein, M. Zhang, L. Douthit, M. Kubin, C. de Lichtenberg, L. Vo Pham, H. Nilsson, M. H. Cheah, D. Shevela, C. Saracini, M. A. Bean, I. Seuffert, D. Sokaras, T. C. Weng, E. Pastor, C. Weninger, T. Fransson, L. Lassalle, P. Bräuer, P. Aller, P. T. Docker, B. Andi, A. M. Orville, J. M. Glownia, S. Nelson, M. Sikorski, D. Zhu, M. S. Hunter, T. J. Lane, A. Aquila, J. E. Koglin, J. Robinson, M. Liang, S. Boutet, A. Y. Lyubimov, M. Uervirojnangkoorn, N. W. Moriarty, D. Liebschner, P. V. Afonine, D. G. Waterman, G. Evans, P. Wernet, H. Dobbek, W. I. Weis, A. T. Brunger, P. H. Zwart, P. D. Adams, A. Zouni, J. Messinger, U. Bergmann, N. K. Sauter, J. Kern, V. K. Yachandra, J. Yano Nature 2016, 7633, 453–457, 10.1038/nature20161

68 Pseudo-Contact NMR Shifts over the Paramagnetic Metalloprotein CoMMP-12 from First Principles L. Benda, J. Mareš, E. Ravera, G. Parigi, C. Luchinat, M. Kaupp, J. Vaara Angewandte Chemie International Edition 2016, 47, 14713–14717, 10.1002/anie.201608829

67 Thermal Dehydrogenation of Methane by [ReN] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 47, 14863–14866, 10.1002/anie.201607960

66 The Origin of the Efficient, Thermal Chemisorption of Methane by the Heteronuclear Metal-Oxide Cluster [Al TaO ] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 47, 14867–14871, 10.1002/anie.201608999

65 Mechanistic aspects of CO2 activation mediated by phenyl yttrium cation: A combined experimental/theoretical study M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Journal of Catalysis 2016, 68–74, 10.1016/j.jcat.2015.09.012

64 A Bis(silylene)-Substituted -Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes Y. P. Zhou, S. Raoufmoghaddam, T. Szilvási, M. Driess Angewandte Chemie International Edition 2016, 41, 12868–12872, 10.1002/anie.201606979

63 Uncovering the prominent role of metal ions in octahedral versus tetrahedral sites of cobalt–zinc oxide catalysts for efficient oxidation of water P. W. Menezes, A. Indra, A. Bergmann, P. Chernev, C. Walter, H. Dau, P. Strasser, M. Driess Journal of Materials Chemistry A J. Mater. Chem. A 2016, 25, 10014–10022, 10.1039/C6TA03644A

62 Thermal Methane Activation by [Si O ] and [Si O H ] : Reactivity Enhancement by Hydrogenation X. Sun, S. Zhou, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 42, 13345–13348, 10.1002/anie.201607864

61 Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC] with Methane under Ambient Conditions J. Li, S. Zhou, M. Schlangen, T. Weiske, H. Schwarz Angewandte Chemie International Edition 2016, 42, 13072–13075, 10.1002/anie.201606707

60 Efficient Room-Temperature Methane Activation by the Closed-Shell, Metal-Free Cluster [OSiOH] : A Novel Mechanistic Variant X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 40, 14257–14263, 10.1002/chem.201601981

59 Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions J. Li, S. Zhou, J. Zhang, M. Schlangen, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 35, 11368–11377, 10.1021/jacs.6b07246

58 Efficient Room-Temperature Activation of Methane by TaN under C−N Coupling S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 38, 11678–11681, 10.1002/anie.201606259

57 The Unique Gas-Phase Chemistry of the [AuO] /CH Couple: Selective Oxygen-Atom Transfer to, Rather than Hydrogen-Atom Abstraction from, Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 36, 10877–10880, 10.1002/anie.201605259

56 Chemical looping as reactor concept for the oxidative coupling of methane over a Na 2 WO 4 /Mn/SiO 2 catalyst V. Fleischer, P. Littlewood, S. Parishan, R. Schomäcker Chemical Engineering Journal 2016, 646–654, 10.1016/j.cej.2016.07.094

55 Investigation of the surface reaction network of the oxidative coupling of methane over Na2WO4/Mn/SiO2 catalyst by temperature programmed and dynamic experiments V. Fleischer, R. Steuer, S. Parishan, R. Schomäcker Journal of Catalysis 2016, 91–103, 10.1016/j.jcat.2016.06.014

54 Silica material variation for the Mn x O y -Na 2 WO 4 /SiO 2 M. Yildiz, Y. Aksu, U. Simon, T. Otremba, K. Kailasam, C. Göbel, F. Girgsdies, O. Görke, F. Rosowski, A. Thomas, R. Schomäcker, S. Arndt Applied Catalysis A: General 2016, 168–179, 10.1016/j.apcata.2016.06.034

53 Oxidative coupling of methane on the Na2WO4-MnxOy catalyst: COK-12 as an inexpensive alternative to SBA-15 M. G. Colmenares, U. Simon, M. Yildiz, S. Arndt, R. Schomaecker, A. Thomas, F. Rosowski, A. Gurlo, O. Goerke Catalysis Communications 2016, 75–78, 10.1016/j.catcom.2016.06.025

52 Vibrational spectroscopy reveals the initial steps of biological hydrogen evolution S. Katz, J. Noth, M. Horch, H. S. Shafaat, T. Happe, P. Hildebrandt, I. Zebger Chemical Science Chem. Sci. 2016, 11, 6746–6752, 10.1039/C6SC01098A

51 On the Activation of Methane and Carbon Dioxide by [HTaO] and [TaOH] in the Gas Phase: A Mechanistic Study M. Firouzbakht, N. J. Rijs, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2016, 30, 10581–10589, 10.1002/chem.201601339

50 Characterization of the [3Fe–4S] cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses L. Lauterbach, L. B. Gee, V. Pelmenschikov, F. E. Jenney, S. Kamali, Y. Yoda, M. W. W. Adams, S. P. Cramer Dalton Transactions Dalton Trans. 2016, 17, 7215–7219, 10.1039/C5DT04760A

49 Supports and modified nano-particles for designing model catalysts C. P. O'Brien, K. H. Dostert, M. Hollerer, C. Stiehler, F. Calaza, S. Schauermann, S. Shaikhutdinov, M. Sterrer, H. J. Freund Faraday Discussions Faraday Discuss. 2016, 309–321, 10.1039/c5fd00143a

48 Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO ] (X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer J. Li, S. Zhou, J. Zhang, M. Schlangen, T. Weiske, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 25, 7973–7981, 10.1021/jacs.6b03798

47 Leader Peptide-Free In Vitro Reconstitution of Microviridin Biosynthesis Enables Design of Synthetic Protease-Targeted Libraries E. Reyna-González, B. Schmid, D. Petras, R. D. Süssmuth, E. Dittmann Angewandte Chemie International Edition 2016, 32, 9398–9401, 10.1002/anie.201604345

46 Spin-Selective Thermal Activation of Methane by Closed-Shell [TaO ] S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 25, 7257–7260, 10.1002/anie.201601965

45 Modelling the production of soluble hydrogenase in Ralstonia eutropha by on-line optimal experimental design F. Neddermeyer, V. Marhold, C. Menzel, D. Krämer, R. King IFAC Symposium on Dynamics and Control of Process Systems including Biosystems Proceedings 2016, 11, 627–632,

44 Apparatus for low temperature thermal desorption spectroscopy of portable samples S. Stuckenholz, C. Büchner, H. Ronneburg, G. Thielsch, M. Heyde, H. J. Freund Review of Scientific Instruments 2016, 4, 45103– 10.1063/1.4945265

43 Differences and Commonalities in the Gas-Phase Reactions of Closed-Shell Metal Dioxide Clusters [MO ] (M=V, Nb, and Ta) with Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 21, 7225–7228, 10.1002/chem.201600498

42 Palladium-mediated borylation of pentafluorosulfanyl functionalized compounds: the crucial role of metal fluorido complexes C. Berg, T. Braun, R. Laubenstein, B. Braun Chemical Communications Chem. Commun. 2016, 20, 3931–3934, 10.1039/C5CC10219G

41 Is it all in the hinge? A kryptoracemate and three of its alternative racemic polymorphs of an aminonitrile R. Laubenstein, M. D. Şerb, U. Englert, G. Raabe, T. Braun, B. Braun Chemical Communications Chem. Commun. 2016, 6, 1214–1217, 10.1039/C5CC08992A

40 Polarization- and Wavelength-Dependent Surface-Enhanced Raman Spectroscopy Using Optically Anisotropic Rippled Substrates for Sensing D. Gkogkou, B. Schreiber, T. Shaykhutdinov, H. K. Ly, U. Kuhlmann, U. Gernert, S. Facsko, P. Hildebrandt, N. Esser, K. Hinrichs, I. M. Weidinger, T. W. H. Oates ACS Sensors ACS Sensors 2016, 3, 318–323, 10.1021/acssensors.5b00176

39 Biochemical Dissection of the Natural Diversification of Microcystin Provides Lessons for Synthetic Biology of NRPS S. Meyer, J. C. Kehr, A. Mainz, D. Dehm, D. Petras, R. D. Süssmuth, E. Dittmann Cell Chemical Biology Cell Chemical Biology 2016, 4, 462–471, 10.1016/j.chembiol.2016.03.011

38 Krypton Derivatization of an O -Tolerant Membrane-Bound [NiFe] Hydrogenase Reveals a Hydrophobic Tunnel Network for Gas Transport J. Kalms, A. Schmidt, S. Frielingsdorf, P. van der Linden, D. von Stetten, O. Lenz, P. Carpentier, P. Scheerer Angewandte Chemie International Edition 2016, 18, 5586–5590, 10.1002/anie.201508976

37 Structures of ribosome-bound initiation factor 2 reveal the mechanism of subunit association T. Sprink, D. J. F. Ramrath, H. Yamamoto, K. Yamamoto, J. Loerke, J. Ismer, P. W. Hildebrand, P. Scheerer, J. Bürger, T. Mielke, C. M. T. Spahn Science Advances Science Advances 2016, 3, 10.1126/sciadv.1501502

36 Interaction of Water with the CaO(001) Surface Y. Fujimori, X. Zhao, X. Shao, S. V. Levchenko, N. Nilius, M. Sterrer, H. J. Freund The Journal of Physical Chemistry C The Journal of Physical Chemistry C 2016, 10, 5565–5576, 10.1021/acs.jpcc.6b00433

35 Enantioselective Nanoporous Carbon Based on Chiral Ionic Liquids I. Fuchs, N. Fechler, M. Antonietti, Y. Mastai Angewandte Chemie International Edition 2016, 1, 408–412, 10.1002/anie.201505922

34 1,2,4-Triazole-Based Approach to Noble-Metal-Free Visible-Light Driven Water Splitting over Carbon Nitrides D. Dontsova, C. Fettkenhauer, V. Papaefthimiou, J. Schmidt, M. Antonietti Chemistry of Materials 2016, 3, 772–778, 10.1021/acs.chemmater.5b03722

33 Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content N. Fechler, N. P. Zussblatt, R. Rothe, R. Schlögl, M. G. Willinger, B. F. Chmelka, M. Antonietti Advanced Materials 2016, 6, 1287–1294, 10.1002/adma.201501503

32 When the inhibitor tells more than the substrate: the cyanide-bound state of a carbon monoxide dehydrogenase A. Ciaccafava, D. Tombolelli, L. Domnik, J. Fesseler, J. H. Jeoung, H. Dobbek, M. A. Mroginski, I. Zebger, P. Hildebrandt Chemical Science Chem. Sci. 2016, 5, 3162–3171, 10.1039/C5SC04554A

31 A Fluorometric Activity Assay for Light-Regulated Cyclic-Nucleotide-Monophosphate Actuators C. H. Schumacher, H. G. Körschen, C. Nicol, C. Gasser, R. Seifert, M. Schwärzel, A. Möglich Methods in Molecular Biology 2016, 1408, 93–105, 10.1007/978-1-4939-3512-3_7

30 Library-Aided Probing of Linker Determinants in Hybrid Photoreceptors R. Ohlendorf, C. H. Schumacher, F. Richter, A. Möglich ACS Synthetic Biology ACS Synthetic Biology 2016, 10, 1117–1126, 10.1021/acssynbio.6b00028

29 Hydrothermal synthesis of bi-functional nanostructured manganese tungstate catalysts for selective oxidation X. Li, T. Lunkenbein, J. Kröhnert, V. Pfeifer, F. Girgsdies, F. Rosowski, R. Schlögl, A. Trunschke Faraday Discussions Faraday Discuss. 2016, 99–113, 10.1039/C5FD00191A

28 Enhancing of catalytic properties of vanadia via surface doping with phosphorus using atomic layer deposition V. E. Strempel, D. Löffler, J. Kröhnert, K. Skorupska, B. Johnson, R. N. d'Alnoncourt, M. Driess, F. Rosowski Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 2016, 1, 1– 10.1116/1.4936390

27 Selective Alkane Oxidation by Manganese Oxide: Site Isolation of MnO Chains at the Surface of MnWO Nanorods X. Li, T. Lunkenbein, V. Pfeifer, M. Jastak, P. K. Nielsen, F. Girgsdies, A. Knop-Gericke, F. Rosowski, R. Schlögl, A. Trunschke Angewandte Chemie International Edition 2016, 12, 4092–4096, 10.1002/anie.201510201

26 Effect of the catalyst pore structure on fixed-bed reactor performance of partial oxidation of n-butane: A simulation study Y. Dong, F. J. Keil, O. Korup, F. Rosowski, R. Horn Chemical Engineering Science 2016, 299–309, 10.1016/j.ces.2015.12.004

25 Bond Activation by Metal–Carbene Complexes in the Gas Phase S. Zhou, J. Li, M. Schlangen, H. Schwarz Accounts of Chemical Research 2016, 3, 494–502, 10.1021/acs.accounts.5b00023

24 Mechanistic Aspects of the Holmium-Mediated, Reciprocal Hydrogen/Sulfur Exchange in the Gas Phase: C H CH +CH S→C H CHS+CH S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 13, 4336–4339, 10.1002/chem.201600061

23 An iron( ) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity H. Gehring, R. Metzinger, B. Braun, C. Herwig, S. Harder, K. Ray, C. Limberg Dalton Transactions Dalton Trans. 2016, 7, 2989–2996, 10.1039/C5DT04266F

22 On the Origin of Room-temperature, Au -mediated Coupling of a Methylene Ligand with H . Implications for the Mechanism of Methane Dehydrogenation. J. Li , S. Zhou, M. Schlangen, T. Weiske, H. Schwarz ChemistrySelect ChemistrySelect 2016, 3, 444–447, 10.1002/slct.201600073

21 Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO] Complexes with Fluoromethanes (CH F , = 1–3) N. J. Rijs, P. González-Navarrete, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2016, 9, 3125–3135, 10.1021/jacs.5b12972

20 Bacterial molybdoenzymes: old enzymes for new purposes S. Leimkühler, C. Iobbi-Nivol FEMS Microbiology Reviews FEMS Microbiology Reviews 2016, 1, 1–18, 10.1093/femsre/fuv043

19 Sustainable Process Design for Oxidative Coupling of Methane (OCM): Comprehensive Reactor Engineering via Computational Fluid Dynamics (CFD) Analysis of OCM Packed-Bed Membrane Reactors M. S. Salehi, M. Askarishahi, H. R. Godini, O. Görke, G. Wozny Industrial & Engineering Chemistry Research 2016, 12, 3287–3299, 10.1021/acs.iecr.5b03292

18 CFD Simulation of Oxidative Coupling of Methane in Fluidized-Bed Reactors: A Detailed Analysis of Flow-Reaction Characteristics and Operating Conditions M. S. Salehi, M. Askarishahi, H. R. Godini, R. Schomäcker, G. Wozny Industrial & Engineering Chemistry Research Industrial & Engineering Chemistry Research 2016, 5, 1149–1163, 10.1021/acs.iecr.5b02433

17 Tet-on, or Tet-off, that is the question: Advanced conditional gene expression in Aspergillus F. Wanka, T. Cairns, S. Boecker, C. Berens, A. Happel, X. Zheng, J. Sun, S. Krappmann, V. Meyer Fungal Genetics and Biology Fungal Genetics and Biology 2016, 72–83, 10.1016/j.fgb.2015.11.003

16 Rational biosynthetic approaches for the production of new-to-nature compounds in fungi S. Boecker, S. Zobel, V. Meyer, R. D. Süssmuth Fungal Genetics and Biology Fungal Genetics and Biology 2016, 89–101, 10.1016/j.fgb.2016.02.003

15 Molecularly Imprinted Electropolymer for a Hexameric Heme Protein with Direct Electron Transfer and Peroxide Electrocatalysis L. Peng, A. Yarman, K. Jetzschmann, J. H. Jeoung, D. Schad, H. Dobbek, U. Wollenberger, F. Scheller Sensors Sensors 2016, 3, 272– 10.3390/s16030272

14 Electrosynthesized molecularly imprinted polymers for protein recognition J. Erdőssy, V. Horváth, A. Yarman, F. W. Scheller, R. E. Gyurcsányi TrAC Trends in Analytical Chemistry TrAC Trends in Analytical Chemistry 2016, 179–190, 10.1016/j.trac.2015.12.018

13 Reprogramming the Biosynthesis of Cyclodepsipeptide Synthetases to Obtain New Enniatins and Beauvericins S. Zobel, S. Boecker, D. Kulke, D. Heimbach, V. Meyer, R. D. Süssmuth ChemBioChem 2016, 4, 283–287, 10.1002/cbic.201500649

12 ZnO Coatings with Controlled Pore Size, Crystallinity and Electrical Conductivity R. SCHMACK, B. ECKHARDT, G. KOCH, E. ORTEL, R. KRAEHNERT Materials Science Materials Science 2016, 1, 10.5755/j01.ms.22.1.8634

11 Quercetin 2,4-Dioxygenase Activates Dioxygen in a Side-On O -Ni Complex J. H. Jeoung, D. Nianios, S. Fetzner, H. Dobbek Angewandte Chemie International Edition 2016, 10, 3281–3284, 10.1002/anie.201510741

10 Reactivation from the Ni–B state in [NiFe] hydrogenase of Ralstonia eutropha is controlled by reduction of the superoxidised proximal cluster V. Radu, S. Frielingsdorf, O. Lenz, L. J. C. Jeuken Chemical Communications Chem. Commun. 2016, 12, 2632–2635, 10.1039/C5CC10382G

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